Petroleum Standards

P E T R O L E U M

AS Ov TM er 1 M 00 et ho ds

Certified Reference Standards 4th Edition

Member

AccuStandard

®

Notice the Difference with AccuStandard Experience in Petrochemical Requirements • Years of Round Robin Studies with ASTM • Ampulled over 300 gallons of ASTM fuel sets including over 35 gasoline and hydrocarbon blends • Standards for over 100 ASTM Methods • 17 years of Manufacturing, Organic & Inorganic Standards • Synthesizes rare Hydrocarbons not otherwise available

Involvement in the Petrochemical Industry • Participation in regular ASTM meetings • Active in D-02 and D-16 subcommittees • Provides support to several Petrochemical Instrument Manufacturers

Resources • Low Sulfur Analyzers (such as XOS) for Measurements to ppb Levels • Instrumention for Analyzing Standards for ICP, ICP-MS, AA, GC/MS, GC/FID, GC/EC, GC/NPD, Karl Fischer Titrator, and others • NIST/NVLAP Accredited (Lab Code 200389-0) as a PT Provider • ISO 9001:2000 Certified (ISO 9001 for the last 10 years) • Extensive Inventory of ASTM and Related Standards

New Products in this Catalog • Low Sulfur and Nitrogen Standards (see pages 6-11) • LUFT/LUST Standards (see pages 81-98) • TPH Standards (see pages 81, 92-93, 96-97) • No Haz Fee ICP & AA Standards (see pages 67-75) • Additional New ASTM Standards PRINTED ON RECYCLED PAPER

© AccuStandard, Inc. 2003

Table of Contents ASTM #

PIANO

81-98

Index Quote Form Order Information

i-vii back back

ICP & AA

LUFT/LUST and TPH (New Section)

ORGANOMETALLIC

Wear Metals Group 10 10, 17 6-11 10 6-11, 31 38 6-11 6-11

D-3605 D-4628 D-4927 D-4951 D-5185 D-5708 D-5863 D-6443 D-6481

Trace Metals in Gas Turbine Fuel by AA Wear Metals in Lube Oil Wear Metals and Additives by WDXRF Wear Metals and Additives by ICP Wear Metals and Additives by ICP Trace Metals by ICP Trace Metals by AA Metals in Oil Lube Oils by ED-XRF

INDEX

Quality System is Certified to comply with the International ISO 9001:2000 Quality Standard

17 22 25, 63-64 26 28 39, 62 52 58, 64 58, 63-64

LUFT/LUST

by XRF by Oxidative Microcoulometry in Petro Gas by Oxidative Microcoulometry by ED-XRF by Ultra Violet Fluorescence Compounds by Sulfur Selective Detection in Gasoline by Wavelength WD-XRF in Gasoline by ED-XRF

WEAR METALS

Sulfur Sulfur Sulfur Sulfur Sulfur Sulfur Sulfur Sulfur

6 62

Organometallic (Wear Metals) Analysis by AA, ICP, DCP, XRF 26, 28, 59-66 Plasma Emission Spectroscopy (ICP) 67-71 ICP (No Haz Fee) New 67-71 Atomic Absorption Spectroscopy (AA) 67, 73-75 AA (No Haz Fee) New 67, 73-75 Plasma Emission / Mass Spectroscopy (ICP/MS) 72 Trace Metals, Chlorine in Lube Oil, and Organo Tin New 66 Ion Chrom 76-79

Sulfur Standards Group D-2622 D-3120 D-3246 D-4294 D-5453 D-5623 D-6334 D-6445

Water in Petroleum V & Ni with Mn

page 30 31 31 31 32 29, 32 32 32-33 34-36 37 37 38 39, 62 40 42-51 52 52 52 52 53 53 53 54 54 54 55 55 5 10, 56 56 56 57 57 57 58-65 10, 58 63, 64 58 57

SULFUR

D-3120 D-3230 D-3231 D-3237 D-3246 D-3340 D-3524 D-3605 D-3606 D-3610 D-3710 D-3798 D-3831 D-4059 D-4110 D-4291 D-4294 D-4377 D-4420 D-4628 D-4629 D-4815 D-4927 D-4928 D-4929 D-4951 D-5056 D-5059 D-5134 D-5184 D-5185 D-5186 D-5188 D-5191 D-5307

Method Description MtBE Analysis by GC Petroleum Waxes by GC PNA Analysis by Multidimensional GC Sulfur by Ultra Violet Fluorescence Engine Oil Volatility by GC Vapor Pressure Standards Ethanol Analysis by GC Aromatics by GC Oxygenates by OFID Trace Metals by ICP Oxygenates by Reductive Pyrolysis Sulfur Compounds by Sulfur Selective Detection Trace Metals by ICP Nitrogen by Chemiluminescence Aromatics by GC/MS Cloud Point of Petro Products Cloud Point of Petro Products (Linear Cooling Rate) Cloud Point of Petro Products (Constant Cooling Rate) Trace Metals by AA Freezing Point Aviation Fuels (Auto Optical Method) Freezing Point Aviation Fuels Oxygenates and Aromatics by GC/FTIR PCBs by GC Solvent Red 164 Dye Concentration in Diesel Fuels Benzene in Spark Ignition Fuels Oxygenates (O-PONA) in Engine Fuels by GC Total Olefins in Spark Ignition Engine Fuels by GC Water in Liquid Petro Products Sulfur in Gasoline by Wavelength WD-XRF Boiling Range Distribution of Petroleum Vapor Pressure Aromatic Hydrocarbon by HPLC Engine Oil by GC Sulfur by ECD Metals in Oil Sulfur in Gasoline by ED-XRF Lube Oils by ED-XRF 58, Olefin Content of Gasoline by SFC Aromatic Hydrocarbon by HPLC

ASTM

D-2887

ASTM # D-5441 D-5442 D-5443 D-5453 D-5480 D-5482 D-5501 D-5580 D-5599 D-5600 D-5622 D-5623 D-5708 D-5762 D-5769 D-5771 D-5772 D-5773 D-5863 D-5901 D-5972 D-5986 D-6160 D-6258 D-6277 D-6293 D-6296 D-6304 D-6334 D-6352 D-6378 D-6379 D-6417 D-6428 D-6443 D-6445 D-6481 D-6550 D-6591 (IP 391) E-1064 ISO/CD

QC

D-56 D-86 D-92 D-93 D-445 D-611 D-1015 D-1319 D-1744 D-2386 D-2500 D-2622 D-2789

Method Description page Cross Reference Tables (ASTM,IP,ISO,DIN,JIS,AFNOR) II Analytical Capabilities III On-Line Ordering IV Quality Control 1-2 Flash Point Standards 3 Synthetic Distillation Standard 3 Flash Point Standards (COC) 3 Flash Point Standards (PMCC) 3 Viscosity Calibration Standard 3 Aniline Point Standard 4 Freezing Point Standards 4 Olefin Analysis by FIA 4 Water in Liquid Petroleum Products 5 Freezing Point Calibration Standards 5 Cloud Point Calibration Standards 5 Sulfur by XRF 10 Hydrocarbon Analysis in Gasoline by GC/MS 11 PIANO, PONA, PNA by GC 12-13 Proposed Method for Detailed Hydrocarbon Analysis 14 Detailed Hydrocarbon Analysis PONA VI 14 Boiling Range by GC 14 Simulated Distillation (SIM DIS) by GC 15 Sulfur by Oxidative Microcoulometry 16 Salts in Crude Oil 16 Phosphorus in Gasoline 16 Lead in Gasoline by AA 16 Sulfur in Petroleum Gas by Oxidative Microcoulometry 17 Li & Na in Lubricating Greases by Flame Photometer 17 Diesel Fuel Analysis by GC 17 Trace Metal in Gas Turbine Fuels by AA 17 Aromatics in Gasoline by GC 18 Total Co Analysis by Potentiometric Titration 18 Boiling Range by GC 20 p-Xylene Analysis by GC 20 Manganese in Gasoline by AA 20 PCB Analysis by GC 21 Ion Chrom 76 Ethylene Glycol by GC 21 Sulfur by ED-XRF 7-11, 21 Water in Liquid Petroleum Products 5, 21 Aromatics in Gasoline by GC 22 Wear Metals in Lube Oil 22 Nitrogen by Chemiluminescence 23 Oxygenates in Gasoline by GC 24 Wear Metals and Additives by WD-XRF 25,63 Water in Liquid Petroleum Products 6, 25 Chlorine in Crude Oil by Microcoulometry 25 Wear Metals and Additives by ICP 26 Trace Metals in Petroleum Coke by AA 26 Lead in Gasoline by X-Ray Spectroscopy 27 Petroleum Naphthas through n-Nonane by GC 27 Al and Si by ICP-AES & AA 28 Wear Metals and Additives by ICP 28 Aromatics by SFC 28 Vapor - Liquid Ratio Temperature 29 Vapor Pressure Standards 29 Boiling Range Distribution of Crude Petroleum by GC 29

QUOTE FORM

Cross Reference Table Sorted by ASTM Method Use the AccuStandard Cross Reference Tables to Match various International Methods for known Petrochemical analysis.

MEMBER

Fully Accredited For over 17 years AccuStandard has been the Leader in the Chemical Standards Industry in both Organic and Inorganic products. AccuStandard is ISO 9001:2000 registered and a NIST/NVLAP accredited Proficiency Testing provider (NVLAP Code 200389-0).

ISO 9001:2000 Certificate Number: 31692

ANALYSIS

ASTM

IP

ISO

DIN

JIS

AFNOR

PAGE

Tag Flash Point

D-56

Distillation

D-86

123

3405

51411

K 2580

M07-003

3

51751

K 2254

M07-002

3

COC Flash Point

D-92

36

2592

51376

K 2265

T60-118

3

PMCC Flash Point

D-93

34

2719

51758

K 2265

M07-019

3

Kinematic Viscosity

D-445

71-1

3104

51562

K 2283

T60-100

3

Aniline Point

D-611

2

2977

51775

M07-021

4

Hydrocarbon Types by FID

D-1319

156

3837

51791

M07-024

4

Water (Karl Fischer)

D-1744

T60-154

5

Freezing Point

D-2386

16

3013

51421

K 2276

M07-048

5

Cloud Point

D-2500

219

3015

51597

K 2269

T60-105

5

Sulfur by XRF

D-2622

51400T6

K 2541

Boiling Range By GC

D-2887

3924

14

Sulfur by Oxidative Microcoulometry

D-3120

16591

16

Lead by AAS

D-3237

428

Sulfur by Oxidative Microcoulometry

D-3246

373

Metals by AA

D-3605

413

Benzene by GC

D-3606

425

Sulfur by ED-XRF

D-4294

336

8754

Water (Karl Fischer)

D-4377

356

10336

Metals by AA

D-4628

308

Nitrogen by Chemiluminescence Detection

D-4629

379

Metals by WD-XRF

D-4927

407

Water (Karl Fischer)

D-4928

386

Lead in Gas By X-Ray

D-5059

228

Vapor Pressure

D-5191

394

Oxygenates

D-5599

408

34-36

Cloud Point

D-5771

444

52

Cloud Point

D-5772

445

52

Cloud Point

D-5773

446

52

Freezing Point

D-5901

434

53

Auto-Freeze Point

D-5972

435

53

Hydrocarbons Automatic

D-6379

436

57

Hydrocarbons Automatic NEW

D-6591

391

57

Metals

K 2536

6296

10

16 M07-052 8691

51790T3

10 17 18

M07-053

21 5

51391T1

22 M07-058

51391T2

23 25, 63

10337

5, 25 27 M07-079

14597

29, 32

62

This is a partial list of Standards available for ASTM Methods Tables Generated from (a) R.A. Nadkarni, “Guide to ASTM Test Methods for the Analysis of Petroleum Products and Lubricants”, Manual 44 (200), ASTM West Conshohocken, PA (b) Annual Book of ASTM Standards 2000, Volumes 05.01 to 05.05

II

Member

AccuStandard is an active member in ASTM and strives to keep abreast of ASTM method revisions. If our listed formulation does not meet the most recent method revision, please contact Technical Support, ext. 117 for an updated product.

Analytical Capabilities Analytical Instruments Inorganic (ICP) PE Optima 3000 Spectro FMD-07 Organics GCs: (6) HP 5890 Series II, FID, NPD, ECD all with auto injectors GC/MS: (3) HP 5971A HP 5971A with OI Analytical Purge & Trap PE Q-Mass 910 HPLC: Varian 5000 with Applied Bioscience Fluorescence detector and HP auto injector Sulfur (low level) XOS (XRF) with monochromatic wavelength disperser Antek 9000 Series (UVF) Miscellaneous Ion Chromatograph, Waters 600E with Conductivity detector 431, Alltech 335 Ion Suppressor Automatic Polarimeter, Zuzi W22 Karl Fischer Titrator

Lab Resources Milligram to Kilogram Scale Glassware Equipment to work under N2/Ar Flash and Liquid Solid Phase Chrom. (mg to 2 kg) Preparative TLC Buchi Rotary Evaporator Vacuum Drying Oven Parr Pressure Reactor (high pressure reaction, hydrogenation) Distillation Equipment - High Vacuum Distillation, Molecular Distillation (Kugelrohr), Spinning Band Columns, Packed and Vigreaux columns Melting Point Apparatus pH meter Viscometer Centrifuge

III

On-Line Ordering There is an

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Over 30,000 Standards just a click away

Custom Formulations AccuStandard offers over 30,000 different standards, and if you can't find the specific standard you need, we will prepare a custom formulation. Our custom organic and inorganic standards are a fast, economical way to address your unique requirements. To make an inquiry for Custom Quotes visit our website. You can also Email your requirements to [email protected] or Fax us at 203-786-5287. Please include the following information: List of analytes and concentrations, Solvent or matrix, Quantity required (milliliters), Packaging unit size (milliliters per ampule, bottle, or vial). Quality Control Options 1. Gravimetric/Volumetric Certification: Each standard is measured gravimetrically and then QC’ed instrumentally (where available). Every component in the standard is guaranteed to be within ±0.5% of the requested value unless otherwise stated. The solutions are made up to volume using class A glassware. A certificate comes with each standard and documents the gravimetric values used. 2. Quantitative Validation: Full QA/QC method includes extended GC analysis using both internal and calibration standards plus statistical analysis. A data package is provided containing analytical and gravimetric data (Organic customs only). Also available: OEM Standards - Privately labeled standards manufactured and tested to your specifications.

IV

Quality Control Standards

Real World Gasoline D-02.03 D-02.04

QC

AccuPetroCheck and AccuPetroTest Real World Gasoline QC Standards

AccuPetroCheck

Consensus Value QC Standards Conventional Gasoline QC Standard

CARB Low Sulfur RFG QC Standard ASTM-FUEL-QCS-01-PAK

$ 60 / 5 x 15 mL

ASTM-FUEL-QCS-02-PAK $ 60 / 5 x 15 mL

Parameter Total Aromatics Total Olefins Total Saturates Sulfur Sulfur Sulfur Sulfur Benzene Toluene Total Aromatics Benzene Total Olefins

Value 24.5 5.3 58.3 0.0057 0.0078 55.76 59.31 0.80 4.92 23.42 0.78 5.3

Parameter Total Aromatics Total Olefins Total Saturates Sulfur Sulfur Sulfur Sulfur Benzene Toluene Total Aromatics Benzene Total Olefins

Method D-1319 D-1319 D-1319 D-2622 D-4294 D-5453 D-6344 D-5769 D-5769 D-5769 D-6277 D-6550

Conc. Vol.% Vol.% Vol.% Wt.% Wt.% µg/g µg/g Vol.% Vol.% Vol.% Vol.% Vol.%

Method D-1319 D-1319 D-1319 D-2622 D-4294 D-5453 D-6344 D-5769 D-5769 D-5769 D-6277 D-6550

Value 34.6 12.4 62.8 0.0338 0.0368 317.36 338.78 0.55 5.53 32.51 0.52 12.4

Conc. Vol.% Vol.% Vol.% Wt.% Wt.% µg/g µg/g Vol.% Vol.% Vol.% Vol.% Vol.%

AccuPetroTest Sulfur in Diesel Fuel QC Standard SBPT-SDF

$ 25 / 2 x 15 mL

Parameter Sulfur

Approx. Range 20 - 11000 µg/g

See ASTM Methods D-2622, D-3120, D-3246-92, D-4294, D-5453 for Sulfur Calibration Standards

Sulfur in White Mineral Oil QC Standard SBPT-SWMO

$ 25 / 2 x 15 mL

Parameter Sulfur

Approx. Range 20 - 11000 µg/g

See ASTM Methods D-2622, D-3120, D-3246-92, D-4294, D-5453 for Sulfur Calibration Standards

AccuPetroTest Gasoline Low Sulfur QC Sample

Olefin QC Sample

SBPT-LSGAS

SBPT-OLEFINSFC

Parameter Sulfur

$ 25 / 2 x 15 mL Method D-5453

Approx. Range 0 - 50 µg/g

Parameter Total Olefins

Method D-6550

AccuPetroTest Gasoline SBPT-COMP

$ 50 / 2 x 15 mL Method D-1319 D-1319 D-1319 D-2622 D-4294 D-5453 D-6344 D-5769 D-5769 D-5769 D-6277 D-6550

Sulfur Single Blind AccuPetroTest Alternative Matrices Standards AccuStandard has manufactured a number of Diesel and White Mineral Oil QC products containing a gravimetrically prepared amount of Sulfur. Use of these alternative matrix materials can provide further evaluation of the QA/QC process in the laboratory. Two samples will be sent for the test parameter and a separate sealed envelope containing the gravimetrically prepared sulfur values is also provided. The second sample is for repeatability testing or for use as a future QA/QC reference.

$ 25 / 2 x 15 mL Approx. Range 1 - 40 Vol.%

Technical Note

Comprehensive Single Blind Gasoline QC Sample Parameter Total Aromatics Total Olefins Total Saturates Sulfur Sulfur Sulfur Sulfur Benzene Toluene Total Aromatics Benzene Total Olefins

AccuPetroCheck QC Standards Two of the fuels are available as AccuPetroCheck Consensus Value QC Standards. The AccuPetroCheck CARB and Conventional gasoline reference materials have all parameters listed on the certificate with the Consensus Values and the regression equations for reproducability. Use of these Reference Materials improve the quality of laboratory results. The Consensus Values listed reflect initial statistical treatment of the data at the time the catalog was published. The actual certificate provided with the AccuPetroCheck QC standard will have the accepted Consensus Value based on statistical treatment of the data.

Approx. Range 8 - 60 1 - 40 30 - 80 0.0001 - 0.0930 0.0016 - 0.0930 0.5 -500 1.0 - 1000 0.1 - 2.0 1.0 - 15 8 - 60 0.1 - 2.0 1 - 40

Conc. Vol.% Vol.% Vol.% Wt.% Wt.% µg/g µg/g Vol.% Vol.% Vol.% Vol.% Vol.%

This comprehensive single blind gasoline QC sample tests for more parameters from a single sample. The actual gasoline sample will have consensus values listed on the datasheet that fall within the range listed for each parameter.

Quality Control Standards continue on next page

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1

QC

In cooperation with ASTM D-02 subcommittee 3 and 4, AccuStandard ampulled 21 Real World gasoline reference fuels. Consensus Values have been determined for these reference fuels by various ASTM Round Robins to provide Petrochemical Laboratories with a source of well characterized gasoline standards for use in QA/QC applications and as Single Blind test samples over an extended period of time. As new ASTM D-02.03 and D-02.04 Test methods are promulgated they require mandatory Quality Control testing of real world samples. AccuStandard’s PetroTest & PetroCheck standards are being successfully used to achieve these new Quality Control requirements.

Quality Control Standards

ASTM Round Robin & PT Samples

QC

QC

AccuPetroTest Gasoline QC Olefins QC Sample SBPT-OLEFIN

Sulfur QC Sample $ 25 / 2 x 15 mL

Parameter Total Aromatics Total Olefins Total Saturates

Method D-1319 D-1319 D-1319

Approx. Range 8-60 Vol.% 1 - 40 Vol.% 30-80 Vol. %

See ASTM Method D-1319 for Sulfur Calibration Standards

Aromatics QC Sample SBPT-AROM Method D-5769

Parameter Sulfur Sulfur Sulfur Sulfur

$ 25 / 2 x 15 mL Method D-2622 D-4294 D-5453 D-6344

Approx. Range 0.0001 - 0.0930 Wt.% 0.0016 - 0.0930 Wt.% 4.0 - 500 µg/g 1.0 - 1000 µg/g

See ASTM Methods D-2622, D-3120, D-3246-92, D-4294, D-5453 for Sulfur Calibration Standards

Benzene/Toluene QC Sample $ 25 / 2 x 15 mL

Parameter Total Aromatics

SBPT-SGAS

Approx. Range 8 - 60 Vol.%

See ASTM Methods, D-3606, D-5580-95, D-5769-95 for Benzene Calibration Standards

SBPT-BENZ Parameter Benzene Toluene

$ 25 / 2 x 15 mL Method D-5769 D-5769

AccuPetroTest Single Blind Standards Petrochemical laboratories looking to test the performance of the laboratory for a specific parameter can order the Single Blind AccuPetroTest sample for the parameter of interest. Two real world gasoline samples will be sent for the test parameter requested and a separate sealed envelope containing the determined Consensus Value is also provided. The second sample is for repeatability testing or as a future QA/QC reference.

Approx. Range 0.1 - 2.0 Vol.% 1.0 - 15 Vol.%

See ASTM Methods, D-3606, D-5580-95, D-5769-95 for Benzene Calibration Standards

Conducting a Petrochemical Round Robin for a new ASTM method? Select AccuStandard to prepare the necessary samples for the Round Robin study AccuStandard has packaged for ASTM committee D-02 various select groups of gasoline fuels and hydrocarbon products for use in various Round Robin studies. Large Sample Offering AccuStandard was selected by ASTM committee D-02 to fill, seal and package an initial set of 21 different types of Round Robin Gasolines. Each gasoline was selected due to its unique properties. These unique properties will be determined by various ASTM methods under evaluation through ASTM subcommittees. AccuStandard has expanded this offering with additional materials blended for other ASTM Round Robins. Flexibility Use the original 21 gasoline samples to conduct a Round Robin and we can label the samples appropriately to protect the integrity of the Round Robin. In addition, we can easily add additional samples to your specific Round Robin study to expand the scope of the method for different matrices, concentrations or instrument types.

NEW

Petro PT Samples

Oxygenate PT Sample With MtBE contamination problems in drinking water, numerous states are now requiring certification for Oxygenate monitoring. Join AccuStandard’s next study for Oxygenate analysis. Our timely PT schedule easily allows your lab to be proactive in new regulatory requirements. The analytes in the standard and the PT sample have been drawn from the California list of known prevalent oxygenates in gasoline. These new Oxygenate PT samples and standards allow your Lab to: • Eliminate standard preparation • Easily combine with other AccuStandard Volatile standards

• Expand testing capabilities • Generate new testing revenue

WS-PT Oxygenates

* * *

OPE-OXY-001-AS OPE-OXY-001-AT OPE-OXY-001-AV Sample conc. after prep 5.0-50 µg/L Contains 4 analytes listed below ETBE Diisopropylether

$ 47 / 2 mL $ 47 / 2 mL $ 47 / 2 mL

Suggested Calibration Standard Oxygenate Gasoline Additive Standard

MtBE ETBE Isopropyl ether

2

NEW

(2000 µg/mL) (2000 µg/mL) (2000 µg/mL)

* * *

IPE-OILG-001-AS IPE-OILG-001-AT IPE-OILG-001-AV Sample conc. after prep Contains 2 analytes listed below Analyte List Total Oil & Grease † TPH

Sample range 5-100 mg/L 5-100 mg/L

$ 32 / 5 mL $ 32 / 5 mL $ 32 / 5 mL

* Designed for NELAC/CA † Indicates that theses analytes are included in the NVLAP Scope of Accreditation, Lab Code 200389-0

Technical Note This PT sample can be used by gravimetric oil and grease methods. In addition, it can also be used for TPH analysis by gravimetric methods including the EPA method 1664. The sample contains real world material commonly found at petroleum containment sites.

Suggested Calibration Standard

MTBE TAME

OGAD-001 OGAD-001-PAK At stated conc. in MeOH

WP-PT Oil, Grease & TPH

$ 30 / 1 x 1 mL SAVE 20% $ 120 / 5 x 1 mL 5 comps. TAME t-Butanol

(2000 µg/mL) (10000 µg/mL)

Oil and Grease WC-OILG-10X-1 1000 µg/mL Total Oil and Grease in n-Propanol

$ 45 / 100 mL

Contains 500 µg/mL vegetable oil and 500 µg/mL of petroleum oil. Shake well before use. SUFFIX KEY "AS" = Formal PT Study "AT" = Pre-Test "AV" = Values Included

Lab Code 200389-0

Quality System is Certified to comply with the International ISO 9001 Quality Standard

Physical Properties

Method 56, 92, 93 86 445 Member

QC

ASTM D-56, D-92, D-93

Flash Point Standards

Verified by consensus analysis using ASTM Method # referenced ASTM # PMCC D93 PMCC D93 COC D92 COC D92

Nominal Flash Point 65°C 93°C 200°C 230°C

Price / Unit $ 110 110 110 110

/ / / /

250 250 250 250

ASTM

Cat. No. ASTM-P-132-01 ASTM-P-132-02 ASTM-P-132-03 ASTM-P-132-04

Originally designed for ASTM D-56-98a, D-92-98a, D-93-99b

mL mL mL mL

Certified Flash Point Standards The reference material is a stable, pure hydrocarbon with a method specific flash point determined by an inter-laboratory study using the ASTM Method # referenced. Cat. No.

ASTM #

ASTM-P-133-01 ASTM-P-133-02 ASTM-P-133-03 ASTM-P-133-04

PMCC D93 PMCC D93 COC D92 TCC D56

ASTM D-86

Nominal Flash Point 65°C 134°C 138°C 67°C

Price / Unit $ 175 130 130 175

/ / / /

250 250 250 250

mL mL mL mL

Synthetic Distillation Standard

The automatic distillation apparatus duplicates the distillation conditions of the manual method. The increased reliance on electronic control requires an independent standard to verify that the apparatus is performing correctly. This synthetic blend of hydrocarbons boil in the temperature range specified in ASTM D-86 distillation groups 1 and 2, and a fuel oil that meets the group 4 criteria. The group 1 and 2 standards cover the boiling range 129 - 368 °F (54 - 187 °C) and are verified by consensus analysis with twelve refinery laboratories. The group 4 standard covers the range from 410 670 °F (210 - 355 °C). Products are packaged in convenient sizes to meet your laboratory sample analysis demands. Cat. No.

Group

Description

ASTM-P-126-01 ASTM-P-126-SET

1, 2 1, 2

Synthetic Distillation Standard Synthetic Distillation Standard

ASTM-P-127-01 ASTM-P-127-02

4 4

Distillation Standard Distillation Standard

ASTM D-92 & ASTM D-93

Price / Unit $ 160 / 500 mL 290 / 2 x 500 mL

Originally designed for ASTM D-86-99a

160 / 250 mL 290 / 500 mL

Flash & Fire Points by Cleveland Open Cup (COC) & Flash Point by Pensky Martin Closed Cup (PMCC)

See Method D-56 on this page for the comprehensive line of flash point standards

ASTM D-445

Viscosity Calibration Standards

Cat. No.

Viscosity @ 40 °C

ASTM-P-128-01 ASTM-P-128-02 ASTM-P-128-03 ASTM-P-128-04 ASTM-P-128-05 ASTM-P-128-06

4 7 19 61 180 520

Cst Cst Cst Cst Cst Cst

Price / Unit $ 60 60 60 60 60 60

/ / / / / /

500 500 500 500 500 500

mL mL mL mL mL mL

Originally designed for ASTM D-445-97

Standards of Interest Technical Note Oils are tested in accordance with ASTM D-445

Also see Cloud Point Standards used for ASTM Method D-2500 on page 5

Fax 203-786-5287 • Toll Free 800-442-5290 / 203-786-5290 • Website www.accustandard.com

3

Method

Physical Properties

611 1015 1319

Member

ASTM

ASTM D-611 (Reapproved 1998)

Technical Note

Aniline Point Standards

The accuracy of automated aniline point apparatus can be verified using a range of standards whose aniline points are determined using ASTM D-611 (Method A) and ASTM D-611 (Method E). Standards are packaged in 20 mL ampules in an inert atmosphere. Cat. No.

Nominal Aniline Point

D-611-SET

D-611-01 D-611-02 D-611-03 D-611-04 D-611-05

Set include 5 Standards listed below Aniline Point Verification Set Method 611(A) 0°C 30°C 55°C 68°C 94°C

Cat. No.

Nominal Aniline Point

D-611E-SET

Set include 3 Standards listed below Aniline Point Verification Set Method 611(E) 43°C 62°C 77°C

$ 90 / 3 x 20 mL

ASTM-P-134-PAK

Pure Aniline

$ 30 / 5 x 15 mL

ASTM D-1015

Freezing Points of High Purity Hydrocarbons

D-611E-01 D-611E-02 D-611E-03

Price / Unit $ 90 / 5 x 20 mL

20 20 20 20 20

For routine purposes pure Aniline is packaged in ampules under dry nitrogen. This minimizes the risk of oxidation.

Originally designed for D-611-82

mL mL mL mL mL

Price / Unit

20 mL 20 mL 20 mL

Cat. No.

Price / Unit

See Method D-2386 page 5 for AccuStandard’s new line of Freezing Point Standards

Technical Note

ASTM D-1319 Calibration Standards by Fluorescent Indicator Adsorption FIA Originally designed for D-1319-99

Olefin FIA Calibration Curve FIA-CAL-SET

$ 300 / Set of 7 x 1 mL Std. 1 Target Vol. %

Total Olefins Total Paraffins Total Aromatics Total Oxygenate

2.0 57.0 23.0 18.0

Std. 2 Vol. %

Std. 3 Vol. %

Std. 4 Vol. %

Std. 5 Vol. %

Std. 6 Vol. %

Std. 7 Vol. %

4.0 55.0 24.0 17.0

5.0 52.0 25.0 18.0

6.0 51.0 26.0 17.0

8.0 45.0 29.0 18.0

10.0 45.0 28.0 17.0

12.0 40.0 30.0 18.0

FIA Paraffin Standard

FIA Olefin Standard

FIA-PAR FIA-PAR-5ML

FIA-OLE FIA-OLE-5ML

n-Pentane n-Hexane Cyclohexane n-Heptane

Vol. % 8 9 15 14

$ 30 / 1 x 1 mL SAVE 33% $ 100 / 1 x 5 mL 8 comps. Vol. % 2,3-Dimethylpentane 14 Isooctane 16 n-Octane 14 n-Decane 7

mix ratio Benzene 4 Toluene 32 Ethylbenzene 8 p-Xylene 8 o-Xylene 8

4

$ 40 / 1 x 1 mL SAVE 40% $ 120 / 1 x 5 mL 3 comps.

1-Pentene 2,3-Dimethyl-2-butene

Vol. % 33.3 33.3

1-Heptene

Vol. % 33.3

Standards of Interest For the mandatory real world QC samples stipulated in the Method, see page 1-2

FIA Aromatic Standard FIA-ARO FIA-ARO-5ML

D-1319 Meets es EPA Guidelin for RFG Analysis

$ 30 / 1 x 1 mL SAVE 33% $ 100 / 1 x 5 mL 10 comps. mix ratio m-Xylene 16 1,2,4-Trimethylbenzene 8 1,3,5-Trimethylbenzene 8 1,2,4,5-Tetramethylbenzene 4 Naphthalene 4

The following set of standards have been prepared for the determination of Aromatics, Olefins, Oxygenates and Saturates in petroleum fractions by Fluorescent Indicator Adsorption (FIA) IP designation 156/95. The final certificate for the FIA calibration curve lists not only the volume percents for the hydrocarbon types, but also the individual volume percents for each analyte in the functional group. To further assist the Petrochemist, the weight fraction for each hydrocarbon type and individual analyte is listed on the final certificate. By providing the individual weights the Petrochemical chemist can use the FIA standards for other types of instrumentation measuring these Petroleum fractions.

Quality System is Certified to comply with the International ISO 9001 Quality Standard

Physical Properties

Method

Member

17446304 2386 2500

ASTM D-1744, E-1064, D-4377 Water in Liquid Petroleum Products by D-4928, D-6304 Karl Fischer Cat. No.

Description

KF-0.6X-5ML-VAP

Water content 60 µg/g

$ 65 / 10 x 5 mL

KF-1X-2ML-VAP KF-1X-5ML-VAP KF-1X-20ML-PAK

Water content 100 µg/g Water content 100 µg/g Water content 100 µg/g

40 / 10 x 2 mL 45 / 10 x 5 mL 50 / 5 x 20 mL

KF-10X-2ML-VAP KF-10X-5ML-VAP KF-10X-20ML-PAK

Water content 1000 µg/g Water content 1000 µg/g Water content 1000 µg/g

40 / 10 x 2 mL 45 / 10 x 5 mL 50 / 5 x 20 mL

KF-50X-2ML-VAP KF-50X-5ML-VAP KF-50X-20ML-PAK

Water content 5000 µg/g Water content 5000 µg/g Water content 5000 µg/g

40 / 10 x 2 mL 45 / 10 x 5 mL 50 / 5 x 20 mL

ASTM D-2386 Cat. No.

ASTM D-2500 Cat. No.

- 50 °C - 45 °C

Price / Unit $ 110 / 250 mL 110 / 250 mL

Originally designed for D-2386-97

Technical Note Verified by consensus analysis by ASTM Method D-2386

Cloud Point Calibration Standards Cloud Point, Approx. Value

ASTM-P-131-01 ASTM-P-131-02 ASTM-P-131-03 ASTM-P-131-04 ASTM-P-131-05

Value Added Paks (Cat. No.’s ending in -VAP) provide multiple single units packaged together for both greater stability and cost savings.

Freezing Point Calibration Standards Nominal Freezing Point

ASTM-P-129-01 ASTM-P-129-02

Price / Unit

Technical Note Many ASTM Petrochemical methods and specifications reference using QA/QC standards for water content measurements. AccuStandard has formulated a comprehensive range of water standards packaged in convenient sizes to meet the various referenced methods.

+ 5 °C - 2 °C - 10 °C - 15 °C - 20 °C

Technical Note

Price / Unit $ 110 110 110 110 110

/ / / / /

250 250 250 250 250

mL mL mL mL mL

Originally designed for D-2500-00

Verified by consensus analysis by ASTM Method D-2500

Fax 203-786-5287 • Toll Free 800-442-5290 / 203-786-5290 • Website www.accustandard.com

5

ASTM

Standards are available for coulometric Karl Fischer titrations and are packaged in 2 mL, 5 mL, and 20 mL ampules in sets of 5 and 10. The following concentrations are available:

ASTM Methods for Sulfur Analysis

Sulfur Standards

SULFUR

ASTM

D-2622-98, D-3120-96, D-3246-96, D-4294-98, D-5453-00, D-6334-98, D-6445-99 & Proposed ASTM Sulfur Methods AccuStandard offers the Petroleum Industry the most complete line of calibration standards designed for today’s Proposed & Promulgated test methods for Sulfur analysis. These calibration standards are designed specifically for the analysis of Sulfur in a wide variety of matrices such as #2 diesel fuel, white mineral oil, kerosene, gasoline, crude oil & residual oil. Traceability, Quality and Certification All Sulfur standards are manufactured from the highest quality raw materials, including well characterized starting materials & the lowest sulfur matrices available from the Petrochemical market. All standards are manufactured on a weight/weight basis using balances that are calibrated and verified daily against reference mass standards directly traceable to NIST under test No. 822/254480. The concentration of these working level Sulfur standards have established traceability links to NIST SRM’s where available. Convenient Packaging Since applicable concentration ranges will vary based on the instrumentation used & the nature of the sample the standards can be ordered as complete sets, individual bottles, or Ready-to-Aspirate AccuShots. AccuShots... Packaged to improve analytical standard integrity AccuStandard is the first standard manufacturer to provide sulfur standards in convenient and Ready-to-Aspirate AccuShot 20 mL sealed ampules. Each 20 mL AccuShot provides the necessary material for calibration curve development or daily QA/QC. By purchasing AccuShots the analytical chemist can open a fresh shot for each analysis which eliminates opening and pipetting repeatedly from a stock bottle. This minimizes contamination and evaporation. These ship with no haz fee for additional savings.

ASTM D-5453 Test to Low

ppb Sulfur

Contact us for a copy of the Southwest Research Institute D-5453 Fitness for Use Report Low Sulfur Standards on following pages

6

Quality System is Certified to comply with the International ISO 9001 Quality Standard

Analytical Capabilities MWD XRF Sulfur Analyzer in Diesel and Gasoline Fuels

Limits of Detection < 1 ppm Fast and easy sample preparation. SULFUR

Typical measurement time: 300 sec. Dynamic range: 0-1000 ppm in one calibration. No sample conversion or reagents required. Exceptional signal-to-background provides high sensitivity for low-level sulfur fuels X-Ray Optical Systems, Inc. 15 Tech Valley Drive East Greenbush, NY 12061 Tel. 518-880-1500 website: www.xos.com

SULFUR ANALYSIS IN

XOS SINDIE Analyzer X-Ray optics enable detection capability well beyond traditional XRF techniques. The same Monochromatic WD XRF technology of the SINDIE bench-top sulfur analyzer is available in an on-line sulfur analyzer.

ULTRA LOW SULFUR FUELS Repeatability: 1 ppm 10 ppm 100 ppm 500 ppm

0.5 1.7 5.3 11.7

ppm ppm ppm ppm

Monochromatic WDXRF Technology

7

Sulfur

Sulfur Standards

in Mineral Oil Diesel Fuel

ASTM Methods

Sulfur Standards for ASTM D-2622, D-3120, D-3246, D-4294, D-5453, D-6334, D-6445 & Proposed ASTM Sulfur Methods

ASTM

ASTM Methods Sulfur in Mineral Oil Sulfur in Heavy Weight Mineral Oil (75 cSt)

SULFUR

Concentration µg/g Blank 100 200 300 400 500 750 1,000 1,500 2,000 3,000 4,000 5,000 7,000 10,000 15,000 20,000 30,000 40,000 50,000 60,000

Wt. % 0.000 0.010 0.020 0.030 0.040 0.050 0.075 0.10 0.15 0.20 0.30 0.40 0.50 0.70 1.00 1.50 2.00 3.00 4.00 5.00 6.00

Set of above Cat. No.’s

Sulfur in White Mineral Oil

Ready-to-Use Sulfur AccuShots

Cat. No. SWMO-BL-4 SWMO-1X-4 SWMO-2X-4 SWMO-3X-4 SWMO-4X-4 SWMO-5X-4 SWMO-7.5X-4 SWMO-10X-4 SWMO-15X-4 -------------------SWMO-30X-4 -------------------SWMO-50X-4 SWMO-70X-4 SWMO-100X-4 SWMO-150X-4 SWMO-200X-4 SWMO-300X-4 SWMO-400X-4 SWMO-500X-4 SWMO-600X-4

Cat. No. SWMO-BL-SHOT SWMO-1X-SHOT SWMO-2X-SHOT SWMO-3X-SHOT SWMO-4X-SHOT SWMO-5X-SHOT SWMO-7.5X-SHOT SWMO-10X-SHOT SWMO-15X-SHOT -------------------------SWMO-30X-SHOT -------------------------SWMO-50X-SHOT SWMO-70X-SHOT SWMO-100X-SHOT SWMO-150X-SHOT SWMO-200X-SHOT SWMO-300X-SHOT SWMO-400X-SHOT SWMO-500X-SHOT SWMO-600X-SHOT

µg/g Blank 100 200 300 400 500 750 1,000 1,500 2,000 3,000 4,000 5,000 7,000 10,000 15,000 20,000 30,000 40,000 50,000 60,000

SWMO-CAL-SET-4 19 x 4 oz. $ 850

Each AccuShot product contains 5 x 20 mL ampules at the stated conc. for $ 60

Set of above Cat. No.’s

Individual Sulfur 1 -10 units 10 +units Standards 4 oz Bottle $ 55 ea $ 50 ea

ASTM Methods Sulfur in #2 Diesel Fuel Concentration µg/g Blank 100 200 300 400 500 750 1,000 1,500 2,000 3,000 4,000 5,000 7,000 10,000 15,000 20,000 30,000 40,000 50,000 60,000

Wt. % 0.000 0.010 0.020 0.030 0.040 0.050 0.075 0.10 0.15 0.20 0.30 0.40 0.50 0.70 1.00 1.50 2.00 3.00 4.00 5.00 6.00

Set of above Cat. No.’s

Sulfur in #2 Diesel Fuel

Ready-to-Use Sulfur AccuShots

Cat. No. SDF-BL-4 SDF-1X-4 SDF-2X-4 SDF-3X-4 SDF-4X-4 SDF-5X-4 SDF-7.5X-4 SDF-10X-4 SDF-15X-4 ------------SDF-30X-4 ------------SDF-50X-4 SDF-70X-4 SDF-100X-4 SDF-150X-4 SDF-200X-4 SDF-300X-4 SDF-400X-4 SDF-500X-4 SDF-600X-4

Cat. No. SDF-BL-SHOT SDF-1X-SHOT SDF-2X-SHOT SDF-3X-SHOT SDF-4X-SHOT SDF-5X-SHOT SDF-7.5X-SHOT SDF-10X-SHOT SDF-15X-SHOT ------------SDF-30X-SHOT ------------SDF-50X-SHOT SDF-70X-SHOT SDF-100X-SHOT SDF-150X-SHOT SDF-200X-SHOT SDF-300X-SHOT SDF-400X-SHOT SDF-500X-SHOT SDF-600X-SHOT

SDF-CAL-SET-4 19 x 4 oz. $ 850

Each AccuShot product contains 5 x 20 mL ampules at the stated conc. for $ 60

Individual Sulfur 1 -10 units 10 +units Standards 4 oz Bottle $ 55 ea $ 50 ea

Technical Note Sulfur conc. calculated from % sulfur in di-n-butyl sulfide

8

Sulfur in Light Weight Mineral Oil (20 cSt) Concentration Wt. % 0.000 0.010 0.020 0.030 0.040 0.050 0.075 0.10 0.15 0.20 0.30 0.40 0.50 0.70 1.00 1.50 2.00 3.00 4.00 5.00 6.00

Sulfur in White Mineral Oil

Ready-to-Use Sulfur AccuShots

Cat. No. SWMO-LT-BL-4 SWMO-LT-1X-4 SWMO-LT-2X-4 SWMO-LT-3X-4 SWMO-LT-4X-4 SWMO-LT-5X-4 SWMO-LT-7.5X-4 SWMO-LT-10X-4 SWMO-LT-15X-4 -------------------SWMO-LT-30X-4 -------------------SWMO-LT-50X-4 SWMO-LT-70X-4 SWMO-LT-100X-4 SWMO-LT-150X-4 SWMO-LT-200X-4 SWMO-LT-300X-4 SWMO-LT-400X-4 SWMO-LT-500X-4 SWMO-LT-600X-4

Cat. No. SWMO-LT-BL-SHOT SWMO-LT-1X-SHOT SWMO-LT-2X-SHOT SWMO-LT-3X-SHOT SWMO-LT-4X-SHOT SWMO-LT-5X-SHOT SWMO-LT-7.5X-SHOT SWMO-LT-10X-SHOT SWMO-LT-15X-SHOT -------------------------SWMO-LT-30X-SHOT -------------------------SWMO-LT-50X-SHOT SWMO-LT-70X-SHOT SWMO-LT-100X-SHOT SWMO-LT-150X-SHOT SWMO-LT-200X-SHOT SWMO-LT-300X-SHOT SWMO-LT-400X-SHOT SWMO-LT-500X-SHOT SWMO-LT-600X-SHOT

SWMO-LT-CAL-SET-4 19 x 4 oz. $ 850

Each AccuShot product contains 5 x 20 mL ampules at the stated conc. for $ 60

Individual Sulfur 1 -10 units 10 +units Standards 4 oz Bottle $ 55 ea $ 50 ea

Ready-to-Use AccuShots... Packaged to improve analytical standard integrity AccuStandard is the first standard manufacturer to provide sulfur standards in convenient and Ready-toAspirate AccuShot 20 mL sealed ampules. Each 20 mL AccuShot provides the necessary material for calibration curve development or daily QA/QC. By purchasing AccuShots the analytical chemist can open a fresh shot for each analysis which eliminates opening and pipetting repeatadly from a stock bottle. This minimizes contamination and evaporation. These ship with no haz fee for additional savings.

Cross Reference Table ASTM IP ISO DIN JIS AFNOR sorted by ASTM Method see beginning of Catalog

Quality System is Certified to comply with the International ISO 9001 Quality Standard

Sulfur Standards

Method

ASTM SulfurMethods for in Kerosene Sulfur

ASTM Methods Sulfur Standards for ASTM D-2622, D-3120, D-3246, D-4294, D-5453, D-6334, D-6445 & Proposed ASTM Sulfur Methods

ASTM Methods Sulfur in Kerosene Ready-to-Use Sulfur AccuShots

µg/g Blank 100 200 300 400 500 750 1,000 1,500 2,000 3,000 4,000 5,000 7,000 10,000 15,000 20,000 30,000 40,000 50,000 60,000

Cat. No. SK-BL-4 SK-1X-4 --------------SK-3X-4 --------------SK-5X-4 SK-7.5X-4 SK-10X-4 --------------SK-20X-4 SK-30X-4 SK-40X-4 SK-50X-4 --------------SK-100X-4 --------------SK-200X-4 ---------------------------------------------------------

Cat. No. SK-BL-SHOT SK-1X-SHOT

SK-CAL-SET-4 12 x 4 oz. $ 500

Each AccuShot product contains 5 x 20 mL ampules at the stated conc. for $ 60

Wt. % 0.000 0.010 0.020 0.030 0.040 0.050 0.075 0.10 0.15 0.20 0.30 0.40 0.50 0.70 1.00 1.50 2.00 3.00 4.00 5.00 6.00

Set of above Cat. No.’s

Individual Sulfur 1 -10 units 10 +units Standards 4 oz Bottle $ 55 ea $ 50 ea

SK-3X-SHOT SK-5X-SHOT SK-7.5X-SHOT SK-10X-SHOT SK-20X-SHOT SK-30X-SHOT SK-40X-SHOT SK-50X-SHOT SK-100X-SHOT SK-200X-SHOT

Concentration

Sulfur in Heavy Distillate Kerosene

µg/g Blank 100 200 300 400 500 750 1,000 1,500 2,000 3,000 4,000 5,000 7,000 10,000 15,000 20,000 30,000 40,000 50,000 60,000

Cat. No. SK-HD-BL-4 SK-HD-1X-4 SK-HD-2X-4 SK-HD-3X-4 SK-HD-4X-4 SK-HD-5X-4 SK-HD-7.5X-4 SK-HD-10X-4 SK-HD-15X-4 SK-HD-20X-4 SK-HD-30X-4 SK-HD-40X-4 SK-HD-50X-4 SK-HD-70X-4 SK-HD-100X-4 SK-HD-150X-4 SK-HD-200X-4 SK-HD-300X-4 SK-HD-400X-4 SK-HD-500X-4 SK-HD-600X-4

Wt. % 0.000 0.010 0.020 0.030 0.040 0.050 0.075 0.10 0.15 0.20 0.30 0.40 0.50 0.70 1.00 1.50 2.00 3.00 4.00 5.00 6.00

Set of above Cat. No.’s

Technical Note Sulfur concentration calculated from % sulfur in di-n-butyl sulfide.

Standards of Interest For the mandatory real world QC samples stipulated in the Method, see pages 1- 2.

SK-HD-CAL-SET-4 21 x 4 oz. $ 950

Individual Sulfur 1 -10 units 10 +units Standards 4 oz Bottle $ 55 ea $ 50 ea

Fax 203-786-5287 • Toll Free 800-442-5290 / 203-786-5290 • Website www.accustandard.com

9

SULFUR

Concentration

Sulfur in Light Distillate Kerosene

Sulfur in Heavy Distillate Kerosene

ASTM

Sulfur in Light Distillate Kerosene

ASTM

Sulfur Standards

26226445

ASTM Methods ASTM D-2622, D-4294 Sulfur Calibration Standards

SULFUR

ASTM

Sulfur Calibration Standards in Isooctane for Gasoline & Reformulated Gasoline Analysis Standards can be mixed for quantity discounts 1 to 4 units 5 to 10 units more than 10 units Cat. No. STP-BL-4 STP-1X-4 STP-2X-4 STP-3X-4 STP-5X-4 STP-10X-4 STP-20X-4 STP-30X-4 STP-40X-4 STP-60X-4 STP-100X-4 STP-200X-4 STP-300X-4 STP-CAL-SET In Isooctane

$ 60 each per Sulfur Standard $ 55 each per Sulfur Standard $ 50 each per Sulfur Standard

Sulfur Conc. Blank 10 µg/g 20 µg/g 30 µg/g 50 µg/g 100 µg/g 200 µg/g 300 µg/g 400 µg/g 600 µg/g 1000 µg/g 2000 µg/g 3000 µg/g

Low Level Sulfur Calibration Standards

Low Level Sulfur Calibration Standards for use on XRF Energy Dispersive or Wavelength Instruments

Originally designed for D-2622-98 D-4294-98

Sulfur Wt. % 0.0 0.001 0.002 0.003 0.005 0.010 0.020 0.030 0.040 0.060 0.10 0.20 0.30

ASTM D-2622, D-6334, D-6445

Unit 4 oz. 4 oz. 4 oz. 4 oz. 4 oz. 4 oz. 4 oz. 4 oz. 4 oz. 4 oz. 4 oz. 4 oz. 4 oz.

$ 650 / set of 13 x 4 oz. Set contains the above 13 individual bottles

Standards can be mixed for quantity discounts 1 to 4 units 5 to 10 units more than 10 units Cat. No. D-2622-LL-BL-4 D-2622-LL-5X-4 D-2622-LL-10X-4 D-2622-LL-30X-4 D-2622-LL-50X-4 D-2622-LL-75X-4 D-2622-LL-100X-4 D-2622-LL-300X-4 D-2622-LL-500X-4 D-2622-LL-1000X-4

$ 60 each per Sulfur Standard $ 55 each per Sulfur Standard $ 50 each per Sulfur Standard Sulfur Conc. Blank 5 µg/g 10 µg/g 30 µg/g 50 µg/g 75 µg/g 100 µg/g 300 µg/g 500 µg/g 1000 µg/g

Sulfur Wt. % 0.0 0.0005 0.0010 0.0030 0.0050 0.0075 0.010 0.030 0.050 0.100

Originally designed for D-2622-98 D-6334-98 D-6445-99 Unit 4 oz. 4 oz. 4 oz. 4 oz. 4 oz. 4 oz. 4 oz. 4 oz. 4 oz. 4 oz.

D-2622-LL-CAL-SET $ 450 / 10 x 4 oz. In Isooctane : Toluene (3:1) Set contains the above 10 individual bottles

Technical Note

Technical Note A well characterized di-n-butyl sulfide starting mat’l is used with a low sulfur Isooctane matrix for RFG/gasoline sulfur standards.

Well characterized Thiophene & 2-Methyl thiophene are used in a low sulfur Isooctane/Toluene matrix for this calibration set.

ASTM D-2622, D-6334, D-6445

ASTM D-3120, D-3246 Sulfur Calibration Set

Mid Level Sulfur Calibration Standards

Sulfur Calibration Set D-3120-92-CAL-SET In Isooctane Cat. No. D-3120-92-BL D-3120-92-1X D-3120-92-3X D-3120-92-10X D-3120-92-30X D-3120-92-50X D-3120-92-75X D-3120-92-100X

$ 75 / set of 8 x 1 mL

Sulfur Conc. Blank 1 µg/g 3 µg/g 10 µg/g 30 µg/g 50 µg/g 75 µg/g 100 µg/g

Sulfur Wt. % ——— 0.0001 0.0003 0.0010 0.0030 0.0050 0.0075 0.010

Originally designed for D-3120-96 D-3246-96

Technical Note Well characterized di-n-butyl sulfide is used in a low sulfur Isooctane matrix for this calibration set.

New Requested Additions for use on XRF Energy Dispersive or Wavelength Instruments Standards can be mixed for quantity discounts 1 to 4 units 5 to 10 units more than 10 units Cat. No. D-2622-LL-200X-4 D-2622-LL-400X-4 D-2622-LL-600X-4 D-2622-LL-700X-4 D-2622-LL-800X-4 D-2622-LL-900X-4 D-2622-LL-1100X-4 D-2622-LL-1200X-4

$ 60 each per Sulfur Standard $ 55 each per Sulfur Standard $ 50 each per Sulfur Standard Sulfur Conc. 200 µg/g 400 µg/g 600 µg/g 700 µg/g 800 µg/g 900 µg/g 1100 µg/g 1200 µg/g

Sulfur Wt. % 0.020 0.040 0.060 0.070 0.080 0.090 0.110 0.120

Originally designed for D-2622-98 D-6334-98 D-6445-99 Unit 4 oz 4 oz 4 oz 4 oz 4 oz 4 oz 4 oz 4 oz

Technical Note Standards of Interest For the mandatory real world QC samples stipulated in many ASTM Sulfur Methods, see page 1-2

Member

10

Well characterized Thiophene & 2-Methyl thiophene are used in a low sulfur Isooctane/Toluene matrix for this calibration set.

AccuStandard is an active member in ASTM and strives to keep abreast of ASTM method revisions. If our listed formulation does not meet the most recent method revision, please contact Technical Support, ext. 117 for an updated product.

Quality System is Certified to comply with the International ISO 9001 Quality Standard

Sulfur Standards

ASTM

2789

ASTM Methods Sulfur Standards for ASTM D-2622, D-3120, D-3246, D-4294, D-5453, D-6334, D-6445 & Proposed ASTM Sulfur Methods

ASTM Methods Sulfur Calibration Standards Sulfur in Crude Oil Standards

Sulfur in Residual Oil Standards

Concentration

Concentration

Sulfur in Crude Oil Wt. % 0.10 0.25 0.50 1.00 2.00 3.00 4.00 5.00

µg/g 3,500 7,000 10,000 15,000 20,000 30,000 40,000

Wt. % 0.35 0.70 1.00 1.50 2.00 3.00 4.00

Set of above Cat. No.’s

SCO-CAL-SET-4 8 x 4 oz. $ 500

Individual Sulfur 1 -10 units 10 +units Standards 4 oz Bottle $ 75 ea $ 65 ea

Cat. No. SRO-35X-4 SRO-70X-4 SRO-100X-4 SRO-150X-4 SRO-200X-4 SRO-300X-4 SRO-400X-4

SULFUR

Set of above Cat. No.’s

Cat. No. SCO-10X-4 SCO-25X-4 SCO-50X-4 SCO-100X-4 SCO-200X-4 SCO-300X-4 SCO-400X-4 SCO-500X-4

AccuStandard's Technical Service Dept. can provide Ready-to-Inject working level calibration standards to meet unique laboratory applications. Call or fax us your standard requirements.

SRO-CAL-SET-4 7 x 4 oz. $ 450

Individual Sulfur 1 -10 units 10 +units Standards 4 oz Bottle $ 75 ea $ 65 ea

ASTM Methods Sulfur Standards Total Sulfur in Aromatic Compounds by Hydrogenolysis & Rateometric Colorimetry

Trace Quantities of Sulfur in Liquid Aromatic Hydrocarbons by Oxidative Microcoulometry

ASTM-P-0010-PAK 1000 µg/mL in Toluene

ASTM-P-0020-PAK 1000 µg/mL in Xylenes

$ 75 / 5 x 1 mL

Sulfur (as Thiophene)

$ 75 / 5 x 1 mL

Sulfur (as Dibenzothiophene)

ASTM-SSTD-A/B-SET $ 100 / 10 x 2 mL The set contains the following 10 standards in isooctane Cat. No.

Description

ASTM-SSTDA-BL ASTM-SSTDA-01 ASTM-SSTDA-02 ASTM-SSTDA-03 ASTM-SSTDA-04

Sulfur Sulfur Sulfur Sulfur Sulfur

Blank @ 0.5 @ 1.0 @ 2.5 @ 5.0

Unit

ASTM-SSTDB-BL ASTM-SSTDB-04 ASTM-SSTDB-05 ASTM-SSTDB-06 ASTM-SSTDB-07

Sulfur Sulfur Sulfur Sulfur Sulfur

Blank @ 5.0 µg/g in Isooctane @ 10.0 µg/g in Isooctane @ 25.0 µg/g in Isooctane @ 50.0 µg/g in Isooctane

µg/g µg/g µg/g µg/g

in in in in

Isooctane Isooctane Isooctane Isooctane

2 2 2 2 2

mL mL mL mL mL

2 2 2 2 2

mL mL mL mL mL

Technical Note

ASTM D-2789 Hydrocarbon Types in Low Olefinic Gas by MS Composition Test Mix D-2789-CTM D-2789-CTM-PAK

2-Methylpentane 2,4-Dimethylpentane n-Octane Methylcyclopentane Methylcyclohexane

$ 40 / 1 x 1 mL SAVE 20% $ 160 / 5 x 1 mL 9 comps. (Vol. %) 7.2 9.4 16.6 7.1 10

cis-1,2-Dimethylcyclohexane Benzene Toluene p-Xylene

Originally designed for D-2789-95

ASTM

µg/g 1,000 2,500 5,000 10,000 20,000 30,000 40,000 50,000

Sulfur in Crude Oil

Technical Note

Both the actual volume % ratio and the final weight fractions for each analyte will be listed on the certificate.

(Vol. %) 15.5 7.7 10 16.5

Fax 203-786-5287 • Toll Free 800-442-5290 / 203-786-5290 • Website www.accustandard.com

11

PIANO

PIANO, PONA, PNA

PIANO PONA PNA

AccuStandard has introduced the PIANO line of quantitative and qualitative Petrochemical Standards for class type analysis of petrochemical samples or product streams. PIANO analysis involves the determination of the percentage of the following five fractions Paraffins, Isoparaffins, Aromatics, Naphthenes, and Olefins. PONA analysis involves analyzing the naphtha sample for Paraffins, Olefins, Naphthenes, and Aromatics. If the Isoparaffins and Olefins are not present, the analysis is just for PNA. The PIANO line of standards is used to determine quantitative and qualitative retention times and indices as well as to monitor response factors within the hydrocarbon blend. These complex mixes are prepared from materials of the highest available purity, accurate to four decimal places, and include a detailed data sheet on the formulation composition. The typical range for the analytes in each formulation has been provided for each catalog item. The exact composition on a weight % basis for each analyte has been provided on the certificate, and a disk deliverable spreadsheet is available on request. Mini Inert Valves Seal The PIANO standards are supplied in convenient to use crimp top vials with Viton septa that resist mineral oil, aliphatic, aromatics hydrocarbons, and higher temperatures. Mini inert valve seals are available for an additional $ 25 vial. To order, add “-MIV” to any of the PIANO catalog numbers on this page.

PIANO, PONA, PNA Analysis PIANO Mixture

High Aromatic PIAN Blend

ASTM-P-0030

ASTM-P-0037

PIONA

$ 250 / 100 µL 135 comps. The PIANO formulation contains the n-Paraffins, Isoparaffins,Aromatics, Naphthenes, and Olefins from the five Cat. No.’s: ASTM-P-0031, ASTM-P-0032, ASTM-P-0033, ASTM-P-0034, ASTM-P-0035 Approximate weight percentages for the total: n-Paraffins 18.5%, Isoparaffins 17.9%, Aromatics 23.6%, Naphthenes 20.9%, Olefins 19.0%. The actual certificate will list the weight % for all analytes in the formulation.

$ 120 / 100 µL 110 comps. High Aromatic blend contains the PIAN components blended to resemble a reformate. The actual certificate will have the exact weight % for each analyte accurate to four decimal places. Analyte list is drawn from Cat. No.’s: ASTM-P-0031, ASTM-P-0032, ASTM-P-0033, ASTM-P-0034

Standards of Interest

Low Aromatic PIAN Blend ASTM-P-0036

$ 120 / 100 µL 110 comps. Low Aromatic blend contains the PIAN components blended to resemble a light naphtha. The actual certificate will have the exact weight % for each analyte accurate to four decimal places. Analyte list is drawn from Cat. No.’s: ASTM-P-0031, ASTM-P-0032, ASTM-P-0033, ASTM-P-0034

For individual PIANO descriptions see next page

AccuStandard, Your Standards and Technical Information Source!

12

Total Petroleum Hydrocarbon Pattern Recognition Standards

Analytical Standards and Reference Material for all 209 PCB Congeners

BOOK-TPH

S-3571

$ 35

$ 25

Quality System is Certified to comply with the International ISO 9001 Quality Standard

PIANO, PONA, PNA PIANO

PIANO PONA PNA

PIANO, PONA, PNA Analysis PIANO Mix Set ASTM-PIANO-SET $ 700 / 6 x 100 µL Set includes the following Cat. No.: ASTM-P-0030, ASTM-P-0031, ASTM-P-0032, ASTM-P-0033, ASTM-P-0034, ASTM-P-0035

Special Packaging Mini inert valve seals are available for an additional $ 25 / vial. To order, add “-MIV” to any of the PIANO cat.# on this page.

PIANO n-Paraffins Mix

PIANO Isoparaffins Mix

ASTM-P-0031 $ 80 / 100 µL 11 paraffins listed below at varying Wt. % typically in the range from 7.0 to 11.0 Wt. %. The actual certificate will have the exact Wt. % for each analyte. Typ. Wt. % n-Pentane 9.4375 n-Hexane 9.5661 n-Heptanea 9.8048 n-Octane 9.5518 n-Nonane 9.0482 n-Decane 9.2517 n-Undecane 9.3172 n-Dodecane 9.1855 n-Tridecane 8.9332 n-Tetradecane 8.7989 n-Pentadecane 7.1057

ASTM-P-0032 $ 120 / 100 µL 35 Isoparaffins listed below at varying Wt. % typically in the range from 0.5 to 6.0 Wt. %. The actual certificate will have the exact Wt. % for each analyte. Typ. Wt. % Isopentane 2.1928 2,3-Dimethylbutane 0.4466 2-Methylpentane 3.2815 3-Methylpentane 5.3865 2,2-Dimethylpentane 1.7747 2,4-Dimethylpentane 3.6993 2,2,3-Trimethylbutane 3.9291 3,3-Dimethylpentane 1.1848 2-Methylhexane 2.2384 2,3-Dimethylpentane 1.7883 3-Methylhexane 1.6708 3-Ethylpentane 0.5080

PIANO Aromatics Mix

PIANO Naphthenes Mix

PIANO Olefins Mix

ASTM-P-0033 $ 120 / 100 µL 38 Aromatics listed below at varying Wt. % typically in the range from 0.2 to 7.0 Wt. %. The actual certificate will have the exact Wt. % for each analyte.

ASTM-P-0034 $ 120 / 100 µL 30 Napthenes listed below at varying Wt. % typically in the range from 0.5 to 8.0 Wt. %. The actual certificate will have the exact Wt. % for each analyte. Typ. Wt. % Cyclopentane 4.9143 Methylcyclopentane 3.2829 Cyclohexane 5.3268 1,1-Dimethylcyclopentane 3.4612 cis-1,3-Dimethylcyclopentane 0.5963 trans-1,2-Dimethylcyclopentane 1.4715 trans-1,3-Dimethylcyclopentane 2.7531 Methylcyclohexane 5.6091 Ethylcyclopentane 3.5534 ctc-1,2,3-Trimethylcyclopentane 1.5859 cct-1,2,4-Trimethylcyclopentane 3.7208 ctc-1,2,4-Trimethylcyclopentane 1.6467 trans-1,4-Dimethylcyclohexane 3.6499 1-Ethyl-1-methylcyclopentane 1.0554 trans-1,2-Dimethylcyclohexane 1.6537 ccc-1,2,3-Trimethylcyclopentane 0.7971 Isopropylcyclopentane 3.5042 cis-1,2-Dimethylcyclohexane 3.7159 n-Propylcyclopentane 3.6438 ccc-1,3,5-Trimethylcyclohexane 3.5263 1,1,4-Trimethylcyclohexane 3.6791 ctt-1,2,4-Trimethylcyclohexane 3.6107 ctc-1,2,4-Trimethylcyclohexane 3.5069 1,1,2-Trimethylcyclohexane 3.3354 Isobutylcyclopentane 3.7123 Isopropylcyclohexane 5.7233 n-Butylcyclopentane 3.6944 Isobutylcyclohexane 5.6729 t-1-Methyl-2-propylcyclohexane 3.8434 t-1-Methyl-2-(4MP)cyclopentane 3.7534

ASTM-P-0035 $ 120 / 100 µL 25 Olefins listed below at varying Wt. % typically in the range from 1.2 to 9.0 Wt. %. The actual certificate will have the exact Wt. % for each analyte.

PIANO Mixture

Typ. Wt. % 2,3-Dimethylheptane 1.4870 3,4-Dimethylheptane 3.7450 2-Methyloctane 3.7576 3-Methyloctane 5.6020 3,3-Diethylpentane 1.5755 2,2-Dimethyloctane 3.4135 3,3-Dimethyloctane 3.2582 2,3-Dimethyloctane 3.8842 3-Ethyloctane 3.7482 2-Methylnonane 3.7144 3-Methylnonane 5.7687

3-Methyl-1-butene 1-Pentene 2-Methyl-1-butene 2-Methyl-1,3-butadiene trans-2-Pentene cis-2-Pentene 4-Methylpentene-1 1-Hexene trans-2-Hexene 2-Methylpentene-2 cis-2-Hexene 1-Heptene trans-3-Heptene cis-3-Heptene trans-2-Heptene cis-2-Heptene 1-Octene trans-2-Octene cis-2-Octene 1-Nonene trans-3-Nonene cis-3-Nonene trans-2-Nonene cis-2-Nonene 1-Decene

PIONA

Typ. Wt. % Benzene 7.1437 Toluene 4.5738 EthylBenzene 6.7670 m-Xylene 2.2259 p-Xylene 4.4815 o-Xylene 2.2519 Isopropylbenzene 2.2248 n-Propylbenzene 4.4979 1-Methyl-3-ethylbenzene 2.2243 1-Methyl-4-ethylbenzene 2.2206 1,3,5-Trimethylbenzene 1.1076 1-Methyl-2-ethylbenzene 2.2611 1,2,4-Trimethylbenzene 2.2535 tert-Butylbenzene 4.5310 Isobutylbenzene 4.4216 sec-Butylbenzene 2.2368 1-Methyl-3-isopropylbenzene 1.1066 1-Methyl-4-isopropylbenzene 1.0668 1-Methyl-2-isopropylbenzene 1.1241 1-Methyl-3-n-propylbenzene 2.1135 1-Methyl-4-n-propylbenzene 2.2336 n-Butylbenzene 2.2087 1,2-Diethylbenzene 1.0947 1-Methyl-2-n-propylbenzene 2.2641 1,4-Dimethyl-2-ethylbenzene 2.2803 1,3-Dimethyl-5-ethylbenzene 2.2858 1,2-Dimethyl-4-ethylbenzene 2.2558 1,3-Dimethyl-2-ethylbenzene 1.1416 1,2-Dimethyl-3-ethylbenzene 2.1864 1,2,4,5-Tetramethylbenzene 0.2360 2-Methylbutylbenzene 1.1453 trans-1-Butyl-2-methylbenzene 0.7641 n-Pentylbenzene 4.4828 t-1-Butyl,3,5-dimethylbenzene 2.1641 t-1-butyl-ethylbenzene 2.2322 1,3,5-Triethylbenzene 4.5671 1,2,4-Triethylbenzene 1.1087 n-Hexylbenzene 4.5029

Typ. Wt. % 2,2-Dimethylhexane 1.3061 2,5-Dimethyl hexane 3.6975 2,2,3-Trimethylpentane 1.7371 2,4-Dimethylhexane 1.6252 2,3-Dimethylhexane 1.6212 2-Methylheptane 4.4073 4-Methylheptane 3.2015 3-Methylheptane 5.5186 3-Ethylhexane 0.6999 3,3-Dimethylheptane 1.7011 2,5-Dimethylheptane 5.6731 3,5-Dimethylheptane 0.7565

Typ. Wt. % 1.9396 4.1355 1.4440 2.3889 1.8034 1.9792 3.4372 7.0484 1.7302 3.3901 3.8765 7.6134 3.3469 5.8657 3.7217 5.7679 7.6901 1.9432 3.9502 7.6425 1.9972 4.0042 1.9848 2.7952 8.2053

Production Note AccuStandard may add and/or subtract PIANO Analytes and vary the weight % for each Analyte. The certificate will reflect the exact Analyte composition.

ASTM-P-0030 $ 250 / 100 µL (135 comps.) The PIANO formulation contains the n-Paraffins, Isoparaffins,Aromatics, Naphthenes, and Olefins from the Five Cat. No.’s: ASTM-P-0031, ASTM-P-0032, ASTM-P-0033, ASTM-P-0034, ASTM-P-0035 Approximate weight %’s for the total: n-Paraffins 18.5%, Isoparaffins 17.9%, Aromatics 23.6%, Naphthenes 20.9%, Olefins 19.0%. The certificate lists the weight % for all analytes in the formulation.

Fax 203-786-5287 • Toll Free 800-442-5290 / 203-786-5290 • Website www.accustandard.com

13

Method

Detailed Hydrocarbon Analysis

2887 DHA

Member

ASTM

Detailed Hydrocarbon Analysis DHA - PONA-VI (PONA 6) is a qualitative mixture of various gasoline and refinery materials prepared to provide nearly every component that may be encountered in feedstock and finished gasolines. Some oxygenates have been added to allow this blend to be used for DHA method setup. This blend contains approximately 450 components (peaks).

Proposed ASTM Method for Detailed Hydrocarbon Analysis (DHA) Determination of Individual Components and Groups of Components in Spark Ignition Engine fuels by High Efficiency Open Tubular Column Gas Chromatography (Detailed Hydrocarbon Analysis)

Detailed Hydrocarbon Analysis (includes oxygenates) ASTM-P-0038 $ 120 / 100 µL 30 Analytes listed below at varying targeted weight %. The actual certificate will has the exact Wt. % for each analyte. Ethanol Pentane 2-Methyl-2-propanol 2-Methylbutene 2,3-Dimethylbutane Methyl-t-butyl ether Hexane Methylcyclopentene

Benzene Cyclohexane 3-Ethylpentane t-1,2-Dimethylcyclopentane Heptane 2,2,3-Trimethylpentane 2,3,3-Trimethylpentane Toluene

p-Xylene Ethylbenzene Octane 2,3-Dimethylheptane Nonane 5-Methylnonane 1-Ethyl-2-methylbenzene

Decane Undecane 1,2,3,5-Tetramethylbenzene Naphthalene Dodecane 1-Methylnaphthalene Tridecane

ASTM-P-0139

$ 120 / 100 µL

ASTM D-2887 Boiling Range Distribution of Petroleum Fractions by GC Calibration Mix DRH-002N DRH-002N-10X Wt. % n-Hexane 6 n-Heptane 6 n-Octane 8 n-Nonane 8 n-Decane 12 n-Undecane 12 n-Dodecane 12 n-Tetradecane 12 n-Hexadecane 10

$ 10 / 100 mg $ 40 / 1 gm 17 comps. Wt. n-Octadecane n-Eicosane n-Tetracosane n-Octacosane n-Dotriacontane n-Hexatriacontane n-Tetracontane n-Tetratetracontane

% 5 2 2 1 1 1 1 1

n-Hexadecane

$ 10 / 1 x 1 mL 2 comps. n-Octadecane

Heptadecane Octadecane Phytane (2,6,10,14-Tetramethylhexadecane) Pristane (2,6,10,14-Tetramethylpentadecane)

DRH-008S-R2 $ 65 / 1 x 1 mL DRH-008S-R2-PAK SAVE 20% $ 260 / 5 x 1 mL 500 µg/mL each in Chloroform 35 comps.

D-2887-REFOIL

NEW

Calibration Solution *

µg/mL 600 600 800 800 1200 1200 1200 1200 1000

ASTM D-2887 Reference Gas Oil Sample Lot #2

Nonadecane Phytane Eicosane Heneicosane Docosane Tricosane Tetracosane Pentacosane Hexacosane Heptacosane Octacosane Nonacosane

$ 35 / 1 x 1 mL

Technical Note

Triacontane n-Hentriacontane Dotriacontane Tritriacontane Tetratriacontane Pentatriacontane Hexatriacontane Heptatriacontane Octatriacontane Nonatriacontane Tetracontane

This sample is a petroleum fraction having a boiling range from 250°F to 850°F, evaluated in round robin studies by the ASTM D-02 committee. Use of this sample and the supplied ASTM boiling range consensus values helps to evaluate system performance

AccuStandard offers a hydrocarbon window defining standard with the C8 to C40 odd and even Alkanes. As an added benefit, AccuStandard included pristane and phytane in the formulation. Use of this one standard measuring the C17/ pristane and C18/ phytane ratio can be used to estimate degradation of fuel oil. If you prefer, AccuStandard has also developed a fuel oil degradation mixture containing just the four required analytes to determine the C17/pristane and C8/ phytane ratio Catalog Numbers DRH-005S-10X.

DRH-005S-10X $ 20 / 1 x 1 mL 2.0 mg/mL each in CH2Cl2 : CS2 (1:1) 4 comps.

n-Hexane n-Heptane n-Octane n-Nonane n-Decane n-Undecane n-Dodecane n-Tetradecane n-Hexadecane

Hydrocarbon Window Defining Standard*

Technical Note

Fuel Oil Degradation/Retention Time Mix for Quantification of C17/Pristane & C18/Phytane ratios

DRH-002S-R1 DRH-002S-R1-PAK At stated conc. in Chloroform

Originally designed for D-2887-99

Octane Nonane Decane Undecane Dodecane Tridecane Tetradecane Pentadecane Hexadecane Heptadecane Octadecane Pristane

Column Test Mixture ASTM-D2887 1% v/v in n-Octane

Complete Hydrocarbon Analysis

$ 50 / 1 x 1 mL SAVE 20% $ 200 / 5 x 1 mL 17 comps.

n-Octadecane n-Eicosane n-Tetracosane n-Octacosane n-Dotriacontane n-Hexatriacontane n-Tetracontane n-Tetratetracontane

µg/mL 500 200 200 100 100 100 100 100

NEW

Calibration Solution * DRH-002S-R2 DRH-002S-R2-PAK 1 % Wt./Wt. each in Chloroform n-Tetratetracontane n-Tetracontane n-Hexatriacontane n-Dotriacontane n-Octacosane n-Tetracosane n-Eicosane

$ 50 / 1 x 1 gm SAVE 20% $ 200 / 5 x 1 gm 20 comps.

n-Octadecane n-Hexadecane n-Tetradecane n-Dodecane n-Undecane n-Decane

n-Nonane n-Octane n-Heptane n-Hexane n-Pentane n-Pentadecane n-Heptadecane

* Can be shipped by Air and Sea

14

Quality System is Certified to comply with the International ISO 9001 Quality Standard

Petrochemical Standards

Method

SIM DIS

Member

SIM DIS Standards Simulated Distillation Stock SIM DIS Paraffin Solution ASTM-P-0050

$ 85 / 1 x 5 mL 14 comps.

Wt. % n-Pentane 6.66 n-Hexane 6.66 n-Heptane 6.66 n-Octane 6.66 n-Nonane 6.66 n-Decane 6.66 n-Undecane 6.66

Wt. % n-Dodecane 13.33 n-Tetradecane 6.66 n-Pentadecane 6.66 n-Hexadecane 6.66 n-Heptadecane 6.66 n-Octadecane 6.66 n-Eicosane 6.66

$ 20 / 2 grams

n-Pentane n-Hexane n-Heptane n-Octane n-Nonane n-Decane n-Undecane n-Dodecane

Wt. % 0.0333 0.0333 0.0333 0.0333 0.0333 0.0333 0.0333 0.0666

n-Tetradecane n-Pentadecane n-Hexadecane n-Heptadecane n-Octadecane n-Eicosane Polywax 500

ASTM-P-0137N-2G

$ 20 / 2 grams

AccuStandard designed the following formulations for a Proposed ASTM Method under development for Motor Oil Volatility analysis & SIM DIS applications.

Polywax 1000®

Polywax 655® ASTM-P-0053N-2G

Wt. % 0.0333 0.0333 0.0333 0.0333 0.0333 0.0333 0.5

Standards of Interest See ASTM Methods D-3710, D-5307, D-5442, D-6352 for additional calibration standards for hydrocarbon analysis.

Technical Note

Polywax 850

Polywax 500

Polywax 655

ASTM-P-0052 $ 40 / 1 x 1 mL ASTM-P-0052-PAK SAVE 20% $ 160 / 5 x 1 mL At stated conc. in Carbon disulfide 15 comps.

Polywax 850®

Polywax 500® ASTM-P-0051N-2G

Working Level SIM DIS Paraffin Solution with Polywax 500

$ 20 / 2 grams

ASTM-P-0138N-2G

$ 20 / 2 grams

Polywax 1000

For our complete line of Organic Standards, request a copy of our Organic Catalog

For our complete line of Inorganic Standards, request a copy of our Inorganics Catalog

Fax 203-786-5287 • Toll Free 800-442-5290 / 203-786-5290 • Website www.accustandard.com

15

ASTM

Simulated Distillation (SIM DIS) and Proposed Motor Oil Volatility Method AccuStandard has developed an extensive line of SIM DIS standards for normal and high temperature analytical requirements when generating boiling point versus retention time calibration curves. Since normal paraffins above Alkane C60 are not readily available, Polywax 500, Polywax 655, Polywax 850 and Polywax 1000 standards have been incorporated to perform SIM DIS analysis of heavy petroleum fractions with boiling points up to 1350 °F. If you require additional analytes added to the formulations for extended SIM DIS work, use our custom quotation request form located in the back of the catalog.

Method

ASTM Standards

3120 3230 3231 3237

, Member

ASTM D-3120 & D-3246 Trace Quantities of Sulfur in Light Liquid Petroleum Hydrocarbons by Oxidative Microcoulometry Originally designed for D-3120-96 D-3246-96

ASTM

Sulfur Calibration Set D-3120-92-CAL-SET In Isooctane Cat. No. D-3120-BL D-3120-92-1X D-3120-92-3X D-3120-92-10X D-3120-92-30X D-3120-92-50X D-3120-92-75X D-3120-92-100X

$ 75 / set of 8 x 1 mL

Sulfur Conc.

Sulfur Wt.%

Blank 1 µg/g 3 µg/g 10 µg/g 30 µg/g 50 µg/g 75 µg/g 100 µg/g

Blank 0.0001 0.0003 0.0010 0.0030 0.0050 0.0075 0.010

Standards of Interests

Technical Note Well characterized di-n-butyl sulfide is used in a low sulfur Isooctane matrix for this calibration set.

See page 1 for AccuStandard’s comprehensive line of Certified Sulfur calibration standards, AccuPetroCheck, and AccuPetroTest quality control products.

ASTM D-3230 Salts in Crude Oil Mixed Salt Solution D-3230-89-1 $ 75 / 100 mL D-3230-89-5 $ 150 / 500 mL At stated conc. in Alcohol Solution (1-butanol : MeOH) (ratio 63:37) tr. H2O 3 comps. Calcium chloride Magnesium chloride

10 µg/mL 20 µg/mL

Sodium chloride

ASTM D-3231 Phosphorus in Gasoline Element Matrix

Originally designed for D-3230-99

70 µg/mL

Originally designed for D-3231-99

Quantity Conc.

Cat. No.

Price

Phosphorus H2O

100 mL 1000 µg/mL

ICP-41W-1

$ 34

Phosphorus H2O

500 mL 1000 µg/mL

ICP-41W-5

$ 67

1 D-323 Meets es id u elin EPA G FG for R is Analys

ASTM D-3237 Lead in Gasoline by AA Spectroscopy Lead Standard Calibration Curve D-3237-CAL-SET Set includes the following Catalog Numbers: Cat. No. D-3237-01 D-3237-02 D-3237-03 D-3237-04

$ 210 / 4 x 100 mL

Originally designed for D-3237-97

Description Blank 1% Aliquot 336/MIBK 0.02 g Pb / gal ( 5.3 mg Pb/ L) in 1% Aliquat 336 / MIBK 0.05 g Pb / gal ( 13.2 mg Pb/ L) in 1% Aliquat 336 / MIBK 0.10 g Pb / gal ( 26.4 mg Pb/ L) in 1% Aliquat 336 / MIBK

$ $ $ $

Price / Unit 20 / 100 mL 80 / 100 mL 80 / 100 mL 80 / 100 mL

7 D-323 Meets es uidelin EPA G FG for R is Analys

Ready-to-Inject Petrochemical Standards and Calibration Curves Reduce Costs

Ready-to-Inject

Increase Time Spent for Sample Analysis Are Validated Against Independent Lots Include Internal Standards or Surrogates

Working Level Standards & Continuing Calibration Check (CCC)

Follow ASTM Method Guidelines Allow Direct Transfer to Autosampler Vials

16

Quality System is Certified to comply with the International ISO 9001 Quality Standard

ASTM Standards

Method

Member

3246 3340 3524 3605

ASTM D-3246 Sulfur in Petroleum Gas by Oxidative Microcoulometry See pages 6 - 11 for AccuStandards comprehensive line of certified sulfur calibration standards

ASTM

ASTM D-3340 Lithium & Na in Lubricating Greases by Flame Photometer AccuStandard AccuTrace brand AA standards are produced under our rigorous ISO 9001 quality system to exacting specifications. Each standard is prepared from high purity starting materials; deionized water and high purity acids. Every standard is instrumentally assayed to verify 1000 ppm concentration of specified element; Actual Lot Analysis is provided on the label and a Certificate of Analysis is included for ease of record keeping and availability at audits. Originally designed for D-3340-98 Element

Unit

Matrix

Cat. No.

Price

Technical Note

1,000 µg/mL 100 mL 500 mL

AA30H-1 AA30H-5

$ 12 30

Sodium * HCl

100 mL 500 mL

AA54H-1 AA54H-5

13 33

ASTM D-3524 (Reapproved 1999) Diesel Fuel Diluent in Used Diesel Engine Oils by GC D-3524 Calibration Curve D-3524-CAL-SET-5ML D-3524-CAL-SET-10ML

Test to

Low ppb

Originally designed for D-3524-90

$ 150 / set of 6 x 5 mL $ 250 / set of 6 x 10 mL

Sulfur

Analyte

Standard 1 Target Wt. %

Standard 2 Target Wt. %

Standard 3 Target Wt. %

Standard 4 Target Wt. %

Standard 5 Target Wt. %

Standard 6 Target Wt. %

# 2 Diesel 30 W Motor oil

10 90

7.5 92.5

5 95

2.5 97.5

1 99

0 100

Internal Standard Solution

Mid Level Daily QC Solution

D-3524-IS-10ML $ 25 / 1 x 10 mL D-3524-IS-10ML-PAK SAVE 20% $ 100 / 5 x 10 mL At stated conc. in n-Heptane 2 comps. Wt. / Wt. % n-Decane 1.0 n-Octadecane 0.2

D-3524-QC-10ML

# 2 Diesel 30 W Motor oil

WEAR METALS

Lithium * HCl

* For your convenience these elements are also available in HNO3. To order HNO3 change the H to N at the end of the Cat. No.

See Pages 6-11

$ 30 / 1 x 10 mL 2 comps. Wt. / Wt. % 5.0 95

Column Resolution Mix D-3524-CR $ 10 / 1 x 1 mL D-3524-CR-PAK SAVE 20% $ 40 / 5 x 1 mL At stated conc. in n-Heptane 2 comps. Wt. / Wt. % n-Hexadecane 1.0 n-Octadecane 1.0

ASTM D-3605 (Reapproved 1995)

Trace Metals in Gas Turbine Fuels by AA & Flame Emission Spectroscopy

D-3605-91 Trace Metals Standard D-3605-91-1 $ 165 / 1 x 100 mL At stated conc. in 1,2,3,4-Tetrahydronaphthalene 4 comps. Na (Sodium) Pb (Lead)

(250 µg/mL) (250 µg/mL)

Ca (Calcium) V (Vanadium)

Originally designed for D-3605-91

Standards of Interests See Table of Contents for the Wear Metals Group pages

(250 µg/mL) (250 µg/mL)

Fax 203-786-5287 • Toll Free 800-442-5290 / 203-786-5290 • Website www.accustandard.com

17

Method

ASTM Standards

3606 3610

, Member

Originally designed for D-3606-99

ASTM D-3606 Benzene & Toluene in Finished Motor & Aviation Gasoline by GC Aromatics Quantitative Calibration Standard (without Internal Standards)

ASTM

D-3606-SET-25ML

Benzene Toluene Isooctane

$ 800 / set of 7 x 25 mL

Analyte Calibr. range

Std. 1 Target Vol. %

Std. 2 Vol. %

Std. 3 Vol. %

Std. 4 Vol. %

Std. 5 Vol. %

Std. 6 Vol. %

Std. 7 Vol. %

0.06 - 5.0 0.5 - 20

5.00 20.00 75.00

2.50 15.00 82.50

1.25 10.00 88.75

0.67 5.00 94.33

0.33 2.50 97.17

0.12 1.00 98.88

0.06 0.50 99.44

6 D-360 Meets es uidelin EPA G FG for R is Analys

Aromatics Quantitative Calibration Standard (with Internal Standard: MEK) D-3606/IS-SET D-3606/IS-SET-2ML D-3606/IS-SET-2ML-PAK

$ 115 / set of 7 x 1 mL $ 190 / set of 7 x 2 mL $ 760 / 5 x (7 x 2) mL

Analyte Calibr. range Benzene 0.06 - 5.0 Toluene 0.5 - 20 Isooctane Methyl ethyl ketone (Internal Std.)

Std. 1 Target Vol. %

Std. 2 Vol. %

Std. 3 Vol. %

Std. 4 Vol. %

Std. 5 Vol. %

Std. 6 Vol. %

Std. 7 Vol. %

4.8 19.2 72.0 4.0

2.4 14.4 79.2 4.0

1.2 9.6 85.2 4.0

0.6432 4.8000 90.5568 4.0

0.3168 2.4000 93.2832 4.0

0.1152 0.9600 94.9248 4.0

0.0576 0.4800 95.4624 4.0

Gasoline Refinery Quality Control Standards Daily Quality Control Standard (with Internal Standard: MEK)

Daily Quality Control Standard (without Internal Standard)

D-3606-QC/IS-10ML D-3606-QC/IS-10ML-PAK Each at stated quantities

D-3606-QC-25ML D-3606-QC-25ML-PAK Each at stated quantities

Compound Benzene Toluene Isooctane Methyl ethyl ketone (ISTD)

$ 75 / 1 x 10 mL $ 300 / 5 x 10 mL 4 comps. Target Vol. % 0.6432 4.8000 90.5568 4.0

Compound Benzene Toluene Isooctane

$ 125 / 1 x 25 mL $ 600 / 5 x 25 mL 3 comps. Target Vol. % 0.67 5.00 94.33 100

100

Technical Note

Aromatics Quantitative Calibration Standard (w/ Internal Standard: sec Butanol) D-3606/IS2-SET D-3606/IS2-SET-PAK

$ 115 / set of 7 x 1 mL $ 500 / 5 x (7 x 1) mL

Analyte Calibr. range Benzene 0.06 - 5.0 Toluene 0.5 - 20 Isooctane sec Butanol (Internal Standard)

Std. 1 Target Vol. %

Std. 2 Vol. %

Std. 3 Vol. %

Std. 4 Vol. %

Std. 5 Vol. %

Std. 6 Vol. %

Std. 7 Vol. %

4.8 19.2 72.0 4.0

2.4 14.4 79.2 4.0

1.2 9.6 85.2 4.0

0.6432 4.8000 90.5568 4.0

0.3168 2.4000 93.2832 4.0

0.1152 0.9600 94.9248 4.0

0.0576 0.4800 95.4624 4.0

Gasoline Refinery Quality Control Standards Daily Quality Control Standard Daily Quality Control Standard (without Internal Standard) (with Internal Standard: sec Butanol) D-3606-QC-IS2-25ML D-3606-QC-IS2-25ML-PAK Each at stated quantities Compound Benzene Toluene Isooctane sec-Butanol (ISTD)

$ 125 / 1 x 25 mL $ 600 / 5 x 25 mL 4 comps. Target Vol. % 0.6432 4.8000 90.5568 4.0 100

D-3606-QC-25ML D-3606-QC-25ML-PAK Each at stated quantities Compound Benzene Toluene Isooctane

Due to changes in the possible use of other oxygenates like ethanol added to gasoline, AccuStandard formulated a new calibration curve using sec-butanol as an Internal Standard. The use of this new ISTD minimizes coelution caused by the oxygenate(s) and pre column - standard column configuration in the GC system.

$ 125 / 1 x 25 mL $ 600 / 5 x 25 mL 3 comps. Target Vol. % 0.67 5.00 94.33 100

ASTM D-3610 Total Cobalt in Alumina-Base Cobalt-Molybdenum Catalyst by Potentiometric Titration Cobalt Oxide Standard D-3610-93-1

$ 50 / 1 x 100 mL

Originally designed for D-3610-88 (Re-Approved 1993)

Cobalt oxide @ 1500 µg/mL in Water

18

Quality System is Certified to comply with the International ISO 9001 Quality Standard

On-Line Ordering There is an

easier way to get Chemical Reference Standards ®

e-Standards from AccuStandard.com ASTM

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Over 30,000 Standards just a click away

Cross Reference Table ASTM IP ISO DIN JIS AFNOR sorted by ASTM Method see beginning of Catalog

Test to

Low ppb

Sulfur See Pages 6-11

Fax 203-786-5287 • Toll Free 800-442-5290 / 203-786-5290 • Website www.accustandard.com

19

Method

ASTM Standards

3710 3798 3831

, Member

ASTM

ASTM D-3710 (Reapproved 1999) Boiling Range Distribution of Gasoline & Gasoline Fractions by GC This SIM DIS (Simulated Distillation or GCD) Method is used to determine the boiling range distribution of gasoline and gasoline components. ASTM Method D-3710 is used for petroleum products and fractions with a final boiling point of 500°F (260°C) or lower. By having an insight into the composition of the gasoline blend, essential data for the calculation of vapor pressure and a prediction of the D-86 distillation curve can be made.

Qualitative Calibration Standard

Quantitative Calibration Standard

D-3710-QUAL D-3710-QUAL-PAK

ASTM-D3710 ASTM-D3710-PAK

$ 30 / 1 x 1 mL SAVE 20% $ 120 / 5 x 1 mL 19 comps.

Approx. Wt./ Wt. % n-Butane 4.5 n-Butylbenzene 3.2 n-Decane 3.2 2,4-Dimethylpentane 5.4 n-Dodecane 3.2 n-Heptane 9.7 n-Hexane 5.4 2-Methylbutane 9.7 2-Methylpentane 5.4 2-Methylpropane 1.5

Approx. Wt./ Wt. % n-Octane 5.4 n-Pentadecane 2.2 n-Pentane 7.6 n-Propane 1.5 n-Propylbenzene 4.3 n-Tetradecane 2.2 Toluene 10.8 n-Tridecane 2.2 p-Xylene 13

$ 25 / 1 x 1 mL SAVE 36% $ 80 / 5 x 1 mL 16 comps.

Vol./Vol. % n-Butylbenzene 3.5 n-Decane 3.5 2,4-Dimethylpentane 5.8 n-Dodecane 3.5 n-Heptane 10.5 n-Hexane 5.8 2-Methylbutane 10.5 2-Methylpentane 5.8 Vol./Vol. %

n-Octane n-Pentadecane n-Pentane n-Propylbenzene n-Tetradecane Toluene n-Tridecane p-Xylene

Originally designed for D-3710-95

Standards of Interests See page 3 for AccuStandard’s new D-86 QA/QC Standards.

5.8 2.3 8.1 4.7 2.3 11.6 2.3 14.0

NEW

ASTM D-2887-99 Boiling Range Distribution of Petroleum Fractions by GC Calibration Solution * DRH-002S-R1 DRH-002S-R1-PAK At stated conc. in Chloroform µg/mL µg/mL 1200 n-Hexane 600 n-Undecane 1200 n-Heptane 600 n-Dodecane 1200 n-Octane 800 n-Tetradecane 1000 n-Nonane 800 n-Hexadecane n-Decane 1200

n-Octadecane n-Eicosane n-Tetracosane n-Octacosane

µg/mL 500 200 200 100

$ 50 / 1 x 1 mL SAVE 20% $ 200 / 5 x 1 mL 17 comps. µg/mL n-Dotriacontane 100 n-Hexatriacontane 100 n-Tetracontane 100 n-Tetratetracontane100 * Can be shipped by Air and Sea

ASTM D-3798 Analysis of p-Xylene by GC

Technical Note

AccuStandard’s R & D team has developed a special highly purified p-Xylene designed for ASTM Method D-3798 specifications. The incorporation of this p-Xylene into the formulation allows the analytical chemist to qualitatively and quantitatively measure the impurities in the p-Xylene feedstock streams.

p-Xylene Impurity Standard with ISTD

p-Xylene Impurity Standard without ISTD

D-3798-IS $ 30 / 1 x 1 mL D-3798-IS-PAK SAVE 33% $ 100 / 5 x 1 mL At stated conc. by weight 11 comps.

D-3798-10ML $ 65 / 1 x 10 mL D-3798-10ML-PAK SAVE 20% $ 260 / 5 x 10 mL At stated conc. by weight 10 comps.

Wt./Wt. % n-Pentane 0.15 n-Octane 0.15 Benzene 0.15 Toluene 0.15 Ethylbenzene 0.15 p-Xylene 98.65 m-Xylene 0.15

Wt./Wt. % 0.15 0.15 0.15

o-Xylene Cumene Propylbenzene

Total Analytes 100 plus n-Undecane* (ISTD) 0.500 grams

n-Pentane n-Octane Benzene Toluene Ethylbenzene

Wt./Wt. % 0.15 0.15 0.15 0.15 0.15

p-Xylene m-Xylene o-Xylene Cumene Propylbenzene

Wt./Wt. % 98.65 0.15 0.15 0.15 0.15

Bulk Packaged p-Xylene without Internal Standard Other suggested internal standards can be used in conjunction with the bulk packaged D-3789 1 x 10 mL ampule to meet your company’s application. If you prefer to eliminate making standards, contact AccuStandard’s Technical Department with your unique formulation for a custom quotation. The custom quotation request form is located in the back of this catalog.

ASTM D-3831 Manganese in Gasoline by AA Spectroscopy Manganese Stock Solution D-3831

$ 65 / 1 x 100 mL

Originally designed for D-3831-98

Manganese @ 1.0 g Mn / gal (264.2 mg Mn / L) in Methyl isobutyl ketone

20

Quality System is Certified to comply with the International ISO 9001 Quality Standard

ASTM Standards

Method

Member

4059 4291 4294 4377

Originally designed for D-4059-96

ASTM D-4059 Polychlorinated Biphenyls in Insulating Liquids by GC Aroclors in PCB-Free Transformer Oil (At 2 concentrations in Transcrest W130) Conc. (ppm w/w)

Cat. No.

1 x 1 mL Price

5 x 1 mL Price

PAK Cat. No.

Aroclor 1016 Aroclor 1016

50 500

C-216-ST-1 C-216-ST-2

$ 25 30

C-216-ST-1-PAK C-216-ST-2-PAK

$ 90 120

Aroclor 1221 Aroclor 1221

50 500

C-221-ST-1 C-221-ST-2

25 30

C-221-ST-1-PAK C-221-ST-2-PAK

90 120

Aroclor 1232 Aroclor 1232

50 500

C-232-ST-1 C-232-ST-2

25 30

C-232-ST-1-PAK C-232-ST-2-PAK

90 120

Aroclor 1242 Aroclor 1242

50 500

C-242-ST-1 C-242-ST-2

25 30

C-242-ST-1-PAK C-242-ST-2-PAK

90 120

Aroclor 1248 Aroclor 1248

50 500

C-248-ST-1 C-248-ST-2

25 30

C-248-ST-1-PAK C-248-ST-2-PAK

90 120

Aroclor 1254 Aroclor 1254

50 500

C-254-ST-1 C-254-ST-2

25 30

C-254-ST-1-PAK C-254-ST-2-PAK

90 120

Aroclor 1260 Aroclor 1260

50 500

C-260-ST-1 C-260-ST-2

25 30

C-260-ST-1-PAK C-260-ST-2-PAK

90 120

Aroclor 1262 Aroclor 1262

50 500

C-262-ST-1 C-262-ST-2

25 30

C-262-ST-1-PAK C-262-ST-2-PAK

90 120

Aroclor 1268 Aroclor 1268

50 500

C-268-ST-1 C-268-ST-2

25 30

C-268-ST-1-PAK C-268-ST-2-PAK

90 120

Additional Aroclors and PCB Congener Standards available in our Organic Catalog

Neat Individual Aroclors Z-008 Aroclor #

Cat. No.

Aroclor Aroclor Aroclor Aroclor Aroclor Aroclor Aroclor Aroclor Aroclor

C-216N C-221N C-232N C-242N C-248N C-254N C-260N C-262N C-268N

1016 1221 1232 1242 1248 1254 1260 1262 1268

Kit of above 9 Aroclors

Price / Unit $ 25 25 25 25 25 25 25 25 25

/ / / / / / / / /

100 100 10 100 10 100 100 100 10

Z-008

mg mg mg mg mg mg mg mg mg

(Kit) 100 100 10 100 10 100 10 10 10

mg mg mg mg mg mg mg mg mg

Aroclor-free transformer oil also available as: T-W130

$ 5 / 1 x 1 mL

$ 125 / 9 vials

ASTM D-4291 (Reapproved 1998) Trace Ethylene Glycol in Used Engine Oil Ethylene Glycol Stock Standard D-4291-93 D-4291-93-PAK

$ 20 / 1 x 1 mL SAVE 20% $ 80 / 5 x 1 mL

Originally designed for D-4291-93

Ethylene glycol @ 2000 µg/mL in water

ASTM D-4294 Sulfur in Petroleum Products by ED-XRF Spectroscopy See page 8-11 for AccuStandard’s comprehensive line of Certified Sulfur Calibration Standards designed for matrix specific applications as described in Method D-4294 in section 9.0 (Calibration & Standardization).

4 D-429 Meets es id u elin EPA G FG for R is Analys

ASTM D-4377 Water in Crude oils by Potentiometric Karl Fischer Titration See page 5 for AccuStandard’s comprehensive line of Certified Karl Fischer Water Standards.

Fax 203-786-5287 • Toll Free 800-442-5290 / 203-786-5290 • Website www.accustandard.com

21

ASTM

Aroclor #

Method

ASTM Standards

4420 4628

, Member

ASTM D-4420 Aromatics in Finished Gasolines by GC Originally designed for D-4420-94

Aromatics in Gasoline by GC/TC

ASTM

D-4420-CAL-SET

$ 105 / set of 7 x 1 mL

Analyte

Std. 1 Target Vol. %

Std. 2 Target Vol. %

Std. 3 Target Vol. %

Std. 4 Target Vol. %

Std. 5 Target Vol. %

Std. 6 Target Vol. %

Std. 7 Target Vol. %

Benzene Toluene Total Xylenes (C8 aromatics) n-Butylbenzene (C9 + aromatics) Isooctane

0.05 0.5 5 30.00 64.45

0.10 1.00 10.00 25.00 63.90

0.25 2.50 15.00 20.00 62.25

0.75 5.00 20.00 10.00 64.25

1.25 10.00 25.00 5.00 58.75

2.50 15.00 1.00 15.00 66.50

5.00 25.00 3.00 2.50 64.50

Aromatics in Gasoline by GC/TX

WEAR METALS

D-4420-94 D-4420-94-PAK

$ 20 / 1 x 1 mL $ 80 / 5 x 1 mL 5 comps.

Benzene Toluene Total Xylenes (C8 aromatics)

Vol. % 3.00 10.00 15.00

Vol. % 15.00 57.00

n-Butylbenzene(C9 + aromatics) Isooctane

ASTM D-4628 Barium, Calcium, Magnesium & Zinc in Unused Lubricating Oil Lubricating Oil, Elements (Nominal Value) Wt.% listed below ASTM-P-0113-SET $ 2850 / 17 x 100 mL Cat. No. ASTM-P-0113-01 ASTM-P-0113-02 ASTM-P-0113-03 ASTM-P-0113-04 ASTM-P-0113-05 ASTM-P-0113-06 ASTM-P-0113-07 ASTM-P-0113-08 ASTM-P-0113-09 ASTM-P-0113-10 ASTM-P-0113-11 ASTM-P-0113-12 ASTM-P-0113-13 ASTM-P-0113-14 ASTM-P-0113-15 ASTM-P-0113-16 ASTM-P-0113-17

Originally designed for D-4628-97

Ba (Wt.%)

Ca (Wt.%)

Mg (Wt.%)

P (Wt.%)

S (Wt.%)

Zn (Wt.%)

0.025 0.000 0.100 0.175 0.150 0.000 0.100 0.200 0.050 0.075 0.010 0.000 0.175 0.005 0.000 0.005 0.000

0.600 0.500 0.400 0.260 0.005 0.400 0.300 0.200 0.060 0.060 0.050 0.025 0.005 0.170 0.100 0.010 0.000

0.100 0.150 0.350 0.225 0.450 0.500 0.325 0.250 0.100 0.400 0.300 0.200 0.375 0.175 0.425 0.275 0.000

0.005 0.200 0.150 0.250 0.005 0.025 0.060 0.100 0.080 0.050 0.120 0.150 0.200 0.250 0.100 0.010 0.000

0.175 0.050 0.300 0.150 0.450 0.350 0.250 0.450 0.300 0.200 0.100 0.200 0.400 0.550 0.200 0.600 0.000

0.060 0.080 0.180 0.120 0.070 0.100 0.120 0.100 0.130 0.050 0.075 0.130 0.150 0.110 0.200 0.250 0.000

Standards of Interests See Table of Contents for the Wear Metals Group pages.

Ready-to-Inject Petrochemical Standards and Calibration Curves Reduce Costs Increase Time Spent for Sample Analysis Are Validated Against Independent Lots Include Internal Standards or Surrogates Follow ASTM Method Guidelines Allow Direct Transfer to Autosampler Vials

Cross Reference Table ASTM IP ISO DIN JIS AFNOR sorted by ASTM Method see beginning of Catalog

22

Quality System is Certified to comply with the International ISO 9001 Quality Standard

ASTM Standards

Method

4629

Member

ASTM D-4629

Trace Nitrogen in Liquid Petroleum Hydrocarbons by Syringe/Inlet Oxidative Combustion and Chemiluminescence Detection. IP Designation 379/88

Originally designed for D-4629-96

Technical Note

Nitrogen Calibration Set-Low Boiling Solvents D-4629-91-LB-CAL-SET

$ 75 / set of 7 x 1 mL Set includes the following Cat. No.s

Cat. No.

Description

D-4629-91-LB-0.3X D-4629-91-LB-1X D-4629-91-LB-10X D-4629-91-LB-25X D-4629-91-LB-50X D-4629-91-LB-75X D-4629-91-LB-100X

Nitrogen Nitrogen Nitrogen Nitrogen Nitrogen Nitrogen Nitrogen

@ @ @ @ @ @ @

ASTM

Method D-4629 is used to determine trace total nitrogen naturally found in liquid hydrocarbons boiling from 50 to 400°C with viscosities between 0.2 and 10 cSt. This method monitors feed stocks for nitrogen to prevent the poisoning of some process catalysts when trace nitrogenous materials are present.

Nitrogen introduced using Pyridine Price / Unit

0.3 1 10 25 50 75 100

µg/mL in µg/mL in µg/mL in µg/mL in µg/mL in µg/mL in µg/mL in

Isooctane Isooctane Isooctane Isooctane Isooctane Isooctane Isooctane

$ $ $ $ $ $ $

20 20 20 20 20 20 20

/ / / / / / /

1 1 1 1 1 1 1

x x x x x x x

1 1 1 1 1 1 1

mL mL mL mL mL mL mL

Stock Nitrogen Solution for Low Boiling Solvents D-4629-91-LB-CON D-4629-91-LB-CON-PAK

$ 20 / 1 x 1 mL $ 80 / 5 x 1 mL

Nitrogen @ 1000 µg/mL in Isooctane (Pyridine @ 5.65 mg/mL in Isooctane)

Technical Note

Nitrogen Calibration Set-High Boiling Solvents D-4629-91-HB-CAL-SET

$ 75 / set of 7 x 1 mL Set includes the following Cat. No.s

Cat. No.

Description

D-4629-91-HB-0.3X D-4629-91-HB-1X D-4629-91-HB-10X D-4629-91-HB-25X D-4629-91-HB-50X D-4629-91-HB-75X D-4629-91-HB-100X

Nitrogen Nitrogen Nitrogen Nitrogen Nitrogen Nitrogen Nitrogen

@ @ @ @ @ @ @

Nitrogen introduced using Carbazole Price / Unit

0.3 1 10 25 50 75 100

µg/mL in Toluene µg/mL in Toluene µg/mL in Toluene µg/mL in Toluene µg/mL in Toluene µg/mL in Toluene µg/mL in Toluene

$ $ $ $ $ $ $

20 20 20 20 20 20 20

/ / / / / / /

1 1 1 1 1 1 1

x x x x x x x

1 1 1 1 1 1 1

mL mL mL mL mL mL mL

Stock Nitrogen Solution for High Boiling Solvents D-4629-91-HB-CON D-4629-91-HB-CON-PAK

$ 20 / 1 x 1 mL SAVE 20% $ 80 / 5 x 1 mL

Nitrogen @ 1000 µg/mL in Toluene : Acetone (9:1) (Carbazole @ 11.95 mg/mL in Toluene : Acetone (9:1) )

Low level Nitrogen Calibration Set ASTM-P-0070-SET Set includes the following Cat. No.s

Technical Note

$ 75 / 6 x 1 mL

Cat. No.

Description

ASTM-P-0070-BL ASTM-P-0070-1X ASTM-P-0070-2X ASTM-P-0070-4X ASTM-P-0070-10X ASTM-P-0070-20X

Isooctane Blank Nitrogen @ 0.5 Nitrogen @ 1.0 Nitrogen @ 2.0 Nitrogen @ 5.0 Nitrogen @ 10.0

Unit µg/g µg/g µg/g µg/g µg/g

Low level Nitrogen & Sulfur Calibration Set ASTM-P-0071-SET

Nitrogen introduced using Aniline

in in in in in

1 1 1 1 1 1

Isooctane Isooctane Isooctane Isooctane Isooctane

x x x x x x

1 1 1 1 1 1

mL mL mL mL mL mL

Technical Note

$ 50 / 4 x 1 mL Set includes the following Cat. No.s

The Nitrogen is introduced using Aniline and the Sulfur is introduced using di-n-Butyl sulfide

Cat. No.

Description

ASTM-P-0071-BL ASTM-P-0071-01 ASTM-P-0071-02 ASTM-P-0071-03

Benzene Blank Nitrogen @ 0.25 µg/g & Sulfur @ 0.25 µg/g in Benzene Nitrogen @ 0.50 µg/g & Sulfur @ 0.50 µg/g in Benzene Nitrogen @ 1.00 µg/g & Sulfur @ 1.00 µg/g in Benzene

Unit 1 1 1 1

x x x x

1 1 1 1

mL mL mL mL

Fax 203-786-5287 • Toll Free 800-442-5290 / 203-786-5290 • Website www.accustandard.com

23

Method

ASTM Standards

4815

, Member

ASTM D-4815

Originally designed for D-4815-99

MtBE, EtBE, TAME, DIPE, Tertiary-amyl Alcohol and C1 to C4 Alcohols in Gasoline by GC

ASTM

Oxygenate Quantitative Calibration Mixtures (without Internal Standard) D-4815-SET-10ML

$ 300 / set of 5 x 10 mL of 5 component mix Std. 1 Wt. %

Analyte Ethanol t-Butanol Methyl t-butyl ether (MtBE) t-Pentanol Isooctane/xylene (65:35)

Std. 2 Wt. %

3.00 0.10 20.0 1.25 75.65

Std. 3 Wt. %

0.10 3.00 15.00 5.00 76.90

6.00 6.00 10.00 2.50 75.50

Std. 4 Wt. % 9.00 8.00 5.00 3.75 74.25

Std. 5 Wt. % 12.00 12.00 0.10 0.10 75.80

Oxygenate Quantitative Calibration Mixtures (with Internal Standard) D-4815/IS-SET of 6 component mix D-4815/IS-SET-PAK

Analyte

$ 125 / set of 5 x 1 mL $ 500 / set of 5 x (5 x 1 mL)

Calibration Range

Std. 1 Wt. %

Std. 2 Wt. %

Std. 3 Wt. %

Std. 4 Wt. %

Std. 5 Wt. %

Ethanol 0.1 - 11.40 t-Butanol 0.1 - 11.40 Methyl t-butyl ether (MtBE) 0.1 - 19.0 t-Pentanol 0.1 - 4.79 1,2-Dimethoxyethane (DME) (Internal Std.) Isooctane/xylene (65:35)

2.85 0.10 19.00 1.19 5.00 71.87

0.10 2.85 14.25 4.75 5.00 73.06

5.70 5.70 9.50 2.38 5.00 71.73

8.55 7.60 4.75 3.56 5.00 70.54

11.40 11.40 0.10 0.10 5.00 72.0

Total Oxgenates & Internal Standard

28.14

26.95

28.28

29.46

28.00

Quantitative Peak ID and Retention Time Mixture D-4815-RT D-4815-RT-PAK

$ 25 / 1 x 1 mL SAVE 20% $ 100 / 5 x 1 mL

Compound Wt. % Methylcyclopentane 4.00 Methanol 7.30 Ethanol 7.30 Isopropanol 7.30 tert-Butanol 7.30 n-Propanol 7.30 Methyl tert-butyl ether (MtBE) 4.00 sec-Butanol 7.30 Diisopropyl ether (DIPE) 4.00 Isobutanol 7.30 Ethyl tert-butyl ether (EtBE) 4.00 tert-Pentanol 7.30 1,2-Dimethoxyethane (ISTD) 6.00 n-Butanol 7.30 Benzene 5.00 tert-Amyl methyl ether 7.30 100 16 comp. core mix

5 D-481 Meets es uidelin EPA G FG for R is Analys

Technical Note Additional Oxygenate calibration, check standards, and independent reference standards can be found in ASTM method D-5599 (pages 34-36) or D-5622-94 (page 37) The required QA/QC procedures in EPA methods stipulate a calibration check standard be used once per analytical batch or per 10 sample set. AccuStandard has bulk packaged our check standards to meet this increased usage.

Valve Timing Mixture D-4815-VT D-4815-VT-PAK

$ 25 / 1 x 1 mL SAVE 20% $ 100 / 5 x 1 mL 5 comps. Compound Wt. % Methylcyclopentane 10.00 Diisopropyl ether (DIPE) 10.00 Ethyl tert-butyl ether (EtBE) 10.00 Methyl tert-butyl ether (MtBE) 10.00 n-Hexane 60.00

Oxygenate Internal Standard Mixture M-GRO-IS-5ML M-GRO-IS-5ML-PAK

$ 10 / 1 x 1 mL SAVE 20% $ 40 / 5 x 1 mL

1,2-Dimethoxyethane (ISTD) (neat)

Test to

Low ppb Oxygenate Free Refinery Gasoline Blank M-GRO-BLNK-10ML $ 10 / 1 x 10 mL M-GRO-BLNK-10ML-PAKSAVE 20% $ 40 / 5 x 10 mL

Sulfur See Pages 6-11

RFA Gasoline (neat)

Custom Formulations AccuStandard offers over 30,000 different standards, and if you can't find the specific standard you need, we will prepare a custom formulation. Our custom organic and inorganic standards are a fast, economical way to address your unique requirements. To make an inquiry for Custom Quotes visit our website. You can also Email your requirements to [email protected] or Fax us at 203-786-5287. Please include the following information: List of analytes and concentrations, Solvent or matrix, Quantity required (milliliters), Packaging unit size (milliliters per ampule, bottle, or vial). Quality Control Options 1. Gravimetric/Volumetric Certification: Each standard is measured gravimetrically and then QC’ed instrumentally (where available). Every component in the standard is guaranteed to be within ±0.5% of the requested value unless otherwise stated. The solutions are made up to volume using class A glassware. A certificate comes with each standard and documents the gravimetric values used. 2. Quantitative Validation: Full QA/QC method includes extended GC analysis using both internal and calibration standards plus statistical analysis. A data package is provided containing analytical and gravimetric data (Organic customs only). Also available: OEM Standards - Privately labeled standards manufactured and tested to your specifications.

24

Quality System is Certified to comply with the International ISO 9001 Quality Standard

ASTM Standards

Method

4927 4928 4929

Member

ASTM D-4927

Elemental Analysis of Lubricant and Additive Components Barium, Calcium,Phosphorus, Sulfur, and Zinc by WD-XRF Spectroscopy

Cat. No.

Ca (Wt.%)

P (Wt.%)

S (Wt.%)

Zn (Wt.%)

0.100 0.175 0.000 0.025 0.150 0.000 0.200 0.000 0.100 0.050 0.075 0.010 0.005 0.000 0.000 0.005 0.000

0.600 0.500 0.400 0.260 0.005 0.400 0.300 0.200 0.060 0.060 0.050 0.025 0.005 0.170 0.100 0.010 0.000

0.005 0.200 0.150 0.250 0.005 0.025 0.060 0.100 0.080 0.050 0.120 0.150 0.200 0.250 0.100 0.010 0.000

0.175 0.050 0.300 0.150 0.450 0.350 0.250 0.450 0.300 0.200 0.100 0.200 0.400 0.550 0.200 0.600 0.000

0.060 0.080 0.180 0.120 0.070 0.100 0.120 0.100 0.130 0.050 0.075 0.130 0.150 0.110 0.200 0.250 0.000

Standards of Interests See Table of Contents for the Wear Metals Group pages

WEAR METALS

ASTM-P-0110-01 ASTM-P-0110-02 ASTM-P-0110-03 ASTM-P-0110-04 ASTM-P-0110-05 ASTM-P-0110-06 ASTM-P-0110-07 ASTM-P-0110-08 ASTM-P-0110-09 ASTM-P-0110-10 ASTM-P-0110-11 ASTM-P-0110-12 ASTM-P-0110-13 ASTM-P-0110-14 ASTM-P-0110-15 ASTM-P-0110-16 ASTM-P-0110-17

Ba (Wt.%)

Originally designed for D-4927-96

ASTM D-4928 Water in Crude Oils by Potentiometric Karl Fischer Titration See page 5 for AccuStandard’s new line of Karl Fischer Water Standards.

ASTM D-4929

Organic Chloride Content in Crude Oil - Test Method B Combustion and Microcoulometry

Originally designed for D-4929-99

Standards of Interests

Working Level Chlorine Standard

Stock Chlorine Standard

D-4929-94 D-4929-94-PAK

D-4929-94-100X $ 15 / 1 x 5 mL D-4929-94-100X-PAK SAVE 20% $ 60 / 5 x 5 mL

$ 10 / 1 x 5 mL SAVE 20% $ 40 / 5 x 5 mL

Chlorine @ 10 µg/mL in Isooctane

ASTM

Lubricating Oil, Elements (Nominal Value) Wt.% listed below ASTM-P-0110-SET $ 2300 / 17 x 100 mL

See page 66 for additional proposed and promulgated Chlorine in Lube Oil standards

Chlorine @ 1000 µg/mL in Isooctane

Custom Ampulling for Bulk Quantity Requirements Automated ampule filling & sealing 0.2 mL up to 20 mL Quantities from 500 to over 500,000 ampules Homogeneity testing Amber ampules for added product stability Private labeling and packaging

We can reduce your costs using the Cozzoli Auto Filling/ Sealing Machine to package just the right size product for your application.

Fax 203-786-5287 • Toll Free 800-442-5290 / 203-786-5290 • Website www.accustandard.com

25

Method

ASTM Standards

4951 5056

, Member

ASTM

ASTM D-4951

20 Wear Metal Multi-Element Standard containing no metallic sulfonates Conc. (µg/g)

Cat. No.

Price

10 30 50 100 300 500 900

WM-20-NMS-1X-1 WM-20-NMS-3X-1 WM-20-NMS-5X-1 WM-20-NMS-10X-1 WM-20-NMS-30X-1 WM-20-NMS-50X-1 WM-20-NMS-90X-1

$ 150 150 150 170 230 350 500

Standards of Interests Each Wear Metal Standard contains the below list of 20 elements in hydrocarbon oil at the stated concentration Al (Aluminum) B (Boron) Ba (Barium) Ca (Calcium) Cd (Cadmium) Cr (Chromium) Cu (Copper) Fe (Iron) Mg (Magnesium) Mn (Manganese)

WM-20-NMS-SET-1 $ 1450 set of above 7 x 100 mL

WEAR METALS

Originally designed for D-4951-96

Additive Elements in Lubricating Oils by Inductively Coupled Plasma Atomic Emission Spectrometry

Mo (Molybdenum) Na (Sodium) Ni (Nickel) P (Phosphorus) Pb (Lead) Si (Silicon) Sn (Tin) Ti (Titanium) V (Vanadium) Zn (Zinc)

Technical Notes This calibration curve has been formulated with starting materials containing no metal sulfonates. This way a sulfur calibration curve can easily be developed using a high concentration sulfur standard.

Recommended Internal Standard (IS) Element

Sulfur free Organometallic (IS) @ 1000 µg/g Price Cat. No. 50 mL

Sulfur free Organometallic (IS) @ 5000 µg/g Price Cat. No. 50 mL

Cobalt

WM-NMS-14

WM-NMS-14-5X

$ 75

$ 110

Originally designed for D-5056-96

ASTM D-5056 Trace Metals in Petroleum Coke by Atomic Absorption Element @ 1000 µg/mL Matrix

See Table of Contents for the Wear Metals Group pages.

Element @ 1000 µg/mL Matrix

Cat. No.

Price

100 mL

AA52W-1

$ 13

500 mL

AA52W-5

33

100 mL

AA54N-1

13

HNO3

500 mL

AA54N-5

33

12

Vanadium

100 mL

AA67N-1

13

30

HNO3

500 mL

AA67N-5

33

Unit

Cat. No.

Price

* Aluminum

100 mL

AA01N-1

$ 13

Silicon

HNO3

500 mL

AA01N-5

33

H2O tr. NaOH

* Calcium

100 mL

AA09N-1

12

* Sodium

HNO3

500 mL

AA09N-5

30

* Iron

100 mL

AA27N-1

HNO3

500 mL

AA27N-5

Nickel

100 mL

AA37N-1

12

HNO3

500 mL

AA37N-5

30

Unit

* For your convenience these elements are available in HCl. To order, change the N to H at the end of the catalog numbers.

Cross Reference Table ASTM IP ISO DIN JIS AFNOR sorted by ASTM Method see beginning of Catalog

26

Quality System is Certified to comply with the International ISO 9001 Quality Standard

ASTM Standards

Method

5059 5134

Member

Originally designed for D-5059-98

ASTM D-5059 Lead in Gasoline by X-Ray Spectroscopy IP Designation 228/79 Technical Notes

Part A - Lead in Gasoline Standards

Internal Standard

D-5059-A-CAL-SET $ 450 / set of 7 x 4 oz The Set contains the following 7 solutions in isooctane

D-5059-IS-4 $ 80 / 1 x 4 oz bottle D-5059-IS-10ML-PAK $ 60 / 5 x 10 mL amps

Cat. No.

Lead Concentration g Pb/US gal g Pb/ UK gal

mg Pb/mL

Bismuth @ 0.793 mg/mL (3.00 g/US gal) (3.60 g/UK gal) in Mineral oil

D-5059-A-01 D-5059-A-02 D-5059-A-03 D-5059-A-04 D-5059-A-05 D-5059-A-06 D-5059-A-07

0.0000 0.1000 1.0000 2.0000 3.0000 4.0000 5.0000

0.000 0.026 0.264 0.528 0.793 1.057 1.321

0.000 0.120 1.200 2.400 3.600 4.800 6.000

Price / Unit $ 10 80 80 80 80 80 80

/ / / / / / /

4 4 4 4 4 4 4

oz oz oz oz oz oz oz

9 D-505 Meets es uidelin EPA G FG for R is Analys

ASTM

AccuStandard has formulated the following standards to measure the lead content in gasoline for both high and low concentrations using bismuth as an internal standard. For long term stability and ease of use AccuStandard provides the internal standard in two convenient packaging sizes. The bulk 4 oz. bottles are designed for laboratories analyzing many samples while the 10 mL ampules are for laboratories that have limited requests for the test method. Should you require bulk quantities of the internal standard conveniently packaged in single-use ampules, contact AccuStandard’s technical department for a quotation. Bulk volumes of 250 mL or more can be sealed into ampules (your choice up to 20 mL size). Use of our ampulling services can provide substantial saving for the Laboratory.

Technical Notes All D-5059 Certificates have the concentrations for the Standard listed in three convenient Lead Concentration units.

Part C - Lead in Gasoline Standards D-5059-C-CAL-SET $ 450 / set of 7 x 4 oz The Set contains the following 7 solutions in isooctane Cat. No. D-5059-C-01 D-5059-C-02 D-5059-C-03 D-5059-C-04 D-5059-C-05 D-5059-C-06 D-5059-C-07

Lead Concentration g Pb/US gal g Pb/ UK gal

µg Pb/mL

0.0000 0.0010 0.0050 0.0100 0.0500 0.1000 0.3000

0.000 0.264 1.321 2.642 13.209 26.417 79.252

0.000 0.001 0.006 0.012 0.060 0.120 0.360

Price / Unit $ 10 80 80 80 80 80 80

/ / / / / / /

4 4 4 4 4 4 4

oz oz oz oz oz oz oz

ASTM D-5134 Petroleum Naphthas through n-Nonane by Capillary GC Originally designed for D-5134-98

Qualitative Reference Petroleum Set D-5134-92-SET

$ 75 / 3 x 1 mL

Cat. No.

Description

Unit

D-5134-92-ALK

Qualitative Reference Alkylate Standard neat fraction approx. 30 components identified

1 x 1 mL

$ 30

D-5134-92-NAP

Qualitative Reference Naphtha Standard neat fraction approx. 70 components identified

1 x 1 mL

30

D-5134-92-REF

Qualitative Reference Reformate Standard neat fraction approx. 100 components identified

1 x 1 mL

30

Column Evaluation Mix

Linearity Check Mix

D-5134-92-CEM

D-5134-92-LCM 10% w/w each component

Wt. / Wt. % Toluene 0.5 n-Heptane 1.0 2,3,3-Trimethylpentane 1.0 2-Methylheptane 1.0

$ 35 / 1 x 1 mL 7 comps. Wt. / Wt. % 4-Methylheptane 1.0 n-Octane 1.0 2-Methylpentane 94.5

Benzene 2,4-Dimethylheptane 2,4-Dimethylhexane n-Heptane n-Hexane

Price

Standards of Interests See page 14 for additional Detailed Hydrocarbon Analysis (DHA) blends.

$ / 1 x 1 mL 10 comps. 2-Methylheptane 2-Methylhexane n-Nonane n-Octane Toluene

Fax 203-786-5287 • Toll Free 800-442-5290 / 203-786-5290 • Website www.accustandard.com

27

Method

ASTM Standards

5184 5185 5186

, Member

ASTM D-5184

ASTM

(Reapproved 1995)

Aluminum and Silicon in Fuel Oils by Ashing, Fusion, ICP-AES Spectrometry & AA Spectrometry Aluminum Standard Solution

Tartaric Acid / Hydrochloric Acid Solution D-5184-91-TA-5

D-5184-91-AL-1 D-5184-91-AL-5

$ 20 / 1 x 500 mL

Silicon Standard Solution $ 34 / 1 x 100 mL $ 67 / 1 x 500 mL

WEAR METALS

Silicon @ 1000 µg/mL in trace NaOH

ASTM D-5185

Technical Note Contact the our Technical department for Ready-toAspirate working level calibration curves designed for your laboratories' specific calibration ranges.

Additive Elements, Wear Metals, & Contaminants in Used Lubricating Oils by ICP-AES

21 Wear Metal Multi-Element Standard Containing No Metallic Sulfonates Conc. (µg/g) 10 30 50 100 300 500

$ 34 / 1 x 100 mL $ 67 / 1 x 500 mL

Al @ 1000 µg/mL in 5 % HCl

Tartaric acid @ 0.5% w/v in 4% HCl

D-5184-91-SI-1 D-5184-91-SI-5

Originally designed for D-5184-91

Cat. No.

Price

WM-21-NMS-1X-1 WM-21-NMS-3X-1 WM-21-NMS-5X-1 WM-21-NMS-10X-1 WM-21-NMS-30X-1 WM-21-NMS-50X-1

Each Wear Metal Standard contains the below list of 21 elements in hydrocarbon oil at the stated concentration Ag (Silver) Al (Aluminum) B (Boron) Ba (Barium) Ca (Calcium) Cd (Cadmium) Cr (Chromium) Cu (Copper) Fe (Iron) Mg (Magnesium) Mn (Manganese)

$ 160 160 160 180 240 350

WM-21-NMS-SET-1 $ 1050 set of above 6 x 100 mL

Mo (Molybdenum) Na (Sodium) Ni (Nickel) P (Phosphorus) Pb (Lead) Si (Silicon) Sn (Tin) Ti (Titanium) V (Vanadium) Zn (Zinc)

Recommended Internal Standard (IS) Element

Sulfur free Organometallic (IS) @ 1000 µg/g Price Cat. No. 50 mL

Sulfur free Organometallic (IS) @ 5000 µg/g Price Cat. No. 50 mL

Cobalt

WM-NMS-14

WM-NMS-14-5X

ASTM D-5186

$ 75

$ 110

Aromatic Content & Polynuclear Aromatic Content of Diesel Fuels & Aviation Turbine Fuels by SFC

Performance Solution

Detector Linearity Check Solution Set

D-5186-96-PM D-5186-96-PM-PAK

D-5186-96-DLC-SET

$ 25 / 1 x 1 mL SAVE 20% $ 100 / 5 x 1 mL 4 comps. Wt. / Wt. % Wt. / Wt. % n-Hexadecane 75 Tetralin 3.0 Naphthalene 2.0 Toluene 20

Originally designed for D-5185-97

Standards of Interests See Table of Contents for the Wear Metals Group pages

Technical Notes This calibration curve has been formulated with starting materials containing no metal sulfonates. So a sulfur calibration curve can easily be developed using a high concentration sulfur standard.

Originally designed for D-5186-99

$ 30 / 2 x 1 mL Set includes the below two Cat. No.'s

D-5186-96-DLC-25X 25% w/w #2 Diesel Fuel in n-Hexadecane D-5186-96-DLC-50X 50% w/w #2 Diesel Fuel in n-Hexadecane

ISO 9001:2000 Certificate Number: 31692

28

Quality System is Certified to comply with the International ISO 9001 Quality Standard

ASTM Standards

Method

Member

5188 5191 & 5482 5307

ASTM D-5188 Vapor - Liquid Ratio Temperature Standards Performance Check Samples for daily monitoring of instrument performance V/L Temp

ASTM-P-125-01-VAP ASTM-P-125-02-VAP

36.1˚C (96.9˚F) 68.0˚C (155.7˚F)

Price / Set $ 45 / 5 x 20 mL 45 / 5 x 20 mL

Originally designed for D-5188-99

Originally designed for D-5191-99 & D-5482-99

ASTM D-5191 & D-5482 Vapor Pressure Standards Vapor Pressure Quality Control Samples Cat. No.

Vapor Pressure

ASTM-P-124-01-VAP ASTM-P-124-02-VAP ASTM-P-124-03-VAP ASTM-P-124-04-VAP ASTM-P-124-05-VAP ASTM-P-124-06-VAP

68.3kPa (9.91 psi) 68.0kPa (9.86 psi) 51.1kPa (7.41 psi) 46.7kPa (6.77 psi) 22.5kPa (3.26 psi) 7.1kPa (1.03 psi)

Technical Note Price / Set $ 65 75 70 115 50 50

/ / / / / /

10 10 10 10 10 10

x x x x x x

10 10 10 10 10 10

mL mL mL mL mL mL

ASTM

Cat. No.

Value Added Paks (Cat. No.’s ending in -VAP) provide multiple single units packaged together for both greater stability and cost savings.

Consists of pure solvents with known vapor pressure

ASTM D-5307-97 Boiling Range Distribution of Crude Petroleum by GC Quantitative Paraffins Standard

Qualitative Paraffins Standard

D-5307-QUANT D-5307-QUANT-PAK Equal Wt. %

D-5307-QUAL $ 40 / 1 x 1 mL D-5307-QUAL-PAK SAVE 20% $ 160 / 5 x 1 mL At stated approx. Wt. % 7 comps.

n-Decane n-Undecane n-Dodecane n-Tridecane n-Tetradecane n-Pentadecane n-Hexadecane n-Heptadecane

$ 60 / 1 x 2 mL SAVE 20% $ 240 / 5 x 2 mL 16 comps. n-Octadecane n-Eicosane n-Tetracosane n-Octacosane n-Dotriacontane n-Hexatriacontane n-Tetracontane n-Tetratetracontane

Propane Butane n-Pentane n-Hexane

Wt./Wt. % 10 15 15 15

n-Heptane n-Octane n-Nonane

Wt./Wt. % 15 15 15

Column Resolution Mixture

Internal Standard

D-5307-CR D-5307-CR-PAK At stated approx. Wt. %

D-5307-IS-10ML $ 30 / 1 x 10 mL D-5307-IS-10ML-PAK SAVE 20% $ 120 / 5 x 10 mL 4 comps.

Wt./Wt. % n-Hexadecane 1.0 n-Octadecane 1.0

$ 15 / 1 x 1 mL SAVE 20% $ 60 / 5 x 1 mL 3 comps.

n-Octane

Wt./Wt. % 98.0

Wt./Wt. % n-Tetradecane 25 n-Pentadecane 25

Member

Wt./Wt. % n-Hexadecane 25 n-Heptadecane 25

AccuStandard is an active member in ASTM and strives to keep abreast of ASTM method revisions. If our listed formulation does not meet the most recent method revision, please contact Technical Support, ext. 117 for an updated product.

Fax 203-786-5287 • Toll Free 800-442-5290 / 203-786-5290 • Website www.accustandard.com

29

Method

ASTM Standards

5441

Member

Originally designed for D-5441-98

ASTM

ASTM D-5441 Analysis of Methyl tert-butyl ether (MtBE) by GC The ASTM Committee D-02 on Petroleum Products and Lubricants has issued the Standard Method D-5441-98 for the determination of the purity of methyl tert-butyl ether (MtBE) by Gas Chromatography. This method provides a procedure to measure impurities in MtBE such as C4 to C12 olefins, methyl, isopropyl and tert-butyl alcohols, methyl sec-butyl & methyl tert-amyl ethers, acetone, and methyl ethyl ketones. The presence of these impurities in MtBE can have a direct effect upon the value of the MtBE as a gasoline additive. AccuStandard has formulated the following reference standards to meet the method specifications. Different packaging sizes are available to meet various sample testing capacities .

MtBE Contaminant Standard Low Concentration

MtBE Contaminant Standard High Concentration

D-5441 D-5441-PAK

D-5441-10X D-5441-10X-PAK

$ 30 / 1 x 1 mL SAVE 20% $ 120 / 5 x 1 mL

D-5441-5ML $ 100 / 1 x 5 mL D-5441-5ML-PAK SAVE 20% $ 400 / 5 x 5 mL Each comp. at 0.1% Wt./Wt. in MtBE 12 comps. tert-Amyl methyl ether tert-Butanol tert-Butyl ethyl ether 4,4-Dimethyl-2-neopentyl-1-pentene Methanol 2-Methylbutane 2-Methyl-2-butene 2,2',4,6,6'-Pentamethyl-3-heptene Pentane cis-2-Pentene trans-2-Pentene 2,4,4-Trimethyl-1-pentene

Qualitative Standard D-5441-QUAL 0.1% Wt./Wt. in n-Dodecane Methanol Isobutylene n-Butane trans-2-butene cis-2-butene 3-Methyl-1-butene Acetone Isopentane 2-Propanol 1-Pentene 2-Methyl-1-butene n-Pentane trans-2-Pentene t-Butanol cis-2-Pentene 2-Methyl-2-butene Cyclopentene

$ 30 / 1 x 1 mL SAVE 20% $ 120 / 5 x 1 mL

D-5441-10X-5ML $ 100 / 1 x 5 mL D-5441-10X-5ML-PAK SAVE 20% $ 400 / 5 x 5 mL Each comp.at 1% Wt./Wt. in MtBE 12 comps. tert-Amyl methyl ether tert-Butanol tert-Butyl ethyl ether 4,4-Dimethyl-2-neopentyl-1-pentene Methanol 2-Methylbutane 2-Methyl-2-butene 2,2',4,6,6'-Pentamethyl-3-heptene Pentane cis-2-Pentene trans-2-Pentene 2,4,4-Trimethyl-1-pentene

Quantitative Standard $ 145 / 1 x 1 mL 33 comps.

MtBE 2,3-Dimethyl-1-butene 4-Methyl-cis-2-pentene 2-Methylpentane Methylethyl ketone 3-Methylpentane sec-Butyl methyl ether ETBE TAME 3,5-Dimethyl-1-hexene 2,4,4-Trimethyl-1-pentene 2,4,4-Trimethyl-2-pentene 3,4,4-Trimethyl-trans-2-pentene 2,3,4-Trimethyl-2-pentene 4,4-Dimethyl-2-neopentyl-1-pentene 2,2’,4,6,6’-Pentamethyl-3-heptene

D-5441-QUANT 0.1% Wt./Wt. in n-Dodecane

$ 130 / 1 x 1 mL 29 comps.

For our complete line of Organic Standards and Inorganic Standards, request a copy of the Catalog(s).

Methanol 2-Methylpentane 3-Methyl-1-butene Methyl ethyl ketone Acetone 3-Methylpentane Isopentane sec-Butyl methyl ether 2-Propanol Ethyl tert-butyl ether 1-Pentene TAME 2-Methyl-1-butene 3,5-Dimethyl-1-hexene n-Pentane 2,4,4-Trimethyl-1-pentene trans-2-Pentene 2,4,4-Trimethyl-2-pentene t-Butanol 3,4,4-Trimethyl-trans-2-pentene cis-2-Pentene 2,3,4-Trimethyl-2-pentene 2-Methyl-2-butene 4,4-Dimethyl-2-neopentyl-1-pentene Cyclopentene 2,2’,4,6,6’-Pentamethyl-3-heptene MtBE 2,3-Dimethyl-1-butene 4-Methyl-cis-2-pentene

MtBE Resolution Test Mixture D-5441-RES D-5441-RES-PAK

$ 20 / 1 x 1 mL SAVE 20% $ 80 / 5 x 1 mL

D-5441-RES-5ML $ 60 / 1 x 5 mL D-5441-RES-5ML-PAK SAVE 20% $ 240 / 5 x 5 mL Each comp. at 1% Wt./Wt. in MtBE 3 comps. trans-2-Pentene tert-Butanol

30

cis-Pentene

Quality System is Certified to comply with the International ISO 9001 Quality Standard

ASTM Standards

Method

5442 5443 5453

Member

Originally designed for D-5442-93

ASTM D-5442 (Reapproved 1998) Analysis of Petroleum Waxes by GC

Wt./Wt. % n-Dodecane 0.02 n-Tetradecane 0.03 n-Hexadecane 0.04 n-Octadecane 0.05 n-Eicosane 0.06 n-Docosane 0.08

$ 95 / 5 x 1 mL 16 comps.

Wt./Wt. % n-Tetracosane 0.10 n-Hexacosane 0.12 n-Octacosane 0.12 n-Triacontane 0.10 n-Dotriacontane 0.08

Retention Time Standard Mix 1 D-5442-RT1 Equal parts by weight n-Hexadecane (c16) n-Octadecane (c18) n-Eicosane (c20) n-Docosane(c22) n-Tetracosane (c24) n-Hexacosane (c26)

Wt./Wt. % n-Hexatriacontane 0.06 n-Tetracontane 0.05 n-Tetratetracontane 0.04 n-Pentacontane 0.03 n-Hexacontane 0.02

NEW

n-Eicosane n-Tetracontane

Wt./Wt. % 0.05 0.05

$ 55 / 500 mg 16 comps.

n-Dodecane (c12) n-Tetradecane (c14) n-Hexadecane (c16) n-Octadecane (c18) n-Eicosane (c20) n-Docosane (c22) n-Tetracosane (c24) n-Hexacosane (c26)

n-Octacosane (c28) n-Triacontane (c30) n-Dotriacontane (c32) n-Hexatriacontane (c36) n-Tetracontane (c40) n-Tetratetracontane (c44)

See ASTM Methods D-3710, D-5307, D-6352 for additional calibration standards for hydrocarbon analysis or page 15 for new proposed methods.

NEW Retention Time Standard Mix 2 D-5442-RT2 Equal parts by weight

$ 50 / 500 mg 12 comps.

ASTM D-5443

D-5442-CR-PAK $ 40 / 5 x 1 mL At stated Wt. % in Cyclohexane 2 comps.

n-Octacosane (c28) n-Triacontane (c30) n-Dotriacontane (c32) n-Hexatriacontane (c36) n-Tetracontane (c40) n-Tetratetracontane (c44) n-Pentacontane (c50) n-Hexacontane (c60)

Paraffin, Naphthene, and Aromatic Hydrocarbon Type Analysis in

Originally designed for D-5443-93

(Reapproved 1998) Petroleum Distillates through 200°C by Multi-dimensional GC Hydrocarbon Test Mixture D-5443-93-HTM At stated Wt. %

Wt./Wt. % 1cis,2-Dimethylcyclohexane 5.00 Isooctane 5.00 n-Octane 5.00 1cis,2 cis,4-Trimethylcyclohexane 4.25 n-Nonane 4.50 n-Decane 4.25 n-Undecane 3.50 n-Dodecane 3.25 Benzene 2.25 Toluene 2.25

Wt./Wt. % Cyclopentane 1.00 n-Pentane 1.00 Cyclohexane 2.00 2,3-Dimethylbutane 2.00 n-Hexane 2.00 n-Hexene 1.50 Methylcyclohexane 4.25 4-Methyl-1-hexene 1.50 n-Heptane 3.50

ASTM D-5453

$ 100 / 1 x 1 mL 28 comps.

Wt./Wt. % trans-Decahydronaphthelene 4.25 n-Tetradecane 4.50 Ethylbenzene 4.50 o-Xylene 4.25 n-Propylbenzene 5.00 1,2,4-Trimethylbenzene 4.50 1,2,3-Trimethylbenzene 5.00 1,2,4,5-Tetramethylbenzene 5.00 Pentamethylbenzene 5.00

Originally designed for D-5453-00

Total Sulfur in Light Hydrocarbons, Motor Fuels and Oils by Ultraviolet Fluorescence

Standards of Interests See pages 6-11 for a comprehensive line of Certified Sulfur Calibration Standards, Petrocheck, & Petrotest quality control products, pages 1-2.

3 D-545 Meets es uidelin EPA G FG for R is Analys

Low Level Sulfur Set D-5453-LL-SET $ 90 / 5 x 2 mL The set contains the following 5 standards in Isooctane Cat. No.

Description

D-5453-LL-BL D-5453-LL-01 D-5453-LL-02 D-5453-LL-03 D-5453-LL-04

Sulfur Sulfur Sulfur Sulfur Sulfur

Blank @ 0.5 @ 2.5 @ 5.0 @ 10.0

Unit ng/µL ng/µL ng/µL ng/µL

2 2 2 2 2

mL mL mL mL mL

Technical Note

Real World Sulfur in Various Gasoline & Fuels QC Samples SBPT-LSGAS $ 25 / 2 x 15 mL Parameter Method Approx .Range Sulfur

D-5453-00

0 - 50 µg/g

Mid Level Sulfur Set

High Level Sulfur Set

D-5453-ML-SET $ 90 / 6 x 2 mL The set contains the following 5 standards in Isooctane

D-5453-HL-SET $ 90 / 5 x 2 mL The set contains the following 5 standards in Isooctane

Cat. No.

Description

D-5453-ML-BL D-5453-ML-01 D-5453-ML-02 D-5453-ML-03 D-5453-ML-04 D-5453-ML-05

Sulfur Sulfur Sulfur Sulfur Sulfur Sulfur

Blank @ 5.0 @ 25 @ 50 @ 100 @ 200

Unit ng/µL ng/µL ng/µL ng/µL ng/µL

2 2 2 2 2 2

mL mL mL mL mL mL

Cat. No.

Description

Unit

D-5453-HL-BL D-5453-HL-01 D-5453-HL-02 D-5453-HL-03 D-5453-HL-04

Sulfur Sulfur Sulfur Sulfur Sulfur

ng/µL ng/µL ng/µL ng/µL

Blank @ 100 @ 250 @ 500 @ 1000

2 2 2 2 2

mL mL mL mL mL

Due to the wide variety of recommended solvents and starting materials mentioned in the preparation of the sulfur standards, please review the current product offering listed for certified sulfur standards. Should AccuStandard’s current sulfur standard line be missing the necessary standards for your application, please use our custom quotation request form to indicate your required formulation. For ppb Sulfur measurements, see page 6-11.

Fax 203-786-5287 • Toll Free 800-442-5290 / 203-786-5290 • Website www.accustandard.com

31

ASTM

D-5442-PAK At stated Wt. % in Cyclohexane

Standards of Interests

Column Resolution Standard

Quantitative Wax Standard

Method

ASTM Standards

5480 5482 5501 5580

Member

Originally designed for D-5480-95

ASTM

ASTM D-5480 Engine Oil Volatility by GC Stock Column Resolution Standard

Internal Standard Solution

D-5480-CR-PAK Each comp. at 10 µg/mL in CS2

$ 40 / 5 x 1 mL 5 comps.

D-5480-CR-100X-PAK Each comp. at 1000 µg/mL in CS2

$ 50 / 5 x 1 mL 5 comps.

D-5480-IS-5ML $ 30 / 1 x 5 mL D-5480-IS-5ML-PAK SAVE 20% $ 120 / 5 x 5 mL Each comp. at equal weights 3 comps.

n-Decane n-Dodecane n-Hexadecane

n-Decane n-Undecane

n-Octadecane n-Tetracosane

n-Dodecane

Tetracosane (Solution A) D-5480-C40-5ML D-5480-C40-5ML-PAK 500 µg/mL in CS2

$ 15 / 1 x 5 mL SAVE 20% $ 60 / 5 x 5 mL

Standards of Interest Alternative n-Paraffin standards are available on page 15 for further method development work or more Detailed Hydrocarbon Analysis (DHA).

n-Tetracosane

Originally designed for D-5482-99 & D-5191-99

ASTM D-5482 & D-5191 Vapor Pressure Standards Vapor Pressure Quality Control Samples Cat. No.

Vapor Pressure

ASTM-P-124-01 ASTM-P-124-02 ASTM-P-124-03 ASTM-P-124-04 ASTM-P-124-05 ASTM-P-124-06

68.3kPa (9.91 psi) 68.0kPa (9.86 psi) 51.1kPa (7.41 psi) 46.7kPa (6.77 psi) 22.5kPa (3.26 psi) 7.1kPa (1.03 psi)

Technical Note Price / Set of 10 $ 65 75 70 125 50 50

/ / / / / /

10 10 10 10 10 10

x x x x x x

10 10 10 10 10 10

Consists of pure solvents with known vapor pressure.

mL mL mL mL mL mL

Technical Note

ASTM D-5501 Ethanol Content of Denatured Fuel Ethanol by GC Originally designed for D-5501-94

Denatured Fuel Ethanol Calibration Set D-5501-94-SET

$ 75 / set of 7 x 1 mL

Cat. No.

Comp.1 Wt./ Wt.%

Comp.2 Wt./ Wt.%

Comp.3 Wt./ Wt.%

D-5501-94-01 D-5501-94-02 D-5501-94-03 D-5501-94-04 D-5501-94-05 D-5501-94-06 D-5501-94-07

Ethanol Ethanol Ethanol Ethanol Ethanol Ethanol Ethanol

Methanol Methanol Methanol Methanol Methanol Methanol Methanol

Heptane Heptane Heptane Heptane Heptane Heptane Heptane

ASTM D-5580

92 93 94 95 96 97 98

0.6 0.5 0.4 0.3 0.2 0.1 0.05

Unit

7.4 6.5 5.6 4.7 3.8 2.9 1.95

1 1 1 1 1 1 1

x x x x x x x

1 1 1 1 1 1 1

mL mL mL mL mL mL mL

Benzene, Toluene, Ethylbenzene, m/p-Xylene, o-Xylene, C9 and Heavier Aromatics, & Total Aromatics in Finished Gasoline by GC

Additional Oxygenate calibration, check standards, and independent reference standards can be found in ASTM method D-4815 (page 24) or D-5622-94 (page 37). The required QA/QC procedures in EPA methods stipulate a calibration check standard be used once per analytical batch or per 10 sample set. AccuStandard has bulk packaged check standards to meet this increased usage.

Originally designed for D-5580-00

Aromatics Quantitative Calibration Mixes (without Internal Standard) D-5580-95-CAL-SET-10ML

Analyte Benzene Toluene Ethylbenzene o-Xylene 1,2,4-Trimethylbenzene Isooctane

$ 300 / set of 5 x 10 mL of 6 component mix Analyte Calibration range

Std. 1 Wt. %

Std. 2 Wt. %

Std. 3 Wt. %

Std. 4 Wt. %

Std. 5 Wt. %

0.10 1.00 0.50 0.50 0.50

0.10 15.00 0.50 1.00 1.00 82.40

0.50 10.00 1.00 2.50 10.00 76.00

1.00 5.00 2.50 10.00 0.50 81.00

2.00 2.50 5.00 5.00 5.00 80.50

5.00 1.00 10.00 0.50 2.50 81.00

-

5.00 15.00 10.00 10.00 10.00

Aromatics Quantitative Calibration Mixes (with Internal Standard) D-5580-95-CAL-IS-SET Analyte Benzene Toluene Ethylbenzene o-Xylene 1,2,4-Trimethylbenzene 2-Hexanone (Internal Std.) Isooctane

32

$ 100 / set of 5 x 1 mL of 7 component mix Analyte Calibration range

Std. 1 Wt. %

Std. 2 Wt. %

Std. 3 Wt. %

Std. 4 Wt. %

Std. 5 Wt. %

0.09 0.90 0.45 0.45 0.45

0.09 13.50 0.45 0.90 0.90 10.00 74.16

0.45 9.00 0.90 2.25 9.00 10.00 68.40

0.90 4.50 2.25 9.00 0.45 10.00 72.90

1.80 2.25 4.50 4.50 4.50 10.00 72.45

4.50 0.90 9.00 0.45 2.25 10.00 72.90

-

4.50 13.50 9.00 9.00 9.00

Quality System is Certified comply with the International 9001 Quality Standard ASTM to D-5580-00 Continued on the ISO Next Page

ASTM Standards

Method

5580

Member

Originally designed for D-5580-00

ASTM D-5580-00 Benzene, Toluene, Ethylbenzene, m/p-Xylene, o-Xylene, C9 & Continued

Heavier Aromatics, and Total Aromatics in Finished Gasoline by GC Valve Timing Calibration Mix (without Internal Standard)

M-GRA-VT/IS-AS M-GRA-VT/IS-AS-PAK Each at stated conc.

M-GRA-VT-AS-10ML $ 100 / 1 x 10 mL M-GRA-VT-AS-10ML-PAK SAVE 20% $ 400 / 5 x 10 mL Each at stated conc. 5 comps. Wt./Wt. % Benzene 5.0 Toluene 5.0 Ethylbenzene 10.0 o-Xylene 10.0 Isooctane 70.0

$ 25 / 1 x 1 mL SAVE 20% $ 100 / 5 x 1 mL 6 comps. Wt./Wt. % Benzene 4.5 Toluene 4.5 Ethylbenzene 9.0 o-Xylene 9.0 2-Hexanone (Internal Std.) 10.0 Isooctane 63.0

Technical Note

Selectivity Check Standard Internal Standard M-GRA-IS-AS-5ML $ 10 / 1 x 5 mL M-GRA-IS-AS-5ML-PAK SAVE 20% $ 40 / 5 x 5 mL

M-GRA-SCS-AS M-GRA-SCS-AS-PAK Each at stated conc.

Wt./Wt. % 1.5 98.5

n-Dodecane Isooctane

2-Hexanone (Neat)

$ 10 / 1 x 1 mL SAVE 20% $ 40 / 5 x 1 mL 2 comps.

Daily Quality Control Standard without Internal Standard

Daily Quality Control Standard without Internal Standard

D-5580-QC-R1 D-5580-QC-R1-PAK

D-5580-QC D-5580-QC-PAK

Wt./Wt. % n-Hexane 12 n-Heptane 20 n-Octane 15 n-Decane 10 n-Dodecane 1 Isooctane 20 Benzene 1

$ 125 / 1 x 10 mL SAVE 20% $ 500 / 5 x 10 mL 14 comps. Wt./Wt. Toluene Ethylbenzene p-Xylene o-Xylene 1,2,4-Trimethylbenzene 1,2,4,5-Tetramethylbenzene Naphthalene

% 9 2 3 2 3 1 1

Wt./Wt. % n-Hexane 12 n-Heptane 20 n-Octane 15 n-Decane 10 n-Triadecane 1 Isooctane 20 Benzene 1

$ 125 / 1 x 10 mL $ 500 / 5 x 10 mL 14 comps. Wt./Wt. Toluene Ethylbenzene p-Xylene o-Xylene 1,2,4-Trimethylbenzene 1,2,4,5-Tetramethylbenzene Naphthalene

% 9 2 3 2 3 1 1

ASTM D-5580 Gasoline Refinery Quality Control Standard AccuStandard was requested by the Petrochemical Industry to manufacture the following QA/QC standards for ASTM Method D-5580. The configuration of your instrument valve time switching and the pre-column incorporated determines which QA/QC standard provides optimum performance when analyzing gasolines samples by Method D-5580. Use of the D-5580 standards in conjunction with the real world gasoline AccuPetroTest & AccuPetroCheck Consensus Value Reference Material (see pages 1-2) can provide added assurance that the analytical results being generated by the laboratory are reproducible and the analytical system is performing to method specifications.

Exclusive Aromatic Chemical Reference Material Benefits from AccuStandard Every analyte in each solution is individually weighed Actual weights and weight percents are available with all ASTM/EPA solutions

Fax 203-786-5287 • Toll Free 800-442-5290 / 203-786-5290 • Website www.accustandard.com

33

ASTM

Valve Timing Calibration Mix (with Internal Standard)

Method

ASTM Standards

5599

ASTM Member

Originally designed for D-5599-95

ASTM D-5599 Oxygenates in Gas by GC & O-FID

ASTM

Oxygenates Calibration Curve with Internal Standard M-GRO-CAL/IS-SET M-GRO-CAL/IS-SET-PAK Analyte Calibration range

$ 250 / set of 8 x 1 mL $ 1,000 / 5 x (8 x 1) mL of 15 Comp. Mix

Technical Note

Every analyte in each solution is individually weighed

Actual weights and weight percents are provided with all ASTM/EPA Solutions

Std. 1 Wt. %

Std. 2 Wt. %

Std. 3 Wt. %

Std. 4 Wt. %

Std. 5 Wt. %

Std. 6 Wt. %

Std. 7 Wt. %

Std. 8 Wt. %

--12 2 0.5 2 5 1 --2 --0.3 1 ---

0.1 --1 0.1 --17 --0.5 0.5 3.5 1 --3.5

2.5 3 --1 0.7 --0.5 0.3 --18 --0.3 1

----0.1 --0.2 --0.1 0.1 1 7.5 0.5 --18

5 8 0.3 2 1 1 --2 0.1 --0.1 0.5 7.5

0.5 5 --0.3 --2.5 2.5 1 0.3 1 2 0.1 12

1 1 0.5 --0.4 10 0.7 ----12 --2 ---

---------------------------

1,2- Dimethoxyethane (ISTD) RFA Gasoline

4 70.2

4 68.8

4 68.7

4 68.5

4 68.5

4 68.8

4 68.4

--100

Total oxygenates & ISTD

29.8

31.2

31.3

31.5

31.5

31.2

31.6

0

Methanol Ethanol Isopropanol t-Butanol Propanol MtBE sec-Butanol Diisopropyl ether iso-Butanol EtBE t-Pentanol Butanol TAME

0.1 - 5.0 1.0 - 12.0 0.1 - 2.0 0.1 - 2.0 0.2 - 2.0 1.0 - 17.0 0.1 - 2.5 0.1 - 2.0 0.1 - 2.0 1.0 - 18.0 0.1 - 2.0 0.1 - 2.0 1.0 - 18.0

Oxygenates Calibration Curve without Internal Standard M-GRO-CAL-SET

$ 850 / set of 8 x 10 mL of 14 Comp. Mix

Analyte Calibration range

Std. 1 Wt. %

Std. 2 Wt. %

Std. 3 Wt. %

Std. 4 Wt. %

Std. 5 Wt. %

Std. 6 Wt. %

Std. 7 Wt. %

Std. 8 Wt. %

--12 2 0.5 2 5 1 --2 --0.3 1 ---

0.1 --1 0.1 --17 --0.5 0.5 3.5 1 --3.5

2.5 3 --1 0.7 --0.5 0.3 --18 --0.3 1

----0.1 --0.2 --0.1 0.1 1 7.5 0.5 --18

5 8 0.3 2 1 1 --2 0.1 --0.1 0.5 7.5

0.5 5 --0.3 --2.5 2.5 1 0.3 1 2 0.1 12

1 1 0.5 --0.4 10 0.7 ----12 --2 ---

---------------------------

RFA Gasoline

74.2

64.8

64.7

64.5

64.5

64.8

64.4

100

Total oxygenates

25.8

27.2

27.3

27.5

27.5

27.2

27.6

0

Methanol Ethanol Isopropanol t-Butanol Propanol MtBE sec-Butanol Diisopropyl ether iso-Butanol EtBE t-Pentanol Butanol TAME

0.1 - 5.0 1.0 - 12.0 0.1 - 2.0 0.1 - 2.0 0.2 - 2.0 1.0 - 17.0 0.1 - 2.5 0.1 - 2.0 0.1 - 2.0 1.0 - 18.0 0.1 - 2.0 0.1 - 2.0 1.0 - 18.0

Oxygenate Calibration Curves ISTD-Free and Larger Packaging Size. AccuStandard has received requests from the Petroleum Industry to formulate our D-5599 Oxygenate product without internal standard (ISTD) and package it in a larger volume. We have met those requests by introducing the M-GRO-CAL-SET calibration curve. This curve is manufactured without incorporating an internal standard and is packaged in Ready-to-Use 10 mL sample volume. The certified oxygenate calibration curve can be used in combination with other aromatic standards for combined oxygenate/aromatic analysis, to change the amount of internal standard added, or to incorporate alternative internal standard analytes.

9 D-559 Meets es uidelin EPA G FG for R is Analys

Technical Note AccuStandard’s M-GRO oxygenate calibration curve has been successfully used by Petroleum Refineries and supporting laboratories for both ASTM Method D-5599 and ASTM Method D-4815. In addition, AccuStandard’s certified oxygenate chemical reference materials provide the following features and benefits for superior performance and value.

Benefits from AccuStandard’s Oxygenates

34

Features:

Benefits:

Analytes checked for chemical purity & water content

The use & validation of the highest purity neats enhance the integrity of the standard.

Analyzed by Independent Laboratories

Independent product validation of certified values.

Certified method specific calibration standards

Increased confidence in analytical results.

Elimination of standards preparation

Time is utilized quantifying samples.

Internal Standards incorporated

Ready-to-Inject Standards.

Weights and weight percents provided

Ease of use in performing back calculations.

All necessary solutions included

Provides single source for sample analysis.

Variations in Packaging size

Meet laboratory sample volumes.

Economical

Time is spent on analysis rather than preparing stds.

7 stds. used to generate 5 point curve

Generate a 5 point curve in 30% less time than competitors' 10 standard set.

Quality System is Certified to comply with the International ISO 9001 Quality Standard

ASTM Standards

Method

5599

Member

ASTM D-5599

Originally designed for D-5599-95

Oxygenates in Gasoline by GC & O-FID

Continued

Daily Quality Control Standard (without Internal Standard)

Revised Daily Quality Control Standard (without Internal Standard)

M-GRO-QC-10ML $ 100 / 1 x 10 mL M-GRO-QC-10ML-PAK SAVE 20% $ 400 / 5 x 10 mL

M-GRO-QC-R-10ML $ 100 / 1 x 10 mL M-GRO-QC-R-10ML-PAK SAVE 20% $ 400 / 5 x 10 mL Compound Target Compound Target Oxygenate Wt. % Oxygenate Wt. %

Compound Oxygenate

Target Wt. %

Methanol Ethanol Isopropanol t-Butanol Propanol MtBE sec-Butanol Di-isopropyl ether

1 1 1 1 1 3 1 3

Compound Oxygenate

Target Wt. %

iso-Butanol EtBE t-Pentanol Butanol TAME

1 3 1 1 3

RFA Gasoline

79

14 comps.

Methanol Ethanol Isopropanol t-Butanol Propanol MtBE sec-Butanol Di-isopropyl ether

1 1 1 1 1 3 1 1

100

iso-Butanol EtBE t-Pentanol Butanol TAME

1 3 1 1 3

RFA Gasoline

81

14 comps.

Revised Daily Quality Control Standard (with Internal Standard)

M-GRO-QC/IS-5ML $ 75 / 1 x 5 mL M-GRO-QC/IS-5ML-PAK SAVE 27% $ 275 / 5 x 5 mL

M-GRO-QC-R/IS-5ML $ 75 / 1 x 5 mL M-GRO-QC-R/IS-5ML-PAK SAVE 27% $ 275 / 5 x 5 mL

Target Wt. %

Methanol Ethanol Isopropanol t-Butanol Propanol MtBE sec-Butanol

1 1 1 1 1 3 1

Compound Oxygenate

Target Wt. %

Di-isopropyl ether iso-Butanol EtBE t-Pentanol Butanol TAME RFA Gasoline

3 1 3 1 1 3

Compound Oxygenate

Target Wt. %

Methanol Ethanol Isopropanol t-Butanol Propanol MtBE sec-Butanol

1 1 1 1 1 3 1

79

Compound Oxygenate

Target Wt. %

Di-isopropyl ether iso-Butanol EtBE t-Pentanol Butanol TAME RFA Gasoline

1 1 3 1 1 3 81

1,2-Dimethoxyethane (ISTD) is combined with 100 the above 14 comps. in a 4 to 100 weight ratio

1,2-Dimethoxyethane (ISTD) is combined with 100 the above 14 comps. in a 4 to 100 weight ratio

15 comps.

15 comps.

Gasoline Refinery Blank (with Internal Standard)

O-FID/EPA Gasoline Refinery Internal Standard

M-GRO-BLNK/IS-10ML $ 15 / 1 x 10mL M-GRO-BLNK/IS-10ML-PAK SAVE 20% $ 60 / 5 x 10mL 2 comps.

M-GRO-IS-5ML M-GRO-IS-5ML-PAK

1,2- Dimethoxyethane (ISTD) RFA Gasoline

Wt. % 4 96

Technical Note The Daily Quality Control Standard M-GRO-QC-R was developed in response to your requests for a QC mix bracketed by the Calibration Curve. AccuStandard reduced the diisopropyl ether content from 3 Wt. % to 1 Wt. % to meet the method specifications.

100

Daily Quality Control Standard (with Internal Standard) Compound Oxygenate

ASTM

ASTM/EPA Oxygenate Quality Control Standards

9 D-559 Meets es uidelin EPA G FG for R is Analys

Technical Note Additional Oxygenate calibration, check standards, and independent reference standards can be found in ASTM method D-4815 (page 24) or D-5622 (page 37). The required QA/QC procedures in EPA methods stipulate a calibration check standard be used once per analytical batch or per 10 sample set. AccuStandard has bulk packaged check standards to meet this increased usage.

$ 10 / 1 x 5 mL SAVE 20% $ 40 / 5 x 5 mL

1,2- Dimethoxyethane (ISTD)

O-FID Gasoline Refinery Blank M-GRO-BLNK-10ML M-GRO-BLNK-10ML-PAK

$ 10 / 1 x 10mL SAVE 20% $ 40 / 5 x 10mL

RFA Gasoline (neat)

Fax 203-786-5287 • AccuStandard • Toll Free 800-442-5290 / 203-786-5290 • Website www.accustandard.com

35

Method

Oxygenates Using O-FID

5599

ASTM Member

EPA O-FID Oxygenate Petrochemical Standards

ASTM

AccuStandard has formulated this second oxygenate version to meet the specific analyte requirements set forth in the EPA methodology. Originally designed for D-5599-95

ASTM D-5599 EPA Gasoline Refinery Oxygenates Calibration Curves EPA O-FID Quantitative Calibration Mixes (without Internal Standard) M-GRO-CAL-EPA-SET-10ML

Methanol Ethanol t-Butanol MtBE RFA Gasoline

$ 350 / set of 5 x 10 mL 5 comps. Analyte Calibr. range

Std. 1 Wt. %

Std. 2 Wt. %

Std. 3 Wt. %

Std. 4 Wt. %

Std. 5 Wt. %

0.30 0.30 0.30 0.30

6.00 0.30 0.30 15.00 78.40

12.00 3.00 6.00 7.50 71.50

3.00 6.00 9.00 11.25 70.75

0.30 9.00 12.00 3.75 74.95

9.00 12.00 3.00 0.30 75.70

-

12.00 12.00 12.00 15.00

For our complete line of Organic Standards, request a copy of our Catalog.

EPA O-FID Quantitative Calibration Mixes (with Internal Standard) M-GRO-CAL-IS/EPA-SET

$ 175 / set of 5 x 1 mL 6 comps.

Methanol Ethanol t-Butanol MtBE 1,2-Dimethoxyethane (ISTD) RFA Gasoline

Analyte Calibr. range

Std. 1 Wt. %

Std. 2 Wt. %

Std. 3 Wt. %

Std. 4 Wt. %

Std. 5 Wt. %

0.29 0.29 0.29 0.29

5.70 0.29 0.29 14.25 5.00 74.48

11.40 2.85 5.70 7.13 5.00 67.93

2.85 5.70 8.55 10.69 5.00 67.31

0.29 8.55 11.40 3.56 5.00 71.20

8.55 11.40 2.85 0.29 5.00 71.92

-

11.40 11.40 11.40 14.29

EPA O-FID Quantitative Calibration Check Standard (without Internal Standard)

EPA O-FID Quantitative Calibration Check Standard (with Internal Standard)

M-GRO-EPA-CC-10ML $ 50 / 1 x 10 mL M-GRO-EPA-CC-10ML-PAKSAVE 20% $ 200 / 5 x 10 mL 5 comps.

M-GRO-EPA-CC/IS-5ML $ 35 / 1 x 5 mL M-GRO-EPA-CC/IS-5MLPAK SAVE 20% $ 150 / 5 x 5 mL 6 comps.

Wt./Wt. % Methanol 4.0 Ethanol 8.0 tert-Butanol 5.0

Wt./Wt. % Methanol 3.80 Ethanol 7.60 tert-Butanol 4.75

Wt./Wt. % Methyl tert-butyl ether 12.0 RFA gasoline 71.0

EPA O-FID Spiking Solution M-GRO-EPA-SP-5ML $ 50 / 1 x 5 mL M-GRO-EPA-SP-5ML-PAK SAVE 20% $ 200 / 5 x 5 mL 4 comps. Wt./Wt. % Methanol 14.3 Ethanol 28.6

Wt./Wt. % tert-Butanol 14.3 Methyl tert-butyl ether 42.8

Wt./Wt. % Methyl tert-butyl ether 11.40 RFA gasoline 67.45 DME (internal standard) 5.0

Oxygenate Free Gasoline Refinery Blank M-GRO-BLNK-10ML M-GRO-BLNK-10ML-PAK

Technical Note Additional Oxygenate calibration, check standards, and independent reference standards can be found in ASTM method D-4815 (page 24) or D-5622 (page 37). The required QA/QC procedures in EPA methods stipulate a calibration check standard be used once per analytical batch or per 10 sample set. AccuStandard has bulk packaged check standards to meet this increased usage.

$ 10 / 1 x 10 mL SAVE 20% $ 40 / 5 x 10 mL

RFA Gasoline (neat)

Internal Standard M-GRO-IS-5ML M-GRO-IS-5ML-PAK

$ 10 / 1 x 10 mL SAVE 20% $ 40 / 5 x 10 mL

1,2-Dimethoxyethane (ISTD)

Cross Reference Table ASTM IP ISO DIN JIS AFNOR sorted by ASTM Method see beginning of Catalog

36

Quality System is Certified to comply with the International ISO 9001 Quality Standard

ASTM Standards

Method

5600 5622

Member

Originally designed for D-5600-98

ASTM D-5600 Trace Metals in Petroleum Coke by ICP-AES

Hydrochloric Acid Diluent

D-5600-01-1 $ 225 / 1 x 100 mL 500 µg/mL each in 2-5% HNO3 tr. HF 12 comps.

D-5600-BLH-5 D-5600-BLH-L

Aluminum Barium Calcium Iron

Magnesium Manganese Nickel Silicon

Sodium Titanium Vanadium Zinc

Standards of Interest Individual ICP Standards are on pages 67-72.

$ 50 / 1 x 500 mL $ 65 / 1 x 1 L

20% HCl in ASTM Type II water

Lithium Borate Diluent D-5600-LIB-1 D-5600-LIB-5

$ 125 / 1 x 100 mL $ 180 / 1 x 500 mL

2.0% Lithium Borate in 10% HCl

ASTM D-5622 Total Oxygen in Gasoline & MeOH Fuels by Reductive Pyrolysis Cat. No.

Description (2 x 10 mL, plus an RFA gasoline blank)

Oxygenate Wt. %

ASTM-P-0061-SET * ASTM-P-0062-SET * ASTM-P-0063-SET * ASTM-P-0064-SET * ASTM-P-0065-SET * ASTM-P-0066-SET * ASTM-P-0067-SET * ASTM-P-0068-SET * ASTM-P-0069-SET *

Ethanol in Oxygenate free RFA gasoline Ethanol in Oxygenate free RFA gasoline t-Amyl methyl ether in Oxygenate free RFA gasoline t-Amyl methyl ether in Oxygenate free RFA gasoline Ethyl t-butyl ether in Oxygenate free RFA gasoline Ethyl t-butyl ether in Oxygenate free RFA gasoline Methyl t-butyl ether in Oxygenate free RFA gasoline Methyl t-butyl ether in Oxygenate free RFA gasoline Methanol & t-Butanol in Oxygenate free RFA gasoline

5.0 10.0 10.0 15.0 10.0 15.0 10.0 15.0 10.0 & 5.0

* Each Set includes M-GRO-BLNK-10ML

Oxygenate Free Gasoline Refinery Blank M-GRO-BLNK-10ML

$ 10 / 1 x 10 mL

RFA Gasoline (neat)

Standards of Interests See ASTM Methods D-4815 (page 24) and D-5599 (pages 34-36) for additional oxygenate calibration standards.

Unit 3 3 3 3 3 3 3 3 3

D-5600 Ready-to-Aspirate Standards AccuStandard has formulated the following stock standards for ASTM Method D-5600. We have prepared numerous Ready-toAspirate ICP multi-element solutions. Should your company want to eliminate the preparation process for Inorganic standards contact our Technical Department for a quote on a Ready-toAspirate working level Inorganic standard. Originally designed for D-5622-95

Price x x x x x x x x x

10 10 10 10 10 10 10 10 10

mL mL mL mL mL mL mL mL mL

$ 50 50 50 50 50 50 50 50 50

Technical Note Use M-GRO-BLNK-10ML as an oxygenate free RFA gasoline matrix to make up your own oxygenate standards or call our Technical Dept. to have a Standard custom made for you.

Technical Note AccuStandard’s Oxygenate reference fuel line was designed as a cost effective alternative for Petrochemical Laboratories. All oxygenate blends come with a certificate to maintain traceability links to NIST SRMs (when available). By packaging the standard in 10 mL sealed ampules your laboratory will realize cost savings. The 10 mL size avoids having special packaging and hazardous material fees billed to your invoice.

For our complete line of Inorganic Standards, request a copy of our Inorganics Catalog.

Fax 203-786-5287 • Toll Free 800-442-5290 / 203-786-5290 • Website www.accustandard.com

37

ASTM

Multi-Element Calibration Standard

Technical Note

Method

ASTM Standards

5623

Member

ASTM

ASTM D-5623

Originally designed for D-5623-94

Sulfur Compounds in Light Petroleum Liquids by GC and Sulfur Selective Detection

This set of qualitative Sulfur Standards are formulated for research evaluation of the presence of the sulfur analytes or their breakdown products. ASTM-P-0091-10X-SET Approx. 2.0 mg/mL each in Toluene

$ 625 / set of 22 x 1 mL

Analyte

Cat. No.

Unit

Hydrogen sulfide Carbonyl sulfide (Carbon oxysulfide) Methyl mercaptan (Methanethiol) Ethyl mercaptan (Ethanethiol) Methyl sulfide (Dimethyl sulfide) Carbon disulfide 2-Propanethiol (Isopropyl mercaptan 2-Methyl-2-propanethiol (t-butyl mercaptan) 1-Propanethiol (Propyl mercaptan) Ethyl methyl sulfide 1-Methyl-1-propanethiol (2-butanethiol) Thiophene 2-Methyl-1-propanethiol (Isobutyl mercaptan) Diethyl sulfide 1-Butanethiol (Butyl mercaptan) Methyl disulfide (Dimethyl disulfide) 2-Methylthiophene 3-Methylthiophene Diethyl disulfide (Ethyl disulfide) 3-Methylbenzo[b]thiophene 5-Methylbenzo[b]thiophene Diphenyl sulfide

ASTM-P-0091-01-10X ASTM-P-0091-02-10X ASTM-P-0091-03-10X ASTM-P-0091-04-10X ASTM-P-0091-05-10X ASTM-P-0091-06-10X ASTM-P-0091-07-10X ASTM-P-0091-08-10X ASTM-P-0091-09-10X ASTM-P-0091-10-10X ASTM-P-0091-11-10X ASTM-P-0091-12-10X ASTM-P-0091-13-10X ASTM-P-0091-14-10X ASTM-P-0091-15-10X ASTM-P-0091-16-10X ASTM-P-0091-17-10X ASTM-P-0091-18-10X ASTM-P-0091-19-10X ASTM-P-0091-20-10X ASTM-P-0091-21-10X ASTM-P-0091-22-10X

1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1

x x x x x x x x x x x x x x x x x x x x x x

1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1

Price mL mL mL mL mL mL mL mL mL mL mL mL mL mL mL mL mL mL mL mL mL mL

$ 35 35 35 35 35 35 35 35 35 35 35 35 35 35 35 35 35 35 35 35 75 35

Custom Ampulling for Bulk Quantity Requirements

• Fill Volumes from 0.2 mL to 20 mL • Flammables • QC Services available AccuStandard has the resources and equipment to meet your custom packaging requirements. Our full automated filler-sealer can accommodate a fill range from 0.2 to 20 mL, and ampule sizes from 1 mL to 20 mL. AccuStandard has extensive experience with Round Robin samples for ASTM committees. Call our Technical Department for a quotation.

We can reduce your costs by using the Cozzoli Auto Filling/Sealing Machine to package just the right size product for your application.

38

Quality System is Certified to comply with the International ISO 9001 Quality Standard

ASTM Standards

Method

5599

Member

ASTM D-5708

Nickel, Vanadium, & Iron in Crude Oils & Residual Fuels by ICP-AES

Originally designed for D-5708-95a

Test Method A - ICP with an Organic Solvent Specimen Solution Sulfur and Metals in Mineral Oil Cat. No.

Sulfur Conc. (Wt. %)

Iron Conc. (µg/g)

Nickel Conc. (µg/g)

Vanadium Conc. (µg/g)

Price 100 mL

0.00 0.50 1.00 2.00 2.50 3.00 3.50 4.50 5.00 5.50

0 300 500 100 200 400 0 500 100 300 200 50

0 10 100 80 40 5 60 0 100 50 20 100

0 500 25 250 100 400 300 200 0 250 500 50

$ 200 200 200 200 200 200 200 200 200 200 200 200

D-5708-A-10X $ 150 / 4 oz. 100 µg/g in 20 cSt mineral oil 3 comps. Iron Nickel Vanadium

Standards of Interests See Table of Contents for the Wear Metals Group pages.

For our complete line of Inorganic Standards, request a copy of our Inorganics Catalog

WEAR METALS

ASTM-P-0102-01 ASTM-P-0102-02 ASTM-P-0102-03 ASTM-P-0102-04 ASTM-P-0102-05 ASTM-P-0102-06 ASTM-P-0102-07 ASTM-P-0102-08 ASTM-P-0102-09 ASTM-P-0102-10 ASTM-P-0102-11 ASTM-P-0102-12

Stock Multi-Element in Mineral Oil

$ 1850 / 100 mL

ASTM

ASTM-P-0102-SET

Sulfur and Metals in Residual Fuel Oil ASTM-P-0103-SET Cat. No. ASTM-P-0103-01 ASTM-P-0103-02 ASTM-P-0103-03 ASTM-P-0103-04 ASTM-P-0103-05 ASTM-P-0103-06 ASTM-P-0103-07 ASTM-P-0103-08 ASTM-P-0103-09 ASTM-P-0103-10 ASTM-P-0103-11 ASTM-P-0103-12

$ 2100 / 100 mL Sulfur Conc. (Wt. %)

Iron Conc. (µg/g)

Nickel Conc. (µg/g)

Vanadium Conc. (µg/g)

Price 100 mL

0.00 0.50 1.00 2.00 2.50 3.00 3.50 4.50 5.00 5.50

0 300 500 100 200 400 0 500 100 300 200 50

0 10 100 80 40 5 60 0 100 50 20 100

0 500 25 250 100 400 300 200 0 250 500 50

$ 200 200 200 200 200 200 200 200 200 200 200 200

Test Method B - ICP after Acid Decomposition of Sample Stock Multi-Element Aqueous Standard

Working Level Multi-Element Aqueous Standard

D-5708-B-10X-1 D-5708-B-10X-5 Each at 100 µg/mL in 2-5% HNO3 Iron Nickel

$ 60 / 100 mL $ 115 / 500 mL 3 comps. Vanadium

D-5708-B-5 Each at 10 µg/mL in 2-5% HNO3 Iron Nickel

$ 105 / 500 mL 3 comps. Vanadium

Nitric Acid Blank CLP-BLN-5 CLP-BLN-L

$ 30 / 500 mL $ 45 / L (2 x 500 mL)

5% HNO3 in ASTM Type I Water

Member

AccuStandard is an active member in ASTM and strives to keep abreast of ASTM method revisions. If our listed formulation does not meet the most recent method revision, please contact Technical Support, ext. 117 for an updated product.

Fax 203-786-5287 • Toll Free 800-442-5290 / 203-786-5290 • Website www.accustandard.com

39

Method

ASTM Standards

5762

Member

ASTM D-5762 Nitrogen in Petroleum & Petroleum Products by Boat-Inlet Chemiluminescence Originally designed for D-5762-98

Stock Nitrogen Standard

ASTM

D-5762-95-500X-PAK

$ 45 / 5 x 1 mL

Nitrogen @ 500 µg/mL in Xylene (Acridine @ 6397 µg/mL)

Nitrogen Calibration Set

Technical Note

D-5762-95-CAL-SET

$ 75 / 6 x 1 mL

Cat. No. D-5762-95-BL D-5762-95-1X D-5762-95-5X D-5762-95-10X D-5762-95-50X D-5762-95-100X

Description Xylene Blank Nitrogen @ 1.0 µg/mL in Xylene Nitrogen @ 5.0 µg/mL in Xylene Nitrogen @ 10 µg/mL in Xylene Nitrogen @ 50 µg/mL in Xylene Nitrogen @ 100 µg/mL in Xylene

1 1 1 1 1 1

x x x x x x

Unit 1 mL 1 mL 1 mL 1 mL 1 mL 1 mL

x x x x x x

Unit 1 mL 1 mL 1 mL 1 mL 1 mL 1 mL

Nitrogen introduced using Acridine.

Low level Nitrogen Calibration Set

Technical Note

ASTM-P-0070-SET

$ 75 / 6 x 1 mL

Cat. No. ASTM-P-0070-BL ASTM-P-0070-1X ASTM-P-0070-2X ASTM-P-0070-4X ASTM-P-0070-10X ASTM-P-0070-20X

Description Isooctane Blank Nitrogen @ 0.5 µg/g in Isooctane Nitrogen @ 1.0 µg/g in Isooctane Nitrogen @ 2.0 µg/g in Isooctane Nitrogen @ 5.0 µg/g in Isooctane Nitrogen @ 10.0 µg/g in Isooctane

1 1 1 1 1 1

Nitrogen introduced using Acridine.

Low level Nitrogen & Sulfur Calibration Set ASTM-P-0071-SET Cat. No. ASTM-P-0071-BL ASTM-P-0071-01 ASTM-P-0071-02 ASTM-P-0071-03

$ 50 / 4 x 1 mL Description Benzene Blank Nitrogen @ 0.25 µg/g & Sulfur @ 0.25 µg/g in Benzene Nitrogen @ 0.50 µg/g & Sulfur @ 0.50 µg/g in Benzene Nitrogen @ 1.00 µg/g & Sulfur @ 1.00 µg/g in Benzene

Technical Note 1 1 1 1

x x x x

Unit 1 mL 1 mL 1 mL 1 mL

The Nitrogen is introduced using Aniline and the Sulfur is introduced using n-Butyl sulfide.

AccuPetroCheck and AccuPetroTest Real World Gasoline QC Standards In cooperation with ASTM D-02 subcommittee 3 and 4, AccuStandard ampulled 21 Real World gasoline reference fuels. Consensus Values have been determined for these reference fuels by various ASTM Round Robins to provide Petrochemical Laboratories with a source of well characterized gasoline standards for use in QA/QC applications and as Single Blind test samples over an extended period of time. As new ASTM D-02.03 and D-02.04 Test methods are promulgated they require mandatory Quality Control testing of real world samples. AccuStandard’s AccuPetroTest & AccuPetroCheck standards are being successfully used to achieve these new Quality Control requirements.

QC Standards CARB Low Sulfur RFG QC Standard

Conventional Gasoline QC Standard

ASTM-FUEL-QCS-01-PAK

$ 60 / 5 x 15 mL

ASTM-FUEL-QCS-02-PAK $ 60 / 5 x 15 mL

Parameter Total Aromatics Total Olefins Total Saturates Sulfur Sulfur Sulfur Sulfur Benzene Toluene Total Aromatics Benzene Total Olefins

Value 24.5 5.3 58.3 0.0057 0.0078 55.76 59.31 0.80 4.92 23.42 0.78 5.3

Parameter Total Aromatics Total Olefins Total Saturates Sulfur Sulfur Sulfur Sulfur Benzene Toluene Total Aromatics Benzene Total Olefins

40

Method D-1319 D-1319 D-1319 D-2622 D-4294 D-5453 D-6344 D-5769 D-5769 D-5769 D-6227 D-6550

Conc. Vol.% Vol.% Vol.% Wt.% Wt.% µg/g µg/g Vol.% Vol.% Vol.% Vol.% Vol.%

Method D-1319 D-1319 D-1319 D-2622 D-4294 D-5453 D-6344 D-5769 D-5769 D-5769 D-6227 D-6550

Value 34.6 12.4 62.8 0.0338 0.0368 317.36 338.78 0.55 5.53 32.51 0.52 12.4

Conc. Vol.% Vol.% Vol.% Wt.% Wt.% µg/g µg/g Vol.% Vol.% Vol.% Vol.% Vol.%

AccuPetroCheck QC Standards Two of the fuels are available as AccuPetroCheck Consensus Value QC Standards. The AccuPetroCheck CARB and Conventional gasoline reference materials have all parameters listed on the certificate with the Consensus Values and the regression equations for reproducability. Use of these Reference Materials improve the quality of laboratory results. The Consensus Values listed reflect initial statistical treatment of the data at the time the catalog was published. The actual certificate provided with the AccuPetroCheck QC standard will have the accepted Consensus Value based on statistical treatment of the data.

Quality System is Certified to comply with the International ISO 9001 Quality Standard

Petrochemical Standards Member

AccuPetroTest Sulfur in Diesel Fuel QC Standard $ 25 / 2 x 15 mL

Parameter Sulfur

Approx. Range 20 - 11000 mg/kg

See ASTM Methods D-2622, D-3120, D-3246-92, D-4294, D-5453, for Sulfur Calibration Standards

Sulfur in White Mineral Oil QC Standard SBPT-SWMO

$ 25 / 2 x 15 mL

Parameter Sulfur

Approx. Range 20 - 11000 mg/kg

See ASTM Methods D-2622, D-3120, D-3246-92, D-4294, D-5453 for Sulfur Calibration Standards

AccuPetroTest Gasoline Low Sulfur QC Sample

Olefin QC Sample

SBPT-LSGAS

SBPT-OLEFINSFC

Parameter Sulfur

$ 25 / 2 x 15 mL Method 5453

Approx. Range 0 - 50 µg/g

Parameter Olefins

$ 25 / 2 x 15 mL

Method 6550

Approx. Range 1 - 40 Vol.%

AccuPetroTest Gasoline QC Olefins QC Sample SBPT-OLEFIN Parameter Total Aromatics Total Olefins Total Saturates

Sulfur QC Sample $ 25 / 2 x 15 mL

Method D-1319 D-1319 D-1319

Approx. Range 8-60 Vol.% 1 - 40 Vol.% 30-80 Vol. %

See ASTM Method D-1319 for Sulfur Calibration Standards

Aromatics QC Sample SBPT-AROM Parameter Total Aromatics

Parameter Sulfur Sulfur Sulfur Sulfur

Approx. Range 8 - 60 Vol.%

See ASTM Methods D-3606, D-5580-95, D-5769-95 for Benzene Calibration Standards

SBPT-BENZ Parameter Benzene Toluene

Approx. Range 0.1 - 2.0 Vol.% 1.0 - 15 Vol.%

Technical Note

$ 50 / 2 x 15 mL Method D-1319 D-1319 D-1319 D-2622 D-4294 D-5453 D-6344 D-5769 D-5769 D-5769 D-6277 D-6550

$ 25 / 2 x 15 mL Method D-5769 D-5769

See ASTM Methods D-3606, D-5580-95, D-5769-95 for Benzene Calibration Standards

Comprehensive Single Blind Gasoline QC Sample Parameter Total Aromatics Total Olefins Total Saturates Sulfur Sulfur Sulfur Sulfur Benzene Toluene Total Aromatics Benzene Total Olefins

Approx. Range 0.0001 - 0.0930 Wt.% 0.0016 - 0.0930 Wt.% 4.0 - 500 µg/g 1.0 - 1000 µg/g

See ASTM Methods D-2622, D-3120, D-3246-92, D-4294, D-5453 for Sulfur Calibration Standards

AccuPetroTest Gasoline

SBPT-COMP

$ 25 / 2 x 15 mL Method D-2622 D-4294 D-5453 D-XXXX

Benzene/Toluene QC Sample $ 25 / 2 x 15 mL

Method D-5769

SBPT-SGAS

Approx. Range 8 - 60 1 - 40 30 - 80 0.0001 - 0.0930 0.0016 - 0.0930 0.5 -500 1.0 - 1000 0.1 - 2.0 1.0 - 15 8 - 60 0.1 - 2.0 1 - 40

AccuPetroTest Single Blind Standards Petrochemical Laboratories looking to test the performance of the laboratory for a specific parameter can order the Single Blind AccuPetroTest sample for the parameter of interest. Two real world gasoline samples will be sent for the test parameter requested and a separate sealed envelope containing the determined Consensus Value is also provided. The second sample is for repeatability testing or as a future QA/QC reference.

Conc. Vol.% Vol.% Vol.% Wt.% Wt.% µg/g µg/g Vol.% Vol.% Vol.% Vol.% Vol.%

Our new comprehensive single blind gasoline QC sample tests for more parameters from a single sample. The actual gasoline sample will have consensus values listed on the datasheet that fall within the range listed for each parameter.

Test to

Low ppb

Sulfur See Pages 6-11

Conducting a Petrochemical Round Robin for a new ASTM method? Select AccuStandard to prepare the necessary samples for the Round Robin study.

Fax 203-786-5287 • Toll Free 800-442-5290 / 203-786-5290 • Website www.accustandard.com

41

ASTM

SBPT-SDF

Sulfur Single Blind AccuPetroTest Alternative Matrices Standards AccuStandard has manufactured a number of Diesel and White Mineral Oil quality control products containing a gravimetrically prepared amount of Sulfur. Use of these alternative matrix materials can provide further evaluation of the QA/QC process in the laboratory. Two samples will be sent for the test parameter and a separate sealed envelope containing the gravimetrically prepared sulfur values is also provided. The second sample is for repeatability testing or for use as a future QA/QC reference.

Method

5769

ASTM Standards

Member

ASTM Method D-5769-98 Benzene, Toluene, and Total Aromatics in Finished Gasoline by GC/MS

ASTM

ASTM D-5769 Benzene, Toluene & Total Aromatics in Finished Gasoline by GC/MS

Originally designed for D-5769-98

All of your standards requirements for ASTM Method D-5769 have been put together in the following 10 pages. These standards and methods are used in the monitoring of Total Aromatics according to the latest methods and amendments to the US Clean Air Act. A set of Amendments, containing more stringent specifications became effective January 1, 1995 limiting the volatility and composition of reformulated gasoline. The D-02 Committee of the American Society of Testing Materials, developed a standard test method D-5769 for the determination of the analyte composition by GC/MS of reformulated gasoline.

Aromatic Product Line yields the following important benefits

Features:

Benefits:

Purity and Identity of all analytes verified .......... Impurity interferences in analyte retention time under identical operating conditions window are compensated. Certified method specific calibration standards . Increased confidence in analytical results. Eliminates preparation of calibration standards ..Time is utilized quantifying actual samples. Internal Standards Incorporated .........................Saves time. Weights and weight percents provided .............. Ease of use in performing back calculations. Includes all necessary solutions .........................Complete single source for reference materials. Variations in packaging size .............................. Meet laboratory sample volumes and demands. Low Cost ............................................................ More economical to purchase than to prepare standards. Flexibility ............................................................ Meet your lab requirements/method changes. Only 5 standards needed for a 5 Point Curve ... Generate a full calibration curve in 1/2 the time of the two set version composed of 10 standards. No charge disk deliverable calibration curve .... Direct computer uploading eliminates the input of 135 weights (CALAMTS™) separate data points.

42

Quality System is Certified to comply with the International ISO 9001 Quality Standard

ASTM Standards

Method

5769

Member

ASTM D-5769 Benzene, Toluene & Total Aromatics in Finished Gasoline by GC/MS

Originally designed for D-5769-95

ASTM

Standards Designed for ASTM D-5769 as published in the 1997 Annual Book of ASTM Standards, Vol. 05.03 Petroleum Products and Lubricants (III): D-4636-latest; Catalysts The following M-GRA catalog numbers contain the necessary calibration curves, daily quality control, and internal standards designed to meet the promulgated GC/MS Aromatic method listed in the 1997 ASTM Book of Standards. AccuStandard offers two different versions of the M-GRA catalog numbers: M-GRA three component internal standard version, and the M-GRA four component internal standard version. The three component internal standard version contains the necessary deuterated analytes for full qualitative and quantitative analysis of the 25 components listed in the published version. The four component internal standard version was designed at the request of the petroleum refinery laboratories. This four internal standard version incorporates not only the Benzene-d6, Ethyl benzene-d10, Naphthalene-d8, but also Toluene-d8. Incorporating the Toluene-d8 as the internal standard for the quantification of gasolines with higher Toluene levels has improved analytical results for this analyte. Incorporation of a 6th Calibration Standard A 6th calibration standard has been formulated for the M-GRA product line to improve the linearity at the high end of the calibration curve see page 44. This sixth standard can be especially important in the quantification of gasoline samples containing high toluene levels. The formulation contains an analyte concentration between the high level standard and the next level, which is standard two. Use of the sixth standard provides an additional calibration point that is desirable when the calibration curve is developed using a quadratic fit.

Aromatics Kits for analysis by GC/MS M-GRA-K1 (Original Formulations) Kit includes: M-GRA-CAL/IS-SET M-GRA-QC/IS-5ML M-GRA-IS-5ML M-GRA-ST

$ 600

5 1 1 1

x x x x

Units 1 mL 5 mL 5 mL 1 mL

Function 5 Pt. Curve w/ 3 ISTD's Daily QC w/ 3 ISTD's Internal Std. 3 comps. Sensitivity Test Solution

For your added convenience we have provided the following Aromatics Kits to meet the analytical requirements for this method.

See page 44 for product description with analytes & conc.

M-GRA-K2 $ 700 (Developed for improved high concentration linearity) Kit includes: M-GRA-CAL/IS-SET M-GRA-ADD/IS M-GRA-QC/IS-5ML M-GRA-IS-5ML M-GRA-ST

5 1 1 1 1

x x x x x

Units 1 mL 1 mL 5 mL 5 mL 1 mL

Function 5 Pt. Curve w/ 3 ISTD's 6th Std. for revison 5 F Daily QC w/ 3 ISTD's Internal Std. 3 comps. Sensitivity Test Solution

See page 44 for product description with analytes & conc.

M-GRA-K4 $ 850 (Used to meet the Toluene-d8 internal standard version recommended by a network of major petroleum refineries) Kit includes: Units M-GRA-CAL-R/IS-R-SET 5 x 1 mL M-GRA-ADD/IS-R 1 x 1 mL M-GRA-QC-R/IS-R-5ML 1 x 5 mL M-GRA-IS-R-10ML 1 x 10 mL M-GRA-ST 1 x 1 mL

Function 5 Pt. Curve w/ 4 ISTD's 6th Standard for rev. 5 F Daily QC w/ 4 ISTD's Internal Std. 4 comps. Sensitivity Test Solution

See page 45 for product description with analytes & conc.

Cross Reference Table ASTM IP ISO DIN JIS AFNOR sorted by ASTM Method see beginning of Catalog

Fax 203-786-5287 • Toll Free 800-442-5290 / 203-786-5290 • Website www.accustandard.com

43

Method

ASTM Standards

5769

Member

ASTM

ASTM D-5769 Calibration Curve with 3 Component Deuterated Internal Standard Added Aromatics Calibration Standards Kit (3 Internal Standard Version) M-GRA-CAL/IS-SET

$ 375 / set of 5 x 1 mL

Optional Sixth Standard with 3 Comp. Deuterated Internal Standard Added M-GRA-ADD/IS

Core Calibr. Mix 24 Comps.

Std. 1 Target Vol. %

Benzene Toluene Ethylbenzene m-Xylene p-Xylene o-Xylene Isopropylbenzene n-Propylbenzene 1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene 1-Methyl-2-ethylbenzene 1,2,4-Trimethylbenzene 1,2,3-Trimethylbenzene Indan 1,4-Diethylbenzene n-Butylbenzene 1,2-Diethylbenzene 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene Naphthalene Pentamethylbenzene 1-Methylnaphthalene 2-Methylnaphthalene Isooctane

Internal Standard Benzene-d6 Ethylbenzene-d10 Naphthalene-d8

3 19 5 6 6 6 3 3 3 3 3 3 5 3 3 3 3 3 2 2 2 2 2 2 --

$ 100 / 1 x 1 mL

Std. 2 Vol. %

Std. 3 Vol. %

Std. 4 Vol. %

Std. 5 Vol. %

Core Calibr. Mix 24 Comps.

1.50 9.50 2.50 3.00 3.00 3.00 1.50 1.50 1.50 1.50 1.50 1.50 2.50 1.50 1.50 1.50 1.50 1.50 1.00 1.00 1.00 1.00 1.00 1.00 Bal

0.75 4.75 1.25 1.50 1.50 1.50 0.75 0.75 0.75 0.75 0.75 0.75 1.25 0.75 0.75 0.75 0.75 0.75 0.50 0.50 0.50 0.50 0.50 0.50 Bal

0.375 2.375 0.625 0.750 0.750 0.750 0.375 0.375 0.375 0.375 0.375 0.375 0.625 0.375 0.375 0.375 0.375 0.375 0.250 0.250 0.250 0.250 0.250 0.250 Bal

0.1875 1.1875 0.3125 0.3750 0.3750 0.3750 0.1875 0.1875 0.1875 0.1875 0.1875 0.1875 0.3125 0.1875 0.1875 0.1875 0.1875 0.1875 0.1250 0.1250 0.1250 0.1250 0.1250 0.1250 Bal

Benzene Toluene Ethylbenzene m-Xylene p-Xylene o-Xylene Isopropylbenzene n-Proplylbenzene 3-Ethyltoluene 4-Ethyltoluene 1,3,5-Trimethylbenzene 2-Ethyltoluene 1,2,4-Trimethylbenzene 1,2,3-Trimethylbenzene Indan 1,4-Diethylbenzene n-Butylbenzene 1,2-Diethylbenzene 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene Naphthalene Pentamethylbenzene 1-Methylnaphthalene 2-Methylnaphthalene Isooctane

(M-GRA-IS) 2 2 2 2 1 1

2 2 1

2 2 1

2 2 1

Optional Std. 6 Target Vol. %

Internal Standard Benzene-d6 Ethylbenzene-d10 Naphthalene-d8

2.25 15 3.75 4.50 4.50 4.50 2.25 2.25 2.25 2.25 2.25 2.25 3.75 2.25 2.25 2.25 2.25 2.25 4.0 1.5 1.5 1.5 1.5 1.5 Bal

(M-GRA-IS) 2 2 1

Daily Quality Control Standard (without Internal Standard)

Daily Quality Control Standard (with Internal Standard)

M-GRA-QC-10ML $ 125 / 1 x 10 mL M-GRA-QC-10ML-PAK SAVE 20% $ 500 / 5 x 10 mL

M-GRA-QC/IS-5ML $ 100 / 1 x 5 mL M-GRA-QC/IS-5ML-PAK SAVE 20% $ 400 / 5 x 5 mL

Compound n-Hexane n-Heptane n-Octane n-Decane n-Dodecane Isooctane Benzene

Wt. Ratio 12 17 17 12 5 12 1

Wt. Compound Ratio Toluene 9 Ethylbenzene 3 m-Xylene 3 o-Xylene 3 1,2,4-Trimethylbenzene 3 1,2,4,5-Tetramethylbenzene 3 13 Comp. Core Mix

Compound n-Hexane n-Heptane n-Octane n-Decane n-Dodecane Isooctane Benzene

Wt. Ratio 12 17 17 12 5 12 1

Use with any M-GRA Calibration Curve.

3 Comp. Deuterated Internal Std. Mix M-GRA-IS-5ML M-GRA-IS-5ML-PAK

44

CALAMTS™ (Disk containing “Calibration Amounts”)

Each analyte in each standard is individually weighed. Actual weights and weight percents are provided.

Includes M-GRA-IS (3 Comp. Internal Standards mix) combined with the above 13 Comp. Core QC Mix: M-GRA-QC in a 5 to 100 weight ratio. 16 comps.

M-GRA-ST M-GRA-ST-PAK 100 µg/mL in Isooctane 1,4-Diethyl benzene

Eliminates hand keyed-in data.

100

ASTM/EPA Sensitivity Test Solution $ 10 / 1 x 1 mL SAVE 20% $ 40 / 5 x 1 mL

Disk Deliverable (At no additional charge)

Wt. Compound Ratio Toluene 9 Ethylbenzene 3 m-Xylene 3 o-Xylene 3 1,2,4-Trimethylbenzene 3 1,2,4,5-Tetramethylbenzene 3 13 Comp. Core Mix

100

Technical Note

Originally designed for D-5769-95

Compound Mix Ratio Benzene-d6 2 mL Ethylbenzene-d10 2 mL

$ 150 / 1 x 5 mL SAVE 20% $ 600 / 5 x 5 mL 3 comps. Compound Mix Ratio Naphthalene-d8 1 gm

Quality System is Certified to comply with the International ISO 9001 Quality Standard

ASTM Standards

Method

5769

Member

ASTM D-5769 Calibration Curve with 4 Component Deuterated Internal Standard Added

M-GRA-CAL-R/IS-R-SET

$ 425 / set of 5 x 1 mL

Optional Sixth Standard with 4 Comp. Deuterated Internal Standard Added M-GRA-ADD/IS-R

Core Calibr. Mix 24 Comps.

Std. 1 Target Wt. %

Benzene 3.13 Toluene 19.65 Ethylbenzene 5.12 m-Xylene 6.27 p-Xylene 6.33 o-Xylene 6.51 Isopropylbenzene 3.06 n-Propylbenzene 3.04 3-Ethyltoluene 3.08 4-Ethyltoluene 3.05 1,3,5-Trimethylbenzene 3.07 2-Ethyltoluene 3.14 1,2,4-Trimethylbenzene 5.18 1,2,3-Trimethylbenzene 3.19 Indan 3.46 1,4-Diethylbenzene 3.04 n-Butylbenzene 3.05 1,2-Diethylbenzene 3.22 1,2,4,5-Tetramethylbenzene 2.10 1,2,3,5-Tetramethylbenzene 2.09 Naphthalene 2.35 Pentamethylbenzene 2.16 1-Methylnaphthalene 2.32 2-Methylnaphthalene 2.41 Isooctane -----

(M-GRA-IS-R) Mix Ratio (2 mL) Benzene-d6 Ethylbenzene-d10 (2 mL) Naphthalene-d8 (1 gm) Toluene-d8 (7 mL)

$ 100 / 1 x 1 mL

Std. 2 Wt. %

Std. 3 Wt. %

Std. 4 Wt. %

Std. 5 Wt. %

Core Calibr. Mix 24 Comps.

1.78 11.11 2.92 3.50 3.50 3.56 1.74 1.74 1.75 1.74 1.75 1.78 2.95 1.81 1.95 1.74 1.74 1.78 1.20 1.20 1.34 1.23 1.34 1.37 43.47

0.95 5.90 1.55 1.86 1.86 1.89 0.93 0.93 0.93 0.93 0.93 0.95 1.57 0.96 1.04 0.93 0.92 0.95 0.64 0.64 0.71 0.66 0.71 0.73 69.96

0.490 3.058 0.805 0.962 0.962 0.980 0.480 0.480 0.481 0.479 0.481 0.490 0.812 0.498 0.536 0.480 0.479 0.490 0.329 0.330 0.369 0.340 0.369 0.378 84.441

0.2490 1.5547 0.4090 0.4891 0.4891 0.4981 0.2439 0.2440 0.2446 0.2437 0.2448 0.2492 0.4130 0.2530 0.2726 0.2439 0.2434 0.2489 0.1674 0.1679 0.1877 0.1727 0.1877 0.1922 92.0905

Benzene Toluene Ethylbenzene m-Xylene p-Xylene o-Xylene Isopropylbenzene n-Propylbenzene 3-Ethyltoluene 4-Ethyltoluene 1,3,5-Trimethylbenzene 2-Ethyltoluene 1,2,4-Trimethylbenzene 1,2,3-Trimethylbenzene Indan 1,4-Diethylbenzene n-Butylbenzene 1,2-Diethylbenzene 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene Naphthalene Pentamethylbenzene 1-Methylnaphthalene 2-Methylnaphthalene Isooctane

Internal Standard

ASTM

Aromatics Calibration Standards Kit (4 Internal Standard Version)

Originally designed for D-5769-95

Optional Std. 6 Target Wt. % 2.48 16.29 4.07 4.87 4.87 4.96 2.43 2.43 2.44 2.43 2.44 2.48 4.11 2.52 2.71 2.43 2.42 2.48 4.44 1.67 1.87 1.72 1.87 1.91 17.67

Technical Note This set of calibration solutions was formulated to improve quantification for Toluene by using Toluene-d8 as an additional Internal Standard.

Internal Standard 16.57 16.76 8.78 57.88

16.57 16.76 8.78 57.88

16.57 16.76 8.78 57.88

16.57 16.76 8.78 57.88

16.57 16.76 8.78 57.88

(M-GRA-IS-R) Benzene-d6 Ethylbenzene-d10 Naphthalene-d8 Toluene-d8

Mix Ratio (2 mL) 16.57 (2 mL) 16.76 (1 mL) 8.78 (7 mL) 57.88

The 4 component internal standard mix (M-GRA-IS-R) is combined with the 25 component core calibration curve mixtures in a 12 to 100 weight ratio to formulate a complete calibration solution containing 29 comps.

Daily Quality Control Standard (without Internal Standard)

Daily Quality Control Standard (with Internal Standard M-GRA-IS-R)

M-GRA-QC-10ML $ 125 / 1 x 10 mL M-GRA-QC-10ML-PAK SAVE 20% $ 500 / 5 x 10 mL

M-GRA-QC/IS-R-5ML $ 125 / 1 x 5 mL M-GRA-QC/IS-R-5ML-PAKSAVE 20% $ 500 / 5 x 5mL

Compound n-Hexane n-Heptane n-Octane n-Decane n-Dodecane Isooctane Benzene

Wt. Ratio 12 17 17 12 5 12 1

Wt. Compound Ratio Toluene 9 Ethylbenzene 3 m-Xylene 3 o-Xylene 3 1,2,4-Trimethylbenzene 3 1,2,4,5-Tetramethylbenzene 3

Compound n-Hexane n-Heptane n-Octane n-Decane n-Dodecane Isooctane Benzene

Wt. Ratio 12 17 17 12 5 12 1

Wt. Compound Ratio Toluene 9 Ethylbenzene 3 m-Xylene 3 o-Xylene 3 1,2,4-Trimethylbenzene 3 1,2,4,5-Tetramethylbenzene 3

4 Comp. Deuterated Internal Std. Mix

13 Comp. Core Mix 100 Includes M-GRA-IS-R (4 Comp. Internal Standards Mix) combined with the above 13 Comp. Core QC Mix: M-GRA-QC in a 12 to 100 weight ratio. 17 comps.

M-GRA-IS-R-10ML $ 225 / 1 x 10 mL M-GRA-IS-R-10ML-PAK SAVE 20% $ 900 / 5 x 10 mL 4 comps.

ASTM/EPA Sensitivity Test Solution

13 Comp. Core Mix

Compound Mix Ratio 2 mL Benzene-d6 Ethylbenzene-d10 2 mL

100

Compound Mix Ratio Naphthalene-d8 1 gm Toluene-d8 7 mL

Technical Note

M-GRA-ST M-GRA-ST-PAK 100 µg/mL in Isooctane

Standards of Interest For the mandatory real world QC samples stipulated in the Method, see pages 1-2

$ 10 / 1 x 1 mL SAVE 20% $ 40 / 5 x 1 mL

1,4-Diethyl benzene

Use with any M-GRA Calibration Curve.

Fax 203-786-5287 • Toll Free 800-442-5290 / 203-786-5290 • Website www.accustandard.com

45

Method

ASTM Standards

5769

Member

Originally designed for D-5769-98

ASTM

ASTM D-5769 Version with No Internal Standard The following D-5769 and M-GRA Standards were formulated to address proposed and promulgated changes to ASTM Method D-5769-98 Aromatics by GC/MS. Many of these changes were evaluated and/ or adopted due to the results generated from the 1997 Round Robin, which used a select group of 21 gasolines ampulized by AccuStandard. AccuStandard is committed to staying abreast of ASTM committee D-02 method developments. We ask that you contact us when your analytical group finds a beneficial procedure or modification. Modifications A Sixth Standard was added to meet the latest D-5769 method requirements and provide improved linearity at the high end of the Calibration curve The Calibration Curve was packaged in two convenient sizes without the internal standard. This packaging scheme allows for the addition of any ISTD formulation or oxygenate components. The Quality Control Standard was reformulated in the latest D-5769 revision. The formulation changes include reducing the 1,2,4,5-Tetramethylbenzene weight ratio and adding Naphthalene. The Benzene Target Weight % has been increased to meet the latest D-5769 method requirements. Pentamethylbenzene has now been removed from the analyte list.

Calibration Curve with No Internal Std. Added

Optional Sixth Standard

D-5769-CAL-SET-5ML D-5769-CAL-SET-10ML

D-5769-ADD-5ML D-5769-ADD-10ML

$ 1500 / Set of 5 x 5 mL $ 2750 / Set of 5 x 10 mL

$ 150 / 1 x 5 mL $ 300 / 1 x 10 mL

Std. 1 Target Wt. %

Std. 2 Wt. %

Std. 3 Wt. %

Std. 4 Wt. %

Std. 5 Wt. %

Core Calibration Mix 23 Comps.

Benzene 5.25 Toluene 19.67 Ethylbenzene 5.18 m-Xylene 6.19 p-Xylene 6.19 o-Xylene 6.30 Isopropylbenzene 3.09 n-Propylbenzene 3.09 3-Ethyltoluene 3.10 4-Ethyltoluene 3.08 1,3,5-Trimethylbenzene 3.10 2-Ethyltoluene 3.15 1,2,4-Trimethylbenzene 5.23 1,2,3-Trimethylbenzene 3.20 Indan 3.45 1,4-Diethylbenzene 3.09 n-Butylbenzene 3.08 1,2-Diethylbenzene 3.15 1,2,4,5-Tetramethylbenzene 2.12 1,2,3,5-Tetramethylbenzene 2.12 Naphthalene 2.37 1-Methylnaphthalene 2.37 2-Methylnaphthalene 2.43 Isooctane -----

2.95 11.06 2.91 3.48 3.48 3.54 1.74 1.74 1.74 1.73 1.74 1.77 2.94 1.80 1.94 1.74 1.73 1.77 1.19 1.19 1.34 1.34 1.37 43.77

1.575 5.898 1.552 1.856 1.856 1.890 0.925 0.926 0.928 0.925 0.929 0.945 1.567 0.960 1.034 0.925 0.923 0.945 0.635 0.637 0.712 0.712 0.730 70.015

0.8144 3.0505 0.8026 0.9598 0.9598 0.9776 0.4786 0.4787 0.4801 0.4782 0.4804 0.4890 0.8104 0.4965 0.5350 0.4786 0.4776 0.4885 0.3284 0.3295 0.3683 0.3683 0.3773 84.4922

0.4143 1.5519 0.4083 0.4883 0.4883 0.4973 0.2435 0.2435 0.2442 0.2433 0.2444 0.2488 0.4123 0.2526 0.2722 0.2435 0.2430 0.2485 0.1671 0.1676 0.1874 0.1874 0.1919 92.1105

Benzene 4.16 Toluene 16.41 Ethylbenzene 4.10 m-Xylene 4.91 p-Xylene 4.91 o-Xylene 5.00 Isopropylbenzene 2.45 n-Propylbenzene 2.45 3-Ethyltoluene 2.45 4-Ethyltoluene 2.44 1,3,5-Trimethylbenzene 2.46 2-Ethyltoluene 2.50 1,2,4-Trimethylbenzene 4.14 1,2,3-Trimethylbenzene 2.54 Indan 2.73 1,4-Diethylbenzene 2.45 n-Butylbenzene 2.44 1,2-Diethylbenzene 2.50 1,2,4,5-Tetramethylbenzene 1.68 1,2,3,5-Tetramethylbenzene 1.68 Naphthalene 1.88 1-Methylnaphthalene 1.88 2-Methylnaphthalene 1.93 Isooctane 19.92

Core Calibr. Mix 23 Comps.

4 Comp. Deuterated Internal Std. Mix M-GRA-IS-R-10ML $ 225 / 1 x 10 mL M-GRA-IS-R-10ML-PAK SAVE 20% $ 900 / 5 x 10 mL 4 comps. Mix Compound Ratio 2 mL Benzene-d6 Ethylbenzene-d10 2 mL

Mix Compound Ratio Naphthalene-d8 1 gm Toluene-d8 7 mL

3 Comp. Deuterated Internal Std. Mix M-GRA-IS-5ML M-GRA-IS-5ML-PAK Compound Benzene-d6 Ethylbenzene-d10 Naphthalene-d8

46

$ 150 / 1 x 5 mL SAVE 20% $ 600 / 5 x 5 mL 3 comps. Mix Ratio 2 mL 2 mL 1 gm

Target Wt. %

Disk Deliverable (At no additional charge) Eliminates hand keyed-in data. ®

CALAMTS

(Disk containing “Calibration Amounts”)

Each analyte in each standard is individually weighed. Actual weights and weight percents are provided.

Daily Quality Control Standard (without Internal Standard) D-5769-QC-10ML $ 125 / 1 x 10 mL D-5769-QC-10ML-PAK SAVE 20% $ 500 / 5 x 10 mL Compound n-Hexane n-Heptane n-Octane n-Decane n-Dodecane Isooctane Benzene

Wt. Ratio 12 17 17 12 5 12 1

Wt. Compound Ratio Toluene 9 Ethylbenzene 3 m-Xylene 3 o-Xylene 3 1,2,4-Trimethylbenzene 3 1,2,4,5-Tetramethylbenzene 2 Naphthalene 1 14 Comp. Core Mix

100

Quality System is Certified to comply with the International ISO 9001 Quality Standard

ASTM Standards

Method

5769

Member

Originally designed for D-5769-98

ASTM D-5769 Version with 3 Internal Standards Optional Sixth Standard with a 3 Comp. Deuterated Internal Standard added

D-5769-CAL/IS-SET

D-5769-ADD/IS

$ 375 / 5 x 1 mL

$ 100 / 1 x 1 mL

Std. 1 Target Wt. %

Std. 2 Wt. %

Std. 3 Wt. %

Std. 4 Wt. %

Std. 5 Wt. %

Core Calibration Mix 24 Comps.

Benzene 5.25 Toluene 19.67 Ethylbenzene 5.18 m-Xylene 6.19 p-Xylene 6.19 o-Xylene 6.30 Isopropylbenzene 3.09 n-Propylbenzene 3.09 3-Ethyltoluene 3.10 4-Ethyltoluene 3.08 1,3,5-Trimethylbenzene 3.10 2-Ethyltoluene 3.15 1,2,4-Trimethylbenzene 5.23 1,2,3-Trimethylbenzene 3.20 Indan 3.45 1,4-Diethylbenzene 3.09 n-Butylbenzene 3.08 1,2-Diethylbenzene 3.15 1,2,4,5-Tetramethylbenzene 2.12 1,2,3,5-Tetramethylbenzene 2.12 Naphthalene 2.37 1-Methylnaphthalene 2.37 2-Methylnaphthalene 2.43 Isooctane -----

2.95 11.06 2.91 3.48 3.48 3.54 1.74 1.74 1.74 1.73 1.74 1.77 2.94 1.80 1.94 1.74 1.73 1.77 1.19 1.19 1.34 1.34 1.37 43.77

1.575 5.898 1.552 1.856 1.856 1.890 0.925 0.926 0.928 0.925 0.929 0.945 1.567 0.960 1.034 0.925 0.923 0.945 0.635 0.637 0.712 0.712 0.730 70.015

0.8144 3.0505 0.8026 0.9598 0.9598 0.9776 0.4786 0.4787 0.4801 0.4782 0.4804 0.4890 0.8104 0.4965 0.5350 0.4786 0.4776 0.4885 0.3284 0.3295 0.3683 0.3683 0.3773 84.4922

0.4143 1.5519 0.4083 0.4883 0.4883 0.4973 0.2435 0.2435 0.2442 0.2433 0.2444 0.2488 0.4123 0.2526 0.2722 0.2435 0.2430 0.2485 0.1671 0.1676 0.1874 0.1874 0.1919 92.1105

Benzene Toluene Ethylbenzene m-Xylene p-Xylene o-Xylene Isopropylbenzene n-Propylbenzene 3-Ethyltoluene 4-Ethyltoluene 1,3,5-Trimethylbenzene 2-Ethyltoluene 1,2,4-Trimethylbenzene 1,2,3-Trimethylbenzene Indan 1,4-Diethylbenzene n-Butylbenzene 1,2-Diethylbenzene 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene Naphthalene 1-Methylnaphthalene 2-Methylnaphthalene Isooctane

Core Calibr. Mix 24 Comps.

Internal Standard Compound Benzene-d6 Ethylbenzene-d10 Naphthalene-d8

M-GRA-IS

Mix ratio 2 mL 2 mL 1 gm

Wt. % 3.0 3.0 94

Sulfur See Pages 6-11

M-GRA-IS-5ML M-GRA-IS-5ML-PAK Compound Benzene-d6 Ethylbenzene-d10 Naphthalene-d8

$ 150 / 1 x 5 mL SAVE 20% $ 600 / 5 x 5 mL 3 comps. Mix Ratio 2 mL 2 mL 1 gm

Sensitivity Test Solution M-GRA-ST M-GRA-ST-PAK 100 µg/mL in Isooctane

$ 10 / 1 x 1 mL SAVE 20% $ 40 / 5 x 1 mL

1,4-Diethyl benzene 100

Resolution Standard

1,3,5-Trimethylbenzene 1-Methyl-2-ethylbenzene Isooctane

Low ppb

3 Comp. Deuterated Internal Std. Mix

D-5769-QC/IS-5ML $ 100 / 1 x 5 mL D-5769-QC/IS-5ML-PAK SAVE 20% $ 400 / 5 x 5 mL 17 comps. Wt. Wt. Ratio Compound Ratio Compound 9 n-Hexane 12 Toluene 3 n-Heptane 17 Ethylbenzene 3 n-Octane 17 m-Xylene 3 n-Decane 12 o-Xylene 3 n-Dodecane 5 1,2,4-Trimethylbenzene Isooctane 12 1,2,4,5-Tetramethylbenzene 2 1 Benzene 1 Naphthalene

M-GRA-RES M-GRA-RES-PAK

4.16 16.41 4.10 4.91 4.91 5.00 2.45 2.45 2.45 2.44 2.46 2.50 4.14 2.54 2.73 2.45 2.44 2.50 1.68 1.68 1.88 1.88 1.93 19.92

Test to

The 3 Comp. Internal Standard Mix (M-GRA-IS) is combined with the 24 Comp. Core Calibration Curve Mixes above in a 5 to 100 weight ratio to formulate these 27 Comp. calibration solutions.

Daily Quality Control Standard (with Internal Standard)

Includes M-GRA-IS (3 component mix) added in 5 to 100 weight ratio

Target Wt. %

ASTM

Calibration Curve with a 3 Comp. Deuterated Internal Standard added

Fragmentation Pattern Standard $ 30 / 1 x 1 mL $ 120 / 5 x 1 mL 3 comps.

M-GRA-FP M-GRA-FP-PAK 3.0% w/w in Isooctane

$ 20 / 1 x 1 mL SAVE 20% $ 80 / 5 x 1 mL

1,2,3-Trimethylbenzene

Mass Scan Range Standard M-GRA-MSR M-GRA-MSR-PAK 3.0% w/w in Isooctane

$ 20 / 1 x 1 mL SAVE 20% $ 80 / 5 x 1 mL

Toluene

Fax 203-786-5287 • Toll Free 800-442-5290 / 203-786-5290 • Website www.accustandard.com

47

Method

ASTM Standards

5769

Member

Originally designed for D-5769-98

ASTM D-5769 4 Internal Standard Version (includes Toluene-d8)

ASTM

Calibration Curve with a 4 Comp. Deuterated Internal Standard added D-5769-CAL/IS-R-SET

$ 425 / 5 x 1 mL

Optional Sixth Standard with a 4 Comp. Deuterated Internal Standard added D-5769-ADD/IS-R

Core Calibr. Mix 24 Comps.

$ 100 / 1 x 1 mL

Std. 1 Target Wt. %

Std. 2 Wt. %

Std. 3 Wt. %

Std. 4 Wt. %

Std. 5 Wt. %

Core Calibration Mix 24 Comp.

Benzene 5.25 Toluene 19.67 Ethylbenzene 5.18 m-Xylene 6.19 p-Xylene 6.19 o-Xylene 6.30 Isopropylbenzene 3.09 n-Propylbenzene 3.09 3-Ethyltoluene 3.10 4-Ethyltoluene 3.08 1,3,5-Trimethylbenzene 3.10 2-Ethyltoluene 3.15 1,2,4-Trimethylbenzene 5.23 1,2,3-Trimethylbenzene 3.20 Indan 3.45 1,4-Diethylbenzene 3.09 n-Butylbenzene 3.08 1,2-Diethylbenzene 3.15 1,2,4,5-Tetramethylbenzene 2.12 1,2,3,5-Tetramethylbenzene 2.12 Naphthalene 2.37 1-Methylnaphthalene 2.37 2-Methylnaphthalene 2.43 Isooctane -----

2.95 11.06 2.91 3.48 3.48 3.54 1.74 1.74 1.74 1.73 1.74 1.77 2.94 1.80 1.94 1.74 1.73 1.77 1.19 1.19 1.34 1.34 1.37 43.77

1.575 5.898 1.552 1.856 1.856 1.890 0.925 0.926 0.928 0.925 0.929 0.945 1.567 0.960 1.034 0.925 0.923 0.945 0.635 0.637 0.712 0.712 0.730 70.015

0.8144 3.0505 0.8026 0.9598 0.9598 0.9776 0.4786 0.4787 0.4801 0.4782 0.4804 0.4890 0.8104 0.4965 0.5350 0.4786 0.4776 0.4885 0.3284 0.3295 0.3683 0.3683 0.3773 84.4922

0.4143 1.5519 0.4083 0.4883 0.4883 0.4973 0.2435 0.2435 0.2442 0.2433 0.2444 0.2488 0.4123 0.2526 0.2722 0.2435 0.2430 0.2485 0.1671 0.1676 0.1874 0.1874 0.1919 92.1105

Benzene Toluene Ethylbenzene m-Xylene p-Xylene o-Xylene Isopropylbenzene n-Propylbenzene 3-Ethyltoluene 4-Ethyltoluene 1,3,5-Trimethylbenzene 2-Ethyltoluene 1,2,4-Trimethylbenzene 1,2,3-Trimethylbenzene Indan 1,4-Diethylbenzene n-Butylbenzene 1,2-Diethylbenzene 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene Naphthalene 1-Methylnaphthalene 2-Methylnaphthalene Isooctane

Internal Standard M-GRA-IS-R

Compound Mix ratio 2 mL Benzene-d6 Ethylbenzene-d10 2 mL Naphthalene-d8 1 gm Toluene-d8 7 mL

Daily Quality Control Standard (with Internal Standard)

Compound n-Hexane n-Heptane n-Octane n-Decane n-Dodecane Isooctane Benzene

Wt. Compound Ratio Toluene 9 Ethylbenzene 3 m-Xylene 3 o-Xylene 3 1,2,4-Trimethylbenzene 3 1,2,4,5-Tetramethylbenzene 2 Naphthalene 1

Includes M-GRA-IS-R (4 component mix) added in 12 to 100 weight ratio

The 4 Comp. Internal Standard Mix (M-GRA-IS-R) is combined with the 24 component core calibration curve mixtures above in a 12 to 100 weight ratio to formulate these 28 component calibration solutions.

M-GRA-ST M-GRA-ST-PAK 100 µg/mL in Isooctane

$ 10 / 1 x 1 mL SAVE 20% $ 40 / 5 x 1 mL

1,4-Diethyl benzene

Resolution Standard M-GRA-RES M-GRA-RES-PAK

$ 30 / 1 x 1 mL SAVE 20% $ 120 / 5 x 1 mL 3 comps. Compound Wt. % 1,3,5-Trimethylbenzene 3.0 1-Methyl-2-ethylbenzene 3.0 Isooctane 94

100

4 Comp. Deuterated Internal Std. Mix

Fragmentation Pattern Standard

M-GRA-IS-R-10ML $ 225 / 1 x 10 mL M-GRA-IS-R-10ML-PAK SAVE 20% $ 900/ 5 x 10 mL

M-GRA-FP M-GRA-FP-PAK 3.0 w/w in Isooctane

Compound Mix Ratio Benzene-d6 2 mL Ethylbenzene-d10 2 mL

48

4.16 16.41 4.10 4.91 4.91 5.00 2.45 2.45 2.45 2.44 2.46 2.50 4.14 2.54 2.73 2.45 2.44 2.50 1.68 1.68 1.88 1.88 1.93 19.92

Sensitivity Test Solution

D-5769-QC/IS-R-5ML $ 100 / 1 x 5 mL D-5769-QC/IS-R-5ML-PAK SAVE 20% $ 400/5 x 5 mL 18 comps. Wt. Ratio 12 17 17 12 5 12 1

Target Wt. %

Compound Mix Ratio 1 gm Naphthalene-d8 Toluene-d8 7 mL

$ 20 / 1 x 1 mL SAVE 20% $ 80 / 5 x 1 mL

1,2,3-Trimethylbenzene

Quality System is Certified to comply with the International ISO 9001 Quality Standard

ASTM Standards

Method

5769

Member

Originally designed for D-5769-98

ASTM D-5769 New Proposed / Promulgated Method Modifications

D-5769-CAL/IS-R2-SET

$ 375 / 5 x 1 mL

Optional Sixth Standard with a 3 Comp. Chlorinated Internal Standard added D-5769-ADD/IS-R2

$ 100 / 1 x 1 mL

Std. 1 Target Wt. %

Std. 2 Wt. %

Std. 3 Wt. %

Std. 4 Wt. %

Std. 5 Wt. %

Core Calibration Mix 24 Component

Benzene 5.25 Toluene 19.67 Ethylbenzene 5.18 m-Xylene 6.19 p-Xylene 6.19 o-Xylene 6.30 Isopropylbenzene 3.09 n-Propylbenzene 3.09 3-Ethyltoluene 3.10 4-Ethyltoluene 3.08 1,3,5-Trimethylbenzene 3.10 2-Ethyltoluene 3.15 1,2,4-Trimethylbenzene 5.23 1,2,3-Trimethylbenzene 3.20 Indan 3.45 1,4-Diethylbenzene 3.09 n-Butylbenzene 3.08 1,2-Diethylbenzene 3.15 1,2,4,5-Tetramethylbenzene 2.12 1,2,3,5-Tetramethylbenzene 2.12 Naphthalene 2.37 1-Methylnaphthalene 2.37 2-Methylnaphthalene 2.43 Isooctane -----

2.95 11.06 2.91 3.48 3.48 3.54 1.74 1.74 1.74 1.73 1.74 1.77 2.94 1.80 1.94 1.74 1.73 1.77 1.19 1.19 1.34 1.34 1.37 43.77

1.575 5.898 1.552 1.856 1.856 1.890 0.925 0.926 0.928 0.925 0.929 0.945 1.567 0.960 1.034 0.925 0.923 0.945 0.635 0.637 0.712 0.712 0.730 70.015

0.8144 3.0505 0.8026 0.9598 0.9598 0.9776 0.4786 0.4787 0.4801 0.4782 0.4804 0.4890 0.8104 0.4965 0.5350 0.4786 0.4776 0.4885 0.3284 0.3295 0.3683 0.3683 0.3773 84.4922

0.4143 1.5519 0.4083 0.4883 0.4883 0.4973 0.2435 0.2435 0.2442 0.2433 0.2444 0.2488 0.4123 0.2526 0.2722 0.2435 0.2430 0.2485 0.1671 0.1676 0.1874 0.1874 0.1919 92.1105

Benzene Toluene Ethylbenzene m-Xylene p-Xylene o-Xylene Isopropylbenzene n-Propylbenzene 3-Ethyltoluene 4-Ethyltoluene 1,3,5-Trimethylbenzene 2-Ethyltoluene 1,2,4-Trimethylbenzene 1,2,3-Trimethylbenzene Indan 1,4-Diethylbenzene n-Butylbenzene 1,2-Diethylbenzene 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene Naphthalene 1-Methylnaphthalene 2-Methylnaphthalene Isooctane

Core Calibr. Mix 24 Comps.

Internal Standard M-GRA-IS-R2

Compound Mix ratio Chlorobenzene 2 mL 1,2-Dichlorobenzene 2 mL 1,2,4-Trichlorobenzene 1 mL

Daily Quality Control Standard (with Internal Standard)

Includes M-GRA-IS-R2 (3 component mix) added in 5 to 100 weight ratio

4.16 16.41 4.10 4.91 4.91 5.00 2.45 2.45 2.45 2.44 2.46 2.50 4.14 2.54 2.73 2.45 2.44 2.50 1.68 1.68 1.88 1.88 1.93 19.92

The 3 Comp. Internal Standard Mix (M-GRA-IS-R2) is combined with the 24 Comp. Core Calibration Curve mixtures above in a 5 to 100 weight ratio to formulate these 27 Comp. calibration solutions.

M-GRA-ST M-GRA-ST-PAK 100 µg/mL in Isooctane

Eliminates hand keyed-in data. ®

CALAMTS

(Disk containing “Calibration Amounts”)

Each analyte in each standard is individually weighed. Actual weights and weight percents are provided.

$ 10 / 1 x 1 mL SAVE 20% $ 40 / 5 x 1 mL

Standards of Interest

1,4-Diethyl benzene

Fragmentation Pattern Standard M-GRA-FP M-GRA-FP-PAK 3.0 w/w in Isooctane

Disk Deliverable (At no additional charge)

For the mandatory real world QC samples stipulated in the Method, see pages 1-2.

$ 20 / 1 x 1 mL SAVE 20% $ 80 / 5 x 1 mL

1,2,3-Trimethylbenzene

100

3 Comp. Chlorinated Internal Std. Mix M-GRA-IS-R2-SET M-GRA-IS-R2-25ML

Target Wt.%

Sensitivity Test Solution

D-5769-QC/IS-R2-5ML $ 100 / 1 x 5 mL D-5769-QC/IS-R2-5ML-PAKSAVE 20% $400/5 x 5 mL 17 comps. Wt. Wt. Compound Ratio Compound Ratio n-Hexane 12 Toluene 9 n-Heptane 17 Ethylbenzene 3 n-Octane 17 m-Xylene 3 n-Decane 12 o-Xylene 3 n-Dodecane 5 1,2,4-Trimethylbenzene 3 Isooctane 12 1,2,4,5-Tetramethylbenzene 2 Benzene 1 Naphthalene 1

ASTM

Calibration Curve with a 3 Comp. Chlorinated Internal Standard added

$125 / set of 25 x 1 mL $ 100 / 1 x 25 mL 3 comps. Compound Mix Ratio Chlorobenzene 2 mL 1,2-Dichlorobenzene 2 mL 1,2,4-Trichlorobenzene 1 mL

Resolution Standard M-GRA-RES M-GRA-RES-PAK

$ 30 / 1 x 1 mL SAVE 20% $ 120 / 5 x 1 mL 3 comps. Compound Wt. % 1,3,5-Trimethylbenzene 3.0 1-Methyl-2-ethylbenzene 3.0 Isooctane 94

Fax 203-786-5287 • Toll Free 800-442-5290 / 203-786-5290 • Website www.accustandard.com

49

Method

ASTM Standards

5769

Member

Originally designed for D-5769-98

ASTM

ASTM D-5769 Special QA/QC Formulations Daily Quality Control Standard (without Internal Standard)

Technical Note

M-GRA-QC-R-10ML $ 125 / 1 x 10 mL M-GRA-QC-R-10ML-PAK SAVE 20% $ 500 / 5 x 10 mL Compound n-Hexane n-Heptane n-Octane n-Decane n-Dodecane Isooctane Benzene Toluene

Wt. Ratio 12 17 17 12 5 12 1 9

Wt. Compound Ratio Ethylbenzene 3 m-Xylene 3 o-Xylene 3 1,2,4-Trimethylbenzene 3 1,2,4,5-Tetramethylbenzene 1 Pentamethylbenzene 1 1-Methylnaphthalene 1 15 Comp. Core Mix

Specially formulated Daily Quality Control Standards originally designed in response to client requests for QC mixes that bracket the curve and contain more C9+ analytes to verify the instrument and QC solution integrity.

Save 20-40% Buy AccuPAKs

100

For use with any M-GRA Calibration Curve

Daily Quality Control Standard (with Internal Standard M-GRA-IS)

Daily Quality Control Standard (with Internal Std. M-GRA-IS-R)

M-GRA-QC-R/IS-5ML $ 100 / 1 x 5 mL M-GRA-QC-R/IS-5ML-PAK SAVE 20% $ 400 / 5 x 5 mL 18 comps. Wt. Wt. Compound Ratio Compound Ratio n-Hexane 12 Ethylbenzene 3 n-Heptane 17 m-Xylene 3 n-Octane 17 o-Xylene 3 n-Decane 12 1,2,4-Trimethylbenzene 3 n-Dodecane 5 1,2,4,5-Tetramethylbenzene 1 Isooctane 12 Pentamethylbenzene 1 Benzene 1 1-Methylnaphthalene 1 Toluene 9

M-GRA-QC-R/IS-R-5ML $ 125 / 1 x 5 mL M-GRA-QC-R/IS-R-5ML-PAK SAVE $ 500 / 5 x 5 mL 19 comps. Wt. Wt. Ratio Compound Ratio Compound 3 n-Hexane 12 Ethylbenzene 3 n-Heptane 17 m-Xylene 3 n-Octane 17 o-Xylene 3 n-Decane 12 1,2,4-Trimethylbenzene n-Dodecane 5 1,2,4,5-Tetramethylbenzene 1 1 Isooctane 12 Pentamethylbenzene 1 Benzene 1 1-Methylnaphthalene Toluene 9 100 Includes M-GRA-IS-R (4 Comp. Internal Standards mix) combined with the above 15 Comp. Core QC Mix: M-GRA-QC-R in a 12 to 100 Wt. ratio

Includes M-GRA-IS (3 Comp. Internal Standards Mix) combined with the above 15 Comp. Core QC Mix: M-GRA-QC-R in a 5 to 100 weight ratio

100

3 Comp. Deuterated Internal Std. Mix

4 Comp. Deuterated Internal Std. Mix

M-GRA-IS-5ML M-GRA-IS-5ML-PAK

M-GRA-IS-R-10ML $ 225 / 1 x 10 mL M-GRA-IS-R-10ML-PAK SAVE 20% $ 900 / 5 x 10 mL 4 comps. Compound Mix Ratio 2 mL Benzene-d6 Ethylbenzene-d10 2 mL Naphthalene-d8 1 gm Toluene-d8 7 mL

Compound Benzene-d6 Ethylbenzene-d10 Naphthalene-d8

$ 150 / 1 x 5 mL SAVE 20% $ 600 / 5 x 5 mL 3 comps. Mix Ratio 2 mL 2 mL 1 gm

AccuPAK

Reduce reordering frequency Reduce data entry time for Calibration tables due to Lot No. consistency Economical

Custom Ampulling for Bulk Quantity Requirements Volumes from 0.2 mL to 20 mL • Fill Flammables • QC Services available •

AccuStandard has the resources and equipment to meet your custom packaging requirements. Our full automated filler-sealer can accommodate a fill range from 0.5 to 20 mL, and ampule sizes from 1 mL to 20 mL. AccuStandard has extensive experience with Round Robin samples for ASTM committees. Call our Technical Department for a quotation.

50

®

Quality System is Certified to comply with the International ISO 9001 Quality Standard

ASTM Standards

Method

5769

Member

Through a collaborative effort involving the instrument manufactures, Petrochemical end users, and Chemical Reference Standard manufacturers, the following proposed D-5769 method is under consideration. A number of end users would like to evaluate this proposed D-5769 method and have asked AccuStandard to make the standards. We have formulated the following certified standards to meet those requests.

ASTM D-5769-XX Calibration Curve with No Internal Standard Added ASTM-P-0140-SET

$ 1500 / Set of 5 x 5 mL

05 014 -0 -P M ST A 04 014 -0 -P M ST 03 A 014 -0 -P M ST 02 A 014 -0 -P M ST 01 A 014 -0 -P M ST A

Core Calibr. Mix Level 1 Compound Target Mass %

Level 2 Level 3 Level 4 Level 5 Mass % Mass % Mass % Mass %

Benzene 5 Toluene 12 Ethylbenzene 5 1,3-Dimethylbenzene 10 1,4-Dimethylbenezene 5 1,2-Dimethylbenezene 5 (1-Methylethyl)-benzene 3 1-Methyl-3-ethylbenzene 3 1-Methyl-4-ethylbenzene 3 1,3,5-Trimethylbenzene 3 1-Methyl-2-ethylbenzene 3 1,2,4-Trimethylbenzene 6 1,2,3-Trimethylbenzene 3 Indan 3 1,2-Diethylbenzene 2 2 NaphthaleneA A 2-Methylnaphthalene 2 1-MethylnaphthaleneA 2 Isooctane (solvent) * balance

3 9 3.75 7.5 3.75 3.75 2.25 2.25 2.25 2.25 2.25 4.5 2.25 2.25 1.5 1.5 1.5 1.5 balance

1 6 2.5 5 2.5 2.5 1.5 1.5 1.5 1.5 1.5 3 1.5 1.5 1 1 1 1 balance

0.5 3 1.25 2.5 1.25 1.25 0.75 0.75 0.75 0.75 0.75 1.5 0.75 0.75 0.5 0.5 0.5 0.5 balance

0.1 0.5 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.1 0.1 0.1 balance

A = This component is a solid at room temperature

Technical Note

4 Comp. Deuterated Internal Std. Mix

4 Comp. Deuterated Internal Std. Mix

ASTM-P-0140-IS ASTM-P-0140-IS-PAK

ASTM-P-0140-IS2 ASTM-P-0140-IS2-PAK

Compound Mass % Benzene-d6 2 Ethylbenzene-d10 2

$ 75 / 1 x 10 mL $ 300 / 5 x 10 mL 4 comps. Compound Mass % Naphthalene-d8 1 Isooctane * balance

Compound Mass % Benzene-d6 2 Ethylbenzene-d10 2

$ 95 / 1 x 10 mL $ 380 / 5 x 10 mL 5 comps. Compound Mass % Naphthalene-d8 1 Toluene-d8 7 Isooctane * balance

Performance Evalutation Standard

Composition of Daily QC Standard

ASTM-P-0140-PES ASTM-P-0140-PES-PAK

ASTM-P-0140-QC ASTM-P-0140-QC-PAK

$ 55 / 1 x 1 mL $ 220 / 5 x 1 mL 11 comps. Target

Compound Mass % Benzene 1 1,2-Diethylbenzene 0.005 1,3,5-Trimethylbenzene 1 1-Methyl-2-ethylbenzene 1 Styrene 0.1 Indene 0.1 Biphenyl 0.1 1,2,4,5-Tetramethylbenzene 1 1,2,3,5-Tetramethylbenzene 1 Hexadecane 1 Isooctane:Toluene(1:1) * balance

Compound Benzene Toluene Ethylbenzene 1,3-Dimethylbenzene 1,2-Dimethylbenzene 1,2,4-Trimethylbenzene 1,2-Diethylbenzene Naphthalene Isooctane (solvent) *

* The isooctane balance is the amount of material to make up a 100 mL calibration standard. Certificate will reflect actual weight of each component in the 100 mL batch including the isooctane.

$ 125 / 1 x 10 mL $ 500 / 5 x 10 mL 9 comps. Target Mass % 1 10 3 6 3 3 0.02 1 balance

Fax 203-786-5287 • Toll Free 800-442-5290 / 203-786-5290 • Website www.accustandard.com

51

ASTM

Summary Proposed Modifications for D-5769 • Calibration standards when combined with internal standards are diluted into significantly more isooctane. • The analytes in the Performance Standard have been expanded to better tune the GC/MS system for optimum performance. • The number of components in the QA/QC mix has been reduced with new QA/QC tolerances. • The number of analytes in the calibration mix has been reduced. • Samples that exceed the linear range are to be diluted, reducing the number of extra calibration points required.

Method

ASTM Standards

5771 5772 5773 5863

Member

ASTM D-5771 Cloud Point of Petroleum Products

ASTM

See page 5 for AccuStandard’s comprehensive line of certified Cloud Point Standards.

ASTM D-5772 Cloud Point of Petroleum Products (Linear Cooling Rate Method) See page 5 for AccuStandard’s comprehensive line of certified Cloud Point Standards.

ASTM D-5773 Cloud Point of Petroleum Products (Constant Cooling Rate Method)

WEAR METALS

See page 5 for AccuStandard’s comprehensive line of certified Cloud Point Standards.

ASTM D-5863

Nickel, Vanadium, Iron, & Sodium in Crude Oils & Residual Fuels by Flame AA Spectrometry

Originally designed for D-5863-00

Test Method A - Sample Decomposition with Acid for Total Ni, V and Fe Determination Stock Multi-Element Matrix Blank Aqueous Standard Nitric Acid Blank D-5863-95A-10X-1 2-5% HNO3 Iron Nickel

µg/mL 100 200

$ 75 / 1 x 100 mL 3 comps. Vanadium

µg/mL 200

CLP-BLN-5 CLP-BLN-L

$ 30 / 500 mL SAVE 33% $ 45 / L (2 x 500 mL)

5% HNO3 in ASTM Type I Water

Individual High Concentration Elements in Aqueous Matrix Element

Matrix

Iron

Fe

1,000 µg/mL Conc. Cat. No. Price

Unit 500 mL

ICP-27N-5

$ 67

in HNO3 Nickel

Ni in HNO3

500 mL

ICP-37N-5

67

Vanadium

V2O5

500 mL

ICP-67N-5

67

Standards of Interest See page 73-75 for additional Trace Metal Standards by AA.

in HNO3

Test Method B - Sample Dilution with Organic Solvent for the Determination of Ni, V and Na using Oil-Soluble Metals as Calibrants. Stock Multi-Element Standard in Mineral Oil D-5863-95B-10X At stated conc. in 20 cst Mineral Oil Sodium Nickel

52

µg/g 50 200

Vanadium

$ 160 / 1 x 4 oz 3 comps. µg/g 150

Standards of Interest See pages 59-65 for AccuStandard’s comprehensive line of Certified Oil Dissolved Wear Metal calibration standards designed for flame AA Applications.

Quality System is Certified to comply with the International ISO 9001 Quality Standard

ASTM Standards

Method

5901 5986

Member

ASTM D-5901 Freezing Point Aviation Fuels (Automated Optical Method) Standards of Interest See page 5 for AccuStandard’s comprehensive line of Certified Freezing Point Standards.

ASTM D-5972 Freezing Point Aviation Fuels (Automated Phase Transition Method) See page 5 for AccuStandard’s comprehensive line of Certified Freezing Point Standards.

ASTM D-5986 Oxygenates, Benzene, Toluene, C8-C12, Aromatics & Total Aromatics in Finished Gasolines by GC/FTIR Technical Note

Daily Quality Control Standard (without Internal Standard) M-GRA-QC-10ML $ 125 / 1 x 10 mL M-GRA-QC-10ML-PAK SAVE 20% $ 500 / 5 x 10 mL Compound n-Hexane n-Heptane n-Octane n-Decane n-Dodecane Isooctane Benzene

Wt. Ratio 12 17 17 12 5 12 1

Wt. Compound Ratio Toluene 9 Ethylbenzene 3 m-Xylene 3 o-Xylene 3 1,2,4-Trimethylbenzene 3 1,2,4,5-Tetramethylbenzene 3 13 Comp. Core Mix

AccuStandard formulated this quality control standard to meet Section 11 of ASTM D-5986-96 specifications stipulating to “analyze the quality control reference material before every batch of samples. Bracket the samples with the reference materials”. Oxygenate QC samples are available on pages 1- 2 or can be custom formulated.

Originally designed for D-5986-96

Standards of Interest See page 34 for AccuStandard’s Oxygenate Calibration Curve (Cat. No. M-GRO-CAL-SET) and page 46 for AccuStandard’s Aromatic Calibration Curve (Cat. No. D-5769-CAL-SET-5ML).

100

Cross Reference Table ASTM IP ISO DIN JIS AFNOR sorted by ASTM Method see beginning of Catalog

Fax 203-786-5287 • Toll Free 800-442-5290 / 203-786-5290 • Website www.accustandard.com

53

ASTM

Also see Cloud Point standards used for ASTM Method D-2500 on page 5.

Method

ASTM Standards

6160 6258 6277

Member

Originally designed for D-6160-98

ASTM D-6160 Polychlorinated Biphenyls (PCBs in Waste Materials by GC) SAVE 20% in PAK

ASTM

Aroclor Solutions (Individual and Kit) Aroclor #

(35 µg/mL in Isooctane) Cat. No.

(35 µg/mL in MeOH) Cat. No.

(35 µg/mL in Hexane) Cat. No.

Aroclor Aroclor Aroclor Aroclor Aroclor Aroclor Aroclor Aroclor Aroclor

C-216S C-221S C-232S C-242S C-248S C-254S C-260S C-262S C-268S

C-216S-M C-221S-M C-232S-M C-242S-M C-248S-M C-254S-M C-260S-M C-262S-M C-268S-M

C-216S-H-10X C-221S-H-10X C-232S-H-10X C-242S-H-10X C-248S-H-10X C-254S-H-10X C-260S-H-10X C-262S-H-10X C-268S-H-10X

Z-008S

Z-008S-M

Z-008S-H-10X

1016 1221 1232 1242 1248 1254 1260 1262 1268

Kit of all 9 above

1 x 1 mL Price $ 15 15 15 15 15 15 15 15 15

Cat. No. Cat. Cat. Cat. Cat. Cat. Cat. Cat. Cat. Cat.

5 x 1 mL Price

#-PAK #-PAK #-PAK #-PAK #-PAK #-PAK #-PAK #-PAK #-PAK

$ 60 60 60 60 60 60 60 60 60

$ 78 / 9 x 1 mL

Additional Ready-to-Inject PCB Aroclor Calibration Curves available in our Organic Catalog

Originally designed for D-6258-98

ASTM D-6258 Solvent Red 164 Dye Concentration in Diesel Fuels Stock Solvent Red 26 Standard D-6258-CONC-5ML

$ 45 / 1 x 5 mL

Solvent Red 26 @ 300 µg/mL in Xylene

D-6258 Calibration Curve D-6258-CAL-SET-5ML

$ 125 / set of 6 x 5 mL Set includes the following Cat. No.’s

Cat. No.

Description

D-6258-BL D-6258-01 D-6258-02 D-6258-03 D-6258-04 D-6258-05

Xylene Blank Solvent Red 26 Solvent Red 26 Solvent Red 26 Solvent Red 26 Solvent Red 26

Unit Dye Dye Dye Dye Dye

@ @ @ @ @

3 6 9 12 15

µg/mL in µg/mL in µg/mL in µg/mL in µg/mL in

Xylene Xylene Xylene Xylene Xylene

1 1 1 1 1 1

x x x x x x

5 5 5 5 5 5

mL mL mL mL mL mL

ASTM D-6277 Benzene in Spark - Ignition Engine Fuels using Mid Infrared Spectroscopy See page 1 for AccuStandard’s QA/QC material reference in the method.

Member

54

Technical Note Solvent Red 26 is the azo dye standard against which the concentration of Solvent Red 164 is measured. The visible spectrum of Solvent Red 164 is virtually identical to the spectrum of Solvent Red 26.

AccuStandard is an active member in ASTM and strives to keep abreast of ASTM method revisions. If our listed formulation does not meet the most recent method revision, please contact Technical Support, ext. 117 for an updated product.

Quality System is Certified to comply with the International ISO 9001 Quality Standard

ASTM Standards

Method

6293 6296

Member

ASTM D-6293

Oxygenates & Paraffin, Olefin, Naphthene, Aromatics (O-PONA) Hydrocarbon types in Low-Olefin Spark-Ignition Engine Fuels by GC Originally designed for D-6293-98

O-PONA Olefin Mix

ASTM-P-0080 ASTM-P-0080-PAK

ASTM-P-0081 $ 45 / 1 x 1 mL ASTM-P-0081-PAK $ 180 / 5 x 1 mL At stated conc. in Hexane : Heptane (1:1) 5 comps. Wt./Wt. % 1-Pentene 5.0 1-Hexene 2.0 1-Heptene 2.0 1-Octene 2.0 1-Nonene 3.0

$ 135 / 1 x 1 mL SAVE 26% $ 500 / 5 x 1 mL 33 comps.

Wt./Wt. % Cyclopentane 1.5 n-Pentane 1.5 Cyclohexane 2.0 2,3-Dimethylbutane 2.0 n-Hexane 2.0 1-Hexene 1.5 Methylcyclohexane 3.5 4-Methyl-1-hexene 1.5 n-Heptane 3.0 cis-1,2-Dimethylcyclohexane 4.5 Isooctane 4.0 n-Octane 4.0 1,2,4-Trimethylcyclohexane 3.5 n-Nonane 3.0 n-Decane 3.5 n-Undecane 2.0 n-Dodecane 2.0

Wt./Wt. % Benzene 2.5 Toluene 2.5 trans-Decahydronaphthelene 3.5 n-Tetradecane 2.0 Ethylbenzene 3.5 o-Xylene 3.0 n-Propylbenzene 3.5 1,2,4-Trimethylbenzene 3.0 1,2,3-Trimethylbenzene 2.0 1,2,4,5-Tetramethylbenzene 2.0 Pentamethylbenzene 2.5 Ethanol 5.0 t-Butanol 4.0 MtBE 8.0 ETBE 3.0 TAME 5.0

ASTM

O-PONA System Validation Mixture

O-PONA Paraffin Mix ASTM-P-0082 $ 25 / 1 x 1 mL ASTM-P-0082-PAK $ 100 / 5 x 1 mL At stated conc. in Hexane : Heptane (1:1) 2 comps. Wt./Wt. % n-Nonane 5.0 n-Decane 2.0

O-PONA Paraffin Mix Standards of Interest

ASTM-P-0082-R1 $ 25 / 1 x 1 mL ASTM-P-0082-R1-PAK $ 100 / 5 x 1 mL At stated conc. in Hexane : Heptane (1:1) 2 comps.

For the mandatory real world QC samples stipulated in QA/QC section 8.6 of the method see pages 1-2.

Wt./Wt. % 3.0 3.0

n-Nonane n-Decane

ASTM D-6296 Total Olefins in Spark-Ignition Engine Fuels by Multidimensional GC

Originally designed for D-6296-98

System Setup & Verification Standards D-6296-VER-SET $ 40 / 2 x 1 mL Set contains 1 ampule of each Cat. No. listed below D-6296-VER-SET-PAK SAVE 23% $ 150 / 5 x (2 x 1 mL) 5 sets containing 1 ampule of each Cat. No. listed below

System Setup & Verification Standards

System Setup & Verification Standards

D-6296-VER1

D-6296-VER2

1 x 1 mL 2 comps.

Wt. % 5% 95%

MTBE Isooctane

1 x 1 mL 2 comps.

Wt. % 5% 95%

ETBE Isooctane

Calibration Standard with MTBE

Calibration Standard with ETBE

D-6296-CAL1 D-6296-CAL1-PAK

D-6296-CAL2 D-6296-CAL2-PAK

Pentene Hexene Heptene Octene Nonene

Wt. % 1.0 1.0 1.0 1.0 1.0

$ 65 / 1 x 1 mL SAVE 23% $ 250 / 5 x 1 mL 10 comps. Decene Undecane Dodecane Isooctane MTBE

Wt. % 1.0 1.0 1.0 87.0 5.0

Pentene Hexene Heptene Octene Nonene Decene

Wt. % 1.0 1.0 1.0 1.0 1.0 1.0

$ 65 / 1 x 1 mL SAVE 23% $ 250 / 5 x 1 mL 11 comps. Decane Undecane Dodecane Isooctane ETBE

Wt. % 1.0 1.0 1.0 86.0 5.0

Isooctane Blank Compensation Standard D-6296-BL

$ 15 / 1 x 5 mL

Isooctane (Neat)

Fax 203-786-5287 • Toll Free 800-442-5290 / 203-786-5290 • Website www.accustandard.com

55

Method

ASTM Standards

6304 6334 6352

Member

ASTM

ASTM D-6304

Determination of Water in Petroleum Products Lubricating oil, and additives by Coulometric Karl Fischer Titration

See page 5 for AccuStandard’s comprehensive line of Certified Water Standards, for Karl Fischer Analysis.

ASTM D-6334

Sulfur in Gasoline by Wavelength Dispersive X-Ray Fluorescence

See Sulfur Standards Group listing in the Table of Contents for AccuStandard’s comprehensive line of Certified Sulfur Calibration Standards.

ASTM D-6352 Boiling Range Distribution of Petroleum Distillates from 174 to 700ºC by GC Polywax 850®

Polywax 500® ASTM-P-0051N-2G

$ 20 / 2 grams

ASTM-P-0137N-2G

Contact AccuStandard’s Technical Department regarding the availability of a QA/QC Reference Oil Sample under development in ASTM.

Polywax 1000®

Polywax 655® $ 20 / 2 grams

ASTM-P-0138N-2G

$ 20 / 2 grams

Polywax 1000

Polywax 655

Calibration Mix

Hydrocarbon Window Defining Standard* DRH-008S-R2 $ 65 / 1 x 1 mL DRH-008S-R2-PAK SAVE 20% $ 260 / 5 x 1 mL 500 µg/mL each in Chloroform 35 comps. Octane Nonane Decane Undecane Dodecane Tridecane Tetradecane Pentadecane Hexadecane Heptadecane Octadecane Pristane

Standards of Interest

$ 20 / 2 grams

Polywax 850

Polywax 500

ASTM-P-0053N-2G

Originally designed for D-6352-98

Nonadecane Phytane Eicosane Heneicosane Docosane Tricosane Tetracosane Pentacosane Hexacosane Heptacosane Octacosane Nonacosane

Triacontane n-Hentriacontane Dotriacontane Tritriacontane Tetratriacontane Pentatriacontane Hexatriacontane Heptatriacontane Octatriacontane Nonatriacontane Tetracontane

* Can be shipped by Air and Sea

ASTM D-6378

DRH-002N DRH-002N-10X Wt. % n-Hexane 6 n-Heptane 6 n-Octane 8 n-Nonane 8 n-Decane 12 n-Undecane 12 n-Dodecane 12 n-Tetradecane 12 n-Hexadecane 10

$ 10 / 100 mg $ 40 / 1 gm 17 comps. Wt. n-Octadecane n-Eicosane n-Tetracosane n-Octacosane n-Dotriacontane n-Hexatriacontane n-Tetracontane n-Tetratetracontane

% 5 2 2 1 1 1 1 1

Column Test Mixture ASTM-D2887 1% v/v in n-Octane n-Hexadecane

$ 10 / 1 x 1 mL 2 comps. n-Octadecane

Vapor Pressure (VPx) of Petroleum Products, Hydrocarbons, & Hydrocarbon-Oxygenate Mixtures (Triple Expansion Method)

See pages 29 & 32 for AccuStandard’s comprehensive line of Vapor Pressure Standards & Instrument Quality Control Samples.

56

Quality System is Certified to comply with the International ISO 9001 Quality Standard

ASTM Standards

Method

Member

ASTM D-6379

Aromatic Hydrocarbon Types in Aviation Fuels & Petroleum Distillates HPLC method with Refractive Index D-6379 Calibration Curve

D-6379-SRS $ 40 / 1 x 1 mL D-6379-SRS-PAK SAVE 30% $ 140 / 5 x 1 mL At stated Conc. in n-Heptane 3 comps.

D-6379-SET $ 100 / 4 x 1 mL D-6379-SET-PAK SAVE 30% $ 350 / 5 x (4 x 1 mL) At stated Conc. in n-Heptane

Cyclohexane o-Xylene 1-Methyl naphthalene

10 mg/mL 0.5 mg/mL 0.05 mg/mL

Analyte

Std. 1 (mg/mL)

Cyclohexane o-Xylene 1-Methyl naphthalene

D-6591 IP 391

Std. 2 (mg/mL)

Std. 3 (mg/mL)

Std. 4 (mg/mL)

2 5 1.0

0.5 1.0 0.2

0.1 0.1 0.05

5 15 5

Originally designed for D-6379-99

ASTM

System Resolution Standard

Aromatic Hydrocarbon Types in Middle Distillates HPLC method with Refractive Index Detection

System Performance Standard

IP 391-95 Calibration Curve

ASTM-P-0135 ASTM-P-0135-PAK SAVE 20% At stated Conc. in n-Heptane Cyclohexane o-Xylene Dibenzothiophene 9-Methylanthracene

ASTM-P-0136-SET At stated Conc. in n-Heptane

ASTM D-6417

$ 75 / 1 x 5 mL $ 300 / 5 x 5 mL 4 comps. 10 mg/mL 5.0 mg/mL 0.5 mg/mL 0.5 mg/mL

Analyte

$ 145 / 4 x 1 mL

Std. 1 (mg/mL)

Std. 2 (mg/mL)

Std. 3 (mg/mL)

Std. 4 (mg/mL)

50 40 40 4

20 10 10 2

5 2.5 2.5 0.5

1 0.5 0.2 0.1

Cyclohexane o-Xylene 1-Methyl naphthalene Phenanthrene

Standards of Interest

Estimation of Engine Oil Volatility by Capillary GC

See ASTM Methods D-3710, D-5307, D-5442, D-6352 for additional calibration standards for hydrocarbon analysis.

See page 15 for Alkane and Polywax standards suitable for D-6417.

ASTM D-6428

Sulfur by Combustion and Electrochemical Detection

D-6428-R1-4-SET D-6428-R1-SET Sulfur as Dibenzothiophene D-6428-R1-4-SET Cat. No.

Unit

D-6428-R1-SET Cat. No.

Sulfur Sulfur Sulfur Sulfur Sulfur Sulfur Sulfur

D-6428-BL-4 D-6428-0.1X-4 D-6428-0.5X-4 D-6428-1X-4 D-6428-2.5X-4 D-6428-5X-4 D-6428-10X-4

4 4 4 4 4 4 4

D-6428-BL D-6428-0.1X D-6428-0.5X D-6428-1X D-6428-2.5X D-6428-5X D-6428-10X

Blank @ 0.1 µg/g @ 0.5 µg/g @ 1.0 µg/g @ 2.5 µg/g @ 5.0 µg/g @ 10 µg/g

oz oz oz oz oz oz oz

D-6428-R2-4-SET D-6428-R2-SET Sulfur as Dibenzothiophene

Unit 1 1 1 1 1 1 1

mL mL mL mL mL mL mL

$ 275 / 6 x 4 oz $ 65 / 6 x 1 mL

Description

D-6428-R2-4-SET Cat. No.

Unit

D-6428-R2-SET Cat. No.

Sulfur Sulfur Sulfur Sulfur Sulfur Sulfur

D-6428-BL-4 D-6428-10X-4 D-6428-25X-4 D-6428-50X-4 D-6428-75X-4 D-6428-100X-4

4 4 4 4 4 4

D-6428-BL D-6428-10X D-6428-25X D-6428-50X D-6428-75X D-6428-100X

Blank @ 10 µg/g @ 25 µg/g @ 50 µg/g @ 75 µg/g @ 100 µg/g

NEW

$ 300 / 7 x 4 oz $ 65 / 7 x 1 mL

Description

oz oz oz oz oz oz

Unit 1 1 1 1 1 1

6379 IP 391 6417 6428

mL mL mL mL mL mL

Fax 203-786-5287 • Toll Free 800-442-5290 / 203-786-5290 • Website www.accustandard.com

57

Method

ASTM Standards

6443 6481 6550

Member

ASTM

ASTM D-6443

Cat. No.

Ca (Wt.%)

Cl (Wt.%)

Cu (Wt.%)

Mg (Wt.%)

P (Wt.%)

S (Wt.%)

Zn (Wt.%)

0.020 0.020 0.020 0.020 0.400 0.400 0.400 0.400 0.200 0.000

0.030 0.020 0.200 0.200 0.020 0.020 0.200 0.200 0.100 0.000

0.010 0.050 0.010 0.050 0.010 0.050 0.010 0.050 0.025 0.000

0.200 0.200 0.040 0.040 0.040 0.040 0.200 0.200 0.080 0.000

0.250 0.020 0.250 0.020 0.020 0.250 0.020 0.250 0.150 0.000

1.000 0.020 0.150 1.000 1.000 0.020 0.020 1.000 0.500 0.000

0.020 0.250 0.250 0.020 0.250 0.020 0.050 0.250 0.100 0.000

ASTM D-6445

Originally designed for D-6443-99

Standards of Interest

Lubricating Oil, Elements, WLXRF ASTM Method (Nominal Value) Wt.% listed below ASTM-P-0117-SET $ 2100 / 10 x 100 mL

ASTM-P-0117-01 ASTM-P-0117-02 ASTM-P-0117-03 ASTM-P-0117-04 ASTM-P-0117-05 ASTM-P-0117-06 ASTM-P-0117-07 ASTM-P-0117-08 ASTM-P-0117-09 ASTM-P-0117-10

WEAR METALS

Ca, Cl, Cu, Mg, P, S, Zn in Unused Lubricating Oils & Additives by Wavelength Dispersive X-ray Fluorescence & Spectrometry

See the Wear Metal Group listing in the Table of Contents for AccuStandard’s comprehensive line of Certified Oil Dissolved Wear Metal Calibration Standards.

Sulfur in Gasoline by ED - XRF

See the Sulfur Standards Group listing in the Table of Contents for AccuStandard’s comprehensive line of Certified Sulfur Calibration Standards.

ASTM D-6481

P, S, Ca and Zn in Lube Oils by ED-XRF

Originally designed for D-6481-99

Lubricating Oil, Elements, EDXRF ASTM Method (Nominal Value) Wt.% listed below ASTM-P-0114-SET $ 1900 / 17 x 100 mL Cat. No. ASTM-P-0114-01 ASTM-P-0114-02 ASTM-P-0114-03 ASTM-P-0114-04 ASTM-P-0114-05 ASTM-P-0114-06 ASTM-P-0114-07 ASTM-P-0114-08 ASTM-P-0114-09 ASTM-P-0114-10 ASTM-P-0114-11 ASTM-P-0114-12 ASTM-P-0114-13 ASTM-P-0114-14 ASTM-P-0114-15 ASTM-P-0114-16 ASTM-P-0114-17

Ca (Wt.%)

P (Wt.%)

S (Wt.%)

Zn (Wt.%)

0.005 0.600 0.000 1.000 0.000 0.005 0.500 0.010 0.050 0.100 0.200 0.400 0.600 0.800 1.000 0.400 0.000

0.005 0.000 0.300 0.000 0.000 0.250 0.150 0.200 0.010 0.150 0.200 0.005 0.100 0.010 0.300 0.050 0.000

0.050 0.000 0.000 1.000 0.000 0.800 0.500 0.100 0.400 0.200 0.800 0.800 0.500 0.050 1.000 0.600 0.000

0.050 0.000 0.000 0.000 0.300 0.300 0.150 0.250 0.075 0.200 0.100 0.300 0.050 0.100 0.150 0.250 0.000

ASTM D-6550 Olefin Content of Gasolines by SFC Stock Olefin Calibration Standard D-6550-CONC D-6550-CONC-5ML At stated Conc. by Wt. % Wt. % 1-Nonene 2.5 Cyclohexene 5 1-Hexene 5 1-Octene 5 1-Decene 5 2-Methyl-1,3-butadiene 5 4-Methyl-1-pentene 5 1,5-Hexadiene 3

58

$ 80 / 1 x 1 mL $ 350 / 1 x 5 mL 15 comps. Wt. % 3-Methyl-1,3-pentadiene 2 2-Methyl-1-butene 25 2-Methyl-2-pentene 10 1-Heptene 10 2-Methyl-1-octene 2.5 2-Methyl-1-heptene 5 5-Methyl-1-hexene 10

Originally designed for D-6550-00

Standards of Interest Technical Note AccuStandard worked in conjunction with the D-02 technical committee and Shell Oil to develop this stock Olefin Standard proven useful in creating the required calibration curve.

See page 2 for consensus value QA/QC material available for this method.

Quality System is Certified to comply with the International ISO 9001 Quality Standard

Organometallic Standards

Wear Metals

for AA, ICP, DCP & XRF Analysis These Standards were formulated for the analysis of metals in oils and other organic matrices. These Standards and curves provide a convenient way to analyze for metals (wear metals, additives and contaminants) in lubricating oils, gasolines, residual oils, crude oils, turbine fuels and environmental samples. All standards undergo rigorous quality assurance checks. Major constituents in the final Standard are typically analyzed by both plasma emission and rotrode techniques. Organometallic Standards listed on this page may contain sulfur which can be introduced by possible sulfonate starting materials used to formulate the actual organometallic standard. AccuStandard has developed a New Premium Organometallic line for those clients preferring to have organometallic standards with