The Complete Organic Chemistry Worksheet

The Complete Organic Chemistry Worksheet The Complete Organic Chemistry Worksheet.doc

Name ________________________________ Date ___________________________ Period ___ 1.

Name the following hydrocarbons. CH3 CH3 a. CH3

CH2

CH2

CH3

CH

CH

CH3

e. CH3

CH

CH2

CH

CH

CH3

CH3 CH3

CH3

CH2

CH3 f. CH3

CH3

CH2

CH

C

CH3

CH

CH3 CH2

CH3

CH

g. CH3

CH3 c. CH3

C

CH

CH3

CH

CH2

CH3

CH3

CH2 CH3 CH2 d. CH3

CH2

C

CH2 CH2

CH2

2.

CH3

CH2

CH3 CH3

h. CH3

CH

CH

CH3

CH

CH3

CH3

CH3

Name the following hydrocarbons. CH3 a. CH3CH2CH2CHCH3

d. CH3CH2CHCH2CH3 CH2 CH3

CH3 b. CH3CHCH2CH3

CH3 c. CH3CHCHCH3 CH2CH3

CH3

CH3

e. CH3CHCH2CHCH3 CH3 f. CH3CHCHCH2CH3 CH3

CH3 CH2 g. CH3CHCH2CH3 CH2 CH3

CH

CH3

CH3 CH2 b. CH3

CH

h. CH3CHCHCH3 CH3

CH3

3.

Listed below are the condensed structural formulas or names of the nine isomers of heptane, C 7H16. Write the formula and name for each.

CH3 a. CH3CH2CH2CH2CH2CH2CH3 CH3

f. CH3CH2CHCH2CH2CH3

CH3

CH3

b. CH3CHCH2CHCH3

g. CH3CCH2CH2CH3 CH3

CH3 CH3 c. CH3C

CHCH3 h. 2-methylhexane

CH3

i. 3-eth l enta entan ne

4.

Name (use common and systematic for benzene if appropriate) the compounds represented by the following formulas. a. CH3CH

b.

CHCH2CH3 CH3

d.

CH3

5.

Draw the structural formulas for the following: a. 3-heptyne

b.

cyclopentene

c.

3-phenyl-2,2-dimethylhexane

d.

1,3-butadiene

e.

1-ethyl-2-methylbezene

f.

2,4-dimethyl-2-pentene

e.

c.

C

CH

f.

CH

CCH3

6.

Listed below are the condensed condensed structural formulas or the names names for the eight isomers isomers of C 5H11Cl.Write either formula and the name for each.

Cl a. CH3CH2CH2CH2CH2Cl

e. CH3CH2CHCH2CH3

CH3 Cl

CH3

CHCH3

b. CH3CHCH2CH2Cl

f. CH3CH

c. 2-chloropentane d. 2-chloro-2-methylbutane

g. 1-chloro-2-methylbutane h. 1-chloro-2, 2-dimethylpropane

7. Name the following compounds. CH3

CH3

h. CH3CHCH

a. CH3CH2CCH2CH2Br CH2

CH3 CH3

CH3

i.CH i. CH3C

CH3 b. CH2

CHCHCH

CCH2CH3 CH3 CH3

CH2

CH3 c. CH2

CHCH3

CHCCH3

 j. CH

2

CCH2C CH3 CH3

k.CH k. CH2

C

C CH3

CH3

Br l.

d. C6H5Cl e. CH3CH CHCH2CH3 CH3 f. CH3C

CHCH3

g. CH3CH2CH 8.

CH2

Draw structural formulas for the following. a. 3-heptene

b.

2-methylnapthalene

c.

trichloromethane

d.

2-chloro-3-phenylhexane

e.

1,3-cyclopentadiene

f.

toluene (methylbenzene)

g.

1,4-dibromobenzene

h.

2-bromo-3-methyl-2-butene

CH2

Br

CH

CHCH3

9.

Write structural formulas for the following compounds. a. 2-chlorobutane

b.

2-butene

c.

2-ethyl-3-methyl-1-butanol

d.

3,3-dimethylbutanoic acid

e.

2,5,5-trimethyl-4-heptone

f.

1,8-nonadiyne

g.

1,3-diiodobenzene

h.

ethoxybenzene

i.

1-butanol

 j.

3-methyl-2-pentene

k.

2-ethyl-4-methylpentanal

l.

3-ethyl-2,4-dimethyl-3-hexanol

5-chloro-3-ethyl-2-methylheptanoic acid m. 5-chloro-3-ethyl-2-methylheptanoic

n.

2-phenylbutane

o.

7-bromo-2-naphthol

p.

4-bromobenzoic acid

10. Name the following organic compounds. O a. CH3CH

CHCH2CH3

CH3

d. CH3CH2CH2C H

OH

CH3

O

e. CH3CCH2CH2CH2OH

b. CH3CH2CCHCH3

CH3

CH3 f. CH2 c. CH3CHCH

CH2

CH3 CHCH3

CHCCH OH

CH3

11. Name the following organic compounds. CH3 a. CH3CH2CHCH2Cl

CH3

e. CH3CCH2CH3

OH

CH3 b. CH3C

CHCH2Br

f. CH3CH2C

CHCH3

Br

CH3 CH3

g. CH3(CH2)2CH2NH2 c.

Br

d. CH3CH2CHCH2CH3

Cl

h. H2N

C

CH2CH3

O

12. Each of the following formulas can be w ritten as two compounds with different functional groups. Write the structural formulas, name the compounds, and identify the functional groups. a. C2H6O b. C3H6O c. C5H10

13. Draw structural formulas for the following. a. Ethanal

b.

2-butanone

c.

2-methyl-2-propanol

d.

ethanoic acid

e.

trimethanamine

f.

propane

g.

2-pentyne

h.

cyclobutane

i.

cyclohexanamine

 j.

2-aminopentane

k.

2,4-nitrophenol

l.

1,3-nitrobenzoic acid

m. ethanenitrile

n.

propenoic acid

14. Draw and name the five structural isomers of hexane (C 6H14)

15. Draw the structural formula for each of the following. a. 2-Methylpentane

b.

2,2,4-Trimethylpentane, also called

isooctane .

c.

2-tert-Butylpentane

d.

The name given in part c is incorrect. Give the correct name for this hydrocarbon.

16. Name each of the following: a. CH3

CH3

CH

C

CH3

CH3

This compound is the reference for octane ratings for gasoline.

b.

CH3 CH2CH2CH

CH2CH2CH3

CH3 CH3

C

CH3

c.

CH3

CH2

CH2

CH

CH3

CH2

CH3

17. Name each of the following alkenes. CH3

a.

CH2

CH

CH2

b.

CH3

C

CH3

CH3

c.

CH3 CH3CH2CH

CH

CH

CH CH3

CH

CH3

CH2CH2CHCH2CH3

CH2CH3

18. Give the structure for each of the following: a.

3-hexene

b.

2,4-Heptadiene

c.

2-Methyl-3-octene

19. Give the structure for each of the following aromatic hydrocarbons. a.

o-Ethyltoluene

b.

p-Di-tert -butylbenzene -butylbenzene

c.

m-Diethylbenzene

d.

1-Phenyl-2-butene

20. Name each of the following: a.

CH2

Cl

CH2

CH

Cl

b.

CH3CH2CH2CC CCll3

CH3

CH3 CCl

c. CH3

CH

CH CH2CH3

Cl

CH3