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Page 1 of 98 TABLE OF CONTENTS PAGE GENERAL KILN SECTION 1 Description of Main Kiln System 04 2 Kiln Operation Priorities 05 3 Kiln System Stability 06 4 Main Parameters, Trends and Absolute Values 08 5 Main Parameters to Control and Evaluate Kiln 13 6 Variables which the Operator Cannot Control 15 7 Variables which the Operator Can Control 15 8 Kiln Limitation Factor 16 9 Kiln Operation Target 17 10 Optimization of Kiln System 18 11 List of Most Frequent Factors when Kiln Operation Is not Satisfactory 19 12 List of Typical Kiln Operation Problems 20 13 What to Look for When Looking Inside a Kiln 21 14 Kiln Upsets 27 15 Kiln Cycling 28 16 How to Break a Cycle in a Kiln 29 KILN EMERGENCY CONDITIONS SECTION 17 Red Spot on Kiln Shell 30 18 Raw Unburned Feed in Clinker Cooler 31 19 Large Ring Broken Loose in Kiln 32 20 Burning Zone Dangerously Hot 33 21 Sudden Sharp Raise in Back End Temperature (B.E.T.) 34 22 Black Smoke Emission from Kiln Stack 35 23 Distorted Flame Shape 36 Page 2 of 98 24 Loss of Section of Refractory Lining 37 25 Cooler Drive or Clinker Conveyor Stopped 37 26 Red Clinker at Cooler Discharge 38 27 Rapid Rise of Temperature in Coal System 39 28 Power Failure 40 29 A Chain Fire 42 30 Heavy Rain or Thunder Storm 43 31 Sudden High Positive Pressure 43 32 Overheated Kiln Bearing 44 33 Kiln Hazardous Conditions 44 KILN OPERATION SECTION 34 Kiln Operation Techniques 47 35 Burning Zone Evaluation 48 36 Kiln Stable Temperature Profile 49 37 Target Set Point and Operation References 50 38 Back End Temperature Control 51 39 The Three Basic Variables 51 40 Target Range for the Three Variables 51 41 The Three Basic Conditions 52 42 The 27 Conditions (Kurt Peray) 53 43 Kiln Slow Down 56 44 Normal Operation Procedures on Shift 59 45 Plan of Action 59 46 Oxygen Level in Automatic Mode 60 KILN START-UP AND SHUTDOWN PROCEDURES 47 Light-up Flame Example (Gas) 61 48 Preheat or Drying of Refractory Lining 62 49 Heating to Reach Temperature Ready to put Feed On. 63 50 Feed On 64 Page 3 of 98

51 Kiln Start-up Procedures after a Brick Job 64 52 Example of How to Re-start if Preheat is Required 68 53 Example of How to Re-start if No Preheat is Required 69 54 Kiln Shutdown General Information 70 55 Cooling Procedures 70 56 Kiln Rotation Schedule 71 57 Burner Pipe and Hood Protection 72 58 Emptying the Feed from the Kiln 73 59 Kiln Shutdown Procedures for Brick Job and Red Spot 73 COOLER SECTION 60 Cooler Function 76 61 Cooler Operation 77 62 Cooler Controllers 77 63 Rule on Cooler Operation 78 64 Main Sensors to Control the Cooler Operation 79 65 Particle Size of Clinker 80 66 Operation of Cooler Fans 80 67 Clinker and Air Distribution 81 COMBUSTION SECTION 68 Flame 82 69 Rules on Flame 85 70 Combustion 86 71 Heat Transfer in Rotary Kiln 89 72 Burner Pipes and Nozzles 89 73 Fuels in Cement Industry 92 74 Solid Fuels 94 75 Drying, Grinding and Firing Solid Fuels 96 76 Comparison of the Three Major Fuels 97 77 Combustion Reaction 97 Page 4 of 98 78 Non-Combustibles (Ash) 98 BASIC PRINCIPLES SECTION 79 Basic Principles, System of Units 98 80 Temperature Scale n/a 81 Some Useful Conversion Factors n/a 82 Basic Principles, Pressure and Flows n/a 83 Basic Principles, Heat and Temperature n/a 84 Basic Principles, Heat Exchange or Transfer n/a GENERAL KILN SECTION DESCRIPTION OF MAIN KILN SYSTEMS Wet Process Better homogeneity of raw feed Dust produced is approximately 15 to 20% of clinker production Dust return to kiln by means of Vortex at feed location (mixing problem) Scoop near kiln discharge Dust insulation in burning zone Back end temperature is the main parameter to control and react on behavior of s lurry through chain system. (ring formation in chain, spillage near feed end) High heat consumption (near 1300 kilocalories or 4676 MBtu/st), therefore there is a lower secondary air temperature. All other parameters are the same as a dry process kiln. Long Dry Feed is dry dust. Page 5 of 98 Long residence time (up to 2 hours), so we have to take this into account when s tabilizing the kiln. Heat consumption is approximately 920 kilocalories (3309 MBtu/st). Natural load movement often unstable and creates “pushes”. Pre-calciner and Pre-heater

51 Kiln Start-up Procedures after a Brick Job 64 52 Example of How to Re-start if Preheat is Required 68 53 Example of How to Re-start if No Preheat is Required 69 54 Kiln Shutdown General Information 70 55 Cooling Procedures 70 56 Kiln Rotation Schedule 71 57 Burner Pipe and Hood Protection 72 58 Emptying the Feed from the Kiln 73 59 Kiln Shutdown Procedures for Brick Job and Red Spot 73 COOLER SECTION 60 Cooler Function 76 61 Cooler Operation 77 62 Cooler Controllers 77 63 Rule on Cooler Operation 78 64 Main Sensors to Control the Cooler Operation 79 65 Particle Size of Clinker 80 66 Operation of Cooler Fans 80 67 Clinker and Air Distribution 81 COMBUSTION SECTION 68 Flame 82 69 Rules on Flame 85 70 Combustion 86 71 Heat Transfer in Rotary Kiln 89 72 Burner Pipes and Nozzles 89 73 Fuels in Cement Industry 92 74 Solid Fuels 94 75 Drying, Grinding and Firing Solid Fuels 96 76 Comparison of the Three Major Fuels 97 77 Combustion Reaction 97 Page 4 of 98 78 Non-Combustibles (Ash) 98 BASIC PRINCIPLES SECTION 79 Basic Principles, System of Units 98 80 Temperature Scale n/a 81 Some Useful Conversion Factors n/a 82 Basic Principles, Pressure and Flows n/a 83 Basic Principles, Heat and Temperature n/a 84 Basic Principles, Heat Exchange or Transfer n/a GENERAL KILN SECTION DESCRIPTION OF MAIN KILN SYSTEMS Wet Process Better homogeneity of raw feed Dust produced is approximately 15 to 20% of clinker production Dust return to kiln by means of Vortex at feed location (mixing problem) Scoop near kiln discharge Dust insulation in burning zone Back end temperature is the main parameter to control and react on behavior of s lurry through chain system. (ring formation in chain, spillage near feed end) High heat consumption (near 1300 kilocalories or 4676 MBtu/st), therefore there is a lower secondary air temperature. All other parameters are the same as a dry process kiln. Long Dry Feed is dry dust. Page 5 of 98 Long residence time (up to 2 hours), so we have to take this into account when s tabilizing the kiln. Heat consumption is approximately 920 kilocalories (3309 MBtu/st). Natural load movement often unstable and creates “pushes”. Pre-calciner and Pre-heater

Residence time in tower is from 2 to 5 seconds. Residence time in kiln is approximately 30 minutes. Fast reaction time, requires fast action to control the kiln. About 50 to 90% calcinations is done in tower. More stable than long dry, because calcinations is taking place in tower. Heat consumption nears 800 kilocalories (2878 MBtu/st). Very high secondary air temperature especially with pre-calciner need tertiary a ir duct. Fuel ratio split: kiln = +/- 40%, pre-calciner = +/- 60% KILN OPERATION PRIORITIES 1. Protection of the personnel working in and around the kiln system is a basic safety rule that must be strictly followed at all times. 2. Protection of the equipment. Around the kiln, the safety of the equipment is mainly related to overheating pr oblems and could be: a) Back-end of kiln Do not exceed 840oF (450oC) at precipitator inlet b) Feed Do not exceed 10 minutes without feed as the feed end temperature would go high. c) Chain inlet temperature Do not exceed metallurgical maximum temperature of chain system. (usually approx imately 1900oF or 1038oC) Page 6 of 98 d) Burning zone Do not over-heat; keep the raw load near end of flame. Set a maximum amps level on kiln motor. e) Cooler Avoid overloaded cooler grates, cut kiln speed down to protect the cooler grates . Avoid high exhaust gas temperature; could damage dust filter system. Avoid high clinker temperature; could damage the clinker evacuation circuit. 3. Quality. To produce a well-burned clinker with good free-lime at the desired liter-weight 4. Stability. Continuous operation should always have priority over maximum production. Stable kiln operation is the key to long refractory life, high fuel efficiency a nd uniform quality clinker. 5. Optimization. Strive for optimum production level at the lowest possible cost. KILN SYSTEM STABILITY 1. Stable Feed a) Chemical Feed quality range should be: +/- 0.4% in CaO +/- 0.4% in SiO2 +/- 0.2% in Al2O3 C3S variations in clinker not to exceed +/- 3% Page 7 of 98 Approximately 25% relative potential liquid phase in the clinker is good for kil n burning and fuel saving. b) Physical Good and accurate feed rate indication. Weigh-feeder should be linear at low, medium and high feed rate. Good calibration by physical weight of the material should be done at every majo r kiln shutdown. Good feed and speed ratio. 2. Stable Dust Re-introduction to Kiln Dust collector cleaning cycle sequencing. Dust circuit configuration should provide stable re-introduction. Monitoring of the dust return flow is an added advantage.

If dust wasting is required, wasting should be done in such a way not to upset t he dust return to the kiln. 3. Stable Water Spray Injection in Kiln or in Conditioning Tower Good spray injects into gas stream, not in material load. Good regulation of water injection with respect to ESP inlet temperature control . (will cause changes in kiln oxygen level if water flow is not changing smoothl y). 4. Good Chain System Design (Wet and Long Dry) Act as a good dust curtain (dust trap). Wet kiln design needs to favor a good “plastic zone” in order to prevent ring format ion. Chain tonnage should be between 12 to 14% of clinker production for large kiln a nd 10 to 12% for small kiln. Good chains should stand high temperature so that in return enable high producti on rates. 5. Good Control of Hood Pressure Page 8 of 98 Hood pressure control is critical because it prevents the cooler variations to u pset the burning zone conditions. Hood pressure set point should be set as close as possible to zero, while remain ing negative. 6. Stable Secondary Air Temperature The temperature variations during normal operation should not exceed +/- 85oF (2 9oC) Good regulation of the cooler under-grate pressure is then required with a thick clinker bed depth. The secondary air temperature should be as hot as possible, without damaging the nose ring or the refractory at the kiln discharge section. 7. Good Production Level Lower limit: Under-60% capacity kiln tends to become unstable Upper limit: Production restriction due to: Kiln diameter; (maximum flame size, flame erosion on kiln walls). ID fan capacity; (no leeway on oxygen level) Precipitator capacity (cooler grates overloaded and high clinker temperature at cooler outlet) 8. Constant Fuel Quality and Quantity Constant fuel quality and quantity to allow constant heat input inside the kiln. MAIN PARAMETERS, TRENDS AND ABSOLUTE VALUES Back End Temperature Set point varies with the kiln production level. Set point varies with the condition of the chain system. Page 9 of 98 Absolute value allows one to draw conclusions about efficiency of the kiln syste m and the kiln operation. BET trend is important for the kiln operation. With the use of water spray in the back end, the water volume will show the reac tions of the back end temperature. Material Temperature Slow reaction compared to gas temperature. In wet process kiln, material temperature is a good indication of the behavior o f the material in the chain system. Chain Gas Temperature This temperature is generally a limiting parameter for the kiln operation. The chain gas temperature set point is generally fixed by the metallurgy of the chain system and its design. Absolute value is very important and must be held below the allowed “T” for the chai n system. The trend is representative but has slow reactions with respect to the back end temperature.

Very important to the kiln operation in order to make a good material preparatio n before it reached the burning zone. Burning Zone Temperature Importance of this instrument is often overestimated. Precise only when kiln conditions are clear. The secondary air dust influence in the indication of the instrument and reading s are in error when kiln gets hot and dusty. It must be correlated with the kiln amps indication and the secondary air temper ature to ensure the validity of the reading. Shell Temperature (Scanner) Importance of this instrument is underestimated. Page 10 of 98 It is often used only to detect hot spots on the kiln shell, an estimation of br ick thickness, and coating in the kiln. On bigger charts, it gives a good indication of the burning zone temperature pro file. It is one of the fastest indications of a slowly moving ignition point in burnin g zone. It is a very good indication of flame variations due to the burner pipe position , flame shape and direction. (Good indication when adjusting flame in kiln). Absolute value is important to detect hot spots and rings. Trend indicates changes in the burner system, kiln speed, ignition point movemen t and operating conditions which are affecting the temperature profile of the bu rning zone. Kiln Drive Amps It is the most important sensor used to evaluate the burning zone state. The running set point will change according to the raw material composition. Amperage value changes with ring formation. Amperage value changes with the size of the clinker. The absolute value is important only when amperage is high (fuse protection limi tations). The trend is a very good indication of burning zone length and temperature; ther efore the amps should be recorded in such a way to give a good indication in its variations. A drastic increase of the amps trend, followed by a fast decrease is an indicati on of loss of coating or a broken ring inside the kiln. A target amps range should be established (depending on raw mix and other factor s) through which this variable can fluctuate safely. A drastic increase in amps could indicate a possible mechanical condition proble m. NOx Analyzer Essentially it is an indication of the flame temperature. Higher is the flame te mperature, the higher will be the NOx concentration. NOx content in the flue gases in the smoke stack originate partly from high temp erature synthesis in flame from oxygen and nitrogen. NOx level has been measured in the range between 500 and 2000 ppm in the Lafarge group. NOx increase with excess air and is strongly correlated to low excess air levels . Page 11 of 98 At higher levels, i.e. 3% and greater, NOx is weakly dependent on excess air. Correlation between burning zone temperature and NOx level is good. NOx is generally, but not systematically correlated with the kiln drive amps. NO x gives a truer picture of burning conditions. Kiln drive amps will change due t o ring formation and degradation, whereas NOx signal will not. NOx correlates better with clinker liter weight than free lime. NOx is affected by fuel changes. Natural gas flames yield the highest NOx level. All the factors having an impact on the flame temperature will affect the NOx si gnal like the following: The secondary air temperature,

The primary air temperature, The burning zone temperature, Chemical composition and fineness of the fuel, The air and fuel ratio and The flame environment (reduced or oxidized atmosphere). A quick decrease in the NOx signal is an indication of the burning zone temperat ure dropping. A slow and even decrease on the NOx signal is an indication of a slow cooling of the burning zone and is related to a bad material preparation from the kiln bac k end. On the automatic kiln control system developed by Lafarge, the program is giving 30% of it as evaluation of the burning zone state to the NOx signal, 55% to the kiln amps, and 15% to the clinker temperature at the kiln outlet. Secondary Air Temperature It should be kept as stable as possible by the automatic cooler control system ( +/- 85oF or 39oC). Absolute value is not important because most indications are incorrect due to in strument inaccuracy. Trend is very important as it shows variations of material from the kiln and the gas temperature variations to the kiln. The secondary air temperature should be as high as possible in respect of the va rious refractory temperatures in front of the kiln. Page 12 of 98 Hood Draft Absolute value is important and is automatically controlled at a constant value (usually looped to cooler exhaust fan damper / fan). It should be low as possible (to reduce in-leakage). It is the separation between cooler and kiln and it should be always constant to avoid influences of changes in the cooler gas flow to the kiln operation. A poor regulation of this signal will induce variations in the kiln gas flow and could bring the kiln into cycling. Feed End Draft and ID Fan Draft Trend and absolute value help to detect build-up in the kiln. This is a very important sensor if many ring problems occur in a plant. Cooler Exhaust Gas Temperature Trend will give you information about the temperature profile in cooler gas flow variations and clinker temperature. Absolute value is an important limitation for protection of the dust collection system. The cooler exhaust temperature is a more reliable clinker discharge indication t han the clinker temperature. Clinker Discharge Temperature Trend has no importance for cooler operation. Absolute value is an important limitation for safety of the clinker transport sy stem. Clinker temperature measurements are generally not very accurate. Under Grate Pressure The absolute value should be maintained constant with automatic control. The value varies with the cooler bed depth and with clinker size. It must be hel d constant in order to achieve a constant secondary air temperature. Also, only a constant air flow can allow the relationship between under grate pressure, bed depth and secondary air temperature to be valid. Page 13 of 98 Variations of the under grate pressures trend are reflected by variations in the cooler grate speed. Under grate pressures together with cooler drive amps, should give an indication of the clinker size. Under grate pressure set point should be at least 5 inches (H2O) in order to get good heat recuperation from the clinker bed in the cooler. Oxygen Analyzer

Trend and set point value are very important. It should be maintained as constant as possible. It can supply indications about general kiln conditions, burning zone and back e nd temperature. One of the best indications when the kiln is pushing to indicate if the push is still on or over (related with the amount of CaO in the kiln gases). It should be kept as low as possible when the kiln is stable, without going into CO range. However, when using coal or coke, set point should be increased to overcome the fuel quality variations. MAIN PARAMETERS USED TO CONTROL AND EVALUATE KILN Kiln Amps It is a very good indication of the burning zone state, accurate at 80% of the t ime. NOx Analyzer Nitrogen Oxide level is related to the flame temperature than the burning zone t emperature. NOx vary all the factors that has an effect on the flame. It is a very good indication of the burning zone state. Fuel Flow Page 14 of 98 It should be related to the kiln feed rate. It should be used as the main controller for the burning zone and the kiln back end temperature. Kiln Speed It should be related to feed rate. It should be set with a constant feed ratio. Small variations of the kiln speed (1 to 3 revs) could be used to control the bu rning zone state. However, kiln speed variations should be used only after the fuel flow rate has been used as the primary controller on long wet and dry kiln. Often if over used, speed variations in the material loading of the kiln and wil l lead the kiln into a cycle. On large temperature variations in burning zone like raw material pushes, the ki ln speed must be used with wide variations (as example 30 revs or even a complet e stop) to avoid raw materials to go in the cooler and to re-heat the burning zo ne. Fan Draft It should be related to the oxygen level, fuel flow rate and feed rate. It is the main controller to keep the temperature profile along the kiln. The rpm variations should be small during kiln normal operation +/- 15 rph. During kiln pushes and kiln slow speed, large speed variations will be required to maintain the chain gas temperature under safe limit of the chain system. Back End Temperature It should be kept at constant level according to feed rate. It should be kept stable in auto by the water spray system. Good indication of the feed end “T”. Indicate variations in the feed and dust variations to the kiln. When in auto, use water flow variations for indication. Gas Temperature It is the main variable to control the kiln. Page 15 of 98 It should be kept inside a certain “T” range. It is controlled by the ID fan speed variations and the fuel rate. Oxygen level It is related to the ID fan speed and fuel rate. Minimum and maximum level limits need to be established, to control combustion e fficiency. When kiln stability has been reached the O2 level should be set in auto with the ID fan speed to lock the temperature profile of the kiln.

Hood Pressure Control of excess air by cooler exhaust fan Open during kiln pushes Need to be kept stable to avoid variations in cooler to upset the burning zone Secondary Air Temperature Temperature of combustion carried back to kiln from the cooler Large variations during kiln pushes Should be controlled in a very small range in auto during normal kiln operation with a good regulation of the clinker cooler (+/- 85oF or 39oC) Cooler Exhaust Temperature Varies with clinker input to cooler Will indicate variations during a push Under Grate Pressure Related to cooler grate speed Set point controlled by the under grate pressure of second compartment to keep a constant clinker bed depth in order to get stable and high secondary air temper ature VARIABLES WHICH THE OPERATOR CANNOT CONTROL Page 16 of 98 Quality and characteristics of the raw materials Quality of the fuel used as a example: heat value, ash content, volatile matter and moisture level Dust quality and quantity returned to the kiln Accuracy of the feeders Chain system design Accuracy and good response of all control loops and sensors of the kiln system For these variables that he cannot control, the operator should be kept informed of any changes done and should make sure that those variables are kept inside a n acceptable range to maintain a good kiln stabilization. VARIABLES WHICH THE OPERATOR CAN CONTROL Material feed to the kiln Fuel feed to the kiln Speed rotation of the kiln Temperature profile along the kiln Draft at the feed end of the kiln Supply of combustion air Retention time of the material in the kiln Temperature of the combustion air Flame shape Observation of instruments, and correct reaction to their readings Observation of the kiln burning zone, and correct reaction to this evaluation However, some restrictions are sometimes given on the utilization of those varia bles and may vary from plant to plant due to local conditions and are usually th e following: Set point on the maximum speed of the kiln Set point on the maximum feed rate to the kiln Automatic loop set point for oxygen level and ID fan speed Page 17 of 98 Settings on the burner pipe and its position Primary air settings and fuel tip velocity Set point on cooler fans flow Set point for the under grate pressure and the clinker bed depth in the cooler KILN LIMITATION FACTORS Dust Emission at Precipitator Stack (Local emission regulations) Gas Chain Temperature Maximum value depend on chain quality and position Diameter of Kiln Gas velocity in kiln (70 ft/sec in free section of kiln and 30 ft/sec in chain s ection maximum) Heat load in front of kiln, flame erosion on kiln walls

ID Fan Capacity Maximum fan speed and low oxygen level Cooler Capacity No red clinker should be present after third compartment of cooler in normal ope ration Clinker discharge temperature not to exceed 170oF (80oC) Cooler exit gas should be about 370oF (190oC) Bed depth to allow good under grate pressure (15”) with sufficient fan capacity KILN OPERATION TARGET Highest clinker production with Good quality clinker Page 18 of 98 Stable kiln operation Oxygen level as low as possible Gas and fuel oil – 1.0 to 1.5% Coal and coke around – 2.0% (depending on the variations in fuel mixture) Kiln exit temperature as low as possible Flame as short as possible (with respect of the burning zone refractory) Keep burning zone short in front of the kiln Secondary air temperature as high as possible but stable Temperature not above liquid phase temperature in front of kiln to protect refra ctory and coating Run with an under grate pressure as high as possible Compatible with the cooler fans static pressure capacity Primary air as low as possible As combustion air to replace by hot air from cooler as much as possible Clinker Temperature Not to exceed 230oF (110oC) as it could promote quality problems (false set) dur ing the grinding process Gravel bed filter Normal operation temperature is 350oF (180oC) Maximum temperature for normal operation is 660oF (350oC) For 2 hours, up to 750oF (400oC) For 20 minutes, up to 840oF (450oC) OPTIMAZATION OF THE KILN SYSTEM Page 19 of 98 Operate the kiln: With higher free lime Reduce air leakages: Around and near the nose ring area and seal Air in-leakage on kiln hood Around blast pipe port holes and doors Hood pressure set point as close as possible to zero Primary air should be kept as low as possible Reduce length of pre-cooling zone by: Adjusting the burner position Proper material load (kiln speed/feed ratio) Increase clinker bed depth in cooler (near 15 inches) Oxygen to be maintained at minimum level Good flame shape and temperature Good chemical composition Good burnability factors Constant raw mix TYPICAL KILN PROBLEMS List of most frequent factors at work when kiln operation is unsatisfactory 1) High leakage, pre-heater only into feed end seal (more than 5%) Page 20 of 98 2) Faulty suspension results in high pre-heater outlet temperatures, thus reduce s capacity (bleed air) 3) Poor operating practices (burning techniques)

4) Reducing conditions in kiln 5) Reducing conditions in burning zone due to flame impingement with load 6) Lack of momentum at burner tip leads to long, lazy flame 7) High primary air, (30%+) due to direct firing of coal, (critical in dry proce ss kiln) 8) High level of volatile elements in raw feed particularly chlorine 9) Systematically hot burning 10) Inadequate chain system 11) Poor cooler heat recovery due to cooler fan design 12) Poor cooler heat recovery due to excessive air flows, insufficient pressure in under grate compartments 13) Chemically variable raw mix C3S, more than 10 points over a shift 14) Variable slurry moisture (more than 3 points) 15) Variable addition of hi-alkali or hi-volatile dust from precipitator (over a period of more than one-half hour) 16) Erratic feed rate 17) Erratic fuel rate (wet coal) 18) High leakage into hood seal (more than 10% of combustion air) 19) Inadequate or obsolete design of equipment or facilities 20) High leakage into pre-heater and down-comer duct 21) Flame erosion on lining could create premature brick failure 22) Kiln misalignment, excessive tire clearances and other factors of shell defl ection 23) Bricking techniques lead to rings not tight enough 24) Low slurry moisture 25) High slurry moisture List of Typical Kiln Operating Problems Page 21 of 98 1) Heat consumption higher than normal Long dry: Higher than 3.4 MBtu/ton Long wet: Higher than 5.2 MBtu/ton Four stage Pre-heater: Higher than 3.1 MBtu/ton 2) Output lower than nominal and / or standard 3) Kiln is unstable and requires frequent massive shutdowns 4) Kiln is cycling spontaneously without any action of operator 5) Kiln is out of draft with output below nominal 6) Stack stinks – SO2 emissions are high 7) Mud ring in chain section on wet kiln 8) Back-spills on wet kiln 9) Burning zone rings 10) Discharge end rings 11) Snowmen in cooler 12) Frequent burning zone burnouts (brick life is less than 3 months) 13) High dust return (above 20% of clinker) causes handling problems 14) Cyclones plug-ups (four stage pre-heater) 15) Build-ups in pre-heater feed box (four stage pre-heater) 16) Cooler exhaust system seems undersized/under-designed - Hood frequently under pressure (during pushes) - Exhaust temperature is higher than normal - Bleed in damper is open very often - Frequent bag burnouts in cooler bag house 17) Red grates in the cooler all the time. Frequent grates burnouts 18) Red rivers on side of cooler 19) Under pushes, cooler speed up to maximum, yet some fans stop blowing any air (pressure overload) 20) Kiln drive seems undersized, kicks out upon start-up after a short shutdown WHAT TO LOOK FOR WHEN LOOKING INSIDE A KILN Page 22 of 98 Viewing the kiln interior This may sound somewhat elementary, but we should never forget that we are looki

ng into an extremely luminous source. Although filtering glasses are used, the l ight source is so strong that focusing the eyes into it for too long a time coul d cause partial blindness. One should look no longer than one minute at a time i nto the fire. If longer viewing is required, look a side for few seconds occasio nally to rest the eyes. Looking steadily too long at the flame results in the ey e losing its ability to see details, hence the need for a short rest every minut e or so. The question of what type of colored filter glass to use must be left to the ope rators. Burning with a natural gas flame usually makes necessary a darker colore d than oil fire would require, because of the greater luminosity of the flame. A s a rule, one should always use a glass that enables him to see under and behind the flame. Once a certain glass has been chosen, the operators should stay with this glass at all times in order to properly judge the burning zone conditions. How frequently should one look into the burning zone? There is no set answer to this question. Experienced operators sometimes become over-confident and think that it would be perfectly safe to leave the kiln alone for periods in excess of 30 minutes. This action however, is against good burning practice. The secret o f every good operator is his ability to recognize a change in kiln condition at the time a change takes place and not later. For this reason, a good operator wi ll never leave a kiln too long a time unchecked. When things are going smoothly, the kiln should be checked every half hour, with more frequent checks if adjust ments are being made. There is no such thing as operating a kiln by the instrume nt alone, as the instruments do not show, for example heavier and lighter loads entering the burning zone until it is almost too late to make the necessary adju stment. The kiln condition can be estimated from the color observed in the hottest part of the flame. Dark red cherry red orange-yellow white Cold - - normal hot Any deviations from the orange-yellow range should be investigated to determine the cause and when adjustments need to be made to the kiln operation to get back to normal kiln condition. Page 23 of 98 Appearance of burning zone Good or bad visibility Bright white or dark red color Good appearance is an orange-yellow color The gas stream should be calm without great turbulence Appearance of coating Coating should begin approximately ½ diameter of kiln size from the nose ring Color of coating tells a great deal about the condition in burning zone as coati ng acts as heat storage in burning zone Overall thickness of coating should be between 9 and 12 inches and is dependent of the type of raw mix Check for ring formation near lower or upper section of the kiln If the surface of the coating appears smooth, then the burning zone in this area is hot If the coating appears “lumpy” then the burning zone is okay A bare spot without coating could be due to flame erosion, thick brick or high f lame temperature in this location Appearance of the coating falling off from the top of the kiln shell: Large pieces: normal Fine noodles dripping: too hot The location where the coating pieces are falling from the top of the kiln wall, above the end of the flame is generally where the raw load is. So whenever the raw load cannot be seen in the bottom and behind the flame of the kiln, try to l ook at the top. Appearance of material load Page 24 of 98 Is clinker balling or fine?

Is material sticky? Is material heavy or light? Is material movement fast or slow? Is material climbing low or high in the wall? (material should climb up +/- to t he 10 o’clock position in normal operation) Appearance of material before falling in the cooler, fine or nodular Upper burning zone section Are rings building up or not? Is coating formation seem normal? Try to evaluate the length of the coating (50 to 100 feet from burning zone to f ar up) Raw feed location Look behind the flame at the bottom of the kiln Normal position is approximately ¼ diameter distance under the flame Never allow raw feed to come ½ way under the flame as kiln speed will have to be r educed to control it (kiln low speed) An advancing or receding dark feed is the earliest indication of a burning zone that is warming up or cooling down. So that is why it is important for the kiln operation to be able to see this load. Every effort should be done during normal operation to keep this load in sight. Flame appearance Should always be evaluated during stable kiln condition Long (100 ft) or short (30 ft) Hard or lazy Bushy or narrow Page 25 of 98 Bright or dark White or orange yellow Eroding the coating or the brick wall Aiming high, low or in the center Eroding the material load If fuel is burning in suspension or in the material load Position of the ignition point when coal or coke is used The flame temperature should be as hot as possible as long as it does not create problems with the coating and the kiln refractory. Whenever a change is made on the flame shape, a close monitoring of the shell temperature should be done. Coal flames Coal normally burns with longer flame than oil A coal flame normally starts at 3 to 5 feet from the burner tip Coal fineness to be about 85% passing 200 mesh Keep the coal system air flow at about 70 ft/sec to avoid coal deposit inside pi pe, while keeping primary air to minimum (direct system and burner design) On direct firing system, coal fan damper setting should be set at minimum value and the fuel rate changes made only by making changes with the coal feeder syste m in order to keep the flame shape short and as constant as possible. Burner pipe appearance Is the tip of the blast pipe in good condition? Is the burner cast-able in good condition? Is the burner pipe aimed correctly? How is the pipe location relative to the nose ring? Are snowmen building up on top of burner pipe? Whenever a bad condition deflecting the flame is observe, a quick evaluation sho uld be done to evaluate if the kiln can continue its operation or if it needs to be shut down to fix the burner pipe. Page 26 of 98 Nose ring appearance  Check the condition of the cast-able or the refractory on the top of the nose ri ng if okay  Check the temperature aspect and the wear of the nose ring castings  Check if the nose ring seal is in good condition

Secondary air Calm or upset Dusty if the clinker is fine Clear if clinker is balling Foggy and white if temperature is hot The secondary air temperature has a major influence on the flame and its shape. Primary air Should be as low as possible to obtain satisfactory heat recuperation from coole r Has an important influence on the shape of the flame (bushy or narrow) Pressur e should be as constant as possible When good settings of the flame have been found, the primary air settings should not be changed in normal operation unless a high temperature condition in the k iln refractory has raised and required to change the flame. When the kiln is down Look for ball or ring formation at upper section of burning zone Evaluate length of coating if okay, too long means we burned the kiln too far up Load level ins ide kiln if even and normal Page 27 of 98 Appearance on load during kiln jacking (sticky or normal) Look at the sealing efficiency of the kiln back end (no suction or gases movemen t inside of kiln should be observed). When kiln is shutdown, the gases should be bottled inside of the kiln as fast as possible by closing the kiln back end damper or its equivalent and by adjusting the hood pressure set point, slightly positive. The procedure need to be done to avoid heat loss from the kiln to insure a slow cooling of the refractory and avoid thermal shocks on the bricks. KILN UPSETS Burning zone too hot Too much liquid is formed and all temperatures are above the solid state tempera ture therefore no coating is formed. Coating will be lost and this could damage the refractory. A) Appearance the kiln could be white and hazy in front end and the clinker will be balling. B) Appearance of the kiln could appear cold if burning is too far. The clinker c ould be fine (very long burning zone). A) Hot burning zone with high secondary air temperature The front of kiln is very hot and white, often hazy The secondary air temperatur e is high The clinker is balling and getting bigger Often the dark load is visib le behind the flame These conditions occurs when the burning zone length is moving down and concentr ating the heat on a shorter burning zone length in front of kiln. This situation can be overcome quite easily by reducing the fuel rate and the ID fan slowly step by step until the burning zone gets back to its normal conditio n. B) Hot burning zone with dusty secondary air Page 28 of 98 Can be caused by burning too far back into the kiln Flame too long and ignite to o far Pre-cooling zone is too long in front of the kiln Long burning zone promot es very fine clinker formation which is sent back as dust into the kiln with the secondary air gas stream Whenever dusty conditions prevail in front, corrective measures should be based on the clinkering conditions behind the flame rather than on the color of the fr ont of the kiln. Aspect of the clinker falling in cooler is very important at that time to evalua te the kiln condition. Kiln amps, fuel flow rate, shell temperature and back-end temperature are usuall y above the normal operation settings during these conditions. Get free lime done from clinker coming out of the kiln to see if OK If operator is in doubt about the kiln being cold or hot, the kiln rotation coul d be stopped (out of the interlock for a few seconds) to allow condition of the burning zone to clear and to view inside the kiln If doubt still persists, the kiln should be assumed to be hot and it should be c

ooled down by reducing the fuel and the ID fan speed until the burning zone get back normal or end up to be completely cold. Except for very hot and emergency conditions, such as cooling should take as lon g as a full shift to be done, to avoid high heat concentration in front and quic k losses of coating from the upper section of the burning zone which could upset the burning zone temperature. KILN CYCLING This is an unstable condition when the load in the kiln decreases, causing the t emperature of the burning zone to rise and forcing the operator to reduce the fu el rate. Then, the burning zone starts to cool off in turn forcing the operator to increase the fuel rate. In severe cases, the temperature continue Page 29 of 98 to drop, even though the fuel rate is at maximum and it become necessary to redu ce the kiln speed to slow down the entry of the feed into the burning zone. Once a kiln gets into an upset such as this, the cycle will repeat. Kiln cycling could be related to the following reasons; Variations in kiln feed: physical or chemical, Variations in dust re-introduction to kiln, Variations in the water spray control system in kiln inlet (if any), Materials hold up in the chain system (for wet process kilns), Poor chain system design (for wet process kilns), Variations in hood pressure control Poor cooler settings and control wh ich promote secondary air temperature variations, Operating the kiln above its p roduction capacity, Variations in the quality and the quantity of the fuel suppl y to the kiln, Bad operating practices, especially over reacting with the kiln s peed and Volatile recirculation inside the kiln system especially chlorine So all the above reasons should be investigated in order to find the cause of th e cycling problem and corrected. HOW TO BREAK A CYCLE IN A KILN Reduce feed/speed ratio by approximately 10% in order to change the material loa d in the kiln (also mainly to change the material load in the chain system). Increase the fuel flow rate by 5% above the normal setting of the current produc tion level. Keep the oxygen level above 2% and try to control the back end temperature varia tions as much as possible by using fuel rate and ID fan variations. Page 30 of 98 Let the kiln amps vary and do not attempt to chase them by varying the kiln spee d. Just try to control them if they get above or below the critical range by var ying the fuel flow rate. If the kiln speed need to be varied than it should be done with very small varia tions, in order to avoid upsetting the material in the kiln. If the kiln speed needs to be increased to go back to normal production level, t hen it should be carried out more slowly than normal. As you get to normal production level, fuel settings should be held above normal before returning to normal operation settings. KILN EMERGENCY CONDITIONS SECTION RED SPOT ON KILN SHELL Indicators: By visual observations Shell scanner sharp and rapid shell temperatu re increase to level above 850oF (450oC) Visual observations of loose refractory bricks in the material load of the kiln or in the clinker at the cooler dischar ge Possible Effects and Danger Severe warping and damage to kiln shell Shell temper ature between 900 and 1100oF (480 and 590oC), deep red color on shell Shell temp erature over 1200oF (650oC), very bright red and shell bulges and warps Recommended Actions to Take A) For small red spot located in the upper transition or center of burning zone Continue normal operation of kiln but: Page 31 of 98 Place shell cooling fans in the area of red spot Shorten flame to bring black fe ed over area of red spot in attempt to form new coating Keep watching the shell temperature trend Maintain normal burning zone temperature Change kiln feed chem istry to obtain an easier burning mix

B) For large red spot located under or near a kiln tire or in areas were no coat ing is formed SHUT DOWN KILN IMMEDIATELY Warning: Under no circumstances should a water spray be used on the red spot, as this could result in severe kiln shell damage. Possible Measures to Prevent Re-occurrence Make sure flame configuration and cha racteristics are not causing localized coating erosion or continuous and excessi ve overheating Employ proper refractory installation methods Minimize frequency of kiln shutdowns and upsets Minimize frequency of clinker type changes over Avo id “hard” burning mixes (i.e. ensure sufficient percentage of liquid content in mix to promote coating formation) RAW, UNBURNED FEED IN CLINKER COOLER Indicators: On rush of raw feed into and beyond burning zone “Black feed” position a dvanced more than ½ way under the flame “Black-out” in burning zone Red grates in cool er Rapid rise in cooler grate and clinker discharge temperatures Cooler drag-cha in amperage increases rapidly Possible Effects and Danger Page 32 of 98 Thermal damage to cooler grates and grate drive mechanism Fire on clinker convey or belts Excessive high temperatures in coal mill air circuit Warning: Watch for incomplete combustion when visibility in burning zone is seve rely restricted. Actions to Take First and foremost, do not wait until raw feed is in the cooler; act when the fi rst signs of impending problems are visible in the burning zone. Immediately red uce kiln speed to minimum (or turn on auxiliary drive) Reduce fuel and ID fan sp eed in accordance with standard slowdown procedures to protect the kiln back end temperature Reduce cooler grate drive speed (switch to manual control) to allow material in cooler more time for cooling Adjust cooler air flow rates to obtain maximum cooling without the hood pressure going positive Advise all unauthorize d personnel to stay clear of the firing floor, cooler and coal mill area Preventive Measures to Avoid Re-occurrence Accelerate frequency of visual observ ations of burning zone for early detection of impending cooler upsets Evaluate k iln output rates vs. capabilities and kiln operating stability LARGE RING BROKEN LOOSE IN KILN Indicators Visual observations of large junks in burning zone Sudden drop in kil n back end draft Large drop in oxygen content of kiln exit gases Hood pressure t ending towards positive side Sudden change in kiln drive amperage Page 33 of 98 Possible Effects and Dangers Overloading cooler with unburned feed On rush of ex cessive amounts of feed into the burning zone Damage to cooler drives and grates Large pieces jamming cooler hammer crusher Red hot clinker leaving cooler Actions to Take When amount of feed and ring fragments in burning zone are extre mely large: Immediately reduce kiln speed to minimum Reduce fuel and ID fan spee d to keep back end temperature under control Switch cooler grate control to manu al and reduce grate speed Adjust cooler air flows to maximum flow possible, with out the hood pressure going positive Have personnel on standby to watch the cool er and the hammer crusher for possible overloading, overheating and jamming Possible Preventive Measures to Avoid Re-occurrence Laboratory to reevaluate che mistry of kiln feed (including dust return rates) for possible elimination of ri ng formation if no solution in this area possible, then Initiate regular schedul e to remove rings and heavy build-up by means of special devices design for this purpose Initiate regular procedures to displace the burning zone location on a daily basis BURNING ZONE DANGEROUSLY HOT Indicators Clinker balling in burning zone Material load sausage-like Coating dr ipping off the wall Sliding molten clinker bed in burning zone Burning zone reco rding temperature too high Page 34 of 98 Cooler under grate pressure too high Material load turning to liquid in burning

zone Very brilliant and white burning zone Possible Effects and Dangers Loss of coating and thermal damage to refractory Re d spot in the kiln shell Thermal damage to cooler and kiln hood components Possible Actions Reduce fuel flow rate to minimum until sausaging stops Increase kiln speed approximately 10 rph until sausage is broken Provide maximum air in cooler (without hood pressure going positive) The kiln rotation to be adapted is the aspect of the material near to fall into the cooler. No liquid material in the cooler, stop kiln rotation if needed. Reduced primary air flow, then as soon as the objective of breaking the agglomeration is accomplished, Reduced the kil n and ID fan speed then increase fuel flow rate to normal operating conditions Preventive Measures If “sausaging” is frequent and result of easy-burning mix, have laboratory evaluate possibility of providing a mix with less percentage of liqui d content Make more frequent, vigilant observation of the burning zone condition s Evaluate flame position and shape to determine if thinner, longer flame is pos sible SUDDEN, SHARP RAISE IN BACK-END TEMPERATURE Possible Reasons Feed shortage Combustion in exit gas Page 35 of 98 ID fan speed too high Kiln speed too low Chain fire Possible Effects and Dangers Chain fire on wet and dry kilns Thermal damage to b ack end, dust collector and pre-heater tower equipment Delayed ignition of fuel in back end of kiln Possible Actions Immediately de-energize electrostatic precipitator Immediately reduce fuel flow rate and ID fan speed to obtain less than 0.3% oxygen in exit g as Warning: Do not cut off fuel flow rate completely as this could trigger an explo sion. Increase kiln speed and feed rate Warn personnel to stay clear of kiln bac k-end Do not open any doors in kiln back-end Then as soon as the primary objective of bringing the kiln back-end temperature under control is accomplished: Return kiln control variables to normal to restor e operating conditions Check out back-end to determine if thermal damage had occ urred Preventive Measures Do not operate kiln without feed for more than 10 minutes Pr ovide alarms and properly maintain kiln instrumentation to obtain warnings befor e the back-end temperature gets out of maximum range Maintain close vigilance ov er combustion, back-end and flow conditions during kiln starts, shutdowns and up sets BLACK SMOKE EMMISION FROM KILN STACK Page 36 of 98 Indicators Combustibles in exit gases Oxygen in exit gas too low Flame extinguis hed for poor ignition conditions Burning zone temperature too low Excessive fuel rates and/or insufficient kiln draft Possible Actions Immediately de-energize electrostatic precipitator Immediately reduce fuel flow rate (do not shut off) Increase ID fan speed to obtain: a) Zero combustible in exit gas b) Oxygen between 0.2 and a maximum of 0.5% in exit gas After black smoke has cl eared, maintain the low oxygen/zero combustibles for at least 10 minutes before restoring kiln variables to normal Preventive Measures Improve control over flame and firing conditions Make freque nt, vigilant observation of fuel flow rates, gas analysis, flame and kiln draft conditions during kiln starts and upsets DISTORTED FLAME SHAPE Indicators Irregular and unusual flame shape Fragmented flame where part of flam e impinges on lining near kiln discharge area Possible Effects and Dangers Inspect burner pipe for damage or plugged circuit I f flame is erratic and severely impinges upon lining near the kiln discharge are a: Shutdown kiln immediately! Page 37 of 98 If flame is only slightly distorted; adjust burner position and primary air flow

Check shell temperature on kiln scanner Schedule a burner pipe repairs for next kiln shutdown Preventive Measures Frequent visual inspection when looking inside the kiln Regu lar inspection and maintenance of burner pipe during each prolonged kiln shutdow n Improve protection (castables, air cooling) for burner pipe Maintain primary a ir flow for at least 2 hours after a kiln has been shutdown or pull back the bur ner pipe immediately when kiln is being shutdown LOSS OF SECTION OF REFRACTORY LINING Indicators Loose bricks in clinker bed of burning zone Delineated (linear instea d of round) red spot on kiln shell Rapid rise in kiln shell temperature Possible Effects and Dangers Thermal damage and distortion of kiln shell and tir e Further collapse of large sections of linings (especially in alumina brick sec tions) Possible Actions Immediately shutdown the kiln Preventive Measures Employ proper refractory installation methods and procedures Make annual checks of kiln alignment and shell ovality Have refractory manufact urer provide uniform shapes and proper expansion allowance for each type of bric k Page 38 of 98 Avoid excessive turning when kiln is cold during shutdowns COOLER DRIVES OR CLINKER BELT STOPPED Indicators Cooler overloaded Large chunks of coating in cooler High under grate pressure High cooler drive amps prior to drive stop Clinker transfer chutes plug ged Possible Effects and Dangers Thermal damage to cooler components Possible Actions Immediately reduce kiln speed to minimum and attempt to restart clinker belt and/or cooler drive If drives cannot be restarted within 5 minutes , shutdown the kiln Note: After kiln has been shutdown, consider possibility of turning the kiln in less frequent intervals to prevent further overloading of cooler. (Kiln still ha d to be rotated periodically nevertheless) Preventive Measures Know at what amperage the cooler drive is likely to fail and provide alarm for overload Adjust kiln parameters (namely kiln speed) before co oler can become overloaded at the times when heavier feed load is observed in th e burning zone RED CLINKER AT COOLER DISCHARGE Indicators Page 39 of 98 High drag chain amps Sudden drop in under grate pressure (grate out) Excessively high under grate pressure (cooler overloaded) Cooler drive amps and clinker bed depth too high Cooler loaded with coating and ring fragments Snowman formation at cooler inlet Possible Effects and Dangers Thermal damage to cooler components Thermal damage to clinker transport equipment Possible Actions Immediately make a visual check of the cooler to determine reas on for red-clinker discharge If cooler grate out, shutdown kiln If cooler overloaded, reduce kiln speed to minimum and reduce cooler grate drive speed to allow more time for cooling Increase air flow into cooler Activate wat er spray at cooler discharge and reroute clinker to prevent damage to conveyor b elts Preventive Measures a) On frequent grate failures Investigate for possible faulty grate installation methods by maintenance department Investigate quality of grates and bolts used b) On frequent one-sided loading of cooler bed Investigate possible cooler desig n changes Investigate possibilities for elimination of stalagmite (snowmen) form ation at cooler inlet c) On frequent overloading of cooler due to upsets Slow down kiln speed before r aw feed enters cooler or cooler can become overloaded (make your corrective move s before things get out of control)

Page 40 of 98 RAPID RAISE OF TEMPERATURE IN COAL SYSTEM Possible Effects and Dangers Explosion Thermal damage to coal system Possible Actions Warning: Do not open any door in the system that could provide the oxygen for an explosion or a more serious fire. Inject inert gas (CO2) into coal mill inlet F lood coal mill with kiln feed or excessive coal Warn all personnel to stay clear of system Stop or reduce air flow to coal mill to minimum Preventive Measures for Re-occurrence Provide coal mill inlet with magnetic devi ce to extract metal fragments from coal feeder belt Keep paper, rags, etc. out o f coal storage pile Do not feed coal mill with coal that has undergone spontaneo us ignition (smothering) while in storage Keep coal mill de-tramp chute clear Pr ovide coal mill system with automatic fire-extinguishing devices Do not operate coal mill above predetermined safe temperature for any given type of coal POWER FAILURE Possible Effects and Dangers Warping of kiln shell Thermal damage to burner pipe , instrumentation and equipment at kiln discharge area Page 41 of 98 On coal-fired kilns, settlement of ground coal in coal system that could lead to a fire and/or explosion Possible Actions Immediately start auxiliary power generator and primary air fan (coal mill fan on direct fired kilns) Retract burner pipe and protect TV monito r in kiln hood Start ¼ turn on kiln not later than 10 minutes after the power fail ure If available, close feed-end damper manually to prevent hot gases from escap ing from kiln by natural draft Power Failure Main Procedures Start generator or auxiliary drive If it is rainin g, carry out ¼ turn as described previously Close kiln back-end, ID fan damper, or precipitator inlet damper if power failure is of long duration Keep primary air fan running to cool down the burner pipe (and pre-calciner burners) or pull the burners out of the kiln Try to restore power as soon as possible The following should be connected on the auxiliary power system: Emergency light in control room Emergency light in kiln platform Telephone system for outside c alls Radio system inside the plant ID fan louvers and precipitator inlet damper Kiln auxiliary drive Primary air fan Recirculation pump for the industrial water system (water cooling system) Page 42 of 98 Instructions should be given to all members of the shift for specific responsibi lities during a power failure as example: Operator A: Carry out safety procedures on kiln system Start the auxiliary power system Close kiln back end (if on auxiliary system) Rotate the kiln If it is ra ining continuously, rotate kiln as soon as possible Protection of burner pipe (p ull out of kiln Call the power company Operator B: Get to main power breaker and try to reset it Go to kiln back-end an d close ID fan louvers (if they are not connected on the auxiliary drive) If the auxiliary drive control is not remote, make kiln rotation in local A CHAIN FIRE Indicators Rapid, sudden rise in intermediate and exit gas temperatures By visua l observation Possible Effects and Dangers Melt-down and loss of chains Damage to kiln shell i n chain system area On wet process kilns; steam explosion Thermal damage to kiln back-end equipment Possible Actions Warning: Under no circumstances should water be added at the feed end. Page 43 of 98 Immediately reduce fuel rate to minimum (but don’t shut fuel off completely) At th e same time, reduce ID fan speed to obtain zero combustibles and less than 0.3% oxygen Increase kiln speed and feed rate to maximum until the back end temperatu re is under control On wet process kilns, clear all personnel from firing floor Preventive Measures Avoid operating the kiln for more than 10 minutes when there is feed shortage Establish and enforce maximum permissible operating limits for

intermediate and/or exit gas temperatures HEAVY RAIN OR THUNDERSTORMS Possible Effects and Dangers On kilns that are exposed to elements; Loss of coat ing and collapse of refractory lining Thermal damage and warping of kiln shell P ossibility of power failure Possible Actions If storm occurs shortly after a kiln shutdown; Jack (turn) kiln more frequently or continuously on auxiliary drive Start auxiliary power generator in preparatio n for a possible power failure SUDDEN, HIGH POSITIVE HOOD PRESSURE Possible Reasons ID fan failure Large ring or build-up broken loose inside kiln Instrumentation failure of cooler air flow, cooler stack damper, or ID fan contr ol Page 44 of 98 Steam explosion on wet-process kilns Possible Effects and Dangers All personnel on firing floor is in danger Thermal damage to equipment on firing floor and hood Danger of backfire in coal system Possible Actions Immediately clear all personnel from firing floor Immediately r educe fuel rate to minimum and increase ID fan speed Reduce cooler air flow rate s into under grate compartments Open cooler excess air damper manually OVERHEATED KILN BEARINGS (Procedure needs to be approved by your Maintenance Department) Slow down kiln speed near minimum 20 rph. Do not stop the kiln (bearing will sei ze) Open reset door on top of bearing and pour in sulfur until noise stops You can add also “powdered graphite” to the bearing lubricating oil The sulfur must be poured on the shaft and not on the bearing casing Keep a bag of sulfur near the control room location Call the Maintenance Supervisor Check if the oil heating is on or not, and stop it if it is in operation (breake r location must be known to all) Check if the water or glycol circulation is okay. If there is no circulation, op en the water valve very slowly If you cannot reach the Maintenance Supervisor, call for an Oiler and a Maintena nce man Install a water hose to get cold water in the bearing (not a close circuit loop) Drain the oil and add new oil until the new oil has reached its normal temperatu re (below 120oF/50oC you should have a temperature gauge showing the oil tempera ture on each bearing) Temperature sometimes requires from 6 to 12 hours to reach 120oF/50oC Page 45 of 98 Type of oil to use for the bearings to be confirmed by your maintenance departme nt KILN HAZARDOUS CONDITIONS Shooting Rings with Gun Do not allow any employees other than the gun crew on th e firing hood during ring shooting Do not tamper with the ammunition Keep all li ve ammunition locked up and away from the firing floor when not in use Permit on ly experienced and trained persons to operate the kiln gun Use ear muffs when fi ring gun Cotton stuffed in the ear is not adequate Clean gun at frequent interva ls and do not attempt to fire an apparent defective gun If kiln has no chain sec tion, keep all persons away from the kiln back end and rope this area off before shooting Clinker, Fuel Oil and Coal Dust Spills Clean up spills immediately Provide adequ ate clean-up cans and facilities for easy removal of spills Initiate repair acti on when spills are caused by leaks that can be repaired Gas, Fuel Oil, Coal and Steam Leaks in Fuel System Report any gas odor on the fi ring floor immediately to the shift supervisor Provide for periodic inspection o f fuel and steam lines and system to detect leaks and other defects as a prevent ive measure against major breaks in the system Burner Hood, Porthole and Cooler Doors Do not allow anyone to look into the burn

ing zone while the kiln is on operation unless approved safety equipment for vie wing is used Use proper protective clothing when working near open burner hood a nd cooler doors while the kiln is in operation Page 46 of 98 Instruct all persons to stay clear of the portholes whenever the hood pressure i s temporarily on the positive side Relining the Kiln with Refractory Bricks and Materials Use protective screen whe n working under loose refractory and coating, if no alternate procedure is possi ble Any employee working inside the kiln should have positive means, such as loc king out the kiln drive with his own lock, to assure that the kiln cannot be sta rted while he is inside Have proper posture and steady footing when lifting bric ks or scaling coating Do not work underneath the burner hood bridge while materi al is being hauled in and out of the kiln Do not test run cooler fans when workm en are inside the kiln Do not run ID fan when workmen are at kiln rear or in cha in section Working Near or on Dust Collecting Equipment Wear extra protective clothing to g uard against burns from hot dust Wash skin thoroughly with clear water after con tact with alkaline dust Have a second workman as safety man standing by whenever working under or in bins or hoppers containing material Do not allow workmen to work inside hopper without being properly secured on safety lines and belts Whe n working on plugged flue hangers, be constantly on guard against potential dust flushes and cave in of overhanging materials Backfire and explosion During Kiln Light-up Open either one cooler or burner hoo d door before lighting fire in kiln Secure proper draft in kiln before fire is l ighted (very important) Do not allow unauthorized person to stand near the burne r hood during light-up Stay clear of burner hood ports when igniting the fuel Av oid excessive fuel flow on initial light-up of flame Start the primary air fan b efore opening the fuel valve Page 47 of 98 When firing coal, make sure that no coal dust spills are present on firing floor , around coal feeder, or in the primary air pipe Setting any Kiln Machinery into Motion During Start-up Make sure all persons are clear of kiln equipment before each unit started Sound horn to signal startup I nspect all circuit breakers before the startup to make sure that all safety tags and locks have been removed Make sure all machine guards are in place before an y equipment is started Relining the Kiln with Refractory Bricks Construct a proper bridge across the burner hood from firing floor to kiln nose Inspect coating and remove loose overhangs before passing underneath Keep all unauthorized personnel out of kiln interior KILN OPERATION SECTION KILN OPERATION TECHNIQUES There are Three Common Techniques for Burning Clinker in a Rotary Kiln Maintain a constant kiln speed, and vary the fuel rate to counteract the tempera ture changes in the burning zone Maintain a constant fuel rate, and vary the kil n speed to hold the burning zone temperature at the desired label Vary the kiln speed, the fuel rate or both to maintain the desired burning zone temperature These techniques have one error in common. They show concern only for the burnin g zone temperature. Page 48 of 98 Unfortunately, many kiln operators think that this is good enough, reasoning tha t, as long as good-clinkers are produced, what more is necessary? The fallacy of this reasoning lie in the fact that ideal stable kiln conditions can be obtain faster and more economically when equal consideration is given to all zones in t he kiln and not the burning zone alone. The process of clinker burning, therefore the process of rotary kiln control sta rts not at the place where the feed enters the burning zone but at the point whe re feed enters the kiln. The Proper Operation Technique is: Vary the kiln speed, the fuel rate and the induced draft fan in any combination

to maintain the proper burning zone temperature and maintain a constant back-end temperature for a given rate of feed. This technique is called; “Burning a kiln f rom the rear”. By doing so, you prevent the variations instead of reacting to them when they re ached the burning zone. If you stabilize the kiln back-end temperature you will be able most of the time to overcome the burning zone temperature variations mainly by using the fuel in put to the kiln and the ID fan speed. In long wet and dry kilns, kiln speed variations should be avoided as much as po ssible in normal operation as it create variations in the material loading of th e kiln and eventually could lead to the kiln into an upset. If kiln speed variations is to be used, then they should be small (1 to 3 rph) k eeping in mind that the material load of the kiln will be more or less +/- 2 hou rs later as it will reach the burning zone, (kiln retention time). However, speed variations must be used on pre-calciner kilns to control the burn ing zone temperature as the calcinations rate or the feed preparation is done by the fuel input on the pre-calciner burners. The feed/speed ratio must remain constant all the time once the perfect loading of the kiln has been found. Speed/feed ratio should not be changed to control th e kiln. Page 49 of 98 BURNING ZONE EVALUATION The burning zone condition can be estimated from the colors observed in the hott est part of the flame. An orange-yellow color is normal. When looking into burning zone, one will observe a sharp color change of the low est part of the feed bed under the flame from dark to bright. This point in burning zone is of great importance to the operator as it is the e arliest indication when the burning zone tends to warm up or to cool down. In normal operation, the position of the dark feed remains stationary approximat ely one quarter of the distance into the flame. This point should be used at the main indicator for evaluation of the burning zone. If the dark feed move further under the flame (towards the front of the kiln) th e burning zone is cooling down. If the dark feed shifts in the direction of the kiln rear the burning zone is wa rming up. The position of the dark feed can feed can move because of changes in the flame shape, the feed loading of the kiln or if the feed to kiln is harder to burn. An y change in the position of the dark feed must be viewed in the light of all of these influences. The operator must be able to see the dark feed whenever he looks inside the kiln and he must regulate the operation of the kiln so as to achieve this; A slow shifting of the dark feed in either direction can usually be counteracted by a small change in the fuel input rate in order to keep the feed in its prope r place. Page 50 of 98 If it become necessary to counteract the condition in which the feed has slipped too far under the flame than the kiln speed should be varied to restore the dar k feed position to the proper location. STABLE KILN TEMPERATURE PROFILE When there is no movement (up or down) of the dark feed, and no changes were mad e on the kiln speed, the fuel rate and the ID fan speed for the last 2 hours, an d the back-end temperature has remained stable than; The kiln temperature profile should be considerately satisfactory and the kiln s ystem stable, Then the burning zone should be considered as set point for this kiln feed; When the burning zone as reached this condition than the related back-end temper ature, and gas chain temperature should be considered as set point also for this kiln feed. TARGET SET POINT AND OPERATION REFERENCES Whenever the operator has achieved a perfect and stable temperature profile on t

he kiln system, the value of the following sensors should be taken as references set point for future operation and are: Back-end temperature Gas chain temperat ure Material chain temperature Kiln amps Burning zone temperature NOx value And these values need to be correlated to the main controllers on the kiln which are: The feed rate to the kiln (and the type of clinker produced) The kiln spee d The ID fan speed The fuel rate to kiln Page 51 of 98 The oxygen level References and set point for operation need to be established on each type of cl inker produced and this, at the maximum feed rate on each kiln system. Also a copy page of the kiln operation should be taken. With all these references, the operator has all the tools to make an optimized k iln operation. BACK END TEMPERATURE CONTROL Back End Temperature is controlled principally by 3 factors; ID fan speed - Chan ge in kiln exit draft (oxygen level) Fuel rate - Causing changes in heat input i n kiln Feed rate - From feed variations in feed ratio, kiln speed, or dust retur n rate to kiln Back End Temperature control goes hand in hand with oxygen, fuel rate and burnin g zone control. As a matter of fact, whenever the operator makes an adjustment i n any one of the main control variables, he has to consider the reaction that wi ll take place in all regions of the kiln. Of these, the ID fan speed and the fue l rate are the usual causes for changes in back-end temperature, as the feed rat e should remain constant. THE THREE BASIC VARIABLES Variable Conditions in the kiln are indicated by: The Burning Zone Temperature or dark load position, NOx signal, and kiln amps le vel which has the dominant influence on the clinker quality The Back-End Tempera ture or the gas chain temperature which are the principal controls on the operat ion stability The Percentage of Oxygen in the exit gas, which governs the combus tion and the fuel efficiency Page 52 of 98 In most conditions, except for the emergencies or upset conditions, the operator will find that these three variables can be maintained within reasonable limits by means of adjustments of one or more of the 3 basic controls. TARGET RANGES FOR THE THREE VARIABLES Ranges for the Three Variables For the kiln operation, it is necessary to establish target ranges for the three variables. This information will be supplied by the past experience and depend on the raw mix composition, clinker type and other factors. These ranges has to be established where these variables can safely be permitted to fluctuate without upsetting the kiln operation. Examples of Values which have been established: target range limits Burning Zone Temperature 2800oF (1550oC) +/- 50oF (+/- 50oC) 2750oF to 2850oF (1500oC to 1600oC) Back-End Temperature 1450oF (800oC) +/- 20oF (+/- 20oC) 1430oF to 1470oF (780oC to 820oC) Oxygen Percentage 1.2%

+/- 0.8% 0.4% to 2.0% THE THREE BASIC CONTROLS Fuel flow to the burner Change in the kiln speed Change in the speed of the ID f an The operator needs to use one or all of its three controllers to keep these vari ables inside their limits. The operator must be alert and correct any out of range conditions as soon as it reaches the limits of tolerance. Page 53 of 98 Correction should be made promptly, but care must be exercised to avoid overreac ting as this could lead the kiln to an upset. THE 27 CONDITIONS (KURT E. PERAY) Because any of these variables can be within, below or above the allowable range , there are 27 possible conditions that will be encountered by the operator. These are shown graphically in the following figure. Note that a case number has been assigned to each condition as an aid to identification. This chart should be used by the operators to understand the logic of good kiln operation procedur es where the Back-End Temperature, the Burning Zone Temperature and Oxygen level were all taken in consideration in order to make a logic correction to an out o f range variable. Case Condition Action to be taken Reasons 1 BZT low Ox low BET low When BZT is drastically low, a) reduce kiln speed b) reduce fuel rate When BZT is slightly low, c) increase ID fan speed d) increase fuel rate a) to increase BZT and BET b) to move Ox percentage into range c) to raise BET and Ox d) to raise BZT and Ox into range 2 BZT low Ox low BET OK a) reduce kiln speed b) reduce fuel rate c) reduce ID fan speed a) to raise BZT b) to raise Ox percentage into range c) to maintain BET 3 BZT low Ox low BET high a) reduce kiln speed b) reduce fuel rate c) reduce ID fan speed a) to raise BZT b) to increase Ox c) to reduce BET 4

BZT low Ox OK BET low When BZT is drastically low, a) reduce kiln speed When BZT is slightly low, b) increase ID fan speed c) increase fuel rate a) to raise both BZT and BET b) to raise BET and Ox c) to raise BZT 5 BZT low Ox OK BET OK When BZT is drastically low and Ox is in lower part of range, a) reduce kiln speed b) reduce fuel rate c) reduce ID fan speed a) to raise BZT b) to raise Ox c) to maintain BET Page 54 of 98 When BZT is slightly low and Ox is in higher part of range, d) increase fuel rate d) to raise BZT 6 BZT low Ox OK BET high When BZT is drastically low, a) reduce kiln speed b) reduce fuel rate c) reduce ID fan speed When BZT is slightly low and Ox in higher part of range, d) reduce ID fan speed a) to raise BZT b) to raise Ox c) to lower BET d) to reduce BET and raise BZT 7 BZT low Ox high BET low When BZT is drastically low, a) reduce kiln speed b) reduce ID fan speed When BZT is slightly low, c) increase fuel rate a) to raise both BZT and BET b) to maintain BET c) to raise BZT and lower Ox & BET. BET should be rising also, if not keep increasing fuel rate and ID fan speed 8 BZT low Ox high BET OK When BZT is drastically low, a) reduce kiln speed b) reduce ID fan speed

When BZT is slightly low, c) increase fuel rate a) to raise BZT b) to maintain BET. If Ox is still available after this move, increase fuel also c) to raise BZT and lower Ox 9 BZT low Ox high BET high When BZT is drastically low, a) reduce kiln speed b) reduce ID fan speed c) increase fuel rate When BZT is slightly low, d) reduce ID fan speed a) to raise BZT b) to lower BET and Ox c) to raise BZT and lower Ox d) to raise BZT and reduce BET & Ox 10 BZT OK Ox low BET low a) increase ID fan speed b) increase fuel rate a) to raise BET and Ox b) to maintain BZT 11 BZT OK Ox low BET OK a) decrease fuel rate slightly a) to raise Ox 12 BZT OK Ox low BET high a) reduce fuel rate b) reduce ID fan speed a) to increase Ox b) to lower BET and maintain BZT 13 BZT OK Ox OK BET low a) increase ID fan speed b) increase fuel rate a) to raise BET b) to maintain BZT 14 BZT OK Ox OK BET OK None, however do not get overconfident 15 BZT OK Ox OK When Ox is in upper part of range, Page 55 of 98 BET high

a) reduce ID fan speed When Ox is in lower part of range, b) reduce fuel rate c) reduce ID fan speed a) to reduce BET b) to raise Ox c) to lower BET and maintain BZT 16 BZT OK Ox high BET low a) increase ID fan speed b) increase fuel rate a) to raise BET b) to maintain BZT and reduce Ox 17 BZT OK Ox high BET OK a) reduce ID fan speed slightly a) to lower Ox 18 BZT OK Ox high BET high a) reduce ID fan speed slightly b) reduce fuel rate slightly a) to lower BET and Ox b) to maintain BZT 19 BZT high Ox low BET low When BZT is drastically high, a) increase kiln speed b) increase ID fan speed c) reduce fuel rate When BZT is slightly high, d) increase ID fan speed a) to avoid overheating BZT b) to raise BET and Ox c) – do – d) to lower BZT and raise BET & Ox 20 BZT high Ox low BET OK When BZT is drastically high, a) increase kiln speed b) decrease fuel rate c) increase ID fan speed When BZT is slightly high, e) increase ID fan speed a) to avoid overheating b) to lower BZT c) to increase Ox and maintain BET d) to lower BZT and raise Ox 21 BZT high Ox low

BET high When BZT is drastically high, a) increase kiln speed b) reduce fuel rate When BZT is slightly high, c) decrease fuel rate a) to lower BET and avoid overheating b) to lower BZT and increase Ox c) to lower BZT, BET and increase Ox 22 BZT high Ox OK BET low When BZT is drastically high, a) increase kiln speed b) increase ID fan speed c) reduce fuel rate When BZT is slightly high, d) increase ID fan speed a) to avoid overheating b) to raise BET c) to lower BZT d) to raise BET and lower BZT (see note A) 23 BZT high Ox OK BET OK When BZT is drastically high, a) increase kiln speed b) decrease fuel rate c) increase ID fan speed When BZT is slightly high, d) reduce fuel rate a) to avoid overheating b) to lower BZT c) to maintain BET d) to lower BZT (see note A) 24 BZT high Ox OK When BZT is drastically high, a) increase kiln speed a) to avoid overheating & lower BET Page 56 of 98 BET high b) decrease fuel rate When BZT is slightly high, c) decrease fuel rate b) to lower BZT c) to lower both BZT and BET (see note A) 25 BZT high Ox high BET low When BZT is drastically high, a) increase kiln speed b) increase ID fan speed When BZT is slightly high, c) increase ID fan speed a) to avoid overheating

b) to increase BET and lower BZT c) to raise BET & lower BZT (note A) 26 BZT high Ox high BET low When BZT is drastically high, a) increase kiln speed b) increase ID fan speed c) decrease fuel rate When BZT is slightly high, d) reduce fuel rate a) to avoid overheating b) to maintain BET c) to reduce BZT d) to lower BZT (see note A) 27 BZT high Ox high BET high When BZT is drastically high, a) increase kiln speed b) decrease fuel rate When BZT is slightly high, c) decrease fuel rate d) decrease ID fan speed a) to lower BZT and BET b) – do – c) to lower BZT d) to lower BET (see note A) NOTE A: If the % O2 increased during this adjustment, disregard it until tempera tures are brought under control. KILN UPSET CONDITIONS – SLOW DOWN Kiln cannot operate in a stable condition at all times and it will eventually ge t colder. Sometimes heavy rush of feed might end up too far under the flame (halfway under the flame). Operator must then decide if he will be able to control the heavy feed load only by increasing the fuel flow, or if he needs to reduce the kiln speed. The determinant factors to be considered are the oxygen level, back-end temperat ure, movement of the feed rush, and conditions in the cooler. Assuming that it is impossible to maintain the same kiln speed, the operator mus t determine how much the kiln speed can be slowed down depending on the magnitud e of the push. Page 57 of 98 Only experience can tell the operator how much the kiln has to be slowed down. In those cases the following rules apply all the time; When in doubt, the kiln speed reduction should be greater than required. This wi ll help to overcome the problem faster. Never allow the raw, unburned feed to enter into the cooler, even if it means th at the kiln must be stopped and rotated on ¼ turn or the auxiliary drive. As soon as the kiln has been slowed down, the operator must; Try to keep the back-end temperature within acceptable limits variation (i.e. 75 to 100oF). Cut down the fuel flow to maintain the oxygen level above 0.5% and to keep backend temperature inside the limit range. Evaluate the cooler conditions, grate speed, grate temperature, inlet temperatur e of gravel bed collection system and secondary air temperature. Often, the cooler will have to be switched on manual mode to protect it to becom e overheated as often regulation of cooler are made for small variations only.

As the kiln is on slow speed, it is necessary to determine when the speed can be increased back again. In that case, the oxygen level is the main factor to look at. Try to keep the same values on the fuel flow and ID fan speed in order to observ e the O2 variations. When O2 level increases, the burning zone is warming up. As soon as the oxygen level start to increase, increase the kiln speed slowly i. e. +/- 3 rph if the burning zone is still dark and very dusty. Page 58 of 98 Observe the reaction of the O2 level if it keeps on raising. If so, increase kiln speed by 3 rph at every 10 minutes, and keep on increasing as long as the oxygen level does not drop. Keep fuel flow always one step ahead of normal operation level, (i.e. when rotat ion speed is at 24 revs, set fuel flow for 27 revs), and ID fan speed accordingl y. Stop increasing kiln speed approximately 1 ½ to 2 hours after initial slow speed i n order to overcome any upset in the material load of the kiln created by the sp eed variation. Restart increase the kiln speed after reception of material from slowdown is ove r. Kiln speed increase should be reduced around 80 revs as we are getting near full production (i.e. 2 revs at every 20 minutes). When full production has been reached (i.e. 85 revs) the fuel flow must be kept one step higher than normal for at least 2 more hours, and then it must be cut d own slowly following the normal operating procedures to get the load at the end of the flame again. A slowdown made in time and at proper speed will requires about 20 minutes befor e to restart to increase the kiln speed again (as O2 start to go back up). Usually, the kiln should be back in full production about 4 hours after the slow down was made. Slowdown Example: revs t/h Fuel flow ID fan speed O2 Operation 86 93 102 m3/h 530 rpm 1.5% Normal 66 72 85 m3/h acc. O2 level 0.7 Slowdown 36 40 50 m3/h acc. O2 level 0.7 slowdown Page 59 of 98 NORMAL OPERATING PROCEDURES ON SHIFT Take Over of Shift by Operators Check: Visual inspection of burning zone, look for dark load Oxygen level and tr end Back-end temperature and trend Kiln amps and trend NOx signal and trend Kiln speed Kiln feed indicator Secondary air temperature and trend Clinker load on g

rate in cooler Cooler fans under grate pressure Kiln draft and hood pressure Gra vel bed filter or DC temperature Water spray and precipitator Then an evaluation of the kiln and burning zone state need to be done in order t o compare actual settings with the target value and limit ranges established bef ore. Wait at least 30 minutes before changing any values, unless there is an emergenc y condition in order to evaluate if the kiln is warming up, cooling down or stab le. PLAN OF ACTION Page 60 of 98 If the burning zone is hot (not drastically hot) and the kiln is stable Decrease fuel flow by 3% Then decrease ID fan speed to keep the same O2 level Wait appro ximately 20 min (retention time of the burning zone) to see the reaction of your move Then repeat the same procedure again or stay there if dark load is moving in pos ition or if the kiln amps are dropping. Repeat the operation until you get; The dark load at the right position The kiln amps inside its target range The kiln gas temperature and back-end temperature inside their target range If burning zone is cold (not drastically cold) The same approach is to be done but in reverse This procedure should be done on each shift in order to get the best kiln condit ion and the best heat consumption possible at all times. Whenever the dark load, the kiln amps and the kiln back-end temperature are back inside their target range, then the 27 conditions procedures should be done aga in to maintain the kiln back-end and the burning zone temperature on set point a nd the kiln temperature profile stable. OXYGEN LEVEL IN AUTOMATIC MODE When the perfect temperature profile balance has been reached, we can eventually set the oxygen level on automatic (looped to the ID fan speed). This will allow the gas flow in the kiln to be constant and will help to maintain the kiln syst em stability. Page 61 of 98 Theoretically speaking, as we reach this situation, no more moves on the fuel ra te, feed rate and kiln speed need to be done and the kiln should remain in balan ce until an upset on the material load or a mix change creates an upset again. So the oxygen level control should be set on automatic whenever the temperature profile in kiln is satisfactory. Every time this is not so or the kiln is slight ly upset, the oxygen should remain in manual and used to establish a good temper ature profile inside the kiln. KILN START-UP AND SHUTDOWN PROCEDURES KILN PREHEAT Light-Up Flame Example (gas) 1) Call the gas company to tell them that you are going to light up 2) Open one side of precipitator (inlet and outlet damper) 3) Start dust handling system on the side of precipitator in use with dust going to the ground (to avoid plugging the circuit with moist material) 4) Start up ID fan at minimum speed (damper closed) 5) Open ID fan damper at 10%. Use a rag in front of kiln door to evaluate suctio n in the kiln and adjust damper to obtain proper suction 6) Start primary air fan with damper closed 7) Install torch under burner pipe 8) Set natural gas to obtain approximately 13 m3/min (450 ft3/min) 9) Slowly open manual valve on gas line 10) Adjust primary air damper, primary and secondary gas pressure, and ID fan da mper for best flame possible 11) If flame goes out, make sure to purge the air inside the kiln before any att empt to try lighting up again Page 62 of 98 12) Don’t turn the kiln for the first 2 hours

13) Start nose ring fan one hour after the flame on PRE-HEAT or Drying of the Refractory Lining General Information: The pre-heat period last around 12 hours. A minimum of 8 to 12 hours is necessary The reference temperature during this period should be th e kiln feed end temperature The target temperature should be approximately 300oC or 575oF at the precipitator inlet Start kiln rotation (1/4 turn) 2 hours after flame on After make ¼ turn every 30 minutes until the end of pre-heat period If New Castable was Installed: Pre-heat period could take as long as 36 hours depending on the location and the quality of the castable installed and could be divided in three periods as foll ows: First Period: For 12 hours with gas flow of 13 m3/min or 450 ft3/min Do not exce ed 170oC or 340oF at the filter inlet during this period Two hours after the fla me on, make ¼ turn every 30 minutes during the balance of this period Second Period For 12 hours, increase the precipitator inlet temperature so it co uld reach 230oC or 450oF Make ¼ turn every 30 minutes during this period Third Period: For 12 hours, increase the precipitator inlet temperature to reach 300oC or 575oF Make ¼ turn every 30 minutes during this period Page 63 of 98 HEATING (To reach temperature ready to put feed on) General Information: The reference temperature is the gas chain inlet temperatur e The target temperature should be approximately 40oC or 105oF lower than the no rmal operation temperature The rate of increase of the temperature should be app roximately 50oC or 125oF per hour The temperature increase per hour should be done according to the following: Length of refractory installed; Complete kiln: 35oC or 100oF per hour increase Repaired burning zone: 50oC or 125oF per hour increase Kiln rotation during heating: 1) ¼ turn every 10 minutes for 2 hours 2) Continuous turn on auxiliary drive for 2 hours 3) Rotation at 0.5 or 30 revs for 1 hour 4) Rotation at 0.7 or 42 revs until 15 minutes before feed on 5) Rotation at 1.0 or 60 revs 15 minutes before putting feed on Oxygen level during this period should be kept between 7 to 10% in order to incr ease the back end temperature to avoid the burning zone to get overheated. Burni ng zone should be pink in color. The cooler system is usually down, leaving only the nose ring fan and the primar y air fan running During this period, it is most important to keep the greasing system on the kiln drive running As soon as the kiln is running continuously, start cooling fans on the burning z one Expansion of the Kiln and Tire Page 64 of 98 Heating rate in large diameter kiln (>14’) should not be higher than 50oC or 125oF per hour to allow both tire and shell to expand at proper rate Clearance between tire and shell should be monitored during start-up The larger the diameter of the kiln, the more care has to be taken to get it run ning FEED ON KILN General Information: Feed rate is approximately 50% of normal feed rate Feed rat e increase of about 5 tons every hour Kiln speed should be maintained at 1.0 rpm or 60 revs until the material reaches the burning zone (to get material in burn ing zone quick) Target for chain inlet temperature; 800oC (1472oF) or 40oC (100o F) below normal operation temperature Set ID fan speed to maintain about 3% the oxygen level Start high voltage on precipitator Start remaining items on cooler system (all cooler fans with dampers set as required) Maintain those settings un til the start-up reactions occurs (push should take +/- 2 hours) In order to pro mote good coating formation in the burning zone, stabilize the kiln at 1.1 rpm o

r 66 revs at about 70 tph for 24 hours After this period, take the kiln up to op timum operation level with normal operation procedures KILN START-UP PROCEDURES (AFTER BRICK JOB) Preparations: 72 hours before light-up, call the gas company to tell them the da te and the hour of the light-up 4 hours before light-up, make dry run on all equ ipment Page 65 of 98 Check burner pipe and its installation Center the burner pipe, or adjust 1” down a nd 1” towards the load (make marks outside the kiln for the burner pipe position r eference) Check fuel on auxiliary drive Take locks off on kiln equipment sets Ta ke off wood shims on kiln rollers Pre-heat: Start kiln section on CRT Open one side of precipitator (outlet and in let damper) Start the dust handling on the side of the precipitator in service, with the dust on ground to avoid plugging the circuit Start-up ID fan at 125 rpm or minimum speed, damper closed Open ID fan damper at 10% Start primary air fan , damper closed Install a torch under burner pipe Set natural gas in control roo m at 13 m3/min or 450 ft3/min Open manual gas on gas line Open supervisory cock valve near burner pipe Adjust primary air, primary and secondary gas and ID fan to get the best flame One hour after, start nose ring fan and make no kiln rotat ion for the first 2 hours The pre-heating period should last around 12 hours. A minimum of 8 to 10 hours i s necessary. The temperature at the inlet of the precipitator must reach 300oC o r 575oF. Special pre-heating after castable has been installed near the burning zone First Period: For 12 hours with gas flow of 13 m3/min or 450 ft3/min No kiln rot ation for the first 2 hours Kiln rotation at ¼ turn every 30 minutes after 2 hours Try not exceed 170oC or 340oF at the filter inlet during this period Page 66 of 98 Second Period For 12 hours, increase the back-end temperature so it could reach 230oC or 450oF Make ¼ turn every 30 minutes during this period Third Period: For 12 hours, increase the back-end temperature to reach 300oC or 575oF Make ¼ turn every 30 minutes during this period HEATING-UP The reference temperature is the chain gas temperature The rate of increase of t he temperature should be approximately 50oC or 125oF per hour The target tempera ture should be approximately 40oC or 100oF lower than normal operation temperatu re Draw a curve on chain inlet temperature chart, so you could follow the temper ature increase Increase progressively fuel and draft (open second precipitator c hamber when required) The burning zone should be kept in place and should be pin k when the feed will be put on During that heating period, the oxygen should be between 7 and 10% Start the water spray to keep the back end temperature at 350o C or 660oF Around 750oC or 1400oF, start kiln feed for 10 minutes for testing Ch eck if any clinker on cooler grate and when necessary start the clinker evacuati on system Start shell fan when kiln is turning on continuously Start cooler fan #1 and #2 at minimum 30 minutes before kiln feed When you reach 800oC or 1475oF at chain inlet temperature (T according to plant normal operation temperature mi nus 40oC or 100oF), start feed Page 67 of 98 FEED ON Start: Kiln feed at 45 tons/hr Kiln speed at 1.0 rpm or 60 revs Increase; Kiln feed at 5 tons per hour Fuel rate and ID fan speed accordingly (maintain fuel rate 1 step ahead of norma l operation) Start fan #3, #4 and #5 (damper closed) 15 minutes after feed is on Start gravel bed filter or its equivalent Put tension on kiln precipitator 15 minutes after kiln feed is on Stabilize the kiln at 1.1 rpm or 66 revs/hr at about 70 tph feed rate for 2 hour

s to promote good coating conditions in burning zone When increasing kiln feed, adjust the pressure and fan flow on cooler fans Check closely the clinker evacuating system When there is a good load in the cooler put the cooler on regulation Kiln turns during heating: ¼ turn every 10 minutes for 2 hours Continuous turn on auxiliary drive for 2 hours Turn at 0.5 rpm or 30 revs/hr for 1 hour Page 68 of 98 Turn at 0.7 rpm or 43 revs/hr until 15 minutes before putting feed on Turn at 1. 0 rpm or 60 revs/hr 15 minutes before feed on EXAMPLE OF HOW TO START KILN IF PRE-HEAT IS REQUIRED (Load in kiln) If pre-heat is required (Function of burning zone and gas chain temperature) Ope n dampers on precipitator (both side) Fuel rate at 44 m3/min or 1554 ft3/min ID fan speed at 25 rpm (minimum speed) ID fan damper position according to O2 level (5% maximum) Maintain these settings until temperature reach on gas chain temperature at 850o C or 1562oF (normal kiln operation temperature). Kiln rotation varied according to gas temperature as follows: If; Chain Gas Temperature Rotation Fuel Rate 750 to 930oF ¼ turn every 20 minutes 44 m3/h or 1553 ft3/min 930 to 1110oF ¼ turn every 15 minutes 50 m3/h or 1766 ft3/min 1110 to 1300oF ¼ turn every 10 minutes 57 m3/h or 2013 ft3/min 1300 to 1562oF ¼ turn every 5 minutes 63 m3/h or 2225 ft3/min Then start the; Kiln at 60 revs Feed at 63 tph Fuel at 88 m3/min or 3108 ft3/min ID fan speed at 350 rpm and to maintain O2 near 4% Start burning zone cooling f ans Page 69 of 98 Wait at this setting to receive the material and then increase slowly like norma l procedures but always maintain on fuel and ID fan speed settings one step ahea d. During this period, the nose ring fan is on. The primary air fan is on with normal setting. The cooler fans #1 and #2 on cooler are running. Grates, clinker circuit and gravel bed filter are running. Guidelines: For a shutdown less than 5 hours, warm-up period should be around 1.5 to 2 hours . For a shutdown between 5 to 12 hours, warm-up period should be around 4 hours. EXAMPLE OF HOW TO RESTART IF NO PRE-HEAT IS REQUIRED Start-up speed is related to the gas chain temperature of the kiln and burning z one aspect. Start-up could be as follows: If; Chain Gas Temperature Rotation Rotation Fuel Rate 1435oF 60 revs

65 tons/hr 3110 ft3/min 1475oF 66 revs 70 tons/hr 3425 ft3/min 1508oF 72 revs 76 tons/hr 3745 ft3/min 1545oF 75 revs 79 tons/hr 3885 ft3/min 1580oF* 78 revs 82 tons/hr 4025 ft3/min *1580oF being the normal operation temperature Adjust draft and fuel as required. After material reception, increase according to normal procedures but keep 1 ste p ahead on fuel and ID fan settings for 2 hours after you reach normal productio n level (retention time of material in burning zone). Page 70 of 98 This procedure is to be developed in order to restart a kiln faster and having l ess perturbation in the material load of the kiln (long dry and wet kilns). KILN SHUTDOWN (General Information) There are many reasons why kiln must be shutdown periodically and in most cases, the operator must decide when an immediate unscheduled shutdown of the kiln sys tem is required. There is often not enough time available in such situation to w eigh or discuss the merits of a shutdown because a few minutes of delay could le ad to major equipment damage. So clearly, an operator should be fully trained in what to do and what to do if such situation occurs. Written standard procedures to cover these situations should be at the disposal of the operators to allow them to review those procedures periodically. COOLING PROCEDURES In case of a shutdown, slow cooling of the refractory must be ensured. The Stacks Registers: Must be kept shut for a sufficient period of time Cooling schedule should provide gradual cooling of the burning zone refractory at a maxi mum temperature rate of 100oC (212oF) per hour For smaller kiln, i.e. diameter < 13’, maximum rate is 100oC or 212oF For larger kiln, i.e. diameter > 13’, maximum rate is 75oC or 167oF The ID fan; Should be shutdown immediately as soon as fire is cut off Page 71 of 98 Should not be used for forced cooling at least for the first 12 hours after kiln shutdown This is an absolute must on long dry and wet process kilns equipped wi th internal heat exchangers such as chain The ID fan inlet damper should also be closed completely for at least 12 hours During short shutdown; The kiln back-end should be closed completely for at leas t 12 hours During short shutdown; The kiln back-end should be closed completely to avoid ho t gases to escape from kiln Hood Pressure: Flow adjustments on the cooler fans have to be made to avoid the kiln hood to get on to high pressure The hood pressure set point should be set s lightly on the positive side to prevent air from burning zone to escape through the cooler exhaust fan KILN ROTATION SCHEDULE The kiln must be rotated on a regular schedule to insure uniform cooling, as the feed bed and the refractory underneath it, take more time to cool down than the

refractory wall exposed to the kiln gases. Kiln Rotation for Short Maintenance Repair ¼ turn every 5 minutes 4 times during 20 minutes ¼ turn every 10 minutes 4 times during 40 minutes ¼ turn every 15 minutes 8 times during 2 hours ¼ turn every 30 minutes 8 times during 4 hours ¼ turn every 60 minutes until the end ---------------Page 72 of 98 If it is Raining, Continuous rotation should be done on the auxiliary drive or on main drive at mi nimum speed Kiln Rotation for Long Kiln Shutdown (brick lining repair) Before: Stabilize kiln rotation at 1.0 rpm or 60 revs before shutdown (flame sti ll on) Then: Maintain continuous rotation at 0.6 rpm or 36 revs during 30 minutes (flam e is off) Maintain continuous rotation at 0.5 rpm or 30 revs during 2.5 hours Ma intain continuous rotation at 0.4 rpm or 24 revs during 1 hour Maintain continuo us rotation at minimum speed on auxiliary drive for 1 hour Then: If it is raining, continuous rotation should be done on the auxiliary drive or a t minimum speed on main drive. Shutdown for long periods also included purging of the following: Fuel firing sy stem Feed system Dust system from precipitator or dust collector system Dust sys tem of conditioning tower Clinker from cooler system BURNER PIPE AND HOOD PROTECTION The burner pipe must be protected as the hood and the kiln discharge area remain s at high temperature for several hours after the fire has been cut off. Page 73 of 98 Some kilns are equipped with movable burner pipes to allow partial or full retra ction of the burner. Others have to rely on primary air fan to provide necessary cooling of the burner. Primary air fan and nose ring fan should be running at least 10 hours after the flame has been cut off. EMPTYING THE FEED FROM THE KILN Emptying the feed from the kiln takes special skills and experience. It could be very dangerous and could result directly in overheating conditions either at th e back-end of the kiln, the burning zone, or the cooler. So called “chain and coal mill fires” have occurred as direct result of attempting to burn out a kiln. Therefore, burning out a kiln is far too risky and should never be attempted. As soon as the feed is cut off, the flame should be cut off. KILN SHUTDOWN PROCEDURES (FOR BRICK JOB OR RED SPOT) Time (- 2 hours) Cut down kiln speed at 1.0 rpm or 60 revs Time (- 15 minutes) Cut off coal extraction from silo if required Time (- 5 minutes) Cut off feed extraction from homo silo Time (- 2 minutes) Cut off high voltage on precipitator

Time (0 hour) Cut off feed and purge circuit completely Cut off fuel when system is purged Time (+ 2 minutes) Stop ID fan Reduce air flow under cooler Page 74 of 98 Time (+ 4minutes) Close ID fan louvers slowly, or equivalent equipment Adjust cooler fans to keep hood pressure slightly positive Stop water spray system or any water system at back-end Time (+ 6 minutes) Cut down kiln speed at 0.6 rpm or 36 revs Reduce primary air fan (1000 Pascals or 10 mbars) Put cooler system on manual mode Reduce grate speed at 4 strokes per minute Reduce fan #1, #2 and #3 at 50% of normal air flow Reduce other fans according to gravel bed filter inlet temperature or Other de-dusting system Time (+ 10 minutes) Close main damper on precipitator, (line 1 & 2) or any equiv alent equipment Keep the extraction of the dust system running Keep nose ring fan running Time (+ 15 minutes) Retract burner from kiln hood if possible if not keep primar y air fan running for cooling Time (+ 30 minutes) Reduce kiln speed to 0.55 rpm or 33 revs Pull water spray out of the kiln Time (+ 1 hour) Reduce cooler fans #1, #2 and #3 to 25% of normal flow Reduce other fans according to gravel bed filter inlet temperature or other de-d usting system Time (+ 1.5 hour) Reduce kiln speed to 0.5 rpm or 30 revs Watch for unburned clinker and send it to proper location Time (+ 2 hours) Stop cooling fans under kiln shell Page 75 of 98 Readjust air flows under cooler If possible, stop last fan according to filter inlet temperature Time (+ 4 hours) Reduce kiln speed to 0.4 rpm or 24 revs Time (+ 5 hours) Stop rotation with main motor Start continuous rotation with the auxiliary drive Stop extraction of dust on the precipitator or dust collector system Time (+ 6 hours) Stop continuous rotation with the auxiliary drive Make ¼ turn every 15 minutes (attention to greasing system in the main kiln drive to be started in manual) Time (+ 8 hours) Make ¼ turn every 30 minutes Time (+ 10 hours) Stop nose ring fan and primary air fan Time (+ 12 hours) Make ¼ turn every hour Time (+ 15 hours) Stop cooler fans Stop gravel bed filter system if required Time (+ 16 hours) Open main damper on one side of the precipitator Start the ID fan a few seconds with damper closed every hour Time (+ 18 hours) Start ID fan a few seconds Open ID fan damper at 10% Time (+ 20 hours) Start ID fan a few seconds Open ID fan damper at 25% Open door on kiln hood Page 76 of 98 Time (+ 22 hours) Start ID fan a few seconds Open ID fan at 75% Time (+ 24 hours) Close ID fan completely Time (+ 26 hours) Start ID fan at minimum speed Open ID fan at 10% Time (+ 27 hours) Open ID fan at 30% Time (+ 28 hours) Open ID fan at 50% Time (+ 29 hours) Open ID fan at 75%

Time (+ 30 hours) Open ID fan damper completely Stop kiln rotation completely Start to open kiln hood front door Make security on kiln system (lock procedures) Start to clean cooler system This shutdown procedure could also be used as an emergency shutdown on red spot. CLINKER COOLER SECTION COOLER FUNCTION a) The main function of the cooler is to recuperate the heat contained in the cl inker coming from the kiln as heat recovery from secondary, tertiary and to coal mill air is important for kiln efficiency and fuel saving. Page 77 of 98 b) The cooler must also lower the temperature of the clinker before it leaves so it can be safely transported to the storage area c) The clinker breaker at the cooler outlet reduce the clinker size so it can be transported on the conveyor system COOLER OPERATION Cooling of the clinker material is accomplished by forcing ambient air upward th rough the material as it is being conveyed through the length of the cooler by r eciprocating action of the grates. The clinker cooler is divided into two major areas, which are separated by the g rate line. They are the over grate area where the clinker is cooled down and whe re the hot gases are handled and the under grate compartment where cooling air i s blown into the system. The grate line consists of many perforated grate plates arranged in overlapping rows. The alternate rows are movable and are connected to a wheel mounted frame which is moved back and forth on its tracks by a crank type drive that drives th e grates their reciprocating motion. See figures 2 to 6. In normal operation, the cooler is running in auto to keep a constant under grat e pressure and air flow under the second compartment in order to control the sec ondary air temperature. However under upset conditions, the cooler must be switched on manual. COOLER CONTROLLERS In normal operation: The speed of the grate change the residence time of the cli nker inside the cooler (to control the cooling rate of the clinker and to protec t the grate to get overheated) The air flow distribution under each compartment to maintain good heat recuperation and good cooling of the clinker In case of emergency: (such as a badly overheated cooler condition, the operator must always) Decrease the kiln speed in order to reduce the clinker input to th e cooler and control the heat input OPERATION OBJECTIVES Page 78 of 98 To keep as much as possible: The clinker temperature at the cooler discharge as low as possible (high temperature could damage the clinker transport system) The secondary air temperature as stable and as high as possible to get the best rec uperation from the clinker and improve the fuel efficiency of the kiln To keep t he depth of the clinker bed near 15” water gage in order to get good heat recupera tion from the clinker in cooler (according to fan capacity) To keep the hood pre ssure always slightly negative To set the cooler fans flow in such away to have enough capacity to get air through the clinker bed and to insure proper cooling of the grates and the clinker load inside the cooler Cooler settings should be such that bed grates, cooler drive unit, clinker crush er, cooler wall and clinker conveyors system cannot become overheated. RULE IN COOLER OPERATION A fundamental rule on grate cooler is to never permit raw feed or extremely fine clinker to enter the cooler as the cooler can become overheated and damage. During kiln pushes, lower the kiln speed in order to reduce fine clinker input i n the cooler. Never run the kiln with positive pressure as this result in troubled kiln operat

ing conditions as: Fine clinker in nose ring resulting to wear of kiln seal View ing in kiln is unpleasant and unsafe Could damage the optical equipment and the TV camera Formation of rings and “snowmen” in cooler inlet can be attributed to posi tive pressure Exception: One exception to this rule if ever very high temperature in cooler an d if needed to introduce sufficient air in cooler. MAIN SENSORS Page 79 of 98 The Main Sensors to Control the Cooler Operations are: The fans flow for each co mpartment The under grate pressures under grate #1 and #2 The secondary air temp erature The grate speed under grate #1 and #2 The clinker discharge temperature at the cooler outlet Also Secondary Sensors as: Grate temperature in #1 and #2 compartments TV camera showing the cooler interior Hood Draft Control by regulation the excess air inside the cooler by the cooler exhaust fan damper It maintains a constant pressure in front of the kiln A good hood pressure regulation is important for the burning zone stability Assuming other Factors Remain Constant: An increase in the ID fan speed will low er the hood pressure A decrease in the ID fan speed will increase the hood press ure Also increasing the amount of air in cooler results in higher hood pressure Under Grate Pressures and Air Flow Rates The under grate pressure is govern by the following factors: Depth of the clinke r bed over the grate Average particle size of clinker in the cooler Amount of ai r flow into the cooler Should be at 15” water gage (under 2nd compartment) to get good heat recuperation Clinker Bed Depth The depth of the clinker bed is controlled by the speed of the cooler grate The faster the grate, the thinner becomes the bed and lower is the under grate pressure Page 80 of 98 Because of the relation between the grate speed, bed depth and under grate press ure, it is possible to maintain a constant under grate pressure by regulating th e grate speed It is usually done under the second compartment of the cooler because it is that location at the cooler inlet where the clinker bed is more stable and give an e arly and good under grate pressure signal for the automatic cooler control. PARTICLE SIZE OF CLINKER A critical factor in under grate reaction is the average particle size of the cl inker in the cooler. A fine clinker bed impose more resistance against air flow, when the under grate pressure increase, the fan has to use more force to push t he air through this kind of bed Then the under grate pressure increase when the clinker gets finer because the smaller particles impede the air flow through the bed Therefore, the airflow rate is increased to restore the normal flow through the bed and the clinker bed can become fluidized A fluidized clinker bed is hig hly undesirable and dangerous, because the bed in such a state does not move alo ng properly in the cooler On horizontal grate, the clinker tend to remain statio nary and tend to build on top of the grates and when sufficient weight has been acquired by the bed, it starts to move again So the clinker cannot be properly c ooled down and could choke off the airflow through the bed OPERATION OF COOLER FANS The air volume for cooler fans is most commonly carried out by means of fan outl et damper. The fan speed is constant so it is necessary to change the position o f the damper to reduce or to increase the air moved by the fan. Fan damper is no rmally open at 60% as necessary leeway is required to increase air flow. Maximum air flow is when the fan damper reached about 88% open. The air volume output i s directly related to the under grate pressure. Page 81 of 98 The fan must have sufficient capacity to provide necessary amount of air at maxi mum under grate pressure. The maximum operating under grate pressure needs to ta ke into account the cooler fans capacity. Flow rate for each fan and under grate pressure set point need to be set on for a good cooler operation. The fan manuf

acturers provide performance curve for each compartment fan. Fan Static Pressure Fan static pressure is the total pressure developed by the fan, less the velocit y pressure in the fan discharge duct. For practical purposes, fan static pressure in a cooler system is equal to the u nder grate pressure, and the air flow is a function of this static pressure and the power applied to the fan. (Figure 7) Whenever the under grate pressure exceed the limit of the fan, the flow decrease s and less cooling is taking place then the cooler could be damaged. CLINKER AND AIR DISTRIBUTION For proper cooling, it is essential that clinker is evenly spread over the width of the cooler so that the bed offers a uniform resistance of the air passage th rough its width. When clinker passes to one side of the cooler leaving a thinner bed on the other side, the air will naturally seek a passage through the bed where it offers the least resistance. So air passes through bed where it is least needed and little air passes where i t is needed most. Formation of “snowmen” at the cooler inlet is the prime cause of t his condition. Various devices as dead grate, spreaders or grate with their own air supply to spread the clinker rapidly over the width of the cooler inlet are used to fight “snowmen” formation. For proper air distribution and good cooler regul ation, no air should freely pass from one cooler compartment to another through leaks or other opening on the compartment walls. Page 82 of 98 The under grate pressure is usually set that the highest pressure is found in th e first compartment, and the lowest in the last compartment. Emergency High Clinker Temperature Installed on the drag conveyor is this sensor to measure the clinker temperature at the cooler discharge. If the clinker temperature is above 300oF (150oC), it will transfer the clinker to the emergency bin automatically and will stay there until the desired temperature will come back. High clinker temperature is cause d by inadequate cooling of clinker in cooler. Guideline: In cooler normal operation, no red clinker should be seen passing the third comp artment. COMBUSTION SECTION FLAME A flame is a stream of gases at extremely high temperature (around 3500oF or 193 0oC) where the reactions of combustion of the fuel with secondary and primary ai r are taking place. Anything exposed to such a flame is bound to receive heat fr om it. Flame Evaluation Should always be evaluated during stable kiln condition Flame Length Could refer to the distance between the burner tip and the end of t he flame which is a total flame length It could also refer to a distance between the point where ignition of the fuel start and where the reaction of fuel combu stion ends It is desirable to operate a kiln with the flame as short as possible , as long as it will not create problem in front of the kiln, hood, nose ring an d refractory (Figure #1) Page 83 of 98 Flame Shape Could be long and “lazy” as heat is released over a relatively long dist ance (example A) Could be “snappy” as heat is released over a shorter distance (exam ple C) Flame Direction The flame path is not a straight line The flame has a tendency o f lift upward toward the top resulting in uneven entrance of secondary air, or m echanical condition of the primary air pipe nozzle A good direction target for t he flame could be 2A or 2B in Figure # 2, or one inch down center line and one i nch towards the material load The flame temperature is related to: 1. Quality and type of fuel used

Gas: 1830oC or 3325oF Fuel oil: 1956oC or 3553oF Coal: 1927oC or 3500oF 2. Total combustion air temperature Secondary air temperature Primary air temperature Air in-leakage temperature 3. Oxygen level at kiln outlet 4. Brick and coating temperature in the burning zone Flame Target Ignition as quick as possible Highest flame temperature as possible Page 84 of 98 Length as short as possible As constant as possible Primary air flow minimum to carry fuel in kiln All above combined in such a way for not making erosion and d irect contact of the flame on the refractory Shell temperature scanner is a good indication of flame profile. Flame Adjustment Increase in primary air The speed will increase Temperature will increase The vo lume will become wider Increase in primary air temperature The plume will get shorter The flame will be come shorter The flame will become wider Increase in secondary air temperature The flame temperature will increase The fl ame length will decrease The plume will decrease Increase on the oxygen level The flame length will increase The flame temperatur e will decrease The following factors serve to raise the flame temperature: Page 85 of 98 Increasing the secondary air temperature Using less primary air, thus making it possible to utilize more secondary air which is preheated to higher temperature Promoting rapid mixing of the air and fuel upon leaving the burner by improving the design of primary air pipe and burner Better atomization of the fuel oil by increasing the fuel oil temperature or employing a mechanical device in the burn er nozzle to bring a better atomization By keeping hood pressure as close as pos sible from “0” in order to avoid air in-leaking in front of kiln Operating the kiln with neither a deficiency or excess of air by maintaining the oxygen content of not less than 0.7% and not more than 3.0% Rules on Flames a) When the primary air pipe nozzle has accidentally been warped, resulting in a n erratic flame shape and direction, immediate steps should be taken to repair t his condition b) A flame should never be allowed to impinge upon the coating or bare refractor y for a prolong length of time c) A flame should never be allowed to strike too hard upon the feed bed d) Oil burners or gas burners should be centered well in the primary air pipe in order that an even envelopment of air around the fuel jet takes place e) Flame direction should be adjusted only when the kiln is in stable operating conditions and the temperatures, fuel pressures, and air flow rates are at norma l level. Flame direction changes can be caused by unusual operating conditions. If any attempt were made to adjust the flame at such a time, there will most lik ely be an undesirable flame once the kiln returns to normal operating conditions again f) It is better to make the desired adjustments in flame direction in several sm all steps instead of a large one in order that the operating stability of the ki ln is not affected adversely g) Once the ideal flame direction has been obtained, the primary air pipe positi on should not be changed unless a definite reason (such as to combat a ring form ation or hot shell conditions) makes it desirable Page 86 of 98 h) To protect the primary air pipe from possible damage during a shutdown, a cer tain amount of primary air flow must be maintained until the temperature inside the kiln is low enough (approximately 600oF or 315oC) that the pipe cannot be da

maged. Upon power failure when primary air fan stops, the primary air pipe must be immediately removed from the burner hood. COMBUSTION What is combustion? Rapid combination of oxygen with fuel resulting into heat Fuels contains, Carbon Hydrogen Sulfur Oxygen Comes from Combustion Air Carbon + Oxygen = Carbon dioxide + heat Hydrogen + Oxygen = Water vapor + heat Sulfur + Oxygen = Sulfur dioxide + heat Proper Proportioning of Fuel, Oxygen and Heat Perfect combustion Combustion air = Neutral (stoichiometric) combustion air Deficiency of Air (Reducing Conditions) Incomplete combustion Heat released is low (4500 Btu vs. 14500 Btu per lb carbon) Unsafe operation (explosion in precipitator or anywhere in the system) Page 87 of 98 Excess of Air (Oxidizing Conditions) Complete combustion Flame temperature decreases with increasing air, lower fuel economy Recommended back-end oxygen is 1.0 to 1.5% Combustion Air + Fuel = Combustion Gases Combustion Air = Primary Air + Secondary Air + Leakage Combustion Gases: Carbon monoxide (CO) with incomplete combustion Carbon dioxide (CO2) with complete combustion Water vapor (H2O) Sulfur dioxide (SO2) Nitrogen (N2) from air Excess oxygen (O2) Good Combustion Requirements: Proper proportioning of fuel and air Thorough mixing of fuel and air Initial and sustained ignition of the mixture Mixing of Fuel and Air Good mixing is important for mixture to be uniform throughout Every particle of fuel must be in contact with an air particle Solids must be pulverized to increase surface area for mass transfer Liquids must be atomized (breaking up into tiny particles) to speed up evaporati on (resulting to vapors burn as gases) Process of starting combustion Can start at low temperatures, but may not be sustained Minimum ignition temperature required for sustained ignition Page 88 of 98 (Ignition continues without any external source of heat) At this point: Heat from Reaction > Heat Lost to Surroundings Fixed carbon:* 400 – 450oC or, 752 – 842oF Volatile Matter: 500 – 600oC or, 932 – 1112oF C & H (methane): 632oC or, 1170oF Coke: +/- 800oC or, 1472oF Fuel oil: 200 – 300oC or, 392 – 572oF * can be considered ignition temperature of coal Theoretical Flame Temperature: Tf = LHV / (NCA + 1) S Where Tf = Maximum (theoretical) flame (in oC or oF)

LHV = Fuel low heating value (in kg/kgf or Btu/lbf) NCA = Neutral combustion air (in kg/kgf or Btu/lbf) S = Specific heat of combustion gases (=/- 0.29) Typical Fuel Data: Fuel LHV Kg/kgf (Btu/lbf) NCA Theo. Max. Flame T oC (oF) Coal 6500 (11,700) 9.1 2460 (4460) Oil 9870 (17,770) 13.7 2480 (4500) Gas 11,500 (20,700) 16.6 2400 (4350) Influences and Impact on Flame Temperature Impact of Oxygen content of Kiln Gases on Flame Temperature (Figure #3) Oxygen 1% 5% Flame To 2465oC 1965oC Page 89 of 98 Impact of Secondary Air Temperature on Flame Temperature Sec. air To 420oC (770oF) 845oC (1553oF) 1093oC (2000oF) Flame To 2180oC (39560oF) 2445oC (4433oF) 2610oC (4730oF) HEAT TRANSFER IN A ROTARY KILN Radiation (Flame Zone) Flame/Gas by Material Flame/Gas by Kiln shell Very important because heat transfer x (Tf4 – Tm4) Conduction Wall to Material Chain/crosses to Material Convection Gas to Material Gas to Wall BURNER PIPES AND NOZZLES What is required from a burner? A stable flame with proper geometry Versatility Safety Parameters Affecting the Flame Page 90 of 98 Fuel characteristics Primary air and secondary air The burner design Key Parameters of Burner Design Number of circuits Primary air Quantity Ejection velocities Minimum velocity Back pressure Specific impulse Diameter Number of Air Circuits (Figure 1 to 6) Single Circuit Control is minimal High velocity requires high fan pressure Resul ts in more wear Two Circuits Swirl + high velocity transport air Additional control due to swirl High fan pressure, high wear rate Three Circuits Swirl + high velocity axial Low velocity transport air More versa tile Primary Air Quantity Page 91 of 98 Natural gas: 0 to 7% of total combustion air Liquids: 7 to 10% of total combustion air

Solid fuels: Firing system dependent Direct firing system: 30 to 35% of total combustion air Semi-direct firing: Mill exit air is 18 to 25% (moisture dependent) Air to burner can be controlled by diverting “Overflow” to kiln hood Indirect firing: 7 to 12% of total combustion air Theoretically, indirect firing is the ideal solution. Ejection Velocities Gaseous and liquid fuels (with atomizing fluid) Sonic range: 330 m/s (1083 ft/s) Solid fuels Single circuit: 50–80 m/s (164–263 ft/s) Multiple circuits: 80–170 m/s (262–558 ft/s) for axial 50–90 m/s (164–295 ft/s) for swirl 20–50 m/s (65–164 ft/s) for transport Minimum Velocities Required to prevent solid fuel accumulation, 20 m/s (66 ft/s) in transport line and in axial $ swirl annulus if these streams carry any fuel dust Knowing the minimum flow rates, the pipe sizes can be determined. Back Pressure Typical values for a three-circuit burner; 700 – 1000 mmH2O for axial air 150 – 600 mmH2O for swirl air 600 – 1000 mmH2O for transport air (up to 1200 mmH2O for modified three-circuit burner) Page 92 of 98 Specific Impulse Typically, 4 to 8 N/Gcal/h Definition Sp. impulse = Impulse (Newton) Heat input (Gcal/h) For Solid Fuel; Impulse = air stream mass flow rate (kg/s) x tip velocity (m/s) For Gaseous and Liquid (pneumatically atomized) Fuels; Impulse = (abP – c) S Where: P = pressure (bars) S = cross-section area (mm2) a,b,c are atomizing fluid dependent * 5 figures of burners to be attached at the above information. FUELS IN THE CEMENT INDUSTRY Solid Fuels: Coal Coal tailings Petroleum coke (fluid, delayed) Wood Tires Munic ipal waste, etc. Liquid Fuels: Oil (bunker C) Liquid waste Page 93 of 98 Coal slurry, etc. Gaseous Fuels: Natural gas (95% methane) Landfill gases, etc. Heating Value Quantity of heat generated from 1 unit (kg, lb, ton, m3, liter) of fuel Measured in kcal/kg, Btu/lb, MJ/ton, MJ/m3, kcal/liter Can be approximated from the fuel composition High Heating Value (HHV) vs. Low Heating Value (LHV) High (or gross) Heating Value Heat produced at constant volume by complete combustion of fuel, combustion prod uct condensed to liquid state, measured in the laboratory in an “oxygen bomb calor imeter”. Low (or net) Heating Value Calculated from HHV by subtracting the latent heat of vaporization The difference between HHV and LLV depends upon the hydrogen content of the fuel . LHV = HHV - 92.7 x % H2 (Btu/lb) Examples of HHV and LHV for Various Fuels

Fuel % H HHV Btu/lb LHV Btu/lb (% of HHV) Coal 5 12,000 11,540 (96%) Coke 4 14,000 13,630 (97%) Waste fuel 10 9,000 8,070 (90%) Fuel oil 10 19,000 18,070 (95%) Natural gas 25 23,300 20,680 (90%) Page 94 of 98 SOLID FUELS Coal, oil, gas and in recent years, petroleum coke are the main fuels used in ce ment kilns. Coals are judged on what is called an proximate analysis which tells the percent age moisture, volatile matter, fixed carbon, ash, sulfur, and heat value. Coal is very complicated in structure, containing carbon, hydrogen, oxygen, nitr ogen and sulfur in various stages of combinations. With the application of heat, these substances from various combustible gases ar e classed as volatile matter. It is the first constituent of the coal to be libe rated on heating. The carbon that remains after the volatile matter is driven off is called fixed carbon. Combustion is the chemical combination of oxygen with certain elements of the fu el to form compounds with the release of heat. See figure below. Every combustible substance has what is called an ignition temperature. This is the temperature to which it must be raised before chemical combinations with oxygen or combustion will take place. These combinations liberate definite amounts of heat depending on the elements e ntering into the combinations. The principal combustible elements in coal are carbon and hydrogen. Any sulfur p resent is also combustible, but is of minor importance from a heat standpoint. The chief non-combustible elements in coal are silica, alumina and iron which fo rm the ash. Page 95 of 98 Bomb Calorimeter The heat value of coal can be determined by using the bomb calorimeter. A precis e amount of dry coal is fired in an oxygen atmosphere in a sealed container whic h is immersed in a water bath. The change in temperature of the water is measure d and knowing the specific heat of water (1.0 Btu/lbm*oF) the heat content of th e coal is determined. Volatile Matter (VM) Portion of solid fuel liberated as gases and vapors, when it is heated in the ab sence of air. (result from thermal decomposition)

For good coal: VM = 30 – 35% For fluid coke: VM = 5 – 6% Combustion start to be difficult when VM < 15% Fixed Carbon (FC) Residue left after volatile matter is driven off. FC = 100 - (VM + Ash + Moisture) For bituminous coal: FC = 40 – 60% Coke: FC = 75 – 85% Ash Residue remaining after the fuel has been burnt. Composed of compounds of silicon, aluminum, iron and calcium Also some traces of Mg, Na, K and Ti. Proximate Analysis Determination of VM, FC, ash and moisture Used for quick, preliminary appraisal of solid fuel Ultimate Analysis Quantitative determination of moisture, C, H, S, O and N Page 96 of 98 DRYING, GRINDING AND FIRING SOLID FUELS Ball Mill or Roller Mills are used. Air from cooler / air heater / pre-heater exit is used for drying. The drying systems can be; (Figure # 1, 2, 3) Direct Semi-direct Indirect Comparison of fuel drying system Direct Semi-direct Indirect Simple operation Most difficult to operate Simple operation Relatively safe Safer than indirect Safety is most important Primary air is high (30-35%) All moisture to kiln Primary air is low but all moisture to kiln Primary air can be as low as desired (operation independent) Result in high heat consumption Heat penalty is lower than direct Good heat consumption Lowest capital cost Capital cost is in between direct and indirect Highest capital cost Liquid Fuels Essentially composed of C, H, and S Evaporation at 200-300oC or 572oF Atomization promotes evaporation Classified according to: Viscosity (measure of internal friction) Specific gravity Page 97 of 98 Heating value Gaseous Fuels Natural gas most commonly used (95% methane) No preparation required for firing Minimum ignition temperature (+/- 650oC or 1200oF) Very little primary air is required Injected at high pressure (i.e. high tip velocity) to promote turbulence Comparison of the Three Major Fuels Coal Oil Natural Gas