SAFETY DATA SHEET according to EC directive 91/155/EEC
TERRALIN
2 l FL
No Change Service! Revision date 13.01.2006
Version 01. 01.04
Print Date 24.05.2006
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product information Trade name Producer/Supplier Producer/Supplier
: :
TERRALIN 2 l FL Schülke & Mayr UK Ltd. Cygnet House 1, Jenkin road S9 1AT South Yorkshire Great Britain Telephone: +441142543500 Telefax: +441142543501
[email protected] WWW.SCHULKE-MAYR.COM
Contact person
:
Product / Application advice +49 (0)40/ 521 00 666
Emergency telephone number
:
+49 (0)40 / 52 100 –0
Application
:
Disinfectants, Biocidal product, Biocidal product type: 2
2. COMPOSITION/INFORMATION COMPOSITION/INFORMATION ON INGREDIENTS Chemical nature
:
(Preparation)
Description
:
Solution of the following substances with harmless additives.
Components Components
CAS-No.
EC-No.
Symbol
Benzyl-C12-1868391-01-5 alkyldimethylammon ium, chlorides Propan-2-ol 67-63-0
269-919-4
C, N
200-661-7
F, Xi
Tridecylpolyethyleng 69011-36-5 lycolether Isodecanpolyethylen 61827-42-7 eglycol(11)ether
Polymer Polymer
Rphrase(s) R21/22, R34, R50
Xn
5 - 15 %
Xn
R22, R41
< 5%
3. HAZARDS IDENTIFICATION Risk advice to man and the environment ICAO-Labels / Indication of danger:
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Corrosive Harmful if swallowed. Causes burns. Page 1/1
20 %
R11, R36, R67 R22, R41
For the full text of the R phrases mentioned in this Section, see Section 16.
C R22 R34
Concentration
3- 8%
SAFETY DATA SHEET according to EC directive 91/155/EEC
TERRALIN
2 l FL
No Change Service! Revision date 13.01.2006
Version 01.04
Print Date 24.05.2006
4. FIRST AID MEASURES General advice Eye contact
: :
Skin contact Ingestion
: :
Take off all contaminated clothing immediately. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wash off immediately with plenty of water. Obtain medical attention.
5. FIRE-FIGHTING MEASURES Special protective equipment for fire-fighters Suitable extinguishing media Extinguishing media which must not be used for safety reasons Specific risk from the substance or the product itself, its combustion products or evolved gases
:
No special precautions required.
:
water, foam, dry powder, carbon dioxide (CO2)
:
No information available.
:
No special risks to be expected.
6. ACCIDENTAL RELEASE MEASURES Personal precautions
:
Environmental precautions
:
Methods for cleaning up
:
Increased risk of slipping in the presence of leaked / spilled product. Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration. Wipe up with absorbent material (e.g. cloth, fleece). Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).
7. HANDLING AND STORAGE Handling Safe handling advice
:
Advice on protection against fire and explosion
:
Prepare the working solution as given on the label(s) and/or the user instructions. The hot product gives off combustible vapours.
Storage Requirements for storage areas and containers Further information
:
Store at room temperature in the original container.
:
Advice on common storage
:
Keep container tightly closed. Protect from frost. Keep away from direct sunlight. Keep away from food and drink.
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SAFETY DATA SHEET according to EC directive 91/155/EEC
TERRALIN
2 l FL
No Change Service! Revision date 13.01.2006
Version 01.04
Print Date 24.05.2006
8. EXPOSURE CONTROLS / PERSONAL PROTECTION Components with workplace control parameters Components Propan-2-ol
CAS-No. 67-63-0
Propan-2-ol
67-63-0
Value MAK: 500 mg/m3 MAK: 200 ppm VLE: 980 mg/m3 VLE: 400 ppm
Basis TRGS 900 INRS
Personal protective equipment Hand protection
:
Eye protection Hygiene measures Protective measures
: : :
Splash protection: disposable nitrile rubber gloves e.g. Dermatril (Layer thickness: 0,11 mm) made by KCL or gloves from other manufacturers offering the same protection. Prolonged contact: Nitrile rubber gloves e.g. Camatril ( >480 Min., Layer thickness: 0,40 mm) or butyl rubber gloves e.g. Butoject (>480 Min., Layer thickness: 0,70 mm) made by KCL or gloves from other manufacturers offering the same protection. tightly fitting safety goggles Keep away from food and drink. Avoid contact with skin and eyes.
9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Colour Odour
: : :
liquid green pleasant
solidification range
:
< -5 °C
initial boiling point
:
ca. 80 °C
Flash point
:
52 °C Method: DIN 51755 Part 1
Vapour pressure
:
ca.25 hPa at 20 °C
Density
:
ca.1,015 g/cm3 at 20 °C
Water solubility
:
at 20 °C in all proportions
pH
:
ca.8,4 at 5 g/l ( 20 °C)
Viscosity, dynamic
:
ca.33 mPa*s at 20 °C Method: DIN 54453
Other data
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SAFETY DATA SHEET according to EC directive 91/155/EEC
TERRALIN
2 l FL
No Change Service! Revision date 13.01.2006
Version 01.04
Print Date 24.05.2006
10. STABILITY AND REACTIVITY Hazardous reactions
:
None reasonably foreseeable.
Hazardous decomposition products
:
None reasonably foreseeable.
11. TOXICOLOGICAL INFORMATION Acute oral toxicity
:
LD50 rat 1100 - 1250 mg/kg
Skin irritation
:
No skin irritation Method: OECD Test Guideline, 404
Sensitization
:
Did not cause sensitization on laboratory animals. Method: OECD Test Guideline, 406
Further information
:
Practical experience: Ingestion causes burns of the upper digestive and respiratory tracts.
12. ECOLOGICAL INFORMATION Biodegradability
:
Readily biodegradable. Method: OECD 301D / EEC 84/449 C6
Toxicity to bacteria
:
EC50 97 mg/l Method: OECD 209
Chemical Oxygen Demand (COD)
:
8600 mg/l Test substance: 0,5% solution
Further information
:
The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their direct request or at the r equest of a detergent manufacturer. Avoid subsoil penetration. Do not flush into surface water or sanitary sewer system.
13. DISPOSAL CONSIDERATIONS Product
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:
Dispose of the product according to the defined EWC (European Waste Code) No.
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SAFETY DATA SHEET according to EC directive 91/155/EEC
TERRALIN
2 l FL
No Change Service! Revision date 13.01.2006
Version 01.04
Print Date 24.05.2006
Contaminated packaging
:
Take empty packaging to the recycling plant.
Waste key for the unused product Waste key for the unused product(Group)
:
EWC 070699
:
Waste material of HZVA from fats, lubricants, soaps, detergents, disinfectants and personal protection products.
14. TRANSPORT INFORMATION
Further information
:
Not classified as supporting combustion according to the transport regulations. Not classified as dangerous in the meaning of transport regulations.
15. REGULATORY INFORMATION Hazardous components which must be listed on the label Benzyl-C12-18-alkyldimethylammonium, chlorides •
General advice
:
Symbol
:
The product is classified and labelled in accordance with EC directives or respective national laws.
R-phrase(s)
:
R22 R34
S-phrase(s)
:
S26
C Corrosive Harmful if swallowed. Causes burns.
S36/37/39 S45
Special labelling of certain preparations
:
Further information
:
Further information
:
Z11814
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
Labelling according to Regulation (EC) No. 648/2004: 5 - 15 % non-ionic surfactants, < 5 % phosphonates, perfumes LIMONENE; LINALOOL The classification as corrosive has been determined on the recommendation of the German Federal Institute f or Comsumer Protection and Veterinary Medicine (BgVV) due to severe burning effects on ingestion of larger amounts. The product is classified in accordance with Annex VI (2.2.5) to Directive 67/548/EEC. Use biocides safely. Always read the label and product Page 5/5
SAFETY DATA SHEET according to EC directive 91/155/EEC
TERRALIN
2 l FL
No Change Service! Revision date 13.01.2006
Version 01.04
Print Date 24.05.2006
information before use. National legislation Legislation on the control of major-accident hazards involving dangerous substances VOC-Content
:
Directive 96/82/EC does not apply
:
VOC-Content
:
5% Directive 1999/13 /EC on the limitation of emissions of volatile organic compounds 0,050 kg/kg Switzerland. VOC Ordinance, Annex II (Products)
16. OTHER INFORMATION Application
:
Information on uses can be found in a separate preparation / product brochure.
Text of R phrases mentioned in Section 2 R11 R21/22 R22 R34 R36 R41 R50 R67
Highly flammable. Harmful in contact with skin and if swallowed. Harmful if swallowed. Causes burns. Irritating to eyes. Risk of serious damage to eyes. Very toxic to aquatic organisms. Vapours may cause drowsiness and dizziness.
Other information Caution! All information concerns the concentrated product! The information given is only of use for possible safety requirements and is based on our actual knowledge. This information does not guarantee any properties. It is the responsibility of the receiver / user of our products to follow existing laws and regulations.
This safety datasheet complies with the requirements of Directive 2001/58/EC. Changes compared with the previous edition!!!
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