Rateof Reaction Part 2

DBOALTXP\ EIPA ?

PGXO IE POGDXLIM

EGDXIPT XBGX GEEODX XBO PGXO IE POGDXLIM

Xoavopgxupo ie Pogdxgmx

Tl{o ie Pogdxgmx

EGDXIPT

Vpottupo ie Pogdxgmx

Dimdomxpgxlim ie Pogdxgmx Dgxgj|tx

TL[O ^bom tl{o ie pogdxgmxt hodpogto* xbo xixgj tupegdo gpog ie pogdxgmx ~ljj lmdpogtoXlao xgcom eip pogdxlim lt jottop- Pgxo ie pogdxlim lt blnbop    ¬

DIMDOMXPGXLIM ^bom dimdomxpgxlim ie pogdxgmxt lmdpogto* xbo blnbop mua`op ie vgpxldjot vop umlx ijuao^ljj dguto xlao xgcom xi elmltboh xbo pogdxlim `odiao jottop- Pgxo ie pogdxlim lt blnbop-

   a    i    d     x    i    v    t XOAVOPGX_PO    n ^bom xoavopgxupo ie pogdxgmxt lmdpogto* clmoxld omopn| ie vgpxldjot lmdpogto   i     j Xlao xgcom xi diavjoxo xbo pogdxlim lt jottop- Pgxo ie pogdxlim lt blnbop     `  VPOTT_PO "imj| eip ngt,    a ^bom vpottupo lmdpogto clmoxld omopn| ie vgpxldjot lmdpogto   v    t Xlao xgcom xi diavjoxo xbo pogdxlim lt jottop- Pgxo ie pogdxlim lt blnbop    8    t    t DGXGJ\TX    g     j ^bom utlmn dgxgj|tx* lx ~ljj vpilho gjxopmgxlo vgxb~g| xi diavjoxo xbo pogdxlim    d Xlao xgcom xi diavjoxo xbo pogdxlim lt jottop- Pgxo ie pogdxlim lt blnbop    a    o     b    d     )     )    ;    v    x    x bxxv;))dboadjgtt8tva-`jintvix-dia ¬     b Dpogxoh `| Mgnul` [gcgplg

4

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DBOALTXP\ EIPA ?

PGXO IE POGDXLIM

TL[O IE POGDXGMXT

Orv 706 da4 ie 6-? aij ha !4 b|hpidbjipld gdlh # ordott ie dgjdlua dgp`imgxo " tagjj dblvt, Owugxlim 0BDj # DgDI4 DgDj0 # B0I # DI0

Orv 006 da4 ie 6-? aij ha !4 b|hpidbjipld gdlh # ordott ie dgjdlua dgp`imgxo " jgpno dblvt, Owugxlim 0BDj # DgDI4 DgDj0 # B0I # DI0

Potujx

   4

   a    d     Z    t    g    n    0

   I    D     e    i    o    a    u     j    i    U

Orv 7-

Orv 0-

    ¬

   a    i    d     x    i    v    t    n    i     j     `     a    v    t    8    t    t    g     j    d

Xlao xgcom ) t

Xbo npghlomx dupo eip Orv- 7 lt BLNBOP xbgm dupo lm Orv- 0 Xbo Xlao Xgcom lm Orv- 7 xi diavjoxo xbo pogdxlim lt TBIPXOP xbgm Orv- 0 Xbo Pgxo ie Pogdxlim lm Orv- 7 lt BLNBOP xbgm Orv- 0 ++ ^bom tagjj tu`txgmdot gpo utoh* xixgj tupegdo gpog ie tu`txgmdot gpo lmdpogto* ti pgxo ie pogdxlim lmdpogtoh-

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DBOALTXP\ EIPA ?

PGXO IE POGDXLIM

XOAVOPGX_PO

Orv ?6 da4 ie 6-0 aij ha !4 tihlua xblitujvbgxo tijuxlim # ? da 4 ie 7-6 aij ha !4 tujvbupld gdlh- Orvoplaomx lt povogxoh gx hleeopomx xoavopgxupo ie tihlua tujvbgxo* 86 iD* 8? iD* ?6 iD gmh ?? iDOwugxlim Mg0T0I4 # B0TI8

0MgTI8 # TI0 # T # B0I

Potujx

   D    i     )    o    p    u    x    g    p    o    v    a    o    X

Xbo BLNBOP xbo xoavopgxupo xbo BLNBOP xbo pgxo ie pogdxlim^bom xbo xoavopgxupo lmdpogtoh* xbo xlao xgcom xi diavjoxo xbo pogdxlim lt hodpogto-

Xlao xgcom ) t

    ¬

   a    i    d     x    i    v    t    n    i     j     `     a    v    t    8    t    t    g     j    d

   D    i     )    o    p    u    x    g    p    o    v    a    o    X

Xbo xoavopgxupo lt hlpodxj| vpivixlimgj xi 7)xlao7)xlao povpotomxt xbo Pgxo ie Pogdxlim Bomdo* Xoavopgxupo lt hlpodxj| vpivixlimgj xi xbo pgxo ie pogdxlim-

 ∑

7

 

)t!7

7



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DBOALTXP\ EIPA ?

PGXO IE POGDXLIM

DIMDOMXPGXLIM

Orv ?6 da4 ie 6-0 aij ha !4 tihlua xblitujvbgxo tijuxlim # ? da 4 ie 7-6 aij ha !4 tujvbupld gdlh- Orvoplaomx lt povogxoh gx hleeopomx dimdomxpgxlim "utlmn hljuxlim aoxbih xi hljuxo xbo tihlua xblitujvbgxo, Owugxlim Mg0T0I4 # B0TI8

0MgTI8 # TI0 # T # B0I

Potujx

Xbo BLNBOP xbo dimdomxpgxlim xbo BLNBOP xbo pgxo ie pogdxlim-

   m    i    l    x    g    p    x    m    o    d    m    i    D

^bom xbo dimdomxpgxlim lmdpogtoh* xbo xlao xgcom xi diavjoxo xbo pogdxlim lt hodpogto-

Xlao xgcom ) t

    ¬

   a    i    d     x    i    v    t    n    i     j     `     a    v    t    8    t    t    g     j    d

Xbo dimdomxpgxlim hlpodxj| vpivixlimgj xi 7)xlao7)xlao povpotomxt xbo Pgxo ie Pogdxlim Bomdo* Dimdomxpgxlim lt hlpodxj| vpivixlimgj xi xbo pgxo ie pogdxlim-

   m    i    l    x    g    p    x    m    o    d    m    i    D

  ∑

7

 

)t!7

7



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DBOALTXP\ EIPA ?

PGXO IE POGDXLIM

DGXGJ\TX Orv 0? da4 6-7 aij ha!4 b|hpidbjipld gdlh pogdx ~lxb ?n npgmujgxoh {lmd ~lxb vpotomdo ie ? da 4 6-? aij ha!4 divvop "LL, tujvbgxo tijuxlim gt dgxgj|txPovogx orvoplaomx ~lbxiux vpotomdo ie dgxgj|tx Owugxlim DuTI 8 0BDj # [m [mDj0 # B0

   4

   a    d  *    t    g    n     e    i    o    a    u     j    i    U

Divvop "LL, tujvbgxo gdx gt dgxgj|tx xi tvooh uv xbo pogdxlimDgxgj|tx lmdpogto xbo pgxo ie pogdxlim `ox~oom {lmd gmh gdlhXbo xlao xgcom xi diavjoxo xbo pogdxlim lm Orvoplaomx utlmn dgxgj|tx lt tbipxop xbgm xbo orvoplaomx ~lxbiux dgxgj|tx-

Xlao xgcom ) t Orv ~lxb dgxgj|tx Orv ~lxbiux dgxgj|tx

    ¬

   a    i    d     x    i    v    t    n    i     j     `     a    v    t    8    t    t    g     j    d

Mixo Gaiumx ie dgxgj|tx utoh lm orvoplaomx ~ljj geeodx xbo xlao xgcom eip xbo pogdxlim xi diavjoxo* `ux lx hiot mix geeodx xbo gaiumx ie vpihudx vpihudoh-