Jee 2014 Booklet4 Hwt Introduction to Organic Chemistry

Vidyamandir Classes

DATE :

  MARKS :    10 

IITJEE :

NAME :

TIME : 25 MINUTES

TEST CODE : IOC [1]

ROLL NO.

START TIME :

END TIME :

STUDENT’S SIGNATURE :

TIME TAKEN:

PARENT’S SIGNATURE :

 This test contains a total of 10 Objective Type Questions.  Each question carries 1 mark. There is NO NEGATIVE marking. Choose the correct alternative. Only one choice is correct. 1.

The IUPAC name of (A)

2.

3.

(B)

(B)

(C)

(D)

The IUPAC name of

pent-4-enoic acid

(D)

prop-2-enoic acid

is :

2-methyl-3-bromohexanal 2-bromo-3-bromobutanal

(B) (D)

3-bromo-2-methylbutanal 3-bromo-2-methylpentanal

(B) (D)

4-hydroxy-4-methylpent-2-en-l-al 2-hydroxy-3-methylpent-2-en-5-al

The IUPAC name of CH3  CH  CH  C  CHO is : (A) (C)

6.

(C)

(A)

| OH

5.

but-1-enoic acid

Which one of the following is s-butyl phynylvinyl methane?

(A) (C) 4.

but-3-enoic acid

is :

| CH3

4-hydroxy-1-methylpentanal 2-hydroxy-4-methylpent-3-en-5-al

The IUPAC name of acryldehyde (CH2 = CHCHO) is : (A) prop-2-en-l-ol (B) propenylaldehyde (C)

The IUPAC name of the compound, (A) (C)

but-2-en-l-al

(D)

propanenal

C2 H 5  C  CH 2 OH || is : CH 2

2-ethylprop-2-en-l-ol 2-methylenebutan-l-ol

VMC/Introduction to Organic Chemistry

(B) (D)

1

2-hydroxymethylbutan-l-ol 2-ethyl-3-hydroxyprop-l-ene

HWT/Chemistry

Vidyamandir Classes 7.

The IUPAC name of the following compound, is :

(A) (C) 8.

4-bromo-3-cyanophenol 2-cyano-4-hydroxybromobenzene

(B) (D)

2-bromo-5-hydroxybenzonitrile 6-bromo-3-hydroxybenzonitrile

(B) (D)

1-chloro-4-ethoxy-4-methylbutane ethyl-l-chloropentylether

Give the correct IUAC name for CH | CH3 .CH 2OCH.CH 2 .CH 2 .CH 2Cl (A) (C)

2-ethoxy-5-chloropentane 1-chloro-4-ethoxypentane

9.

Pick out the correct statement form the following and choose the correct answer from the codes given below : I. Prop-1, 2-diene is conjugated diene II. Hexa-1, 3-diene is conjugated diene III. Buta-1m 3-diene is an isolated diene IV. Prop-1, 2-diene is a cumulative diene (A) II, III (B) IV, V (C) II, V (D) III, V

10.

The correct decreasing order of priority for the functional groups of organic compounds in the IUPAC system of nomenclature is : (A) (B) COOH,  SO3H,  CONH 2 ,  CHO SO3H,  COOH, CONH 2 ,  CHO (C)

CHO,  COOH,  SO3H,  CONH 2

VMC/Introduction to Organic Chemistry

(D)

2

CONH 2 ,  CHO,  SO3H,  COOH

HWT/Chemistry

Vidyamandir Classes

DATE :

  MARKS :    10 

IITJEE :

NAME :

TIME : 25 MINUTES

TEST CODE : IOC [2]

ROLL NO.

START TIME :

END TIME :

STUDENT’S SIGNATURE :

TIME TAKEN:

PARENT’S SIGNATURE :

 This test contains a total of 10 Objective Type Questions.  Each question carries 1 mark. There is NO NEGATIVE marking. Choose the correct alternative. Only one choice is correct. 1.

The IUPAC name of (A) (C)

2.

3.

5.

6.

ethoxy propane 2-ethoxy iso-propane

(B) (D)

Cl | The IUPAC name for CH 3  C  CH 2  CH  CH  CH 3 is : | H (A) 5-chloro-hex-2-ene (B) (C) 1-chloro-1-methyl-pent-3-ene (D)

1, 1-dimethyl ether 2-ethoxy propane

2-chloro-hex-5-ene 5-chloro-5-methyl-pent-2-ene

Give the IUPAC name of the compound :

(A) (C) 4.

is :

1, 1, 3-trimethylcyclohex-2-ene 1, 1, 5-trimethylcyclohex-5-ene

(B) (D)

1, 3, 3-trimethylcyclohex-1-ene 2, 6, 6-trimethylcyclohex-1-ene

The IUPAC name of CH3  CH  CH  C  CH is : (A) pent-3-en-1-yne (B) pent-3-en-4-yne

(C)

pent-2-en-4-yne

The IUPAC name of H3C  CH  C3H 7 is : | OC3H 7 (A) 4-propoxy pentane (C) 2-propoxy pentane

(B) (D)

pentyl-propyl ether 2-pentoxy propane

(B) (D)

4, 4-dimethyl-5, 5-diethylpentane 3-ethyl-4, 4-dimethylpentane

The IUPAC name of (A) (C)

1, 1-diethyl-2, 2-dimethylpentane 5, 5-diethyl-4, 4-dimethylpentane

VMC/Introduction to Organic Chemistry

(D)

pent-2-en-3-yne

is :

3

HWT/Chemistry

Vidyamandir Classes 7.

The IUPAC name of the compound, CH 2  CH  COOH | | OH NH 2

(A) (C)

8.

2-amino-3-hydroxy propanoic acid 1-amino-2-hydroxypropanoic acid

(B) (D)

What is the correct IUPAC name of

?

(A) (C)

(B) (D)

4-methoxy-2-nitrobenzaldehyde 4-methoxy-6-nitrobenzaldehyde

1-hydroxy-2-amino propane-3-oic acid 3-hydroxy-2-amino propanoic acid

4-fromyl-3-nitro anisole 2-formyl-5-methoxy nitrobenzene

The IUPAC name of the compound  CH3 2 CH  CH  CH  CHCO  CH3 is.

9.

(A) (C) 10.

5-methyl-hex-3-en-2-ol 2-hydroxy-5-methyl-3-hexene

(B) (D)

2-methyl-hex-3-en-5-ol 5-hydroxy-2-methyl-3-hexene

(B) (D)

methyl-4-oxoheptanoate methyl 4-oxohexanoate

Give the IUPAC name for, O O || || H 3C  CH 2  C  H 2 C  CH 2  C  OCH 3 (A) (C)

ethyl-4-oxoheptanoate ethyl-4-oxohexanoate

VMC/Introduction to Organic Chemistry

4

HWT/Chemistry

Vidyamandir Classes

DATE :

  MARKS :    10 

IITJEE :

NAME :

TIME : 25 MINUTES

TEST CODE : IOC [3]

ROLL NO.

START TIME :

END TIME :

STUDENT’S SIGNATURE :

TIME TAKEN:

PARENT’S SIGNATURE :

 This test contains a total of 10 Objective Type Questions.  Each question carries 1 mark. There is NO NEGATIVE marking. Choose the correct alternative. Only one choice is correct. 1.

The IUPAC name of the compound

(A) (C) 2.

3.

(B) (D)

1, 1-dimethyl-3-hydroxy cyclohexane 1, 1-dimethyl-3-cyclohexanol

(B) (D)

benzene chloro ketone chloro phenyl ketone

(B) (D)

6-bromo-2-chlorocyclohexene 1-bromo-3-chlorocyclohexene

(B) (D)

3, 5-dimethyl-1-cyclohexene 1, 3-dimethyl-5-cyclohexene

The IUPAC name of the compound shown below is :

2-bromo-6-chlorocyclohex-1-ene 3-bromo-1-chlorocyclohexane

IUPAC name of the following compound is :

(A) (C)

5.

3, 3-dimethyl-1-hydroxy cyclohexane 3, 3-dimethyl-1-cyclohexanol

The IUPAC name of C6H5COCl is. (A) benzoyl chloride (C) benzene carbonyl chloride

(A) (C) 4.

is :

3, 5-dimethylcyclohexene 1, 5-dimethyl-5-cyclohexene

IUPAC name of the compound

(A) (C)

5-methyl-4-isopropyl-6, 6-diethyloctane 3, 3-diethyl-4-methyl-5-(1, 1-dimethyl) octane

VMC/Introduction to Organic Chemistry

is :

(B) (D)

5

3, 3-dimethyl, 3-ethyl-5-isopropyl octane 3, 3-diethyl-4-methyl-5-(1'-methylethyl)octane

HWT/Chemistry

Vidyamandir Classes 6.

The IUPAC name of the compound

HOOC  CH 2  C H  CH 2  CH 2  COOH | COOH (A) (C) 7.

2(carboxymethyl)-pentane-1, 5-dioic acid 4-carboxyhexane-1, 6-dioic acid

(B) (D)

3-carboxyhexane-1, 6-dioic acid 1, 2-dicarboxy pentanoic acid

Which of the following compounds has incorrect IUPAC nomenclature? O || (A) (B) CH3 CHCH 2CHO CH3CH 2CH 2COC2H5 | ethylbu tan oate CH3 O 3 methyl bu tan al || (C) (D) CH3 CH CHCH3 CH3 CHCCH 2CH3 | | | CH3 H3C OH 2  methyl 3 pentanone

2  methyl 3 butanol

The compound which contains all the four 1 , 2 ,3 and 4 carbon atoms is :

8.

(A) (C) 9.

2, 3-dimethylpentane 2, 3, 4-trimethylpentane

(B) (D)

The number of secondary hydrogen in 2, 2-dimetyl butane is : (A) 8 (B) 6 (C)

10.

3-chloro-2, 3-dimethylpentane 3, 3-dimethylpentane

4

(D)

2

3 carbon

(D)

Both 1 and 2 carbon

 C H2  C H  C H2  | | Glycerol  |  contains :  OH OH OH  (A)

1 carbon

(B)

2 carbon

VMC/Introduction to Organic Chemistry

(C)

6

HWT/Chemistry

Vidyamandir Classes

DATE :

  MARKS :    10 

IITJEE :

NAME :

TIME : 25 MINUTES

TEST CODE : IOC [4]

ROLL NO.

START TIME :

END TIME :

STUDENT’S SIGNATURE :

TIME TAKEN:

PARENT’S SIGNATURE :

 This test contains a total of 10 Objective Type Questions.  Each question carries 1 mark. There is NO NEGATIVE marking. Choose the correct alternative. Only one choice is correct. 1.

2.

3.

Which one of the following is a secondary alcohol? (A) 2-methyl-1-propanol (B) 2-methyl-2-propanol (C)

The IUPAC name of an unsymmetrical ether with the molecular formula C4H10O : (A) ethoxy propane (B) methoxy ethane (C) ethoxy ethane

(D)

1-butanol

(D)

methoxy propane

The IUPAC name of the following compound is :

(A) (C) 4.

2-butnol

propionic anhydride ethoxy porpanoic acid

The general formula CnH2nO2 could be for open chain : (A) diketones (B) carboxylic acids

(B) (D)

dipropanoic anhydride propanoic anhydride

(C)

diols

(D)

dialdehydes

5.

2, 3-dimethyl hexane contains ……. Tertiary ……. secondary and ……. Primary carbon atoms, respectively. (A) 2, 2, 4 (B) 2, 4, 3 (C) 4, 3, 2 (D) 3, 2, 4

6.

The correct IUPAC name of the following compound is :

CH 3CH 2 C H  C  C  C H C H 2 CH 2 CH 2 CH 3 | | | CH 3 C2 H 5 C2 H 5 (A) (C) 7.

8.

9.

5, 6-dimethyl-8-methyl dec-6-ene 5, 6-diethyl-3-methyl dec-4-ene

(B) (D)

6-butyl-5-ethyl-3-methyl oct-4-ene 2, 4, 5-triethyl non-3-ene

The structures (CH3)3CBr and CH3[cH2]3Br represent. (A) chain isomerism (C) chain as well as position isomerism

(B) (D)

position isomerism functional isomerism

The number of isomeric pentyl alcohols possible is : (A) two (B) four

(C)

six

The number of isomeric alkanes having the molecular formula C5H12 is : (A) three (B) five (C) nine

VMC/Introduction to Organic Chemistry

7

(D)

eight

(D)

thirty two

HWT/Chemistry

Vidyamandir Classes 10.

MATCH THE COLUMNS : Column 1

Column 2 (p)

Styrene

(q)

Benzo phenone

(r)

Acetophenone

(s)

Toluene

(A)

(B)

(C)

(D)

VMC/Introduction to Organic Chemistry

8

HWT/Chemistry

Vidyamandir Classes

DATE :

  MARKS :    10 

IITJEE :

NAME :

TIME : 25 MINUTES

TEST CODE : IOC [5]

ROLL NO.

START TIME :

END TIME :

STUDENT’S SIGNATURE :

TIME TAKEN:

PARENT’S SIGNATURE :

 This test contains a total of 10 Objective Type Questions.  Each question carries 1 mark. There is NO NEGATIVE marking. Choose the correct alternative. Only one choice is correct. 1.

2.

3.

4.

5.

6.

7.

8.

9.

CH3CH2OH and CH3OCH3 are the example of : (A) chain isomerism (C) position isomerism

(B) (D)

The number of possible alkynes with molecular formula C5H8 is : (A) 3 (B) 4 (C) Methoxy methane and ethanol are : (A) position isomers (B)

chain isomers

functional isomerism metamerism

5

(C) functional isomers

How many primary amines are possible with the formula C4H11N ? (A) 1 (B) 2 (C)

3

The number of isomeric ethers with molecular formula C4H10O is(are) : (A) one (B) two (C) three

(D)

6

(D)

optical isomers

(D)

4

(D)

four

Isomers of propionic acid are : (A) HCOOC 2H5 and CH 3COOCH 3

(B)

HCOOC 2H5 and C3H 7COOH

(C)

(D)

C3H 7OH and CH3COCH 3

Metamers of ethyl propionate are : (A) C4H9COOH and HCOOC4H9 (C) CH3COOCH3 and CH3COOC3H7

(B) (D)

C4H9COOH and CH3COOC3H7 CH3COOC3H7 and C3H7COOCH3

Which one of the following shows functional isomerism? (A) C2H4 (C) C2H5OH

(B) (D)

C3H6 CH2Cl2

CH3COOCH 3 and C3H 7OH

The number of isomers for the compound with the molecular formula C2BrClFI is (excluding geometrical) : (A) 3 (B) 4 (C) 5 (D) 6

VMC/Introduction to Organic Chemistry

9

HWT/Chemistry

Vidyamandir Classes 10.

MATCH THE COLUMNS : Column 1

Column 2 (p)

Glyoxal

(q)

Cinnamic Acid

(C)

(r)

Salicylic acid

(D)

(s)

Cumene

(A)

(B)

O O || || H  C C H

VMC/Introduction to Organic Chemistry

10

HWT/Chemistry

Vidyamandir Classes

DATE :

  MARKS :    10 

IITJEE :

NAME :

TIME : 25 MINUTES

TEST CODE : IOC [6]

ROLL NO.

START TIME :

END TIME :

STUDENT’S SIGNATURE :

TIME TAKEN:

PARENT’S SIGNATURE :

 This test contains a total of 10 Objective Type Questions.  Each question carries 1 mark. There is NO NEGATIVE marking. Choose the correct alternative. Only one choice is correct. 1.

Ethers are isomeric with : (A) aldehydes (B) ketones (C) both aldehydes and ketones (D) alcohols

2.

(A) (C)

n-pentane, iso-pentane, and neo-pentane are examples for isomers of the type : (A) geometrical (B) optical (C) chain (D) positional

3.

Pick out the alkane which differs from the other members of the group : (A) 2, 2-dimethyl propane (B) pentane (C) 2-methyl butane (D) 2, 2-dimethyl butane

4.

How many isomers are possible for the alkane C4H10 ? (A) 3 (B) 5 (C) 2 (D) 4

5.

The number of isomers of the compound with molecular formula C2H2Br2 is :

10.

MATCH THE COLUMNS :

(B)

(D)

7.

Propanol and propanone are : (A) functional isomers (B) (C) chain isomers (D) structural isomers

2-pentanone and 3-methyl-2-butanone are a pair of ……. Isomers : (A) functional (B) chain (C) positional (D) stereo

9.

Which of the following is a pair of functional isomers? (A) CH3COCH3, CH3CHO (B) C2H5CO2H, CH3CO2CH3 (C) C2H5CO2H, CHCO2C2H5 (D) CH3CO2H, CH3CHO

Column 2

CH 2  CH 2  Cl

CH 3  CH  CH 2  CH 2  Cl | CH 3

(q)

Benzyl chloride

(r)

Vinyl chloride

(s)

Iso-pentyl chloride

VMC/Introduction to Organic Chemistry

enantiomers

8.

Acetyl chloride

O || CH 3  C  Cl

3 2

How many structural isomers are possible for C4H9Cl? (A) 2 (B) 4 (C) 8 (D) 10

(p)

(C)

(B) (D)

6.

Column 1 (A)

4 5

11

HWT/Chemistry

Vidyamandir Classes

DATE :

  MARKS :    10 

IITJEE :

NAME :

TIME : 25 MINUTES

TEST CODE : IOC [7]

ROLL NO.

START TIME :

END TIME :

STUDENT’S SIGNATURE :

TIME TAKEN:

PARENT’S SIGNATURE :

 This test contains a total of 10 Objective Type Questions.  Each question carries 1 mark. There is NO NEGATIVE marking. Choose the correct alternative. Only one choice is correct. 1.

2.

3.

4.

5.

The number of isomeric alkenes with molecular formula C6H12 are : (A) 8 (B) 10 (C) 11

(D)

13

How many structures can compound with molecular formula C7H9N have? (A) 5 (B) 4 (C) 3

(D)

2

The number of isomeric hexanes is : (A) 5 (B)

4

(D)

6

Which type of isomerism is most common among ethers? (A) Metamerism (B) Functional (C)

Chain

(D)

Position

The IUPAC name of the given structure (A) diisohexane (C) 2, 2-dimethylbutane

(B) (D)

isohexane 2, 3-dimethylbutate

(B) (D)

N, N-dietheylmethanamine None of the above

(B) (D)

2, 2-dimethyl propane ethyl isopropyl ethane

3

(C)

is :

6. will have the name : (A) N-ethyl-N-methylethanmine (C) N, N-diethylethanamide

7.

The IUPAC name of (A) (C)

8.

2, 2, 4, 4-tetramethyl pentane 4-ethyl-3-methyl hex-3-ene

The IUPAC name of the compound (A) 1, 3, 5-triheptene (C) 2, 4, 6-heptatriene

VMC/Introduction to Organic Chemistry

is :

is : (B) (D)

12

2, 4, 6-triheptene hepta-1, 3, 5-triene

HWT/Chemistry

Vidyamandir Classes 9.

Which Pair of carbon skeleton is an example of isomerism? C C | | (A) (B) C  C  C  Cand C  C  C | C

(C)

10.

(D)

C C | | C  C  C  Cand C  C  C | | C C C | C  C  C  C  C and C  C  C | C

MATCH THE COLUMNS : Column 1

Column 2

(A)

(p)

Resorcinol

(B)

(q)

Catechol

(C)

(r)

Mesitylene

(D)

(s)

Quinol

VMC/Introduction to Organic Chemistry

13

HWT/Chemistry

Vidyamandir Classes

DATE :

  MARKS :    10 

IITJEE :

NAME :

TIME : 25 MINUTES

TEST CODE : IOC [8]

ROLL NO.

START TIME :

END TIME :

STUDENT’S SIGNATURE :

TIME TAKEN:

PARENT’S SIGNATURE :

 This test contains a total of 10 Objective Type Questions.  Each question carries 1 mark. There is NO NEGATIVE marking. Choose the correct alternative. Only one choice is correct. 1.

2.

3.

Which of the following is not an isomer of but-1-yne? (A) But-2-yne (B) Butan-1-ol

(C)

2-methyl n-propyl ether

Which of the following are functional isomers? (A) CH3CH2Cl and CH3CH2Br (C) C2H5OC2H5 and CH3OC3H7

(B) (D)

CH3CHBr2 and CH2Br · CH2Br

Which among the following will not show chain isomerism? (A) C3H8 (B) C4H10 (C)

C5H12O

(D)

(D)

C5H10O

4.

Maximum number of open chain isomers that an alkene can have with the molecular formula C4H8 is : (A) 5 (B) 4 (C) 3 (D) 2

5.

Total number of structural isomers with formula C4H10O are : (A) 1 (B) 2 (C)

6.

3

(D)

4

I and IV

(D)

II and III

Which among the following compounds will show metamerism? (A) CH3COC3H7 (B) CH3OC2H5 (C)

CH3SC2H5

(D)

CH3OCH3

The number of possible alkynes with molecular formula C5H8 is : (A) 3 (B) 4 (C)

5

(D)

6

The compounds which have only primary and tertiary carbon are : (A) 2-methylbutane (B) (C) 2-chloro-2-methylpropane (D)

2, 3-dimethylbutane 2, 2-dimethylpropane

Select pair of chain isomers from the following :

(A) 7.

8.

*9.

Butan-2-one

I and II

(B)

II and III

VMC/Introduction to Organic Chemistry

(C)

14

HWT/Chemistry

Vidyamandir Classes 10.

MATCH THE COLUMNS : Column 1

Column 2

(A)

(p)

m-Xylene

(B)

(q)

Isopthalic acid

(C)

(r)

m-ciesol

(D)

(s)

m-Tolaic-acid

VMC/Introduction to Organic Chemistry

15

HWT/Chemistry

Vidyamandir Classes

DATE :

  MARKS :    10 

IITJEE :

NAME :

TIME : 25 MINUTES

TEST CODE : IOC [9]

ROLL NO.

START TIME :

END TIME :

STUDENT’S SIGNATURE :

TIME TAKEN:

PARENT’S SIGNATURE :

 This test contains a total of 10 Objective Type Questions.  Each question carries 1 mark. There is NO NEGATIVE marking. Choose the correct alternative. Only one choice is correct. 1.

IUPAC name of the compound (A) (C)

2.

The IUPAC name of (A) (C)

3.

Trans-3, 4-dimethylhex-3-ene Cis-3,4-dimethylhex-4-ene

(B) (D)

Cis-3,4-dimethylhex-3-ene Cis-2,3-diethylbut-2-ene

(B) (D)

3-heptylhept-3-ene 5, 6-Diethyl-3-methyldec-4-ene

is :

5-heptenylheptane 3-(3-heptyl) hept-3-ene

Which of the following compounds has been incorrectly named?

(A)

2-chlorocyclohexene

(B)

 CH 3 2 CHCH 2CH 2 Br

1-Bromo-3-methylbutane

(C)

 CH 3 2 C  CH  COOH

3-methyl but-2-enoic acid

(D)

2-cyclopropylbutane

4.

are.

(A) 5.

Position isomers (B)

Chain isomers

(C)

Functional is isomers

(D)

Metamers

IUPAC name of the compound is :

(A) (C)

tans-3-iodo-4-chloro-3-pentene trans-2-chloro-3-iodo-2-pentene

VMC/Introduction to Organic Chemistry

(B) (D)

16

cis-2-chloro-3-iodo-2-pentene cis-3-iodo-4-chloro-3-pentene

HWT/Chemistry

Vidyamandir Classes 6.

7.

The principal function group in the compound BrCH2CH(OH)CH2COCHNO2 is : (A) OH (B) (C)  NO2 CO

(D)

 Br

The IUPAC name for Cl | is : CH 3  C H  CH 2  CH  CH  CH 3 (A) (C)

5-chloro-hex-2-ene 1-chloro-1-methyl-pent-3-ene

(B) (D)

2-chloro-hex-5-ene 5-chloro-5-methyl-pent-2-ene

(B) (D)

4-fromyl-3-nitro anisole 2-formyl-5-methoxy introbenzene

(B) (D)

6-bromo-2-chlorocyclohexene 1-bromo-3-chlorocyclohexene

CHO NO2 8.

?

What is the correct IUPAC name of

OCH3 (A) (C) 9.

4-methoxy-2-nitrobenzaldehyde 4-methoxy-6-nitrobenzaldehyde

The IUPAC name of the compound shown below is :

Cl

Br (A) (C) 10.

2-bromo-6-chlorocyclohex-1-ene 3-bromo-1-chlorocyclohexene

MATCH THE COLUMNS : Column 1

Column 2

(A)

Cl Cl | | CH 2  CH 2

(p)

Ethylene oxide

(B)

OH OH | | CH 2  CH 2

(q)

Glycol

(r)

Ethylidene chloride

(s)

Ethylene chloride

(C)

(D)

Cl | CH 3  CH  Cl

VMC/Introduction to Organic Chemistry

17

HWT/Chemistry