Problemas de Quimica Aplicando Matrices
June 25, 2023 | Author: Anonymous | Category: N/A
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9. Vl kio`ûl cf quïo`kjs trilspjrti pfroilmilitj cf pjtis`j (HOlJ3) aik`i fb pjnbicj cf Mufrrfrj Lfmrj. [`l fonirmj, gustj ib pisir pjr uli cf bis bimulis cf fvipjrik`ûl sudrf ul ikk`cfltf y v`frtf tjci su kirmi fl àsti. Fb prjkfsj cf fvipjrik`ûl cfb imui cf oir aikf quf sf prfk`p`tfl oukais sibfs, uli cf bis kuibfs fs fb subditj cf oilmilfsj (Ol[J3). Ib flkjltrirsf fb pfroilmilitj cf pjtis`j kjl fb subditj cf oilmilfsj sf prjcukf uli rfikk`ûl quf t`flf kjoj prjcuktj ûx`cj cf oilmilfsj (OlJ>), subditj cf pjtis`j (H>[J3) y ék`cj subd÷r`kj (A>[J3). Bjs pr`ofrjs cjs lj sjl tûx`kjs, pfrj fb tfrkfrj pufcf sfr suoiofltf cfsistrjsj piri fb ofc`j ion`fltf, oitilcj tjcj t`pj cf v`ci fl bi bimuli cf fvipjrik`ûl Vli oilfri cf kjoprflcfr fb fdfktj cfb ék`cj fl bi v`ci oir`li, sus kjlsfkuflk`is y bis ofc`cis cf o`t`mik`ûl iprjp`icis, fs fopfzir pjr kjljkfr bis rfikk`jlfs quïo`kis `lvjbukricis, isï kjoj fb nibilkfj quïo`kj kjrrfspjlc`fltf. Bi s`mu`fltf fs bi rfikk`ûl quïo`ki7 Ol[J3 + HOlJ3 + A>J
OlJ> + H >[J3 + A>[J3 [JBVK@JL7
Kjoj sf pufcf iprfk`ir, bi rfikk`ûl quïo`ki LJ sf flkufltri nibilkfici. I pfsir cf quf fx`stfl jtrj t`pj cf oàtjcjs ilibït`kjs piri rfib`zir fb nibilkfj, sf cfk`c`û ut`b`zir fb Ébmfnri B`lfib, fl fspfk`ib bjs s`stfois cf fkuik`jlfs b`lfibfs, piri rfib`zir fb nibilkfj Fb prjkfc`o`fltj fs is`mlir vir`inbfs j `lkûml`tis quf oubt`pb`kil i kici ojbàkubi cf bi fkuik`ûl quïo`ki7 Ol[J3 + HOlJ3 + A>J Q
P
OlJ> + H >[J3 + A>[J3
W
I
N
K
Iajri sf prjkfcf i jntflfr fkuik`jlfs b`lfibfs piri kici fbfofltj. Ujr fgfopbj, kjl rfspfktj ib Oilmilfsj sf t`flf `zqu`frcj bi rfikk`ûl fs oubt`pb`kicj pjr bi Q y(Ol) pjr bi P, y quf cfb cfb bicjbicj cfrfkaj cf bicfrfikk`ûl fs oubt`pb`kicj pjr bi I. Cf tib sufrtf quf bi fkuik`ûl piri fstf fbfofltj qufcirïi7 Ol7
Q+P?I
Cf bi o`soi oilfri sf jnt`flfl bis fkuik`jlfs piri fb rfstj cf bjs fbfofltjs, qufcilcj fb kjlgultj cf fkuik`jlfs b`lfibfs, j [`stfoi cf Fkuik`jlfs B`lfibfs, cf bi s`mu`fltf oilfri7 Ol7 [7 J7 H7
Q+P?I Q?N+K 3Q + 3P + W ? >I + 3N + 3K P ? >N
A7
>W ? >K
Iajri sf `muibil tjcis bis fkuik`jlfs i kfrj y sf fxprfsi fb [`stfoi fl djroi oitr`k`ib7
( )
fl cjlcf bis kjbuolis sjl bjs kjfd`k`fltfs cf7 Q P W I N K. ^fkjrcfojs quf ul [`stfoi cf Fkuik`jlfs B`lfibfs `muibicj i kfrj, fs cfk`r, quf bjs tàro`ljs `lcfpflc`fltfs sjl `muibfs i kfrj, sf cfljo`li [`stfoi Ajojmàlfj y fs s`foprf kjls`stfltf pjr tflfr bi sjbuk`ûl tr`v`ib. [`l fonirmj, àsti sjbuk`ûl lj fs quïo`kiofltf dikt`nbf cfn`cj i quf [@ fx`stf uli rfikk`ûl, pjr bj quf aiy quf nuskir jtri sjbuk`ûl, sjbuk`ûl, s` fs quf fx`stf Fb [`stfoi sf rfsufbvf pjr fb oàtjcj cf Miuss-Gjrcil (sf `lv`ti ib bfktjr i rfsjbvfrbj pjr su kuflti), y sf jnt`flf bi s`mu`fltf oitr`z rfsubticj cf bi rfcukk`ûl miuss`ili7
( )
Fltjlkfs bi sjbuk`ûl qufci cf bi s`mu`fltf oilfri7
Oitfoét`kiofltf ainbilcj sf t`flfl `ld`l`cic cf sjbuk`jlfs. [`l fonirmj, cfn`cj i quf bis rfmbis cfb nibilkfj quïo`kj cf fkuik`jlfs `op`cfl tflfr drikk`jlfs cf ojbàkubis, y i quf sf cfnf sfmu`r bi rfmbi cfb oïl`oj l÷ofrj cf ojbàkubis, sf t`flf quf bi ÷l`ki sjbuk`ûl dikt`nbf quïo`kiofltf ainbilcj fs kuilcj K ? >, pjr bj quf bi sjbuk`ûl fs7 y bi fkuik`ûl quïo`ki nibilkfici qufci7 ;Ol[J3 + >HOlJ3 + >A>J
6OlJ> + H>[J3 + >A>[J3
>. Nibilkfir bi s`mu`fltf fkuik`ûl quïo`ki 7
[JBVK@JL7
^ffskr`n`ojs bi rfikk`ûl quïo`ki cf bi djroi s`mu`fltf7
X_ XX__X_ X_ X__
Fb s`stfoi cf fkuik`jlfs b`lfibfs quf sf jnt`flf sjl7
Bi djroi oitr`k`ib cfb s`stfoi iltfr`jr fs7
( ) ) ( {
^fsjbv`flcj pjr fb oàtjcj cf Miuss-Gjrcil jntflfojs7
Fltjlkfs bi sjbuk`ûl qufci cf bi s`mu`fltf oilfri7
(9/4 8
Oitfoét`kiofltf ainbilcj sf t`flf `ld`l`tis sjbuk`jlfs, ipb`kirfojs fb oïl`oj cf ojbàkubis, sf t`flf quf bi ÷l`ki sjbuk`ûl dikt`nbf quïo`kiofltf ainbilcj fs kuilcj pjr bj quf bi sjbuk`ûl fs7
(968 338 >>8 118 68 05) Fltjlkfs bi fkuik`ûl quïo`ki nibilkfici fs7
X_ X_ X _ X_
;. Nibilkfir bi rfikk`ûl quïo`ki cf bi djtjsïltfs`s 7
[JBVK@JL7
Sflfojs quf nuskir fltfrjs pjs`t`vjs c`dfrfltf kjo÷l cf 9, cf tib oilfri quf7
quf tflmil ul c`v`sjr
Bis fkuik`jlfs quf sf jnt`flfl piri kici fbfofltj sf oufstril i kjlt`luik`ûl7
Flsfmu`ci sf prfsflti fb s`stfoi cf fkuik`jlfs b`lfibfs prfv`is fl djroi oitr`k`ib7
^fsjbv`flcj bi oitr`z pjr fb oàtjcj Miuss-Gjrcil jntflfojs jntflfojs77
Fltjlkfs bi sjbuk`ûl qufci cf bi s`mu`fltf oilfri7
( Oitfoét`kiofltf ainbilcj sf t`flf `ld`l`tis sjbuk`jlfs, ipb`kirfojs fb oïl`oj cf ojbàkubis, sf t`flf quf bi ÷l`ki sjbuk`ûl dikt`nbf quïo`kiofltf ainbilcj fs kuilcj pjr bj quf bi sjbuk`ûl fs7 (48 48 98 4)
Fltjlkfs , bi fkuik`ûl quïo`ki nibilkfici fs 7
3. Fskr`n`r bi fkuik`ûl quïo`ki nibilkfici piri bi s`mu`fltf rfikk`ûl (kjonust`ûl cfb prjpilj) 7
[JBVK@JL7
^ffskr`n`ojs bi rfikk`ûl quïo`ki cf bi s`mu`fltf djroi7
X_ X_ X_ X_
Fb s`stfoi cf fkuik`jlfs b`lfibfs quf sf jnt`flf sjl7
Flsfmu`ci sf prfsflti fb s`stfoi cf fkuik`jlfs b`lfibfs prfv`is fl djroi oitr`k`ib7
^fsjbv`flcj bi oitr`z pjr fb oàtjcj Miuss-Gjrcil jntflfojs jntflfojs77
Fltjlkfs bi sjbuk`ûl qufci cf bi s`mu`fltf oilfri7
Oitfoét`kiofltf ainbilcj sf t`flf `ld`l`tis sjbuk`jlfs, ipb`kirfojs fb oïl`oj cf ojbàkubis, sf t`flf quf bi ÷l`ki sjbuk`ûl dikt`nbf quïo`kiofltf ainbilcj fs kuilcj pjr bj quf bi sjbuk`ûl fs7
(9, 6, ;, 3)
Fltjlkfs, bi fkuik`ûl quïo`ki nibilkfici fs7
6. Fskr`n`r bi fkuik`ûl quïo`ki nibilkfici piri bi s`mu`fltf rfikk`ûl7
[JBVK@JL7
^ffskr`n`ojs bi rfikk`ûl quïo`ki cf bi s`mu`fltf djroi7
X _X_ X_ X_ X_ X__ Fb s`stfoi cf fkuik`jlfs b`lfibfs quf sf jnt`flf sjl7
Flsfmu`ci sf prfsflti fb s`stfoi cf fkuik`jlfs b`lfibfs prfv`is fl djroi oitr`k`ib7
(
)
^fsjbv`flcj bi oitr`z pjr fb oàtjcj Miuss-Gjrcil jntflfojs jntflfojs77
) ( {
Fltjlkfs bi sjbuk`ûl qufci cf bi s`mu`fltf oilfri7
Oitfoét`kiofltf ainbilcj sf t`flf `ld`l`tis sjbuk`jlfs, ipb`kirfojs fb oïl`oj cf ojbàkubis, sf t`flf quf bi ÷l`ki sjbuk`ûl dikt`nbf quïo`kiofltf ainbilcj fs kuilcj pjr bj quf bi sjbuk`ûl fs7 (>, 4, 95, 4, 9, 95)
Fltjlkfs, bi fkuik`ûl quïo`ki nibilkfici fs7
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