Química General Ii UNIDAD V. M.Sc. Marianelly Esquivel A

QUÍMICA GENERAL II . M.Sc. Marianelly Esquivel Esquivel A.

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EQUILIBRIO QUÍMICO



Muchas reacciones no se completan, sino que se aproximan a un estado de equilibrio en el que están presen enttes tanto reactivos como prod oduuctos os..

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

Ejemplo: N2O4 y NO2 N2O4 (g) Incoloro

→

2 NO2 (g)

Pardo rojizo

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MEZCLA

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EQUILIBRIO QUÍMICO 



La condición en la cual las concentraciones de todos los reactivos y productos en un sistema cerrado dejan de cambiar con el tiempo. Reacciones opuestas avanzan a velocidades iguales.

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EQUILIBRIO QUÍMICO Reac eacci ción ón di dire rect cta: a: A eacci ción ón in invver ersa sa:: B  Reac 

→



B velocidad = kd [A] A velocidad = ki [B]

→

kd y ki son las constantes de velocidad de las reacciones.

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PV = nRT

[A] = PA/RT

Molaridad = n/V = P/RT

[B] = PB/RT

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EQUILIBRIO QUÍMICO 

Una vez establecido el equilibrio las presiones parciales de A y B ya no cambian.

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PROCESO HABER N2 (g) + 3 H2 (g)

2 NH3 (g)

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Al colocar solamente NH 

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LEY DE ACCIÓN DE MASAS

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EXPRESIÓN DE EQUILIBRIO

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CONSTANTE CONST ANTE DE EQUILIBRIO

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CONSTANTE CONST ANTE DE EQUILIBRIO

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aA+bB

cC+dD

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CALCULO DE LA CONSTANTE DE EQUILIBRIO DIRECTO 



Es de suma importancia para un proceso industrial tipo Haber, si el valor de Keq era muy pequeño en el equilibrio la cantidad de NH3 sería muy muy pequeña. Se partió de varias mezclas de N2, H2 y NH3, se dejó que alcanzaran el equilibrio y

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EJERCICIO Se permite que una mezcla de hidrógeno y nitrógeno en un recipiente de reacción alcance el equilibrio a 472 C.  Se analiza la mezcla de gases en el equilibrio y se encuentra que contiene 7,38 atm de H2, 2,46 atm de N2 y 0,166 atm de NH3. 

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CALCULO DE LA CONSTANTE DE EQUILIBRIO CONOCIENDO SOLAMENTE UNA CONCENTRACIÓN 



Cuando se conoce al menos una de las concentraciones en equilibrio de una de las especies, la estequiometría permite deducir las concentraciones de equilibrio de las demás especies. ESTRATEGIA: 1. [ ] iniciales y en equilibrio conocidas

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EJERCICIO 

 

Se disuelve suficiente suficiente amoniaco en 5,00 Litros de agua a 25°C para preparar una disolución de amoniaco 0,0124 M. Después, se se permite per mite que la disolución alcance el equilibrio. El análisis de la mezcla de equilibrio muestra que la concentración de OH- es 4,64x10-4 M.

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Inicial

NH3 (ac) + H2O (l)

NH4+ (ac) + OH- (ac)

0,0124 M

0M

0M

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APLICACIONES DE LAS CONSTANTES DE EQUILIBRIO 

La constante de equilibrio permi rmite:

1. P d i l di

ió

l

ll

á

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1. Predicción de la dirección de reacción 

COCIENTE DE REACCIÓN (Q): al sustituir presiones parciales o concentraciones de

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INTERPRETACIÓN 

Sistema ema en equili ilibrio Q = Keq Sis Q>K

S t

i

d l l d

d

h

i

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Ejemplo

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P=nRT/V

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N2 ( ) + 3 H2 (

)

2 NH3 (

)

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2. Cálculo [ ] en el equilibrio

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Ejercicio

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3. EFECTO DE LOS CAMBIOS DE TEMPERA TEMPERATURA TURA 

Si se trata el calor como un reactivo o producto según sea el caso, se explica la dependencia del equilibrio resp respeecto a la temperat ratura. ra.

ENDOTÉRMICA Reactivos + CALOR

Productos

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3. EFECTO DE LOS CAMBIOS DE TEMPERA TEMPERATURA TURA ENDOTÉRMICA Reactivos + CALOR 

Productos

Al aumentar la T, es como si se adicionara un reactivo, el equilibrio se desplaza hacia la derec ha y el valor de K aumenta.

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3. EFECTO DE LOS CAMBIOS DE TEMPERA TEMPERATURA TURA EXOTÉRMICA Reactivos 

Productos Productos + CALOR

Al aumentar la T, el equilibrio se desplaza hacia la izquierda, la Keq disminuye.

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Ejercicio 

Considérese el siguiente equilibrio. En que sentido se desplazará el equilibrio al efectuar los cambios siguientes a un sistema en equilibrio. ΔHº

N2O4 (g) A.

Agreg regar N2O4.

2 NO2 (g)

= 58,0 kJ

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EFECTO DE LOS CATALIZADORES CATALIZADORES 



Aumenta la rapidez con la que se alcanza el equilibrio, pero no modifica la composición de la mezcla. No influye en el valor de la constante de

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Ejercicio 

Se pone yoduro de hidrógeno gaseoso en un recipiente cerrado a 425ºC, donde se

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Ejercicio 

Se coloca una mezcla de 0,10mol de NO, 0,050 mol de H2 y 0,10 mol de H2O en un recipiente

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Ejercicio 

A 100ºC la constante de equilibrio de la reacción tiene un valor de Keq= 6,71x10-9. están en

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Ejercicio 

A 1285ºC la constante de equilibrio de la reacción es Keq = 0,133. un recipiente de 0,200 L

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Ejercicio