Problemas Unidad 4

August 9, 2022 | Author: Anonymous | Category: N/A
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GS^WI @C PC^EI@ADÈEAGH= Z^INOCEHW ^CWSCOPIW 

Z^INOCEHW SDA@H@ 0= Z^IZAC@H@CW \IOSEÁP^AGHW @C OIW LOSA@IW   8. Oh prcsa÷d `c vhpir `co nriei oåqua oåqua`i `i h 1.7ºG cs 8:: Pirr. Wa co ghoir `c vhpirazhga÷d cs `c 7:18: M/eio, ghogýocsc co pudti direho `c cnuooaga÷d `co nriei.

@HPIW= P 5 1.7ºG 5 >6>.03 K

Z* 5 8:: 8:: Pirr

F\   5 7:18: M/eio ˌ

WIOSGA×D=  Gidsa`crhd`i Gidsa `crhd`i quc c o

F\   cs gidsthdtc, cs `cgar, quc di `cpcd`c `c P  y y quc cs hpoaghnoc oh cguhgåid `c ˌ

Gohusaus-Gohpcyrid, Gohus aus-Gohpcyrid, tcdceis=

od Z* 5 ∞

F\  ˌ

^P

 

+  G 5 ∞

F\ 

^

ˌ



+ G   

`id`c=  M F\    7:18: eio  5 5 7282.6>373K   ˌ

 M 6.780 eioK 

^

 H`ceès, oh gidsthdtc G   oh pi`ceis ghoguohr h phrtar `co vhoir gidiga`i `c prcsa÷d `c vhpir Z * h udh tcepcrhturh `h`h P , giei sc ad`agh ad`agh h gidtaduhga÷ gidtaduhga÷d= d=

G

5 od Z * +

F\  ˌ

P

^

 

5 od (8:: ) +

G  5  5

7282.6>373K  >6>.03K 

 

82.2373 + 82.2

^

+ G   

y 

G 5 odZ>

  F +  \  ˌ

P >

^

 

(>)

Abuhohd`i ohs cguhgaidcs (8) y (>), rcsuoth=

E. G. OSAW DACPI OCESW 

LAX-SEWDF

Zèbadh > `c 07 

 

GS^WI @C PC^EI@ADÈEAGH= Z^INOCEHW ^CWSCOPIW 



odZ8



odZ8

F\

^

ˌ

+

P8

  F ∞ odZ> 5  \ Z8



Z>



od

Z8



Z>



^

ˌ

P >

F\ 

^

ˌ

P 8

 

 

F\   8 8     ∞  ^  P> P8   ˌ

ˌ

ˌ

^

6.780 ( 5

F\ 

F  P ∞ P   5    \   8 >    ^  P8 P>   

F\ 

ˌ



P>

od



^

ˌ



^P P Z F\  5   8 > od  8 P8 ∞ P> Z>

5 odZ> +



  P8 P >

5

 

P8 ∞ P>

 M eioK 

od

Z8

 



Z>

)(836.83K )(>18.:3K ) od 8::Pirr

836.83K ∞ >18.:3K

0::Pirr

 

   

  M

ˌ

  eio    F\  5 7118.62677

 H`ceès=  M F\    7118.62677 eio  5 5 06:.87 06:.8717> 17> K    M ˌ

6.780 eioK 

^

G



5 odZ8 +

F\

^

ˌ

P8



5 odZ> +

F\  ˌ

^

P >

 

Zir oi quc, co vhoir `c G  sc  sc puc`c ghoguohr gid nhsc h ois vhoircs gidiga`is `c Z * y P  girrcspid`acdtcs  girrcspid`acdtcs h ohs gid`agaidcs adagahocs adagahocs i ladhocs= 

G 5 odZ8

  F + \  ˌ

P8

^

 

5 od(8:: ) +

06:.8717> K  836.83K 

5 2. P ( K )

+ 2. K  n P  5 G ∞ od Z 5 2.6 0:2.>6K    5 0:2

P 5 Pn 5 870.87 870.87 G   0. Ohs prcsaidcs `c vhpir `co si`a si`ai i oåqua`i si sid= d= P (ºG)

071

301

2:8

Z* (Pirr)

8

8:

8::

@ctcreådcsc co pudti direho `c cnuooaga÷d, co ghoir `c vhpirazhga÷d y oh cdtripåh `c vhpirazhga÷d cd co pudti direho `c cnuooaga÷d `co si`ai oåqua`i.

WIOSGA×D=  Gid nhsc h oh cguhga÷d `c Gohusaus Gohpcyrid, tcdceis quc udh rcprcscdthga÷d `c odZ * vs 8/P(K)  dis `cncråh `hr udh oådch rcgth, cd ghsi `c quc csth cguhga÷d rcsuotc hpoaghnoc phrh co si`ai oåqua`i=

odZ* 5 ∞ 

F\  ˌ



^

od Z* 5 G  ∞ 

+ G  

F\   8 ˌ

^ P 

 

Zir oi thdti, sc prigc`crè h ud hmustc `c ois `htis cxpcraecdthocs scbýd oh rcprcscdthga÷d ad`agh`h= P (K)

28>.83

6>>.83

120.83

Z (Pirr)

8

8:

8::

E. G. OSAW DACPI OCESW 

LAX-SEWDF

Zèbadh 3 `c 07 

 

GS^WI @C PC^EI@ADÈEAGH= Z^INOCEHW ^CWSCOPIW  Ois rcsuoth`is intcda`is sid ois sabuacdtcs=

5 82.8>817.281.2810/P + 82.8>< ^¾ 5 8

0.: 7.3 7.:        Z

>.3

     d        o

>.: 8.3 8.: :.3 :.: :.::8

:.::88

:.::8>

:.::87

:.::80

:.::83

8/P (K) Zir oi thdti, co pudti direho `c cnuooaga÷d `co si`ai oåqua`i scråh= :

P n

5

F\  ^ 8>817.2 .8> 5 881.7ºG 5 71>.03 K

Z>

P 5 3>.3.23 K

Z * 5 8 Pirr

*

 5 0: Pirr

WIOSGA×D=  h) Zraecrhecdtc, co

Fvhp  `co oåqua`i oi ghoguohrceis gid nhsc h oh cguhga÷d `c Gohusaus Gohpcyrid= ˌ

F\  ˌ

^ 

^P P Z F\  5   8 > od  8 P8 ∞ P> Z> ˌ



  P8 P>



PP   Z od  5 8 > od >   5 P8 ∞ P> Z> P> ∞ P8 Z8

6.780 ( 5

Z8

 M eioK 

) (736.13K ) ( 71>.03K ) od 8:Pirr

736.13K ∞ 71>.03K

0:Pirr

 

   

ˌ

  M     eio  F\   5 060

^

 

Zèbadh 2 `c 07 

 

GS^WI @C PC^EI@ADÈEAGH= Z^INOCEHW ^CWSCOPIW 



G 5 odZ8

  F + \  ˌ

^

P8

 

5 od(8: ) +

36>1.00K 736.13K 

5 86.30>1>:  

Gid oi guho, oh cguhga÷d quc rcohgaidh h oh prcsa÷d `co dhlthocdi gid oh tcepcrhturh scråh=

36>1.00 od Z * (Pirr )  5 ∞

+ 86.30>1>  

P ( K )

Zir oi quc, oh tcepcrhturh direho `c cnuooaga÷d cs= :

P n

5

F\  ^   36>1.00 K  5 5 06 061. 1.0 02< 21> ∞ od ( 21>  

737.83 K 

Z* 5 2.< ..3.23 K

Z8

P> 5 6:.:ºG 5 737.83 K

Z>

*

 5 8 Pirr  5 2.     Z8 od  5 ^ P8 ∞ P> Z>

Fs ˌ



^P P Z Fs 5   8 > od  8 P8 ∞ P> Z> ˌ

6.780 ( 5

 M eioK 

 

) (7>3.23K ) (737.83K ) od

7>3.23 K ∞ 737.83 K

8Pirr

 

2.

P8

5 o d (8 ) +

 

P >

6302.3718:K 7>3.23K 

^

5 >7137130 >0: ::6 ei 060 0 >>><   .>71 > 713 3>< >8.: eeFb h 3:ºG ˌ

@HPIW= *

P8 5 0:ºG 5 787.83 K

Z8

P> 5 2:ºG 5 707.83 K

Z>

*

 5 873.77 eeFb  5 30>.3: eeFb

WIOSGA×D=  Zraecrhecdtc, co

Fv   `co oåqua`i oi ghoguohrceis gid nhsc h oh cguhga÷d `c Gohusaus Gohpcyrid= ˌ



^P P Z F\  5   8 > od  8 P8 ∞ P> Z> ˌ

E. G. OSAW DACPI OCESW 

( 6.780 5

 M eioK 

) ( 787.83K ) (707.83K ) od 873.77 eeFb

787.83K ∞ 707.83 K

LAX-SEWDF

30>.3: eeFb

 

Zèbadh 1 `c 07 

 

GS^WI @C PC^EI@ADÈEAGH= Z^INOCEHW ^CWSCOPIW    M F\   5 08706.27677   eio    ˌ

 H`ceès=

odZ* 5 ∞

F\  ˌ

 

+G 5 ∞  

F\  ˌ

^P

Zir oi thdti=

F\  ˌ

^

+ G   



 M   08706.27677 eio 

5

^

 M 6.780 eioK 

5 0127 0127.76  

Gid oi guho, oh cguhga÷d quc rcohgaidh h oh prcsa÷d `co cthdio gid oh tcepcrhturh cs=

od Z * ( eeFb ) 5 ∞ 0127.76:.2613>   P ( K ) Zir oi quc phrh P  5  5 3:ºG 5 7>7.83 K, oh prcsa÷d `c vhpir `co cthdio cs=

(

Z * eeFb









K  + >:.2613>    ) 5 cx p  ∞ 0127.767.83 K 

Z* 5 >> >>8. 8.>> >>< < eeFb  

2. Co ghoir `c vhpirazhga÷d `co átcr ctåoagi, G0F8:I (E 5 20.8> b/eio), cs 67.1 gho/b, cd thdti quc q uc su prcsa÷d `c vhpir h 7:ºG vhoc 5 86. 5 P ∞ P od Z    >



od

   5

8



Z>  `co átcr ctåoagi cs=

Cdtidgcs, phrh P > 5 :ºG 5 >27.83 K, oh prcsa÷d `c vhpir

Z>

8

F\  P> ∞ P8   ˌ

Z8

^

P8 P>  

 

   F\  P> ∞ P8   5 cxp       Z8 ^ P P    8 >  

Z>

ˌ



Z>



Z>

     F\  P> ∞ P 8  5 Z8 cxp      ^ P P  8 >   ˌ

 

 >27. >27.8 83 K ∞ 7:7. 7.83 83 K   5 ( 1.2 7.8 8 3 K K  ( ) ( )   Z> 5   >:6.>1>3 eeFb  

6. Oh prcsa÷d `c vhpir `co goiri e ecthdi, cthdi, GF7Go (E 5 3:.01 b/eio), cdtrc -02 y -8:ºG sc puc`c rcprcscdthr pir oh cguhga÷d=

(

oib8: Z * eeFb

+ 2.068   ) 5 ∞ 8801 P 

¹Guèo scrè co ghoir `c vhpirazhga÷d `c cstc oåqua`i cd ghoiråhs pir brhei9

^. 8:0.8 gho/b @HPIW=  E 5 881.76 b/eio

WIOSGA×D= Oh cguhga÷d quc sc ad`agh=

(

oib8: Z * eeFb

+ 2.068   ) 5 ∞ 8801 P 

cs saeaohr h oh cguhga÷d `c Gohusaus Gohpcyrid, oh `alcrcdgah cs co tapi `c oibhratei cepoch`i, giei sc ad`agh h gidtaduhga÷d= ad`agh od Z*

5∞

F\  ˌ

^P

 

+G 5 ∞  

F\  ˌ



^

+ G   

Zir itrh phrtc, tcdceis quc= oibh n 5

od n odh

 

Cdtidgcs, gid nhsc h oi hdtcrair, oh cguhga÷d pripucsth oh pi`ceis csgranar `c oh sabuacdtc ehdcrh=

E. G. OSAW DACPI OCESW 

LAX-SEWDF

Zèbadh 88 `c 07 

 

GS^WI @C PC^EI@ADÈEAGH= Z^INOCEHW ^CWSCOPIW 

oib8: Z



5

od Z



od8:

5∞

8801 P 

+ 2.068  

Zir oi thdti= od Z



( eeFb )  5 (od8: )  ∞ 8801 + 2.068    P 



od Z



  >>32 K ) ^ 5 (  >3:: gho/eio. Ghoguoc co pudti `c cnuooaga÷d direho `co oåqua`i.

@HPIW=  P 8 5 8>:ºG 5 717.83 K



Z8  5 2>3 eeFb

F\   5 6>:: gho/eio ˌ



Z>  5 2) cepochrceis oh cguhga÷d `c GohusausGohpcyrid= 

^P P Z F\  5   8 > od 8 P8 ∞ P> Z> ˌ



^P P   Z 5 8 > od >   P> ∞ P8 Z8

I nacd=

F\  ˌ

^

  P8 P >

5

P8 ∞ P>



 

od 8 P>

E. G. OSAW DACPI OCESW 

Z8



Z>



P8 ∞ P>

   

8 P8

5

P8 P> ^

F\  ˌ

5

^

F\  ˌ



od

Z8



Z>

 



od

Z8



Z>

LAX-SEWDF

 

Zèbadh 8> `c 07 

 

GS^WI @C PC^EI@ADÈEAGH= Z^INOCEHW ^CWSCOPIW  8 P>

5

8 P8

+



^

F\ 

od

ˌ

P > 5

Z8



Z >

5

8

+

717.8  3 K

gho  8.162 eioK    gho  6>:: eio 

od

2>3eeFb 276 K   710.1> K 5 8>8.22ºG 8>8.22º G

8:. Co pudti `c cnuooaga÷d direho `co G8 egihooK )Pn: 5 (>8 egihooK ) (0>1.7 K ) 5 1:83.7 eghioo      ˌ

Zir oi quc= gho  F\ :   1:83.7 eio  5 5 0372.8080> K   gho  ˌ

^

8.162 eioK 

Zir itrh phrtc, gid nhsc h oh cguhga÷d `c Gohusaus Gohpcyrid, tcdceis quc= od Z*

Zhrh P 5

5∞

F\  ˌ

^P

 

+G 5 ∞  

F\ 

^

ˌ



+ G   

:

P n  5 0>1.7 K tcdceis quc Z* 5 Z : 5 2:>:83   P 0>1.7K  Zir oi quc, oh cguhga÷d quc rcohgaidh h oh prcsa÷d `c vhpir Z * gid P  phrh  phrh co G:>:83  

 H phrtar `c oh cguhga÷d hdtcrair pi`ceis cvho cvhouhr uhr oh prcsa÷d `c vhpi vhpirr h guhoquacr guhoquacr P , cd co ghsi cd co guho P   5 8::ºG 5 727.83 K, rcsuoth=



0372.8080> K 



727.83 K 

Z* 5 c x p  ∞

E. G. OSAW DACPI OCESW 

 + 82.>:>:83  5 830.17>:3 e eFb   

LAX-SEWDF

Zèbadh 87 `c 07 

 

GS^WI @C PC^EI@ADÈEAGH= Z^INOCEHW ^CWSCOPIW  88. Co GGo0 tacdc ohs sabuacdtcs prcsaidcs `c vhpir h ohs tcepcrhturhs ad`agh`hs= ad`agh`hs= P(ºG)

7:

3:

2:

8::

Z*  (eeFb)

80>.7

780.0

8.8

807.83

707.83

727.83

Z*  (eeFb)

80>.7

780.0

8.8

80

oib Z*5 -88 ^¾ 5 :.1116

7.: >.6

        *        Z      b      i        o

>.< >.0 >.> >.: :.::> :. ::>< < :. :.::> ::>2 2 :. :.::> ::>6 6 :. :.::> ::>1 1 :. :.::7 ::7 :. :.::7 ::78 8 :. :.::7 ::7> > :. :.::7 ::77 7 :.: :.::7 :70 0 8/P(K)  H 5

2.33>:3>2

N 5

-8:3>2 ∞

E. G. OSAW DACPI OCESW 

LAX-SEWDF

8.

Nchttac y Ehrpoc [M. He. Gfce. Wig., Wig., 2>, 803: (813:)U `acrid oh sabuacdtc cguhga÷d phrh oh prcsa÷d `c vhpir `co 8-nutcdi giei ludga÷d `c oh tcepcrhturh cdtrc -23 y 8>3 ºG=

(

oib8: Z * hte

∞ 8 

 

F\   csthråh `h`h pir oh sabuacdtc cguhga÷d= ˌ

>

F

^P 

ˌ





  odZ ` `P 

5

 

(8)

Zi Zirr oi th thdt dti, i, praec praecri ri sc tcd`r tcd`rè è quc quc cv cvhou houhr hr oh `cra `cravh` vh`h h`   od Z `P   y pistcra pistcraire irecdtc cdtc sust sustatua atuarr cd oh cgu cguhga÷ hga÷d d (8) phrh intcdcr oh cguhga÷d quc dis pcreath ghoguohr co

F\    

ˌ

cd lu ludga÷ dga÷d d `c   P , giei sc eucstrh h

gidtaduhga÷d=

(

oib8: Z * hte

od Z 8707.38< 5 3.0230 ∞ ∞ 8  ∞ 763.2823  8:∞3 (8 )    P  

` od Z `P

5

7:17 :17.331 .3311 180 >



3 ∞ 763 763.28 .2823 23 8:∞  

(>)

Wustatuycd`i Wustatuycd` i oh cguhga÷d (>) cd oh cguhga÷d (8), rcsuoth=

F\  5 ^P >

` odZ

ˌ

E. G. OSAW DACPI OCESW 

`P

7:17.331180 ∞3  5 ^P >   ∞ 763. 763.282 2823 3 8:  > P   

LAX-SEWDF

Zèbadh 83 `c 07 

 

GS^WI @C PC^EI@ADÈEAGH= Z^INOCEHW ^CWSCOPIW 

F\  ˌ

^

∞3 > 5 7:1 7:17.3 7.3311 31180 80 ∞ 76 763.2 3.2823 823 8: P   

I nacd, nacd, c cd du uda` da`h`c h`css `c `coo WA, oh cg cguhg uhga÷d a÷d quc` quc`hråh hråh `c oh sabuacd sabuacdtc tc lir lireh eh== ∞3 > F\  5  ^ ( 7:17 7:17.3 .331 3118 180 0 ∞ 763.2 763.282 823 3  8: 8: P  ) ˌ

∞7 kM ∞3 > F\  5 ( 6.78 .78 0 8: eio 7:17.3 .33 31180 ∞ 7 76 63.28 .2823  8: P ) ( K ) eio K  ) ( ˌ

kM F\  (  eio    ) 5 >3.28 281 1632 ∞ 7.> .>:< : ,

P (K )

ˌ

 

n) Zhrh P 5 7:: K, co ghoi ghoirr ei eiohr ohr ohtcd ohtcdtc tc `c vhp vhpira irazhg zhga÷d a÷d scr scråh åh cdtid cdtidgc gcs= s= ∞3 > kM F\   5 >3.28 .281632 1632 ∞ 7.> 7.> ::

ˌ

>

  kM

ˌ

F  5 >>.677K  

LAX-SEWDF

 

Zèbadh 8 s÷oa`i cs 2.

^.  Z> P> ∞ P8 Z8 P8 P>

Wusatuycd`i Wusatuycd `i `htis= 

^P P Z Fs 5   8 > od  8 P8 ∞ P> Z> ˌ

(8.162 5

gho  eioK 

) (82:.83K )(810.

  od Z `

 

ˌ

`P 

Zir oi thdti, praecri sc tcd`rè quc cvhouhr oh `cravh`h

(8)

pistcrairecdtc ecdtc sustatuar cd oh c cguhg guhga÷d a÷d  ` odZ `P    y pistcrair

(8) phr phrh h intcdc intcdcrr oh cgu cguhga hga÷d ÷d qu quc c dis pcreath ghog ghoguoh uohrr co

FW   

ˌ

cd ludg ludga÷d a÷d `c   P , giei sc eucstrh h

gidtaduhga÷d=

(

oib8: Z * hte

E. G. OSAW DACPI OCESW 

+ 8.0:3oib ) 5 ∞ 8>10 P 

8:

LAX-SEWDF

P

∞ :.::38P + 0 .6::  

Zèbadh 82 `c 07 

 

GS^WI @C PC^EI@ADÈEAGH= Z^INOCEHW ^CWSCOPIW  od Z



5∞

od8:

od Z

od Z  ` od Z



5

`P

` od Z `P



8>10 P 

odP   + 8.0:3  ∞ :.::38P  + 0.6::    od8: 

  8>10 odP  5 (od  8: )  ∞ + 8.0:3 ∞ :.::38P  + 0.6::    od8: P   

5 ∞ >121.30388 + 8.0:3odP ∞ 882.0786 8: ∞0 P  + 88.:3>0:6   P 

 ∞ >121.30388 + 8.0:  ∞0 0:3 3odP ∞ 882.0 2.0786  8: P  + 88 88..:3> 3>0 0:6     `P  P    ` 



5 ∞>121.30388

` od Z `P



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