ResoNET 2012 Sample Test Paper

IIT-JEE AIPMT AIEEE OLYMPIADS KVPY NTSE SAT

Sample Test Papers (Resonance National Entrance Test : ResoNET - 2012) For Yearlong Classroom Contact Programmes (YCCPs) : IIT-JEE Division

Practice, Persistence and Performance

For Class - X, XI, XII Academic Session : 2012-13

STPFXII1213

INDEX S. No. 1

2 3 4 5

6

7

8

9

10

11

Content

Sample Test Paper (STP) For ResoNET-2012 Eligibility

How to Prepare for the Resonance National Entrance Test (ResoNET)-2012: N.A. List of reference books Resoonance Support Material to Prepare for the Resonance National Entrance Test N.A. (ResoNET)-2012 General Instructions for the Examination N.A. Hall Syllabus for ResoNET-2012 N.A. Sample Test Paper- I (STP-I): Test Paper Class-X Appearing/ Passed students (Moving from Class-X to Class-XI) Class-X Appearing/ Passed Sample Test Paper-I (STP-I) : Answer students (Moving from Key, Hints & Solution Class-X to Class-XI) Sample Test Paper-II (STP-II): Test Paper Class-XI Appearing / Passed students (Moving from Class-XI to Class-XII) Class-XI Appearing / Sample Test Paper-II (STP-II) : Answer Passed students (Moving Key, Hints & Solution from Class-XI to Class-XII) Class-XII Appearing / Sample Test Paper-III (STP-III) : Test Passed students (Moving Paper from Class-XII to ClassClass-XII Appearing / Sample Test Paper-III (STP-III) : Answer XIII) Passed students (Moving from Class-XII to ClassSample ORS Answer Sheet for Resonance XIII) National Entrance Test (ResoNET)-2012 N.A.

Key, Hints & Solution

Course Applied

Target

Page No.

N.A.

ResoNET 2012

1

N.A.

ResoNET 2012

2

N.A.

ResoNET 2012

3

N.A.

ResoNET 2012

4

VIKAAS (JA) & VIPUL (JB)

IIT–JEE 2014

9

VIKAAS (JA) & VIPUL (JB)

IIT–JEE 2014

20

VISHWAAS (JF)

IIT–JEE 2013

27

VISHWAAS (JF)

IIT–JEE 2013

42

VISHESH (JD) & VIJAY (JR)

IIT–JEE 2013

50

VISHESH (JD) & VIJAY (JR)

IIT–JEE 2013

64

N.A.

ResoNET 2012

75

The Sample Test Papers (STPs) are only for reference and guidance. The sample papers given in the booklet are actually the papers of previous year's ResoNET conducted by Resonance for its various courses. Note : Resonance reserves the right to change the pattern of selection test (ResoNET). Pervious year papers do not guarantee that the papers for this year selection test will be on the same pattern. However, the syllabus of the test paper will be equivalent to the syllabus of qualifying school/board examination and as given on page no. 4.

HOW TO PREPARE FOR THE RESONANCE NATIONAL ENTRANCE TEST (ResoNET) - 2012 

For Class-X appearing / passed students (Class-X to Class-XI Moving) : Study thoroughly the books of Science (Physics & Chemistry) and Maths of Classes IX & X. (NCERT & Respective Board)



For Class-XI appearing / passed students (Class-XI to Class-XII Moving): 1. Study thoroughly the books of Physics, Chemistry and Maths of Class XI (Respective Board). 2. Refer to the following books (only Class-XI syllabus) to increase the level of competence:  Physics : Concepts of Physics by H.C. Verma Vol. I & II  Chemistry : NCERT Books  Maths : Higher Algebra By Hall & Knight; Co-ordinate Geometry By S.L. Loney ; Plane Trigonometry By S.L. Loney



For Class-XII appearing / passed students (Class-XII to Class-XIII Moving) : 1. Study thoroughly the books of Physics, Chemistry and Maths of Classes XI & XII (Respective Board). 2. Refer to the following books (Class-XI & Class-XII syllabus) to increase the level of competence :  Physics : Concepts of Physics by H.C. Verma Vol-I & II  Chemistry : Physical Chemistry By R.K. Gupta, Organic Chemistry By Morrison & Boyd, Organic Chemistry By I. L. Finar, Inorganic Chemistry By J.D. Lee, Objective Chemistry By Dr. P. Bahadur  Maths : Higher Algebra By Hall & Knight; Co-ordinate Geometry By S.L. Loney; Plane Trigonometry By S.L. Loney, Differential Calculus By G.N. Berman; Integral Calculus By Shanti Narayan; Vector Algebra By Shanti Narayan ; MCQ By A Das Gupta.

 Copyright reserved 2012-13. All rights reserved. Any photocopying, publishing or reproduction of full or any part of this material is strictly prohibited. This material belongs to only the applicants of RESONANCE for its various Selection Tests (ResoNET) to be conducted for admission in Academic Session 2012-13. Any sale/resale of this material is punishable under law. Subject to Kota Jurisdiction only.

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For More Practice of RESONANCE NATIONAL ENTRANCE TEST (ResoNET) - 2012

Resonance Practice Test Papers (PTPs) To support the preparation of ResoNET; Resonance Practice Test Papers (PTPs) of last few years with Answer Key, Hints & Solutions are available on demand. Following Sets of Practice Test Papers (PTPs), in hard copy, are available with us : S. No.

PTP Set

1

Set-A

10 Papers Set (PTPs)

2

Set-B

3

Set-C

Content

Eligibility

Course (Code)

Target

Remark

Class-X Appearing/Passed students

VIKAAS (JA) & VIPUL (JB)

IIT-JEE 2014

Answer Key, Hints & Solutions

10 Papers Set (PTPs)

Class-XI Appearing/Passed students

VISHWAAS (JF)

IIT-JEE 2013

Answer Key, Hints & Solutions

10 Papers Set (PTPs)

Class-XII Appearing Passed students

VISHESH (JD) & VIJAY (JR)

IIT-JEE 2013

Answer Key, Hints & Solutions

Interested students may collect the PTPs from Resonance Study Centres or Corporate Office at Kota (at Plot No. A-46, A-52, Near City Mall, Jhalawar Road, Reception) by paying an additional fees of Rs.300/- only per set. Any of the above Practice Test Papers (PTPs) sets may be procured through post / courier from 'Resonance Eduventures Pvt Ltd' by sending a Bank Demand Draft (DD) of Rs. 300/- in favour of 'Resonance' and payable at Kota. A student may send the request application on plain paper along with prerequisite fees to the institute to collect any of the sets of Practice Test Papers (PTPs). Please, mention clearly your name and Roll Number (Application Form No.) on the back of the DD and which set of Practice Test Papers (Set A, B or C) is required by you in the request application.

ResoNET Online Practice Test Papers (OPTPs) To support the preparation of ResoNET; interested students may practice the ResoNET Test Papers online through ResoNET Online Practice Test Papers (OPTPs) on Resonance Website: http://elpd.resonance.ac.in Students can buy these Online Test papers at http://elpd.resonance.ac.in S. No.

Content

Eligibility

Course Code

Target

Fee(Taxes included)

1

3 Tests (OPTPs)

Class-X Appearing/Passed students

VIKAAS (JA) & VIPUL (JB)

IIT-JEE 2014

Rs. 300/-

2

6 Tests (OPTPs)

Class-X Appearing/Passed students

VIKAAS (JA) & VIPUL (JB)

IIT-JEE 2014

Rs. 500/-

3

3 Tests (OPTPs)

Class-XI Appearing/Passed students

VISHWAAS (JF)

IIT-JEE 2013

Rs. 300/-

4

6 Tests (OPTPs)

Class-XI Appearing/Passed students

VISHWAAS (JF)

IIT-JEE 2013

Rs. 500/-

5

3 Tests (OPTPs)

Class-XII Appearing/Passed students

VISHESH (JD) & VIJAY (JR)

IIT-JEE 2013

Rs. 300/-

6

6 Tests (OPTPs)

Class-XII Appearing/Passed students

VISHESH (JD) & VIJAY (JR)

IIT-JEE 2013

Rs. 500/-

ResoNET Prepratory Guide (RPG) (Only for Class X to XI moving students) To support the preparation of ResoNET; interested students (only for Class X to XI moving students) may study, learn, understand and strengthen the fundamentals of Class IX & X through ResoNET Prepratory Guide (RPG). The salient features of RPG are as follows : 1. Brief theory of ResoNET syllabus (for Class X to XI moving students). 2. Solved and Unsolved illustrations / examples. 3. Selected questions for practice. Interested students may collect the RPG from Resonance Study Centres or Corporate Office at Kota (at Plot No. A-46, A-52, Near City Mall, Jhalawar Road, Reception) by paying an additional fees of Rs.300/- only. The RPG may also be procured through post / courier from 'Resonance Eduventures Pvt Ltd' by sending a Bank Demand Draft (DD) of Rs. 300/- in favour of 'Resonance' and payable at Kota. A student may send the request application on plain paper along with prerequisite fees to the institute to collect the RPG. Please, mention clearly your name and Roll Number (Application Form No.) and ResNET Prepratory Guide (RPG) on the back of the DD.

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GENERAL INSTRUCTIONS IN THE EXAMINATION HALL (ijh{kk Hkou d sfy , l kekU; funs Z'k) Note: The student should consider the following instructions to be written on the front page of the test paper of ResoNET to be made available in the examination hall. 1.

This booklet is your Question Paper. ¼;g

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2.

The Question Paper Code is printed on the top right corner of this sheet. ¼iz 'u&i=k d ksM

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Blank papers, clip boards, log tables, slide rule, calculators, mobile or any other electronic gadgets in any form are not allowed to be used. ¼[kky h d kxt ] fDy i cks M Z] y ?kqx.kd l kj.kh] Ly kbM

: y ] d SYd qy sVj] eksckby ;k v U; fd l h by SDVªWkfud mid j.k d sfd l h Hkh : i esami;ksx d h v kK k ughagS½ 4.

Write your Name & Application Form Number in the space provided in the bottom of this booklet. (bl i` "B d suhpsfn;sx;sfjDr LFkku esav iuk uke o v kosnu Q kWeZl a[;k v o'; Hkjsa½

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Before answering the paper, fill up the required details in the blank space provided in the Objective Response Sheet (ORS). (iz 'u&i=k gy d jusl sigy s] ORS&'khV esafn;sx;sfjDr LFkkuksaesaiwN sx;s

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Do not forget to mention your paper code and Application Form Number neatly and clearly in the blank space provided in the Objective Response Sheet (ORS) / Answer Sheet. ¼mÙkj&iq fLrd k

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No rough sheets will be provided by the invigilators. All the rough work is to be done in the blank space provided in the question paper. ¼fujh{kd d s}kjkd ks bZjQ 'khV ughanht k;sxhA jQ d k;Ziz'u&i=k

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No query related to question paper of any type is to be put to the invigilator.

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Question Paper

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Marks distribution of questions is as follows.

Part - I Part - II Part - III (Mathematics) (Physics) (Chemistry) 1 to 15

30 to 39

51 to 59

16 to 19

40 to 43

60 to 61

20 to 28

44 to 49

62 to 64

29

50

65

¼iz'uksad sizkIrkad ksd k fooj.k fuEu izd kj l sgSA½ Type

Only one correct

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Name : _________________________________

Marks to be awarded Correct

Wrong

Blank

3

-1

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4

0

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4

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6 [1, 2, 3, 6]

0

0

Application Form Number : _______________

Note: The above instructions are for reference purpose only. The actual instructions in the Test Paper of ResoNET in the examination hall may vary. Page - 3

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Syllabus of ResoNET-2012 CLASS- X (CHEMISTRY) Basic : Cooling by evaporation. Absorption of heat. All things accupy space, possess mass. Definition of matter ; Elementary idea about bonding. Solid, liquid and gas : characteristics-shape, volume, density; change of state - melting, freezing, evaporation, condensation, sublimation. Elements, compounds and mixtures: Heterogeneous and homogeneous mixtures; Colloids and suspension. Mole concept: Equivalence - that x grams of A is chemically not equal to x grams of B; Partical nature, basic units: atoms and molecules; Law of constant proportions; Atomic and molecular masses; Relationship of mole to mass of the particles and numbers; Valency; Chemical formulae of common compounds. Atomic structure: Atoms are made up of smaller particles: electrons, protons, and neutrons. These smaller particles are present in all the atoms but their numbers vary in different atoms. Isotopes and isobars. Gradations in properties: Mendeleev periodic table. Acids, bases and salts: General properties, examples and uses. Types of chemical reactions : Combination, decomposition, displacement, double displacement, precipitation, neutralisation, oxidation and reduction in terms of gain and loss of oxygen and hydrogen. Extractive metallurgy : Properties of common metals ; Brief discussion of basic metallurgical processes. Compounds of Carbon: Carbon compounds; Elementary idea about bonding; Saturated hydrocarbons, alcohols, carboxylic acids (no preparation, only properties). Soap - cleansing action of soap. __________________________________________________

CLASS - X (MATHEMATICS) Number Systems : Natural Numbers, Integers, Rational number on the number line. Even - odd integers, prime number, composite numbers, twin primes, divisibility tests, Co-prime numbers, LCM and HCF of numbers. Representation of terminating/non-terminating recurring decimals, on the number line through successive magnification. Rational numbers as recurring/terminating decimals. Ratio and proportions. Polynomials : Polynomial in one variable and its Degree. Constant, Linear, quadratic, cubic polynomials; monomials, binomials, trinomials, Factors and multiplex. Zeros/roots of a polynomial/equation. Remainder theorem, Factor Theorem. Factorisation of quadratic and cubic polynomials Standard form of a quadratic equation ax2 + bx + c = 0, (a  0). Relation between roots and coefficient of quadratic and relation between discriminant and nature of roots. Linear Equation : Linear equation in one variable and two variable and their graphs. Pair of linear equations in two variables and their solution and inconsistency Arithmetic Progressions (AP) : Finding the nth term and sum of first n terms. Trigonometry : Trigonometric ratios of an acute angle of a rightangled triangle, Relationships between the ratios. Trigonometric ratios of complementary angles and trigonometric identities. Problems based on heights and distances. Coordinate Geometry : The cartesian plane, coordinates of a point, plotting points in the plane, distance between two points and section formula (internal). Area of triangle. Properties of triangle and quadrilateral. (Square, Rectangle rhombus, parallelogram).

Geometry : Lines : Properties of parallel and perpendicular lines. Triangle : Area of a triangle, Properties of triangle, similarity and congruency of triangles. Medians, Altitudes, Angle bisectors and related centres. Geometrical representation of quadratic polynomials. Circle : Properties of circle, Tangent, Normal and chords. Mensuration : Area of triangle using Heron’s formula and its application in finding the area of a quadrilateral. Area of circle ; Surface areas and volumes of cubes, cuboids, spheres (including hemispheres) and right circular cylinders/cones and their combinations. Statistics : Mean, median, mode of ungrouped and grouped data. Probability : Classical definition of probability, problems on single events. Logarithm & exponents : Logarithms and exponents and their properties. Interest : Problem based on simple interest, compound interest and discounts. Mental Ability : Problem based on data interpretation, family relations, Logical reasoning. Direct & Indirect variations : Ratios & proportions, Unitary method, Work and time problems. __________________________________________________

CLASS - X (PHYSICS) Mechanics : Uniform and non-uniform motion along a straight line ; Concept of distance and displacement, Speed and velocity, accelaration and relation ship between these ; Distance-time and velcocity - time graphs. Newton’s Law of motion ; Relationship between mass, momentum, force and accelaration ; work done by a force ; Law of conservation of energy. Law of gravitation ; acceleration due to gravity. Electricity and magnetism : Ohm’s law ; Series and parallel combination of resistances ; Heating effect of current. Magnetic field near a current carrying straight wire, along the axis of a circular coil and inside a solenoid ; Force on current carrying conductor ; Fleming’s left hand rule ; Working of electric motor ; Induced potential difference and current Electric generator : Principle and working ; Comparision of AC and DC ; Domestic electric circuits. Optics : Rectilinear propagation of light ; Basic idea of concave mirror and convex lens ; Laws of refraction ; Dispersion. __________________________________________________

CLASS - XI (CHEMISTRY) Some Basic Concepts of Chemistry : Particulate nature of matter, laws of chemical combination, Dalton’s atomic theory : concept of elements, atoms and molecules. Atomic and molecular masses. Mole concept and molar mass ; percentage composition and empirical and molecular formula ; chemical reactions, stoichiometry and calculations based on stoichiometry. Structure of Atom : Discovery of electron, proton and neutron ; atomic number, isotopes and isobars. Thompson’s model and its limitations, Rutherford’s model and its limitations, concept of shells and sub-shells, dual nature of matter and light, de Broglie’s relationship, Heisenberg uncertainty principle, concept of orbitals, quantum numbers, shapes of s, p, and d orbitals, rules for filling electrons in orbitals - Aufbau principle, Pauli exclusion principle

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and Hund’s rule, electronic configuration of atoms, stability of half filled and completely filleld orbitals. Classification of Elements and Periodicity in Properties : Significance of classification, brief history of the development of periodic table, trends in properties of elements - atomic radii, ionic radii, inert gas radii, ionization enthalpy, electron gain enthalpy, electronegativity, valence. Chemical Bonding and Molecular Structure : Valence electrons, ionic bond, covalent bond, bond parameters, Lewis structure, polar character of covalent bond, covalent character of ionic bond, valence bond theory, resonance, geometry of covalent molecules, VSEPR theory, concept of hybridization involving s, p and d orbitals and shapes of some simple molecules, molecular orbital theory of homonuclear diatomic molecules (qualitative idea only), hydrogen bond. States of Matter : Gases and Liquids : Three states of matter, intermolecular interactions, type of bonding, melting and boiling points, role of gas laws in elucidating the concept of the molecule, Boyle’s law, Charles’ law, Gay Lussac’s law, Avogadro’s law, ideal behavior, empirical derivation of gas equation, Avogadro’s number ideal gas equation, deviation from ideal behaviour, Liquefaction of gases, critical temperature. Liquid State - Vapour pressure, viscosity and surface tension (qualitative idea only, no mathematical derivations) Thermodynamics : Concepts of system, types of systems, surroundings, work, heat, energy, extensive and intensive properties, state functions. First law of thermodynamics - internal energy and enthalpy, heat capacity and specific heat, measurement of U and H, Hess’s law of constant heat summation, enthalpy of bond dissociation, combustion, formation, atomization sublimation, phase transition, ionization, and dilution. Introduction of entropy as a state function, free energy change for spontaneous and non-spontaneous process, equilibrium. Equilibrium : Equilibrium in physical and chemical processes, dynamic nature of equilibrium, law of mass action, equilibrium constant, factors affecting equilibrium - Le Chatelier’s principle ; ionic equilibrium - ionization of acids and bases, strong and weak electrolytes, degree of ionization concept of pH. Hydrolysis of Salts (elementary idea), buffer solutions, solubility product, common ion effect (with illustrative examples). Redox Reactions : Concept of oxidation and reduction, redox reactions, oxidation number, balancing redox reactions, applications of redox reaction. Hydrogen : Position of hydrogen in periodic table, occurrence, isotopes, preparation, properties and uses of hydrogen ; hydrides - ionic, covalent and interstitial ; physical and chemical properties of water, heavy water ; hydrogen peroxide - preparation, reactions and structure ; hydrogen as a fuel. s-Block Elements (Alkali and Alkaline Earth Metals) : Group 1 and Group 2 elements : General introduction, electronic configuration, occurrence, anomalous properties of the first element of each group, diagonal relationship, trends in the variation of properties (such as ionization enthalpy, atomic and ionic radii), trends in chemical reactivity with oxygen, water, hydrogen and halogens ; uses. Preparation and properties of some important compounds: Sodium carbonate, sodium chloride, sodium hydroxide and sodium hydrogen carbonate CaO, CaCO3, and industrial use of lime and limestone, Ca. General Introduction to p-Block Elements : Group 13 elements : General introduction, electronic configuration, occurrence, variation of properties, oxidation states, trends in chemical reactivity, anomalous properties of first element of the group ; Boron - physical and chemical properties, some important compounds borax, boric acids, boron hydrides. Aluminium : uses, reactions with acids and alkalies. Group 14 elements ; General introduction, electronic configuration, occurrence, variation of properties, oxidation states, trends in chemi-

cal reactivity, anomalous behaviour of first element. Carbon - catenation, allotropic forms, physical and chemical propeties ; uses of some important compounds : oxides. Important compounds of silicon and a few uses : silicon tetrachloride, silicones, silicates and zeolites. Principles of qualitative analysis : Determinantion of one anion and one cation in a given salt Cations - Pb2 + , Cu2+, As3+, Al3+, Fe3+, Mn2+, Ni2 +, Zn2+, Co2+, Ca2+, Sr2+, Ba2+, Mg2+, NH4 Anions - CO32– , S 2– , SO32– , SO 24– ,NO2– , NO3– ,NO3– , Cl– , Br – ,  – , PO34– , C 2O 24– CH3 COO–

(Note : Insoluble salts excluded) Organic chemistry - Some Basic Principles and Techniques General introduction, methods of purification, qualitative and quantitative analysis, classification and IUPAC nomenclature of organic compounds. Electronic displacements in a covalent bond : free radicals, carbocations, carbanions ; electrophiles and nucleophiles, types of organic reactions Classification of Hydrocarbons : Alkanes : Nomenclature, isomerism, conformations (ethane only), physical propeties, chemical reactions including free radical mechanism of halogenation, combustion and pyrolysis. Alkenes : Nomenclatures, structure of double bond (ethene), geometrical isomerism, physical properties, methods of preparation ; chemical reactions : addition of hydrogen, halogen, water, hydrogen halides (Markovnikov’s addition and peroxide effect), ozonolysis, oxidation, mechanism of electrophilic addition. Alkynes : Nomenclature, structure of triple bond (ethyne), physical properties, methods of preparation, chemical reactions : acidic character of alkynes, addition reaction of - hydrogen, halogens, hydrogen halides and water. Aromatic hydrocarbons : Introduction, IUPAC nomenclature ; Benzene : resonance, aromaticity ; chemical properties : mechanism of electrophilic substitution - nitration sulphonation, halogenation, Friedel Craft’s alkylation and acylation ; directive influence of functional group in mono-substituted benzene; carcinogenicity and toxicity. __________________________________________________

CLASS - XI (MATHEMATICS) Functions: Sets and their representations. Empty, finite and infinite sets, Subsets, Union and intersection of sets, Venn diagrams. Pictorial representation of a function domain, co-domain and range of a function domain and range of constant, identity, polynomial, rational, modulus, signum and greatest integer functions with their graphs. Sum, difference, product and quotients of functions. Trigonometric Functions: Measuring angles in radians and in degrees and conversion from one measure to another. Signs of trigonometric functions and sketch of their graphs. Addition and subtraction formulae, formulae involving multiple and sub-multiple angles. General solution of trigonometric equations. Complex Number: Algebra of complex numbers, addition, multiplication, conjugation, polar representation, properties of modulus and principal argument, triangle inequality, cube roots of unity, geometric interpretations. Quadratic equations : Quadratic equations with real coefficients, formation of quadratic equations with given roots, symmetric functions of roots. Sequence & Series : Arithmetic, geometric and harmonic progressions, arithmetic, geometric and harmonic means, sums of finite arithmetic and geometric progressions, infinite geometric series, sums of squares and cubes of the first n natural numbers. Logarithm & exponents: Logarithms and exponents and their properties. Exponential and logarithmic series.

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Binomial Theorem: Binomial theorem for a positive integral index, properties of binomial coefficients. Binomial theorem for any index. Permutations and combinations: Problem based on fundamental counting principle, Arrangement of alike and different objects, Circular permutation, Combination, formation of groups. Straight Line : Cartesian coordinates, distance between two points, section formulae, shift of origin. Equation of a straight line in various forms, angle between two lines, distance of a point from a line; Lines through the point of intersection of two given lines equation of the bisector of the angle between two lines, concurrency of lines; Centroid, orthocentre, incentre and circumcentre of a triangle. Conic Sections : Equation of a circle in various forms, equations of tangent, normal and chord. Parametric equations of a circle, intersection of a circle with a straight line or a circle, equation of a through the points of intersection of two circles and those of a circle and a straight line. Equations of a parabola, ellipse and hyperbola in standard form, their foci, directrices and eccentricity, parametric equations, equations of tangent and normal locus problems. Mental Ability : Problem based on data interpretation, family relations & Logical reasoning. __________________________________________________

CLASS - XI (PHYSICS) General : Units and dimensions, dimensional analysis; least count, significant figures; Methods of measurement and error analysis for physical quantities pertaining to the following experiments: Experiments based on using Vernier calipers and screw gauge (micrometer), Determination of g using simple pendulum, Young’s modulus by Searle’s method. Mechanics : Kinematics in one and two dimensions (Cartesian coordinates only), projectiles; Uniform Circular motion; Relative velocity. Newton’s laws of motion; Inertial and uniformly accelerated frames of reference; Static and dynamic friction; Kinetic and potential energy; Work and power; Conservation of linear momentum and mechanical energy. Systems of particles; Centre of mass and its motion; Impulse; Elastic and inelastic collisions. Law of gravitation; Gravitational potential and field; Acceleration due to gravity; Motion of planets and satellites in circular orbits; Escape velocity. Rigid body, moment of inertia, parallel and perpendicular axes theorems, moment of inertia of uniform bodies with simple geometrical shapes; Angular momentum; Torque; Conservation of angular momentum; Dynamics of rigid bodies with fixed axis of rotation; Rolling without slipping of rings, cylinders and spheres; Equilibrium of rigid bodies; Collision of point masses with rigid bodies. Linear and angular simple harmonic motions. Hooke’s law, Young’s modulus. Pressure in a fluid; Pascal’s law; Buoyancy; Surface energy and surface tension, capillary rise; Viscosity (Poiseuille’s equation excluded), Stoke’s law; Terminal velocity, Streamline flow, equation of continuity, Bernoulli’s theorem and its applications. Waves : W ave motion (plane waves only), longitudinal and transverse waves, superposition of waves; Progressive and stationary waves; Vibration of strings and air columns;Resonance; Beats; Speed of sound in gases; Doppler effect (in sound). Thermal physics : Thermal expansion of solids, liquids and gases; Calorimetry, latent heat; Heat conduction in one dimension; Elementary concepts of convection and radiation; Newton’s law of cooling; Ideal gas laws; Specific heats (Cv and Cp for monoatomic and diatomic gases); Isothermal and adiabatic processes, bulk modulus of gases; Equivalence of heat and work; First law of thermodynamics and its applications (only for ideal gases); Blackbody radiation: absorptive and emissive powers; Kirchhoff’s law; Wien’s displacement law, Stefan’s law. __________________________________________________

CLASS - XII (CHEMISTRY) PHYSICAL CHEMISTRY General topics : Concept of atoms and molecules; Dalton’s atomic theory; Mole concept; Chemical formulae; Balanced chemical equations; Calculations (based on mole concept) involving common oxidationreduction, neutralisation, and displacement reactions; Concentration in terms of mole fraction, molarity, molality and normality. Gaseous and liquid states : Absolute scale of temperature, ideal gas equation; Deviation from ideality, van der Waals equation; Kinetic theory of gases, average, root mean square and most probable velocities and their relation with temperature; Law of partial pressures; Vapour pressure; Diffusion of gases. Atomic structure and chemical bonding : Bohr model, spectrum of hydrogen atom, quantum numbers; Wave-particle duality, de Broglie hypothesis; Uncertainty principle; Qualitative quantum mechanical picture of hydrogen atom, shapes of s, p and d orbitals; Electronic configurations of elements (up to atomic number 36); Aufbau principle; Pauli’s exclusion principle and Hund’s rule; Orbital overlap and covalent bond; Hybridisation involving s, p and d orbitals only; Orbital energy diagrams for homonuclear diatomic species; Hydrogen bond; Polarity in molecules, dipole moment (qualitative aspects only); VSEPR model and shapes of molecules (linear, angular, triangular, square planar, pyramidal, square pyramidal, trigonal bipyramidal, tetrahedral and octahedral). Energetics : First law of thermodynamics; Internal energy, work and heat, pressure-volume work; Enthalpy, Hess’s law; Heat of reaction, fusion and vapourization; Second law of thermodynamics; Entropy; Free energy; Criterion of spontaneity. Chemical equilibrium : Law of mass action; Equilibrium constant, Le Chatelier’s principle (effect of concentration, temperature and pressure); Significance of G and Go in chemical equilibrium; Solubility product, common ion effect, pH and buffer solutions; Acids and bases (Bronsted and Lewis concepts); Hydrolysis of salts. Electrochemistry : Electrochemical cells and cell reactions; Standard electrode potentials; Nernst equation and its relation to DG; Electrochemical series, emf of galvanic cells; Faraday’s laws of electrolysis; Electrolytic conductance, specific, equivalent and molar conductivity, Kohlrausch’s law; Concentration cells. Chemical kinetics : Rates of chemical reactions; Order of reactions; Rate constant; First order reactions; Temperature dependence of rate constant (Arrhenius equation). Solid state : Classification of solids, crystalline state, seven crystal systems (cell parameters a, b, c, ), close packed structure of solids (cubic), packing in fcc, bcc and hcp lattices; Nearest neighbours, ionic radii, simple ionic compounds, point defects. Solutions : Raoult’s law; Molecular weight determination from lowering of vapour pressure, elevation of boiling point and depression of freezing point. Surface chemistry : Elementary concepts of adsorption (excluding adsorption isotherms); Colloids: types, methods of preparation and general properties; Elementary ideas of emulsions, surfactants and micelles (only definitions and examples). Nuclear chemistry : Radioactivity: isotopes and isobars; Properties of rays; Kinetics of radioactive decay (decay series excluded), carbon dating; Stability of nuclei with respect to proton-neutron ratio; Brief discussion on fission and fusion reactions. INORGANIC CHEMISTRY Isolation/preparation and properties of the following nonmetals : Boron, silicon, nitrogen, phosphorus, oxygen, sulphur and halogens; Properties of allotropes of carbon (only diamond and graphite), phosphorus and sulphur. Preparation and properties of the following compounds : Oxides, peroxides, hydroxides, carbonates, bicarbonates, chlorides and sulphates of sodium, potassium, magnesium and calcium; Boron: diborane, boric acid and borax; Aluminium: alumina, aluminium chloride

Page - 6

STPFXII1213

and alums; Carbon: oxides and oxyacid (carbonic acid); Silicon: silicones, silicates and silicon carbide; Nitrogen: oxides, oxyacids and ammonia; Phosphorus: oxides, oxyacids (phosphorus acid, phosphoric acid) and phosphine; Oxygen: ozone and hydrogen peroxide; Sulphur: hydrogen sulphide, oxides, sulphurous acid, sulphuric acid and sodium thiosulphate; Halogens: hydrohalic acids, oxides and oxyacids of chlorine, bleaching powder; Xenon fluorides. Transition elements (3d series) : Definition, general characteristics, oxidation states and their stabilities, colour (excluding the details of electronic transitions) and calculation of spin (only magnetic moment), Coordination compounds: nomenclature of mononuclear coordination compounds, cis-trans and ionisation isomerisms, hybridization and geometries of mononuclear coordination compounds (linear, tetrahedral, square planar and octahedral). Preparation and properties of the following compounds : Oxides and chlorides of tin and lead; Oxides, chlorides and sulphates of Fe2+, Cu2+ and Zn2+; Potassium permanganate, potassium dichromate, silver oxide, silver nitrate, silver thiosulphate. Ores and minerals : Commonly occurring ores and minerals of iron, copper, tin, lead, magnesium, aluminium, zinc and silver. Extractive metallurgy : Chemical principles and reactions only (industrial details excluded); Carbon reduction method (iron and tin); Self reduction method (copper and lead); Electrolytic reduction method (magnesium and aluminium); Cyanide process (silver and gold). Principles of qualitative analysis : Groups I to V (only Ag+, Hg2+, Cu2+, Pb2+, Bi3+, Fe3+, Cr3+, Al3+, Ca2+, Ba2+, Zn2+, Mn2+ and Mg2+); Nitrate, halides (excluding fluoride), sulphate and sulphide. ORGANIC CHEMISTRY Concepts : Hybridisation of carbon; Sigma and pi-bonds; Shapes of simple organic molecules; Structural and geometrical isomerism; Optical isomerism of compounds containing up to two asymmetric centres, (R,S and E,Z nomenclature excluded); IUPAC nomenclature of simple organic compounds (only hydrocarbons, mono-functional and bifunctional compounds); Conformations of ethane and butane (Newman projections); Resonance and hyperconjugation; Keto-enol tautomerism; Determination of empirical and molecular formulae of simple compounds (only combustion method); Hydrogen bonds: definition and their effects on physical properties of alcohols and carboxylic acids; Inductive and resonance effects on acidity and basicity of organic acids and bases; Polarity and inductive effects in alkyl halides; Reactive intermediates produced during homolytic and heterolytic bond cleavage; Formation, structure and stability of carbocations, carbanions and free radicals. Preparation, properties and reactions of alkanes : Homologous series, physical properties of alkanes (melting points, boiling points and density); Combustion and halogenation of alkanes; Preparation of alkanes by Wurtz reaction and decarboxylation reactions. Preparation, properties and reactions of alkenes and alkynes: Physical properties of alkenes and alkynes (boiling points, density and dipole moments); Acidity of alkynes; Acid catalysed hydration of alkenes and alkynes (excluding the stereochemistry of addition and elimination); Reactions of alkenes with KMnO4 and ozone; Reduction of alkenes and alkynes; Preparation of alkenes and alkynes by elimination reactions; Electrophilic addition reactions of alkenes with X2, HX, HOX and H2O (X=halogen); Addition reactions of alkynes; Metal acetylides. Reactions of Benzene : Structure and aromaticity; Electrophilic substitution reactions: halogenation, nitration, sulphonation, FriedelCrafts alkylation and acylation; Effect of ortho, meta and para directing groups in monosubstituted benzenes. Phenols : Acidity, electrophilic substitution reactions (halogenation, nitration and sulphonation); Reimer-Tieman reaction, Kolbe reaction. Characteristic reactions of the following (including those mentioned above): Alkyl halides: rearrangement reactions of alkyl carbocation, Grignard reactions, nucleophilic substitution reactions; Alcohols: esterification, dehydration and oxidation, reaction with sodium, phosphorus halides, ZnCl2/concentrated HCl, conversion of alcohols into aldehydes and ketones; Ethers:Preparation by Williamson’s Synthesis; Aldehydes and Ketones: oxidation, reduction, oxime and hydrazone formation; aldol condensation, Perkin

reaction; Cannizzaro reaction; haloform reaction and nucleophilic addition reactions (Grignard addition); Carboxylic acids: formation of esters, acid chlorides and amides, ester hydrolysis; Amines: basicity of substituted anilines and aliphatic amines, preparation from nitro compounds, reaction with nitrous acid, azo coupling reaction of diazonium salts of aromatic amines, Sandmeyer and related reactions of diazonium salts; carbylamine reaction; Haloarenes: nucleophilic aromatic substitution in haloarenes and substituted haloarenes (excluding Benzyne mechanism and Cine substitution). Carbohydrates: Classification; mono- and di-saccharides (glucose and sucrose); Oxidation, reduction, glycoside formation and hydrolysis of sucrose. Amino acids and peptides : General structure (only primary structure for peptides) and physical properties. Properties and uses of some important polymers : Natural rubber, cellulose, nylon, teflon and PVC. Practical organic chemistry : Detection of elements (N, S, halogens); Detection and identification of the following functional groups: hydroxyl (alcoholic and phenolic), carbonyl (aldehyde and ketone), carboxyl, amino and nitro; Chemical methods of separation of mono-functional organic compounds from binary mixtures. __________________________________________________

CLASS - XII (MATHEMATICS) Complex Number and Quadratic equations: Algebra of complex numbers, addition, multiplication, conjugation, polar representation, properties of modulus and principal argument, triangle inequality, cube roots of unity, geometric interpretations. Quadratic equations with real coefficients, formation of quadratic equations with given roots, symmetric functions of roots. Sequence & Series: Arithmetic, geometric and harmonic progressions, arithmetic, geometric and harmonic means, sums of finite arithmetic and geometric progressions, infinite geometric series, sums of squares and cubes of the first n natural numbers. Logarithms and their properties. Permutations and combinations, Binomial theorem for a positive integral index, properties of binomial coefficients. Binomial theorem for any index, exponential and logarithmic series. Matrices & Determinants: Matrices as a rectangular array of real numbers, equality of matrices, addition, multiplication by a scalar and product of matrices, transpose of a matrix, determinant of a square matrix of order up to three, inverse of a square matrix of order up to three, properties of these matrix operations, diagonal, symmetric and skew- symmetric matrices and their properties, solutions of simultaneous linear equation in two or three variables. Probability : Addition and multiplication rules of probability, conditional probability, baye’s theorem, independence of events, computation of probability of events using permutations and combinations. Straight Line : Cartesian coordinates, distance between two points, section formulae, shift of origin. Equation of a straight line in various forms, angle between two lines, distance of a point from a line; Lines through the point of intersection of two given lines equation of the bisector of the angle between two lines, concurrency of lines; Centroid, orthocentre, incentre and circumcentre of a triangle. Conic Section: Equation of a circle in various forms, equations of tangent, normal and chord. Parametric equations of a circle, intersection of a circle with a straight line or a circle, equation of a through the points of intersection of two circles and those of a circle and a straight line. Equations of a parabola, ellipse and hyperbola in standard form, their foci, directrices and eccentricity, parametric equations, equations of tangent and normal locus problems. Three dimensions: Direction cosines and direction ratios, equation of a straight line in space, equation of a plane, distance of a point from a plane Vectors: Addition of vectors, scalar multiplication, dot and cross products, scalar triple products and their geometrical interpretations.

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STPFXII1213

Position vector of a point dividing a line segment in a given ratio. Projection of a vector on a line. Function: Real valued functions of a real variable, into, onto and oneto-one functions, sum, difference, product and quotient of two functions, composite functions, absolute value, polynomial, rational, trigonometric, exponential and logarithmic functions. Even and odd functions, inverse of a function, composite function. Limit, Continuity & Derivability: Limit and continuity of a function, limit and continuity of the sum, difference, product and quotient of two functions, L’Hospital rule of evaluation of limits of functions even and odd functions, inverse of a function, continuity of composite function. intermediate value property of continuous functions. Differentiation: Derivative of a function, derivative of the sum, difference, product and quotient of two functions, chain rule, derivatives of polynomial, rational, trigonometric, inverse trigonometric, exponential and logarithmic functions. Derivatives of implicit functions, derivatives up to order two. Tangent & Normal: Geometrical interpretation of the derivative, tangents and normal. Maxima & Minima: Increasing and decreasing functions, maximum and minimum values of a function, rolle’s theorem and Lagrange’s Mean value theorem. Integral calculus: Integration as the inverse process of differentiation, indefinite integrals of standard functions, integration by parts, integration by the methods of substitution and partial fractions. Definite integrals and their properties, fundamental theorem of integral calculus. Application of definite integrals to the determination of areas involving simple curves. Formation of ordinary differential equations, solution of homogeneous differential equations, separation of variables method, linear first order differential equations. Trigonometry: Trigonometric functions, their periodicity and graphs addition and subtraction formulae, formulae involving multiple and submultiple angles, general solution of trigonometric equations. Relations between sides and angles of a triangle, sine rule, cosine rule, half-angle formula and the area of a triangle, inverse trigonometric functions (principal value only) __________________________________________________

CLASS - XII (PHYSICS) General : Units and dimensions, dimensional analysis; least count, significant figures; Methods of measurement and error analysis for physical quantities pertaining to the following experiments: Experiments based on using Vernier calipers and screw gauge (micrometer), Determination of g using simple pendulum, Young’s modulus by Searle’s method, Specific heat of a liquid using calorimeter, focal length of a concave mirror and a convex lens using u-v method, Speed of sound using resonance column, Verification of Ohm’s law using voltmeter and ammeter, and specific resistance of the material of a wire using meter bridge and post office box. Mechanics : Kinematics in one and two dimensions (Cartesian coordinates only), Projectile Motion; Uniform Circular Motion; Relative Velocity. Newton’s laws of motion; Inertial and uniformly accelerated frames of reference; Static and dynamic friction; Kinetic and potential energy; Work and power; Conservation of linear momentum and mechanical energy. Systems of particles; Centre of mass and its motion; Impulse; Elastic and inelastic collisions.

Law of gravitation; Gravitational potential and field; Acceleration due to gravity; Motion of planets and satellites in circular orbits; Escape velocity. Rigid body, moment of inertia, parallel and perpendicular axes theorems, moment of inertia of uniform bodies with simple geometrical shapes; Angular momentum; Torque; Conservation of angular momentum; Dynamics of rigid bodies with fixed axis of rotation; Rolling without slipping of rings, cylinders and spheres; Equilibrium of rigid bodies; Collision of point masses with rigid bodies. Linear and angular simple harmonic motions. Hooke’s law, Young’s modulus. Pressure in a fluid; Pascal’s law; Buoyancy; Surface energy and surface tension, capillary rise; Viscosity (Poiseuille’s equation excluded), Stoke’s law; Terminal velocity, Streamline flow, equation of continuity, Bernoulli’s theorem and its applications. Waves : Wave motion (plane waves only), longitudinal and transverse waves, superposition of waves; Progressive and stationary waves; Vibration of strings and air columns;Resonance; Beats; Speed of sound in gases; Doppler effect (in sound). Thermal physics : Thermal expansion of solids, liquids and gases; Calorimetry, latent heat; Heat conduction in one dimension; Elementary concepts of convection and radiation; Newton’s law of cooling; Ideal gas laws; Specific heats (Cv and Cp for monoatomic and diatomic gases); Isothermal and adiabatic processes, bulk modulus of gases; Equivalence of heat and work; First law of thermodynamics and its applications (only for ideal gases); Blackbody radiation: absorptive and emissive powers; Kirchhoff’s law; Wien’s displacement law, Stefan’s law. Electricity and magnetism : Coulomb’s law; Electric field and potential; Electrical potential energy of a system of point charges and of electrical dipoles in a uniform electrostatic field; Electric field lines; Flux of electric field; Gauss’s law and its application in simple cases, such as, to find field due to infinitely long straight wire, uniformly charged infinite plane sheet and uniformly charged thin spherical shell. Capacitance; Parallel plate capacitor with and without dielectrics; Capacitors in series and parallel; Energy stored in a capacitor. Electric current; Ohm’s law; Series and parallel arrangements of resistances and cells; Kirchhoff’s laws and simple applications; Heating effect of current. Biot–Savart’s law and Ampere’s law; Magnetic field near a currentcarrying straight wire, along the axis of a circular coil and inside a long straight solenoid; Force on a moving charge and on a current-carrying wire in a uniform magnetic field. Magnetic moment of a current loop; Effect of a uniform magnetic field on a current loop; Moving coil galvano- meter, voltmeter, ammeter and their conversions. Electromagnetic induction: Faraday’s law, Lenz’s law; Self and mutual inductance; RC, LR and LC circuits with d.c. and a.c. sources. Optics: Rectilinear propagation of light; Reflection and refraction at plane and spherical surfaces; Total internal reflection; Deviation and dispersion of light by a prism; Thin lenses; Combinations of mirrors and thin lenses; Magnification. Wave nature of light: Huygen’s principle, interference limited to Young’s double-slit experiment. Modern Physics : Atomic nucleus; Alpha, beta and gamma radiations; Law of radioactive decay; Decay constant; Half-life and mean life; Binding energy and its calculation; Fission and fusion processes; Energy calculation in these processes. Photoelectric effect; Bohr’s theory of hydrogen-like atoms; Characteristic and continuous X-rays, Moseley’s law; de Broglie wavelength of matter waves.

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STPFXII1213

SAMPLE TEST PAPER -I (For Class-X Appearing / Passed Students) Course : VIKAAS (JA) & VIPUL (JB) Part - I Part - II Part - III (Mathematics) (Physics) (Chemistry) 1 to 20

39 to 46

52 to 59

21 to 28

47 to 50

60 to 63

51

64

Correct

Wrong

Blank

3

-1

0

4

0

0

4

0

0

6 [1, 2, 3, 6]

0

0

Only one correct

oy ,d fod Yi l gh) (d s One or more than one correct Answer (,d ;k ,d l sv f/kd fod Yi l gh) PN sn) Comprehensions (v uq Matrix Match Type (eS fVªDl l qesy izd kj)

29 to 36 37 to 38

Marks to be awarded

Type

PART - I SECTION - I([k.M - I) Straight Objective Type (lh/ksoLrq fu"B

izd kj)

This section contains 20 multiple choice questions. Each question has choices (A), (B), (C) and (D), out of which ONLY ONE is correct. bl [k.M esa20 cgq& fod Yih iz'u gSA izR;sd iz'u d s4 fod Yi (A), (B), (C) rFkk(D) gSa, ft uesalsflQ Z,d lgh gSA 1.

2.

The HCF of 20x5 – 38x4 + 43x4 – 25x2 and 15x5 – 19x4 + 4x3 is 20x5 – 38x4 + 43x4 – 25x2 vkS j 15x5 – 19x4 + 4x3 d k e-l-i- gS& 2 2 (A) x (x + 1) (B) x2(x2 – 1) (C) x2(x + 1)

A valid reason for concluding that 635 is not a perfect square of an integer is that 635 fd lh iw .kk±d d k oxZughagSbld k ,d lgh d kj.k gSfd & (A) It is an odd integer (;g

,d fo"ke iw.kk±d gS) (C) it ends with 35 (;g 35 ij lekIr gS) 3.

4.

(B) it ends with 5 (;g 5 ij

lekIr gS) (D) sum of its odd digits is 8 (bld sfo"ke va d ksad k ;ksx 8 gS)

The missing number in the following sequence is : 1, 3, 3, 6, 7, 9, ?, 12, 21 vuqØ e 1, 3, 3, 6, 7, 9, ?, 12, 21 d k vKkr in gS& (A) 10 (B) 11 (C) 12

(D) 13

Given : x > 0, y > 0, x > y and z  0. The inequality which is not always correct is ? fn;k gS: x > 0, y > 0, x > y rFkk z  0, d kSulh vlfed k lnSo lgh ughagksxh\ (A) x + z > y + z

5.

(D) x2(x – 1)

(B) x – z > y – z

(C) xz > yz

(D)

x z

2

>

y z2

A bag contains '5 red balls and some blue balls' only. If the probability of drawing a blue ball is double the probability of a red ball, the number of blue balls in the bag is ,d FkSy sesad soy '5 y ky xsansrFkkd qN uhy hxsans' gSaA ;fn ,d uhy hxsan d ksfud ky usd hizkf;d rk,d y ky xsan d ksfud ky us

d h izkf;d rk d h nqxquh gS]rksFkSy sesauhy h xsanksad h la[;k gS& (A) 5 6.

(B) 10

(C) 15

Recurring decimal 0.235 , when expressed in the form

(D) 20

p , is (where p and q are integers and q  0). q

p

vkorhZn'key o 0.235 d ks q d s: i esaO;Dr d jusij cjkcj gS(t gk¡p rFkk q iw.kkZad gSarFkk q  0) (A)

235 1000

(B)

243 990

(C)

233 990

(D)

223 . 990

Page - 9

STPFXII1213

7.

The radii of the bases of two right circular solid cones of same height are 3 cm and 4 cm, respectively. The cones are melted and recast into a solid sphere of radius 5 cm. Then the heights of the given cones is nksleku Å ¡p kbZoky sled ks.kh; o`Ùkkd kj Bksl 'kad qv ksad svk/kkj d hf=kT;k,¡Ø e'k%3 cm rFkk4 cm gSA 'kad qv ksad ksfi?ky kd j 5 cm f=kT;k d k ,d (A) 10

8.

9.

Bksl xksy k cuk;k t krk gS]rksfn;sx;s'kad qv ksad h Å ¡p kbZ;k¡gS& (B) 30

(C) 20

How many numbers between 200 and 600 are divisible by 4, 5, and 6 ? la[;k 200 rFkk 600 d schp esafd rusiw.kk±d 4, 5 vkSj 6 lsHkkT; gSa\ (A) 6 (B) 7 (C) 8

(D) 90

(D) 9

There are four prime numbers written in ascending order. The product of the first three is 385 and that of the last three is 1001. The last number is : pkj vHkkT; la[;kvksad ksc Kc

(D) Kc = Kp (RT)2

Which of the following diagram correctly describes the behaviour of a fixed mass of an ideal gas ? (T is measured in K) (,d vkn'kZxS l d sfuf'pr nzO;eku d sO;ogkj d ksfuEu esalsd kSulkvkjs[kcrkrkgS\ (T d ksK }kjk

ekfir fd ;kx;kgS))

(A)

57.

58.

59.

(B)

(C)

(D)

Number of H+ ions present in 250 ml of lemon juice of pH = 3 is : (pH = 3 oky s250 ml y s eu t wl esamifLFkr H+ vk;uksad h la[;k fuEu gS:) 22 (A) 1.506  10 (B) 1.506  1023 (C) 1.506  1020

(D) 13.012  1021

Baking powder is : (cS fd x ikmMj fuEu gS%) (A) NaHCO3 (B) NaHCO3 .6H2O

(D) Na2CO3.10H2O

(C) Na2CO3

Which of the following gives propyne on hydrolysis ? (fuEu (A) Al4C3 (B) Mg2C3 (C) B4C

esalsd kSu t y vi?kV~u ij izksikbu nsrk gS\) (D) La4C3 Page - 38

STPFXII1213

60.

The correct IUPAC name of the given compound is : (fn,

x;s;kSfxd d k lgh IUPAC uke gS%)

(A) 5-Amino-3-bromo-4-chloro-2-hydroxycyclopentane-1-carbonitrile (5-,ehuks -3-cz ks eks -4-Dyks jks -2-gkbMª kW DlhlkbDyks is UVs u-1-d kcks ukbVª Z kby ) (B) 1-Amino-3-bromo-2-chloro-4-hydroxycyclopentane-5-carbonitirle (1-,ehuks -3-cz ks eks -2-Dyks jks -4-gkbMª kW DlhlkbDyks is UVs u-5-d kcks ukbVª Z kby ) (C) 2-Amino-4-bromo-3-chloro-5-hydroxycyclopentane-1-carbonitirle (2-,ehuks -4-cz ks eks -3-Dyks jks -5-gkbMª kW DlhlkbDyks is UVs u-1-d kcks ukbVª Z kby ) (D) 2-Amino-3-chloro-3-bromo-5-hydroxycyclopentane-1-nitrile (2-,ehuks -3-Dyks jks -3-cz kseks -5-gkbMª kW DlhlkbDyks is UVs u-1-ukbVª kby ) 61.

The number of possible enantiomer pairs that can be produced during monochlorination of Butane is

C;qVsu d seksuksDy ksjhuhd j.k d snkSjku cuusoky slEHko izfrfcEch ;qXeksad h la[;k gS% (A) 2

(B) 3

(C) 4

(D) 1

SECTION - II ([k.M - II) Multiple Correct Answers Type (cgq y

lgh mÙkj izd kj)

This section contains 2 multiple correct answer(s) type questions. Each question has 4 choices (A), (B), (C) and (D), out of which ONE OR MORE THAN ONE is/are correct. bl [k.M es a2 cgqlghmÙkj iz d kj d siz 'u gSa A iz R;s d iz 'u d s4 fod Yi (A), (B), (C) rFkk(D) gSa , ft ues als,d ;k,d lsvfèkd

fod Yi lghgS¼gSa½A 62.

63.

Which of the following methods of expressing concentration are independent of temperature ? (lkUnz rk d ksO;Dr d jusoky h og fof/k t ksrkieku ij fuHkZj ughad jrh gaS]fuEu gS?) (A) Molarity (eks y jrk)

(B) Molality (eks y y rk)

(C) % w/w (Hkkj@Hkkj iz fr'kr)

(D) Mole fraction (eks y &fHkUu)

Which amongs the following are correctly matched. (fuEufy f[kr (A)

esalsd kSu lgh : i lslqesfy r gS:)

& CH2=CH–CH=C=CH–CH=CH2 are ring chain isomers.

(

(B)

rFkkCH2=CH–CH=C=CH–CH=CH2 oy ; J`a[ky k leko;oh gSaA )

&

(

rFkk

are positional isomers.

fLFkfr leko;oh gSaA ) Page - 39

STPFXII1213

(C)

&

are chain isomers.

rFkk

(

(D)

J`a[ky k leko;oh gSaA)

&

are functional group isomers.

rFkk

(

fØ ;kRed lewg leko;oh gSaA)

SECTION - III ([k.M - III) Comprehension Type (c) cks /ku çd kj) This section contains 1 paragraphs. Based upon each paragraph, 3 multiple choice questions have to be answered. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct. bl [k.M esa1 vuqPNsn (paragraphs) gSA çR;sd vuqPNsn ij vk/kkfjr 3 cgq& fod Yih ç'u d smÙkj nsus gSA çR;sd ç'u d s 4 fod Yi (A), (B), (C) rFkk(D) gS, ft ues alsflQ Z,d lgh gSA

Paragraph for Question Nos. 64 to 66 Conditions of geometrical isomerism : (I) Geometrical isomerism arises due to the presence of a double bond or a ring structure. (i.e.

,

– N = N – or ring structure)

Due to the rigidity of double bond or the ring structure to rotate at the room temperature the molecules exist in two or more orientations. This rigidity to rotation is described as restricted rotation / hindered rotation / no rotation.

(II)

(a)

(Restricted Rotation)

(b)

(Restricted Rotation)

Different groups should be attached at each doubly bonded atom. For example and

are identical but not geometrical isomers.

On the other hand, following types of compounds can exist as geometrical isomers : a

a C=C b

b

a

a

,

C=C b

d

ç'u

d

a or

C=C b

64

e

ls66 d sfy , v uqPNsn

T;kferh; l eko;ork d sfy ;sv ko';d 'krs±% (I) T;kfefr; leko;ork ;kS fxd esaf}cU/k ;k oy ; lajpuk d smifLFkr gksusij mRiUu gksrh gSA (t S l sfd , – N = N – ;k oy ; la jpuk) lkekU;r%;kSfxd esamifLFkr f}cU/k;koy; la jpuklst qM+sgq;sijek.kqv ks a;klewgks ad kn` 0 (Sfud k; + Sokrkoj.k > 0) (C) Ssystem + S surrounding < 0 (Sfud k; + Sokrkoj.k < 0) (D) (Gsystem) T,P > 0 ((Gfud k;) T,P > 0)

Columm - II (d kW y e-II) (p) Process is in equilibrium (vfHkfØ ;k lkE; es agSA) (q) Process is nonspontaneous (vfHkfØ ;k vLor%gS A) (r) Process is spontaneous (vfHkfØ ;k Lor%gS A) (s) System is unable to do useful work (fud k; mi;q Dr d k;Zd sv;ksX; gSA)

ANSWER KEY TO SAMPLE TEST PAPER-II 1.

B

2.

B

3.

A

4.

C

5.

B

6.

A

7.

B

8.

B

9.

D

10.

A

11.

B

12.

D

13.

B

14.

C

15.

D

16.

AB

17.

AC

18.

ABC

19.

AB

20.

AD

21.

AC

22.

D

23.

C

24.

B

25.

A

26.

B

27.

D

28.

B

29.

D

30.

A

31.

(A - q), (B - r), (C - s), (D - p)

32.

A

33.

B

34.

C

35.

B

36.

B

37.

A

38.

A

39.

A

40.

A

41.

D

42.

AC

43.

BCD

44.

CD

45.

ACD

46.

D

47.

A

48.

A

49.

D

50.

C

51.

C

52.

(A - r) ; (B - q,s) ; (C - p) ; (D - q,r)

53.

D

54.

A

55.

A

56.

A

57.

C

58.

A

59.

B

60.

C

61.

A

62. BCD

64.

A

65.

C

66.

A

67.

(A - p, s); (B - r) ; (C - q, s) ; (D - q, s).

63. ACD

HINTS & SOLUTION TO SAMPLE TEST PAPER-II 1.

|iz + z0| = |i(z – i) – 1 +5 + 3i| = |i(z – i) + 4 + 3i|  |i| | z – i| + | 4 + 3i |  1 . 2 + 5 = 7

2.

(12 – 22) + (32 – 42) + (52 – 62) + ....+ = (1 + 2) (1 – 2) + (3 + 4)(3 – 4) + (5 + 6) = – 3 – 7 – 11..........199 a = – 3, d = – 4 and  = – 199  = a + (n – 1) d – 199 = – 3 + (n – 1)(– 4) – 199 + 3 = (n – 1)(– 4) 196 n–1= = 49 4 n = 50

(992 – 1002) (5 – 6) +.....+ (99 + 100)(99 – 100)

Page - 42

STPFXII1213

50 [– 3– 199] 2 = 25 [– 202] = – 5050.

S50 = 3.

Required number of ways are = Exactly one toy is exchanged + exactly two toys exchanged + exactly 3 toys exchanged + 4 toys exchanged = 4C1 7C1 + 4C2 7C2 + 4C3 7C3 + 4C4 7C4 = 329 d qy rjhd ksd hla [;k= ,d f[ky kS ukcny usd srjhd ks ad hla[;k+ nksf[kykSuscnyusd srjhd ksad hla [;k+ rhu f[ky kSuscny us d srjhd ksad h la[;k + pkj f[ky kSuscny usd srjhd ksad h la[;kA = 4C1 7C1 + 4C2 7C2 + 4C3 7C3 + 4C4 7C4 = 329

7.

Slope of line parallel to line BC is – 1. (js [kk BC d slekUrj js[kk d h izo.krk– 1 gSA) Equation of line parallel to BC is x + y +  = 0. (BC d slekUrj js [kk d h lehd j.k x + y +  = 0

00 2



1 2

=±



gSA)

1 2

Since, line x + y +  = 0, intersects AB and AC, pw¡fd js[kk x + y +  = 0, AB vkSj AC d ksd kVrh gS]

1

8.



=



x+y+

log

0. 9

2 1 2

=0

log5 ( x 2  5  x ) > 0

log5 ( x 2  5  x ) < 1      11.

(x2 + 5 + x)1/2 < 5 x2 + 5 + x < 25 x2 + x – 20 < 0 (x + 5) (x – 4) < 0 x  (–5, 4) n=8

and

x2 + x + 5 > 0

1 BD 2 Given AB = x AD =

AD + BD = x

1 BD + BD = x 2 2 BD = x 3 Page - 43

STPFXII1213

Now by ABC

y2  x2

BC =

And by BCD CD =

BD 2  BC 2

4 2 x  y2  x2 9

=

9 y 2  5x 2

CD =

sin  =

3 2 x 3

BD = CD

2x

9y 2  5x 2 3

=

2

9y  5x 2

Sol. (22 to 24)  a–50  2a 

a–4

x2 –  a – 5  x +  a – 5  = 0     If roots are  and , then ;fn ewy  v kSj gks] rks 

a–4

For P :  =  a – 5  > 0   or

a (–,4)  (5, ) P = {a : a  (–, 4)  (5, ) } a–4

For Q :  =  a – 5  < 0   or a  (4, 5)  Q = {a : a  (4,5)} For R : D  0 and (v kS j)  > 0 4a2



a–4

4(a – 4 )

– (a – 5)  0 and (v kS j)  a – 5  > 0 (a – 5 ) 2

9a – 20 (a – 5 )2

a– 4  0 and (v kS j)  a – 5  > 0  

 20





 20



a   9 ,   and (v kS j) a  (–,4)  (5, )  



R = a : a  9 , 4   (5,  )    





For S : D  0

   20  S = a : a   ,    {5}  9    For T : D < 0 

a<



20 9

 20   T = a : a   – , 9    

Page - 44

STPFXII1213

22.

(a) P  Q =  (b) R  P (c) P  Q = {a : a  {(–,4)  (5,)  (4,5)} = R – {4,5}

23.

T  P

24.

R = a : a   9 , 4  (5,  )    

 20







 Least positive integer of R is 3. Sol.

(25 to 27) Let 1st term be a . and common difference is 2. (ekuk iz Fke T 2n + 1 = a + 4n = A (say) r =

1 2

Middle term of AP = T n + 1 (l ekUrj

J s ) oky s/kkrq¼izkjEHk esavukosf'kr½ ij vkifrr gksrk gSrks)& (A) all emitted photoelectrons have kinetic energy equal to (h – ). (lHkh mRlft Z r Q ksVksby sDVªkWuksad h xfrt Å t kZ(h – ) d scjkcj gksxhA) (B) all free electrons in the metal, that absorb photons of energy h completely, may not be ejected out of the metal. (/kkrqes amifLFkr lHkh eqä by sDVªkWu t ksh Å t kZd sQ ksVkWuksad ksiw.kZr;k vko'kksf"kr d jrsgS]/kkrqd sckgj

mRlft Zr ughgksld rsgSA) (C) after being emitted out of the metal, the kinetic energy of photoelectrons decreases continuously as long as they are at a finite distance from metal. (/kkrqd sckgj mRlft Z r gks usd si'pkr~Q ksVksby s DVªkW u d hxfrt

Å t kZfujUrj rc rd ?kVrh gSt c rd os/kkrqls,d fu'fpr nwjh ij gksrsgSA) (D) the emitted photo electrons move with constant speed after escaping from the field of metal. (/kkrqd s{ks =k lsckgj fud y usd si'pkr~mRlft Zr Q ksVksby sDVªkWu fu;r pky lsxfr d jrsgSA) 44.

In young’s double slit experiment, slits are arranged in such a way that besides central bright fringe, there is only one bright fringe on either side of it. Slit separation d for the given condition cannot be (if  is wavelength of the light used) : (;a x d sf}fN nziz;ksx esa]fN nzksad ksbl izd kj l sO;ofLFkr fd ;k t krk gSfd d sUnzh;

ped hy h fÝ Ut d sv y kok] d soy ,d ped hy h fÝ Ut bl d sfd l h ,d rjQ curh gSA mijksä fLFkfr d sfy , fN nzksad s e/; nwjh ughagksl d rh (mi;qZä izd k'k d h rjaxnS/;Z gS) : (A)  45.

(B) /2

(C) 2

(D) 3/2

Both a point source of sound & an observer are at rest. If air starts blowoing then (/ofu

d k ,d fcUnqL=kksr o ,d Jksrk nksukasfLFkj gSA ;fn gok cguk izkjEHk gkst krh gSrks) – (A) The velocity of sound will change (/ofu d kos x ifjofrZr gksxkA) (B) The frequency detected by the observer will change (Jks rk}kjklquhx;hvko`fÙkifjofrZr gks xhA) (C) The wavelength of sound will change (/ofu d hrja xnS/;ZifjofrZr gksxhA) (D) The intensity of the sound will change. (/ofu d hrhoz rkifjofrZr gksxhA ) SECTION - III

Comprehension Type This section contains 2 paragraphs. Based upon each paragraph, 3 multiple choice questions have to be answered. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.

[k.M - III c) cks/ku çd kj bl [k.M esa2 vuqPNsn (paragraphs) gSA çR;sd vuqPNsn ij vk/kkfjr 3 cgq& fod Yih ç'u d smÙkj nsus gSA çR;sd ç'u d s 4 fod Yi (A), (B), (C) rFkk(D) gS, ft ues alsflQ Z,d lgh gSA Paragraph for Question Nos. 46 to 48 iz'u 46 l s48 d sfy , v uqPN sn A monoatomic ideal gas is filled in a nonconducting container. The gas can be compressed by a movable nonconducting piston. The gas is compressed slowly to 12.5% of its initial volume.

,d ijek.kqd ,d v kn'kZxSl d ksv pky d ik=k esaHkjk t krk gSA xSl d ks,d xfr d jus;ksX; v pky d fiLVu l sl aihfMr fd ;k t k l d rk gSA xSl d ksizkjfEHkd v k;ru d s12.5% rd /khjs/khjsl aihfMr fd ;k t krk gSA 46. 47.

The percentage increase in the temperature of the gas is : (xS l (A) 400% (B) 300% (C) – 87.5%

d srki esaizfr'kr o`f) ) & (D) 0%

The ratio of the initial adiabatic bulk modulus of the gas to the final value of adiabatic bulk modulus of the gas is : (xS l d sizkjfEHkd : ) ks"e vk;ru izR;kLFkrk xq.kkad d k vfUre : ) ks"e vk;ru izR;kLFkrk xq.kkad d slkFkvuqikr gS) (A) 32 (B) 1 (C) 1/32 (D) 1/4

Page - 58

STPFXII1213

48.

The ratio of work done by the gas to the change in internal energy of the gas is : (xS l }kjk fd ;sx;sd k;Zd k xSl d h v kUrfjd Å t kZesaifjorZu d sl kFk v uqikr gS) & (A) 1 (B) –1 (C)  (D) 0

Paragraph for Question Nos. 49 to 51 iz'u 49 l s51 d sfy , v uqPN sn In the figure shown the loop placed in the plane of the paper has radius 'R', self inductance 'L' and zero resistance. A uniform magnetic field B = B0sint is applied (B0 and  are positive constants) normal to the plane of the paper. Initially the loop has zero current : (çnf'kZ r fp=kesad kxt d sry esaj[ksywi d hf=kT;k'R', Loçsjd Ro 'L' rFkk'kw U;

çfrjks/kgS A ,d leku pqEcd h; {ks =kB = B0sint (B0 rFkk /kukRed fu;rkad gS) d kxt d sry d syEcor~vkjks fir fd ;kt krk gSA çkjEHk esay wi esa'kwU; /kkjk gSA)

49.

Direction of current in the loop at t = (A) clockwise

 : 3

(t =

 3

ij y wi esa/kkjk d h fn'kk gksxh) :

(nf{k.kkorZ )

(B) anticlockwise (okekorZ ) (C) no current will flow at that time (ml

le; ij d ksbZ/kkjk çokfgr ughagksxh) (D) cannot be determined (x.kukughad j ld rs ) 50.

The current in the loop at time t =

(A)

(C) 51.

5 is : 6

B 0 R 2 clockwise (nf{k.kkorZ ) 2L 3 B 0 R 2 clockwise (nf{k.kkorZ ) 2L

(t =

5 6

(B)

B 0 R 2 anticlockwise (okekorZ ) 2L

(D)

le; ij y wi esa/kkjk gksxh) :

3 B 0 R 2 anticlockwise (okekorZ ) 2L

The magnitude of self induced emf in the loop will : (y w i

esaLoçsfjr fo|qr okgd cy d k ifjek.k) & (A) depend on value of L (L d seku ij fuHkZ j gksxkA) (B) not depend on value of R (R d seku ij fuHkZj ughagksxkA) (C) not depend on B0 (B0 ij fuHkZ j ughagksxkA) (D) depend on B0 (B0 ij fuHkZ j gksxkA) SECTION - IV ([k.M - IV)

Matrix - Match Type (eS fVªDl &l qesy izd kj) This section contains 1 question. Each question contains statements given in two columns which have to be matched. Statements (A, B, C, D) in Column-I have to be matched with statements (p, q, r, s) in Column-II. The answers to these questions have to be appropriately bubbled as illustrated in the following example. If the correct matches are A-p , A-r , B-p , B-s , C-r , C-s and D-q, then the p q r s correctly will look like in bubbled matrix. Each statement in Column–I may have A p q r s one or more than one correct options in Column–II. One Mark will be awarded for B p q r s each statement in Column–I is matched with all correct options in Column-II. If all C p q r s the statements in column-I are correctly matched to their D p q r s correct options in column-II , then 6 marks will be awarded.

bl [k.M es a1 iz 'u gS A iz a R;s d iz 'u es anksd kW y e es aoDRO; (statements) fn;sgq , gS aft ud k lq es y (match) d juk gS A d kW ye (Column-I) es afn;sx;soDrO;kas(A, B, C, D) d ksd kW y e (Column-II) es afn;sx;soDrO;ks a(p, q, r, s) lslq es y d jukgS A bu iz 'uks a d smÙkj fn;sx;smnkgj.k d svuq l kj mfpr cq Yyks ad ksd kyk d jd sn'kkZ uk gS A ;fn lgh lq es y A-p, A-r, B-p, B-s, C-r, C-s rFkkD-q gS ]arkslghfof/klsd kysfd , x;scq Yykasd k4 x 4 es faVª Dl (matrix) es an'kk;Zkx;kgS A d kW y e–I d siz R;s d oDÙkO; d k d kWy e–II d s ,d ;k ,d ls T;knk fod Yiksa ls l qesy d jk;k t k l d rk gSA d kWy e–I d s izR;sd oDÙkO; d k Page - 59

STPFXII1213

d kW y e–II d slHkh lgh fod Yiks alslq es y d jkusd sfy , ,d vad iznku fd ;k t k;sxkA ;fn d kW y e–I d slHkh OkDÙkO;ksad k d kW y e–II d slHkh lgh fod Yiksalslqesy fd ;k x;k rks6 vad iznku fd ;st k;sxsaA 52.

Two identical uniform solid smooth spheres each of mass m each approach each other with constant velocities such that net momentum of system of both spheres is zero. The speed of each sphere before collision is u. Both the spheres then collide. The condition of collision is given for each situation of column-I. In each situation of column- information regarding speed of sphere(s) is given after the collision is over. Match the condition of collision in column- with statements in column-. nksle: i ,d leku fpd usxks y kd kj xks y sft ud kiz R;s d d knz O;eku m gS,d nw l jsd hrjQ fu;r os xks alsbl rjg lsut nhd

vkjgsgSfd nksuksaxksy sd sfud k; d kifj.kkehlaosx 'kwU; gSA izR;sd xksy sd hVd d j iwoZpky u gSA nksuksaxksy src Vd jkrsgSA VDd j d h'krZLrEHk-I d hizR;sd fLFkfr d sfy , nhxbZgSA LrEHk- d hizR;sd fLFkfr esaVd d j [kRe gksusd sckn d hlwp uknh xbZgSA VDd j d h 'krZt ksfd LrEHk- esanh xbZgSog LrEHk- esafn;sx;soDrO;ksalslqesfy r d jksA Column- (A) Collision is perfectly elastic and head on (B) Collision is perfectly elastic and oblique (C) Coefficient of restitution is e =

1 and 2

collision is head on

(A) VDd j

iw.kZr;k izR;kLFk gSo l Eeq[k gS (B) VDd j iw .kZr;k izR;kLFk gSo fr;Zd gS d k izR;koLFku e =

1 2

rFkk

VDd j l Eeq[k gSA (D) VDd j

(r) speed of both spheres after collision is same but less than u.

1 (D) Coefficient of restitution is e = and 2 collision is oblique LrEHk-

(C) VDd j

Column- (p) speed of both spheres after collision is u (q) velocity of both spheres after collision is different

(s) speed of one sphere may be more than u.

LrEHk- d sckn nksuksaxksy ksd h pky u gSA (q) VDd j d sckn nks uksaxksy ksd sosx v y x v y x gS (p) VDd j

(r) VDd j

d sckn nksuksaxksy ksd h pky l eku gS

ij u l sd e gSA

d k izR;koLFku xq.kkad e =

rFkk VDd j fr;Zd gSA

1 2

(s) ,d

xksy sd h pky u l sv f/kd gks

Hkh l d rh gSA

PART - III SECTION - I ([k.M - I) Straight Objective Type (lh/ksoLrq fu"B

izd kj)

This section contains 9 multiple choice questions. Each question has choices (A), (B), (C) and (D), out of which ONLY ONE is correct. bl [k.M esa9 cgq& fod Yih iz'u gSA izR;sd iz'u d s4 fod Yi (A), (B), (C) rFkk(D) gSa, ft uesalsflQ Z,d lgh gSA 53.

Which has maximum internal energy at 290 K ? (290 K ij vf/kd re (A) Neon gas ¼fu;kW u

xSl ½ (C) Ozone gas ¼vks t ksu xSl ½ 54.

vkUrfjd Å t kZfd ld h gksrh gS\) (B) Nitrogen gas ¼ukbVª kst u xSl ½ (D) Equal ¼leku½

2.5 L of a sample of a gas at 27°C and 1 bar pressure is compressed to a volume of 500 mL keeping the temperature constant, the percentage increase in pressure is : 27°C rki

vkSj 1 ckj nkc ij ,d xSl d s2.5 L uewusd ks500 mL d svk;ru rd LkEihfM+r d jrsgSa]ft lesarki fu;r jgrk gS]rc nkc esafd rus% o`f) gksxhA (A) 100 %

(B) 400 %

(C) 500%

(D) 80%

Page - 60

STPFXII1213

55.

Which of the following contains the greatest number of atoms ? (fuEu

eslsd kS u ijek.kqd hvf/kd re la [;kj[krkgS \) (A) 1.0 g of butane (C4H10) (1.0 g C;w Vsu (C4H10) (B) 1.0 g of nitrogen (N2) (1.0 g ukbVªkst u (N2) (C) 1.0 g of silver (Ag) (1.0 g flYoj (Ag) (D) 1.0 g of water (H2O) (1.0 g t y (H2O)

56.

Select the correct statement : (l gh d Fku 4–

pqfu;s)

v k;u [XeO6]4– d h T;kfefr v "BQ y d h; gS) (B) XeF2 is bent molecule with 3 lone pairs (l.p) (3 ,d kd h ;q Xe (l.p.) d sl kFk XeF2 eqM +h gqbZv kd `fr d k v .kqgS) (C) XeOF4, XeF4, XeO2F2 all contains one lone pair only (XeOF4, XeF4, XeO2F2 lHkhd s oy ,d ,d kd h;qXe j[krsgS) (D) None of these ¼bues al sd ksbZugha½ (A) Perxenate ion is [XeO6]

57.

with octahedral geometry. (ijft us V

In electrolysis of Al2O3 by Hall-Heroult process : (gkW y &gsjkYV fof/k d s}kjk Al2O3 d sfo|qr vi?kVu esa%) (A) cryolite Na3[AlF6] lowers the melting point of Al2O3 and increases its electrical conductivity. Ø k;ksy kbZV Na3[AlF6], Al2O3 d sxy ukad d ksd e d jrk gSrFkk bld h fo|qr pky d rk d ksc