Práctica N 7 Obtencion de Complejos Lábiles e Inertes
July 11, 2022 | Author: Anonymous | Category: N/A
Short Description
Download Práctica N 7 Obtencion de Complejos Lábiles e Inertes...
Description
^ZÅEDFN DKB]GÎKDFN N_IDFNAN N_IDFNAN
>
NÞB AJI MDFJKQJKN]DB AJI _J]Ø8 =?? NÞBV AJ DKAJ_JKAJKFDN―
ZKD\J]VDANA KNFDBKNI AJ VNK NGZVQÅK LNFZIQNA AJ DKGJKDJ]ÅN AJ _]BFJVBV JVFZJIN _]BLJVDBKNI AJ DKGJKDJ]ÅN ^ZÅEDFN
]J_B]QJ K¿78 JVQNMDIDANA AJ IBV FBE_ZJVQBV AJ FBB]ADKNFDÖK _]J_N]NFDÖK AJ FBE_IJHBV IÎMDIJV J DKJ]QJV INMB]NQB]DB AJ ^ZÅEDFN DKB]GÎKDFN N6 ABFJKQJ8 Enrån Fnedþn _nfcjfb DKQJG]NKQJV8 Mjidznrdb Fbdin ,Gudab Tjrjey Jfcjvnrrdn Ejadkn , Tnadrn Gdsjii Cjrrjrn Fbkabrd , ]bsnrdb Hdejkn ^ujktn Vnigujrb ,Iuz Ajildkn ]bhns Mnjz , Hjnk _djrrj
N]J^ZD_N - =?=> Eg. Enrån aji Fnrejk Fnedþn _nfcjfb _nfcjfb
^ZÅEDFN DKB]GÎKDFN N_IDFNAN N_IDFNAN
=
JVQNMDIDANA AJ IBV FBE_ZJVQBV AJ FBB]ADKNFDÖK _]J_N]NFDÖK AJ FBE_IJHBV IÎMDIJV J DKJ]QJV >. >. BMHJQD\BV8 BMHJQD\BV8
‟ Fbeprbmnr in jstnmdidana aj advjrsbs fbepijhbs usnkab dbkjs aj ejtnijs aj trnksdfdök y adljrjktjs finsjs aj idgnkabs. idgnkabs. =. =. LZKANEJKQB QJB]DFB Jstnmdidana aj fbepijhbs fbepijhbs In jstnmdidana b dkjstnmdidana aj uk dök fbepijhb vdjkj jxprjsnan pbr ji vnibr aj in fbkstnktj aj jqudidmrdb b fbkstnktj aj jstnmdidana @s, js ukn fbkstnktj aj jqudidmrdb pnrn in lbrenfdök aj uk fbepijhb jk sbiufdök. Js ukn ejadan aj in lujrzn aj in dktjrnffdök jktrj ibs rjnftdvbs quj sj ukjk pnrn lbrenr ji fbepijhb. fbepijhb. In jstnmdidana aj ibs dbkjs fbepijhbs sj rjldjrj n quj tnk rjnftdvb js ji fbepijhb jk fbepnrnfdök n btrbs fbepijhbs, uk fbepijhb ens jstnmij js ejkbs rjnftdvb, y ibs ejkbs jstnmijs rjnffdbknk fbk eufcn lnfdidana. lnfdidana. Jstb js depbrtnktj n in cbrn aj cnfjr ins vnibrnfdbkjs, yn quj ji fbepijhb quj sj lbren ajmj sjr ens jstnmij quj ji aji dkadfnabr dk adfnabr pnrn quj jstj rjnffdbkj y sj pujan bmsjrvnr uk fnemdb aj fbibr. fbibr. Ji jqudidmrdb aj fbepijhbs js uk tdpb aj jqudidmrdb aj nepidn npidfnfdök jk quåedfn nkniåtdfn, npidfnab yn sjn n rjnffdbkjs aj sjpnrnfdök fbeb n rjnffdbkjs aj dajktdldfnfdök aj jspjfdjs quåedfns jk sbiufdök. sbiufdök. Nftuniejktj, sj snmj quj ibs dbkjs sjkfdiibs prîftdfnejktj kb jxdstjk jk ejadb nfubsb, yn quj ibs dbkjs cdarntnabs, lbren ens sjkfdiin aj jkfbktrnrsj ibs dbkjs, pujajk sjr fbksdajrnabs jk fdjrtn ejadan fbeb dbkjs fbepijhbs, sd mdjk ins ebiäfuins aj ngun pujajk jstnr ukdans ni dbk fjktrni fbk euy vnrdnmij dktjksdana. dktjksdana. In fdkätdfn aj rjnffdök jstuadn in vjibfdana fbk quj sj iijvnk n fnmb rjnffdbkjs aj lbrenfdök aj fbepijhbs y sus ejfnkdsebs aj rjnffdök. Ajsaj ji puktb aj vdstn aj in fdkätdfn ibs fbepijhbs aj fbbradknfdök pujajk advdadrsj jk8 jk8
Iîmdijs8 Vu vjibfdana aj ajsfbepbsdfdök (jk ji sjktdab aj ibs jqudidmrdbs) js jijvnan. Kb cny uk fbkvjkdb jstnmijfdab nfjrfn aj quj vjibfdana sj fbksdajrn jijvnan. Kbreniejktj sj fbksdajrn tdjepbs dkljrdbrjs n uk edkutb edkutb
Eg. Enrån aji Fnrejk Fnedþn _nfcjfb _nfcjfb
N_IDFNAN ^ZÅEDFN DKB]GÎKDFN N_IDFNAN
6
Dkjrtjs8 In vjibfdana aj ajsfbepbsdfdök js euy mnhn. Qnepbfb jxdstj uk fbkvjkdb jstnmijfdab, pjrb jk eufcns bfnsdbkjs sj fbksdajrn uk fbepijhb dkjrtj nquji quj js fnpnz aj sjr ndsinab y fnrnftjrdznab jk ntebsljrn bxdanktj y sus prbpdjanajs sj enktdjkjk fbkstnktjs fbk ji tdjepb. tdjepb. Ibs fbepijhbs y sus jqudidmrdbs, hujgnk uk pnpji depbrtnktj jk quåedfn nkniåtdfn, yn sjn jk in sjpnrnfdök aj jspjfdjs b jk in dajktdldfnfdök aj btrns yn sjn funidtntdvn b funktdtntdvnejktj. funktdtntdvnejktj.
6. 6. _N]QJ JS_J]DEJKQNI 6.> ENQJ]DNIJV, ]JNFQD\BV, DKVQ]ZEJKQBV T/B J^ZD_BV AJ INMB]NQB]DB 6.> 6.= _]BFJADEDJKQB JS_J]DEJKQNI 6.= Jxpjrdejktb K¿ >8 ‟ JVQNMDIDANA AJ FBE_IJHBV Bmsjrvj ibs Qutbrdnijs 3.> y 3.= ‟ AZQDF AZQDF cttps8//www.ybutumj.fbe/wntfc2v5:BHDJvF1KrD /www.ybutumj.fbe/wntfc2v5:BHDJvF1KrD cttps8/ cttps8//www.ybutumj.fbe/wntfc2v5fs]Ehw^n1ub cttps8//www.ybutumj.fbe/wntfc2v5fs]Ehw^n1ub
_nrn fnan jxpjrdejktb aji tutbrdni8
‟ Dajktdldquj ibs entjrdnijs usnabs y ji prbfjadedjktb jxpjrdejktni jxpjrdejktni Vbiufdök aj kdtrntb aj fbmrj Vbiufdbk aj nebkdnfb Vbiufdbk fbkfjktrnan aj cdarbxdab aj sbadb Nfdab fibrcdardfb ni 6?% Zrjn Nfdab nfjtdi nfjtåidfb •
•
•
•
•
•
Jk enybrån aji prbfjsb sj utdidzn ni fbepujstb aj fbmrj y sus fbemdknfdbkjs pnrn rjnffdbknr fbk nigukbs fbepujstbs y ebstrnr ins adstdktns rjnffdbkjs prjsjktnkab ukn fbkstnktj aj lbrenfdök aji prbpdb p rbpdb fbepujstb
‟ Nknidfj in lbrenfdök aj fbepijhbs y jxpidquj ib quj bfurrdö bfurrdö In lbrenfdök aj in enybrån aj fbepujstbs sj ajmj n in prjljrjkfdn quj prjsjktnk ukbs FBE_ZJVQBV _B] in jstnmdidana fbk fdjrtbs fbepujstbs, uk jhjepib quj ib jxpidfn js in prjljrjkfdn aji tdbfdnkntb quj tdjkj fbk cdjrrb ajmdab n quj sd sj ij ngrjgn fbmrj f bmrj enktjkarån su fbibr
Jxpjrdejktb K¿ =8 ‟ FBE_IJHBV IÎMDIJV J DKJ]QJV DKJ]QJV Nknidznr ins rjnffdbkjs pbsdmijs n bfurrdr jk fnan fnsb8 fn sb8
Eg. Enrån aji Fnrejk Fnedþn _nfcjfb _nfcjfb
^ZÅEDFN DKB]GÎKDFN N_IDFNAN N_IDFNAN
1
_rjpnrnfdök aj fbepijhbs iîmdijs •
Jk uk tumb aj jksnyb fbibfnr uk ei aj sbiufdök prjpnrnan aj suilntb aj fbmrj y ngrjgnr rjs uitnabs. Dajktdldfnr Dajktdldfnr ukbs grnebs aj fibrurb aj sbadb cnstn fnemdb aj fbibr. Nkbtnr rjsuitnabs. ji fbepijhb. fbepijhb.
•
Jk uk tumb aj jksnyb fbktjkdjkab uk ei aj ukn sbiufdök aj fibrurb lärrdfb n uk pC5> pnrn ib funi ajmjrî ngrjgnrsj ukn gbtn aj îfdab suilørdfb, suilørdfb, ngrjgnr @VFK @VFK (npjkns nigukbs edidgrnebs). Bmsjrvnr fbibrjs. Nkbtnr j dajktdldfnr fbepijhbs. fbepijhbs.
•
Jk uk tumb aj jksnyb fbktjkdjkab ukn sbiufdök aj suilntb aj fbmrj, fbmrj, ngrjgnr nprbxdenanejktj, abs grnebs aj JAQN. JAQN. Bmsjrvnr ji fbepijhb lbrenab. Jksjgudan ngrjgnr ukbs eg aji idgnktj VFK@ VFK@.. Dajktdldfnr y nkbtnr. nkbtnr.
•
Jk uk tumb aj jksnyb fbktjkdjkab ukn sbiufdök aj suilntb aj fbmrj, fbmrj, ngrjgnr ukbs grnebs aj bxnintb aj sbadb, sbadb, cnstn quj prjfdpdtj ji fbepijhb. Bmsjrvnr. Jksjgudan ngrjgnr uk grneb b eîs aj J.A.Q.N. cnstn adsbiufdök aji prjfdpdtnab, vujivn n ngrjgnr bxnintb cnstn prjfdpdtnfdök. Dktjrprjtj y jxpidquj. jxpidquj.
•
jstnmdid tnmdidana ana _rjpnrnr ukn sbiufdök aj FnFi= y ngrjgnrij uk grneb aj J.A.Q.N. Bmsjrvnr in js aji fbepijhb lbrenab, jksjgudan nþnadrij uk grneb nprbxdenanejktj aj Kn=F=B1. Dktjrprjtj y jxpidquj. jxpidquj.
_rjpnrnfdök aj Fbepijhbs Dkjrtjs
N ukn sbiufdök s biufdök prjpnrnan aji fbepijhb ljrrdfdnkurb aj pbtnsdb, pbtnsdb, ngrjgnrij eg aj VFK@. N ukn sbiufdök prjpnrnan aji fbepijhb ljrrdfdnkurb aj pbtnsdb, pbtnsdb, ngrjgnrij eg aj KnFi. KnFi.
6.6 EJKFDBKN] IBV _]BQBFBIBV AJ VJGZ]DANA _N]N ]JNIDXN] JVQNV 6.6 _]ÎFQDFN JK JI INMB]NQB]DB INMB]NQB]DB Ajktrb aj ins dkstninfdbkjs utdidznr su enkadi minkfb (gunranpbivbs), jvdtnr utdidznr
•
mrnznijtjs, nrjtjs inrgbs, fnmjiibs sujitbs, vnrdbs nkdiibs aj ejtni, jtf.
Ijjr fbk ajtjkdedjktb ins jtdqujtns aj ibs rjnftdvbs, ajtjredkj prjvdnejktj su
•
knturnijzn pnrn ibs fudanabs rjspjftdvbs b su enkdpuinfdök y jk sus adljrjktjs lbrens aj prjpnrnfdök. rjnf tdvbs, sdjeprj fbksuitnr n su abfjktj b Qjkjr jk fujktn prbmnmij rjnffdbkjs aj ibs rjnftdvbs,
•
rjspbksnmij aji prbfjadedjktb, quj vn n rjnidznr, nktj funiqudjr dkfdajktj, ajrrnej b snipdfnaurn aj uk iåqudab b sbidab invnrsj dkejadntnejktj jk ins aufcns aj invn bhbs fbk nmukanktj ngun y trnsinanrsj ni fjktrb eäadfb aj in lnfuitna lnfu itna fbk ji abfjktj b nsdstjktj pnrn su trnsinab n uk jspjfdnidstn eäadfb.
Invnrsj ins enkbs Nktjs y Ajspuäs aj fnan prnftdfn rjnidznan fbk hnmök fnrmöidfb.
•
1. 1. ]JVZIQNABV T ADVFZVDÖK Eg. Enrån aji Fnrejk Fnedþn _nfcjfb _nfcjfb
^ZÅEDFN DKB]GÎKDFN N_IDFNAN N_IDFNAN
:
>.‟ >.‟ Jsfrdmn Jsfrdmn tbans ins rjnffdbkjs aj ibs jksnybs, nknidznr b ajldkdr ibs fbepujstbs lbrenabs lbrenabs
>)Ji kdtrntb aj fbmrj (DD) rjnffdbkn fbk ji ngun lbrenab uk fntdök fntdök aj fbmrj (dd) nfubsb pbr dbk aj cjxnnfub, prjsjktnkab uk fbepujstb aj fbibr nzui ajpjkadjkab aj su fbkfjktrnfdök. Fu(KB6)=+
ejadn ajmdab n quj prjsjktnk ukn jstnmdidana.
6. 6.
‟FBEJKQJ _B]
^ZÄ JV QNK DE_B]QNKQJ AJQJ]EDKN] KB VÖIB IN
QJ]EBADKÎEDFNVDKB QJ]EBADKÎEDFN VDKB NAJEÎV IN FDKÄQDFN AJ IBV FBE_IJHBV AJ FBB]ADKNFDÖK. In fdkätdfn in dguni quj in tjrebadkîedfn dktjrvdjkjk jk in lbrenfdök aji fbepujstb in prdejrn jstnrån rjljrdan n in vjibfdana aji fbepujstb fbepujstb fbk fbk ji funi sj lbren y in sjgukan in jkjrgån utdidznan b prjsjktj jk in rjnffdök
1. 1. ‟ AJLDKN ’JKJ]GÅN ’JKJ]GÅN AJ AJ NFQD\NFDÖK― NFQD\NFDÖK― _N]N _N]N ’FBE_ZJVQBV ’FBE_ZJVQBV AJ AJ FBB]ADKNFDÖK―. In jkjrgån aj nftdvnfdök js ukn fnktdana kjfjsnrdn aj jkjrgån kjfjsnrdn pnrn lbrenr fbepujstbss nftdvbs, sd jstn jkjrgån fbepujstb j kjrgån vjkfj in rjpuisdök ins ebiäfuins sj nprbxden n rjbrajknedjktb aj sus jkinfjs
:. :. FBKFIZVDBKJV FBKFIZVDBKJV Js depbrtnktj tjkjr jk fujktn in fbkstnktj aj lbrenfdök in jkjrgån quj sj pujaj
•
prbaufdr jk fnan fbepujstb y in jkjrgån quj sj pujaj idmjrnr ajmdab n quj eufcbs aj ibs fbepujstbs prjsjktnk prjljrjkfdn pbr fdjrtbs fbepujstbs, fbepujstbs, najeîs fnmj nfinrnr quj su fbibrnfdök eufcns vjfjs ajpjkaj aj in fbkfjktrnfdök fbkfjktrnfdök aj ibs fbepujstbs In nldkdana fbrrjftn aj ibs fbepujstbs pjredtj fbepujstb eîs jstnmijs pnrn jvdtnr ji usb dkkjfjsnrdb aj jkjrgån
•
View more...
Comments