SI EmissionMeasurement en V1!0!2012-03 WEB
Short Description
Solutii complete de masurare a emisiilor . CEMS...
Description
Complete Emission Measurement Technology Technology from SICK
Single-source technologies and solutions for future-oriented emissions monitoring
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Complete Emission Measurement Technology from SICK
Emission monitoring from SICK: global solutions for a globally relevant topic Effective climate protection protection as well as the maintenance and restoration of a clean environment environment are among the greatest challenges facing today's global community. community. In addition to efficient energy management, this primarily means effectively reducing pollutants and environmental hard, or better still, preventing them. This must be implemented in all emission-relevant emission-relevant industries and regions – especially those with intensive energy requirements requirements as well as densely populated centers worldwide. The goal of reducing air pollution to the lowest technically feasible level is primarily achieved achieved with state of the art waste gas purification processes. Emissions must be determined both in terms of quantity and quality as well as minimized in a targeted manner, manner, as far as possible. This can be realized with proactive planning of industrial plants as well as the continuous monitoring of emissions. Continuous emission measurement is used to determine the emission behavior of industrial plants. SICK is the only manufacturer worldwide in this area with decades of experience experience offering a complete range of emission measurement technology. We use proven measurement principles and innovative technologies to ensure future-oriented solutions – even under ever increasing environmental environmental and safety-related safety-related requirements. requirements. Make your significant contribution to an intact environment environment for current and future generations with complete emission measurement technology from SICK.
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Convincing Performance Industries and Solutions Technologies and Measuring Principles Systems and Project Engineering Connectivity Services Requirements of Emission Measurement Systems Gas Analyzers
6 8 10 12 14 16 18
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PS_header1_small_blue Company
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We deliver Sensor Intelligence. SICK sensor solutions for industrial automation are the result of exceptional dedication and experience. From development all the way to service: The people at SICK are
committed to investing all their expertise in providing with the very best sensors and system solutions possible.
A company with a culture of success Approximately 5,000 people are on staff, with products and
fosters an optimum work-life balance, thus attracting the best
services available to help SICK sensor technology users increase their productivity and reduce their costs. Founded
employees from all over the world. SICK is one of the best employers – we have been among the winners of the presti-
in 1946 and headquartered in Waldkirch, Germany, SICK is a global sensor specialist with more than 50 subsidiaries and
gious German “Great Place to Work” award for many years in succession.
representations worldwide. Our exemplary corporate culture
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PS_header2_small_blue
PS_header1_small_blue Company
Innovation for the leading edge
A corporate culture for sustainable excellence
SICK sensor systems simplify and optimize processes and allow
SICK is backed by a holistic, homogeneous corporate culture.
for sustainable production. SICK operates thirteen research
We are an independent company. And our sensor technology is
and development centers all over the world. Co-designed with
open to all system environments. The power of innovation has
customers and universities, our innovative sensor products and
made SICK one of the technology and market leader – sensor
solutions are made to give a decisive edge. With an impressive
technology that is successful in the long term.
track record of innovation, we take the key parameters of modern production to new levels: reliable process control, safety of people and environmental protection.
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PS_header1_small_blue Industries and Solutions
Industry
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Requirements
Solutions from SICK
Power plants Various requirements apply to power plants, depending on the fuels used, for example, coal, oil or gas. The following pollutants must be continuously measured, depending on applicable local environmental regulations: CO, NOx SO2 and dust as well as reference parameters such as temperature, temperature, O2 (and H2O, where applicable).
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Various requirements apply depending on the type of incineration plant, for example, household waste, industrial waste or hazardous waste. Pollutants such as HCl, HF, HF, NOx, SO2, VOC and dust load as well as O2 and/ or H2O must be continuously measured in accordance with local environmental stipulations. Increasingly, the additional parameter of total mercury Hg must also be detected.
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Plants for producing cement, as well as
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CO, NOx and SO2 as well as O2 /H2O
• In-situ: GM32, GM35, ZIRKOR302
• Cold extractive: GMS800, SIDOR
• Alternative as complete solution: MKAS/MAC800
• Dust measurement: DUSTHUNTER • Volume ow measurement: FLOWSIC100 • Data acquisition system: MEAC2000
Waste incineration HCl, HF, SO2, CO, NOx and O2 /H2O
• In-situ: GM700
• Hot extractive: MCS100E, MCS100FT (FTIR)
• Hg measurement: MERCEM300Z • Dust measurement: DUSTHUNTER • Volume ow measurement: FLOWSIC100 • Data acquisition system: MEAC2000
Cement production HCl, HF, SO2, CO, NOx, VOC and O2 /H2O
ring and crushing lime. Flue gas pollutants
• Hot extractive:
must be continuously measured depending on local environmental regulations, preferably NOx SO2 and dust as well as reference parameters such as O2 and/or H2O When burring alternative fuels it is also necessary to measure additional components such as HCl, HF, Hg and VOC.
• Hg measurement: MERCEM300Z • VOC: GMS810-FIDOR • Dust measurement: DUSTHUNTER • Volume ow measurement: FLOWSIC100 • Data acquisition system: MEAC2000
MCS100E, MCS100FT (FTIR)
Chemicals, oil and gas Chemical parks generally include a fossil-
fuel red power plant, which generates both electricity as well as steam. Gases produced during the process are exploited thermally and must be monitored accordingly. Parts of the plant may include explosion proof areas.
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VOC, CO, NOx, SO2 and O2 /H2O
• Cold extractive: GMS800 • Hot extractive: MCS100E, MCS100FT • VOC: GMS810-FIDOR • Dust measurement: DUSTHUNTER • Volume ow measurement: FLOWSIC100 • Explosion protected version: GMS815, GMS820
• Data acquisition system: MEAC2000
Metals and steel production Plants for calcination, melting or sintering ores as well as the production of non-ferrous metals. These areas are subject to harsh
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CO, CO2, SO2, NOx, HCl and O2
• In-situ: GM32, GM35, ZIRKOR302
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PS_header1_small_blue Industries and Solutions
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Industry
Requirements
Solutions from SICK
Glass and Ceramics Systems for manufacturing glass and glass
bers, for melting ceramic materials and ring
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CO, NOx and SO2 as well as O2 /H2O
• In-situ:
ceramic products.
GM32, GM35, ZIRKOR302
Typical Typical requirements include ne silicates and borates with high abrasion potential in the ue
• Special in-situ sensors, which are not
gases.
• Dust measurement: DUSTHUNTER • Volume ow measurement: F100 • Data acquisition system: MEAC2000
subject to abrasion
Pulp and Paper So called TRS emissions are created during the kraft pulp production process, primarily in lime kilns and the liquor combustion process. They are strictly regulated by authorities due to the associated intensive odor contamination. For this reason, concentrations of hydrogen
sulde, methylmercaptan, dimethyl-sulde and dimethyl-di-sulde or the sum parameter of TRS
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SO2, H2S, TRS: methylmercaptan, methylmercaptan,
dimethyl-sulde and dimethyl-di-sulde • In-situ: GM32
• Dust measurement: DUSTHUNTER • Volume ow measurement: F100 Data acquisition system: MEAC2000
must be continuously measured.
Maritime On-board systems on cargo and passenger ships for monitoring smoke gas and monitoring of exhaust gas purication systems. Typically these systems are subject to increased vibration. Especially the components NOx, SO2, CO2, O2 are measured and the denitrication plants monitored. Special approvals such as
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NOx, SO2, CO2, O2
• Hot extractive: MCS100E (optional with sample point switching)
Germanischer Lloyd type approval and ef fective sample point switching are essential requirements.
Greenhouse gases The greenhouse gas CO2 is responsible for 75% of global climate change. However, CO2, CH4 and N2O present varying degrees of hazard potential.
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CO2, N2O and CH4
• In-situ: GM35 in combination with
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Technologies and Measuring Principles
Analysis technology – made in Germany SICK has optimal customization solutions for an extremely wide ranging spectrum of plant conditions and for solving complex measurement tasks. This includes in-situ and extractive measurement technology based on powerful measurement principles both for individual sampling points as well as for complete systems.
In-situ gas analysis Innovative in-situ measurement technology for direct installation in devices at the respective measurement site. The analyzers measure in-situ, i.e. directly at the measurement site under system conditions and are available as a device solution. They are characterized primarily by their minimal maintenance requirements and extremely short response times. SICK's in-situ analyzers are available in two different versions:
• The cross-duct version for representative measured results across the entire duct diameter • The measuring probe version, optimized for
singlesided installation allowing simple integration into an extremely varied range of system conditions. For example, overpressure, wet gases and extremely high measured gas concentrations and dust loads.
Extractive gas analysis SICK's extractive gas analyzers can be used in a broad range of applications. They work according to extractive principles, in other words, a partial gas flow is extracted from the gas duct and is fed to the analyzer module under constant conditions. Everything is optimally designed for the measurement task, from gas sampling via selected sensors and optimized gas conditioning, through to the selection of numerous analyzer modules.
Benets: • Continuous and direct measurement, no sampling • The cross-duct version for representative measured results or measuring probe version for simple installation • GMP measuring probe with open measuring gap or GPP gas diffusion probe
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Technologies and Measuring Principles
Dust measurement via laserbased back-scattering technology
UV resonance absorption spec troscopy (UVRAS)
Atom-absorption spectroscopy based on the Zeeman effect
This measurement principle developed by SICK based on back-scatterback-scattering of light enables the measurement of even minute concentrations of dust. A laser diode irradiates the dust particles in the measured medium with modulated light in the visible spectrum. The light scattered by the particles is picked up by a highly sensitive detector, which then feeds the measured signal to an evaluation unit for processing. The compensation of background radiation and ambient light, automatic testing of zero point and reference point as well as a soiling check mean the system delivers stable and reproducible measurement results. Sophisticated measurement tasks, for example, in hot or aggressive measurement media are therefore therefore no longer a problem.
SICK uses cold-extractive cold-extractive process
An Hg-discharge lamp emits an element-specific element-specific spectrum, which enables an extremely sensitive level of mercury measurement. A magnetic field applied around the discharge lamp creates an additional reference reference value wavelength (the Zeeman effect), which lies outside of the absorption range of Hg atoms. This means that cross sensitivities and lamp aging or contamination is optimally compensated for. A high temperature converter converts the bound Hg at approximately 1000 °C into elemental Hg. The advantages of this are that no chemicals or catalyzes are required, required, maintenance is minimal and there are no moving parts. The patented direct Hg measurement system makes the MERCEM300Z into a reference device for continuous mercury analysis.
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photometers photometers equipped with the UV resonance absorption measurement spectroscopy spectroscopy measurement principle
(UVRAS). The system makes use of the fact that certain gases exhibit specific absorption characteristics in the ultraviolet spectrum. In order to achieve this, the measured gas is irradiated with ultraviolet light. The concentration o f gas components can then be determined through selective use of the wavelength and measurement of the absorption. In this manner the analyzer is able to measure gas concentrations of, for example, NO, NO 2, NH3, SO2 and H2S by means of interference filter correlation (IFC).
The gas filter correlation (UVRAS) is used for extremely precise measurement of NO.
DUSTHUNTER product family, Page 25
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GMS800, Page 21
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MERCEM300Z, Page 21 Triple reector
Detectors Filter unit
UV lamp
Sender/receiver unit
Measuring cell
Cell
Measuring volumes
Emitted beam
Reference
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Systems and Project Engineering
Everything from stand-alone devices through to complete analyzer systems SICK is able to supply application-oriented application-oriented applications through a combination of its extensive extensive product range of analyzers and comprehensive comprehensive experience. In addition to the tailor-made designs, we also offer a range of cost-optimized standard solutions, such as the standardized 19" rack or system housing, compact plug-and-play analyzer systems as well as the MAC800 modular complete system for all emission-typical measurement tasks. Beyond system components, we also engineer complete complete gas analyzer systems, for example, ready-to-use analyzer containers including the entire peripheral equipment.
Devices
Compact systems
Complete systems
The GMS800 product family with its standardized 19” housing or optimized system housings for cabinet installation are available for efficient and cost-effective system integration.
Compact analyzer systems with extremely straightforward handling, trouble-free installation and commissioning on site with very low maintenance requirements. Additionally equipped with modern communication options, such as Ethernet, Modbus or GPRS modem, these systems are suitable for remote monitoring of the entire emission monitoring system – and are thereby pre-equipped for future requirements.
These modular complete systems with high-quality serial modules and components can be optimized to meet specific requirements thanks to their customizable design.
GMS810 19" rack housing
GMS830 system integration housing
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Systems and Project Engineering
Custom planning and engineering Planning and engineering at SICK is combined with decades of experience in the field of emissions monitoring monitoring of all kinds. Regardless of whether the application is in a power plants or under difficult conditions in a hazardous area of a refinery – SICK's engineers plan and design tailor-made solutions suitable for your specific requirements using the latest CAD systems. In doing so, not only is the latest technology in analyzers and sample conditioning deployed, but also state-of-the-art communications concepts. All products are designed in accordance with the applicable international and national standards. An experienced project management team and worldwide service organization is available to the customer not only for commissioning, commissioning, but also to ensure reliable and sustained operation of the system.
Ready-to-use analyzer containers Tailor-made designs including the complete range of peripheral equipment with component application consulting and comprehensive comprehensive project management.
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Connectivity – always well connected with SICK
Current data via standardized communication communication SICK's products come with a standardized data communications system for digital controllers, in order that all data, measured values and parameters are available at all times and can be conveniently conveniently visualized and processed. Moreover, Moreover, this is available cross-system from your own system network. As a result, you are able to elegantly access installations in remote areas.
Signals, interfaces and protocols • Analog and digital signals • Interfaces: • Serial interfaces such as RS-232/RS-485/RS-422 • Ethernet network • OPC • Protocols: • Modbus or Modbus TCP
Data acquisition and processing systems
OPC
Modbus
I/O
Ethernet
Ethernet/RS-485
analog, digital
Analyzers and Systems
Operation The operation of analyzers and systems is undertaken:
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Connectivity – always well connected with SICK Operational management level
Measuring systems t e n r e h t E
Dust
Operational monitoring
OPC server
Flow
ERP-system, plant management system
Controller
Temperature, Temperature, pressure Ethernet s r e t e m a r a p e c n e r e f e R
Gas components In-situ gas analysis
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PS_header1_small_blue Services and Consulting – always well advised with SICK
Service for all your plant and measurement system requirements Analyzers and measurement systems supply monitoring and control-relevant information and protect people and systems. When optimally integrated and maintained, these components and systems guarantee safe processes, constant product quality and protect people and the environment.
From the outset and over many years, SICK LifeTime Services offer suitable services for all aspects of your measurement systems and plants: from planning and conception, commissioning and operation through to conversions and upgrades.
Over 60 years of experience in the eld and industrial expertise makes us a competent partner for the specic requirements requirements of our customers.
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Requirements of Emission Measurement Requirements Systems Selection of a continuous emission measurement system The selection of a continuous emission measurement system
Production industries such as the power-supply power-supply industry or
(CEMS) is not a simple process. General inquiries for the low-
the cement industry are generally subject to dened regula-
est initial investment can work out to be the most expensive
tions and laws governing the reduction of emissions. They
solution when viewed over the entire operational lifetime.
are able to select from a broad range of continuous emission
Unfortunately there is no generally-applicable rule that can be applied, as individual requirements relating to the respec-
measurement systems. The operational lifetime of a CEMS is typically more than 10 years. The operating costs can amount
tive industrial plant can have a major impact on the suitability and all important costs of the CEMS technology under
to up to three times the cost of the initial investment, investment, depending on the selected measurement measurement technology (in-situ, cold or
consideration.
hot extractive) and the mix of measurement measurement principles used.
10 steps to a suitable emission measurement system
1
What process parameters and gas components are to be monitored in the system and what measuring ranges are required?
4
Have the operating conditions on-site been clarifed?
Aggressive gas components can inuence the opera -
The number and type of components to be monitored and
tion and reliability of CEMS systems when using alternative fuels.
recorded in accordance with the requirements of environmental authorities determines the selection of a suitable CEMS
•
system.
•
•
What fuel is currently used or is to be deployed in the near future? When using alternative fuels, does the system meet the strin-
Is a complete list of measuring components components and param-
gent thermal requirements for monitoring waste treatment
eters as well as the required measuring ranges and tolerances available?
processes?
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Requirements Require ments of Emission Measurement Systems
What are the requirements for operation
Measuring
Measuring
Measured
I
it
E t
ti
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Gas Analyzers
In-situ gas analyzers
GM32
GM35
Direct measurement of aggressive gases
Efcient control of combustion processes and dehydration plants
Technical data Measuring principle Measuring components TUV-approved measured values max. number of measured
UV spectroscopy
Gas lter correlation, interference lter correlation
NH3, NO, NO2, SO2
CO, CO2, H2O
NO, SO2
CO, CO2, H2O
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Gas Analyzers
GM700
GM901
ZIRKOR302
Greater efciency of process analysis – even under difcult conditions
Reliable CO measurement for emission monitoring and process control
Accurate and rapid oxygen measurement for optimization of industrial processes
Diode laser spectroscopy (TDLS)
Gas lter correlation
zirconium dioxide sensor
HCl, HF, NH3, O2
CO
O2
HF
–
O2
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Gas Analyzers
Extractive Gas Analyzers
Technical data Measuring principle
GMS800
SIDOR
Tailor-made Tailor-made gas analysis for process and emission monitoring
Sets standards for extractive photometers photometers
NDUV-spectroscopy, NDUV-spectroscopy, NDIR-spectroscopy, NDIR-spectroscopy, interference lter correlation, paramagnetic dumbbell principle,
NDIR-spectroscopy, NDIR-spectroscopy, paramagnetic dumbbell principle, electromagnetic cell
electromagnetic cell, thermal conductivity measure-
ment, ame ionization detection
Measuring components
Ar, SO2, CHClF2, CHCl2F, CH2Cl2, CH4, CH3OH, CO,
CH4, CO, CO2, NO, N2O, O2, SO2
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Gas Analyzers
MCS100FT
MERCEM300Z
FID3006
Emission monitoring – everything under control with advanced, high-end technology
Innovative measurement of mercury in
ue gases
Portable analyzer for measurement of volatile organic components
FTIR-spectroscopy, FTIR-spectroscopy, zirconium dioxide sensor,
Zeeman atom absorption spectroscopy
Flame ionization detection
Hg, Hg compounds, Hg total
Corg
ame ionization detection
CH4, CO, CO2, HCl, HF, H2O, NH3, NO, NO2,
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Analyzer systems
Analyzer Systems
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Analyzer systems
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Product family overview
Dust Measuring Devices
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Dustow Gas Measuring measuring Devices devices
Volume Flow Measuring Devices
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Data Acquisition Systems
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