Jee 2014 Booklet3 Hwt Ionic Equilibrium

August 28, 2017 | Author: varunkohliin | Category: Acid Dissociation Constant, Ph, Acid, Dissociation (Chemistry), Buffer Solution
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Jee 2014 Booklet3 Hwt Ionic Equilibrium...

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Vidyamandir Classes

DATE :

  MARKS :    10 

IITJEE :

NAME :

TIME : 25 MINUTES

TEST CODE : ION-EQ [1]

ROLL NO.

START TIME :

END TIME :

STUDENT’S SIGNATURE :

TIME TAKEN:

PARENT’S SIGNATURE :

 This test contains a total of 10 Objective Type Questions.  Each question carries 1 mark. There is NO NEGATIVE marking. Choose the correct alternative. Only one choice is correct. 1.

A weak monobasic acid is 1% ionized in 0.1 M solution at 25 C . The percentage of ionization in its 0.025 M solution is : (A) 1 (B) 2 (C) 3 (D) 4

2.

Three reaction involving H 2PO 4 are given below : I.

H3PO 4  H 2O   H3O   H 2PO 4

III.

H 2 PO4  OH   H 3PO4  O2

In which of the above does H 2PO 4 act as an acid ? (A) II only (B) I and II 3.

II.

H 2PO 4  H 2O   HPO 42   H 3O 

(C)

III only

(D)

At a certain temperature, the dissociation constant of formic acid and acetic acid are 1.8  10

I only 4

and 1.8  105 respectively.

The concentration of acetic acid solution in which the hydrogen ion has the same concentration as in 0.001 M formic acid solution is equal to : (A) 0.01 M (B) 0.001 M (C) 0.1 M (D) 0.0001 M (E) 0.1010 M 4.

5.

For a concentrated solution of a weak electrolyte AxBy of concentration ‘C’, the degree of dissociation '  ' is given as : (A)

  K eq / C  x  y 

(C)

1/  x  y    K eq / C x  y  1 x x y y

7.

8.

9.

(D)

  K eq / Cxy







  K eq / C xy

(E)



5.0  105

(B)

5.0  1015

(C)

5.0  1015

0.2  105

(D)

The ionisation of acetic acid in H2SO4, compared to in water, is : (A) weak, low (B) strong, more (C)

medium, the same (D)

no ionisation, 100 %

CH3COOH is weaker acid than H2SO4. It is due to : (A) more ionisation (B) less ionisation

(C)

covalent bond

electrovalent bond

(B)

C6H5 NH 2 ;

(D)

C9H 7 N;

K b  6.3  1010

5  108

(D)

(D)

Which of the following base is weakest ? (A)

NH 4OH;

(C)

C2H5 NH 2 ;

K b  1.6  106 K b  5.6  104

K b  3.8  1010

    An acid HA ionizes as, HA   H A The pH of 1.0 M solution is 5. Its dissociation constant would be :

(A) 10.

  K eq / C  x y 

The first and second dissociation constant of an acid H 2A are 1.0  105 and 5.0  1010 respectively. The overall dissociation constant of the acid will be : (A)

6.





(B)

1  1010

(B)

5

(C)

pH value of which one of the following is not equal to one ? (A) 0.1 M HNO3 (B) (C) 0.1 M CH3COOH (D)

VMC/Ionic Equilibrium

18

1  105

0.05 M H2SO4 50 cm3 of 0.4 M HCl + 50 cm3 of 0.2 M NaOH

HWT/Chemistry

Vidyamandir Classes

DATE :

  MARKS :    10 

IITJEE :

NAME :

TIME : 25 MINUTES

TEST CODE : ION-EQ [2]

ROLL NO.

START TIME :

END TIME :

STUDENT’S SIGNATURE :

TIME TAKEN:

PARENT’S SIGNATURE :

 This test contains a total of 10 Objective Type Questions.  Each question carries 1 mark. There is NO NEGATIVE marking. Choose the correct alternative. Only one choice is correct. 1.

The pH of 1010 M NaOH solution is nearest to : (A)

2.

5.

10

(C)

4

(D)

7

is less than 25C

(D)

can be more or less than 25C

The solubility of a sparingly soluble salt AB2 in water is 1.0  105 M . Its solubility product will be : (C)

4  1010 M 3

(D)

1  1015 M 3

(C)

11

(D)

unpredictable

A solution contains 10 mL 0.1 N NaOH and 10 mL 0.05 N H2SO4, pH of this solution is : (A) less than 7 (B) 7 (C) zero (D)

greater than 7

(A) 4.

(B)

The pH of a neutral water sample is 6.5. Then the temperature of water : (A) is 25C (B) is more than 25C (C)

3.

4

1.0  1010 M 3

(B)

4  1015 M 3

The pH value of 0.001 M aqueous solution of NaCl is : (A) 7 (B) 4

6.

The pH values of 0.1 M solution of HCl, CH3COOH, NH4Cl and CH3COONa will have the order : (A) HCl < CH3COOH < NH4Cl < CH3COONa (B) CH3COONa < NH4Cl < CH3COOH < HCl (C) NH4Cl < CH3COONa < CH3COOH < HCl (D) All will have same of pH value

7.

When 200 mL of aqueous solution of HCl (pH = 2) is mixed with 300 mL of an aqueous solution of NaOH (pH = 12), the pH of the resulting mixture is : (A) 10 (B) 2.7 (C) 4.0 (D) 11.3

8.

9.

M M M HCl, 20 cc of HNO3 and 40 cc of NaOH solutions are mixed and the volume was made up 1 dm3. The pH of 3 2 4 the resulting solution is : (A) 8 (B) 2 (C) 1 (D) 3 30 cc of

106 M NaOH is diluted 100 times. The pH of the diluted base is : (A)

10.

between 7 and 8

(B)

between 5 and 6

(C)

between 6 and 7

(D)

between 10 and 11

100 mL of 0.015 M HCl solution is mixed with 100 mL of 0.005 M HCl. What is the pH of the resultant solution ? (A) 2.5 (B) 1.5 (C) 2 (D) 1

VMC/Ionic Equilibrium

19

HWT/Chemistry

Vidyamandir Classes

DATE :

  MARKS :    10 

IITJEE :

NAME :

TIME : 25 MINUTES

TEST CODE : ION-EQ [3]

ROLL NO.

START TIME :

END TIME :

STUDENT’S SIGNATURE :

TIME TAKEN:

PARENT’S SIGNATURE :

 This test contains a total of 10 Objective Type Questions.  Each question carries 1 mark. There is NO NEGATIVE marking. Choose the correct alternative. Only one choice is correct. 1.

50 mL of H2O is added to 50 mL of 1  103 M barium hydroxide solution. What is the pH of the resulting solution? (A)

2.

3.

5.

6.

8.

10.

(C)

11.0

(D)

11.7

1 109 M HCl solution

(B)

1 105 M NaOH solution

(C)

1 109 M KOH solution

(D)

Both (A) and (B)

(C)

between 6 and 7

(D)

slightly more than 7

(C)

1

(D)

0.01

(D)

11.4

The pH of 108 M HCl solution is : 8

(B)

more than 8

The approximately pH of 0.005 molar sulphuric acid. (A) 0.005 (B) 2

Calculate pOH of 0.001 M NH4OH, when it is 1% dissociated in the solution : (A) 5 (B) 2.96 (C) 9.04

HA is a weak acid. The pH of 0.1 M HA solution is 2. What is the degree of dissociation    of HA? 0.5

(B)

0.2

An aqueous solutions of 1 M NaCl and 1 M HCl is : (A) not a buffer but pH < 7 (C) a buffer with pH < 7

(C)

0.1

(D)

(B) (D)

not a buffer but pH > 7 a buffer with pH > 7

(C)

log

0.301

pKa or a weak acid is defined as : (A)

9.

3.3

(A)

(A) 7.

(B)

Which of the following solutions will have pH = 9 at 298 K?

(A) 4.

3.0

log K a

(B)

1 log K a

1 Ka

(D)

 log

1 Ka

Which statement is false? (Assume complete dissociation in each case) (A) If 2.0 L of a solution of H2SO4 contains 0.1 mole, then pH of the solutions is 1 (B)

The concentration of OH in 0.005 M HNO3 is 2.0 1012 mol / L

(C)

The pH of 0.01 M KOH is 12

(D)

In a 0.001 M solution of NaOH the concentration of H  is 103 mol / L

In 1L saturated solution of AgCl [Ksp (AgCl) = 1.6 10–10], 0.1 mole of CuCl [Ksp(CuCl) = 1.0 × 10–6] is added. The resultant concentration of Ag in the solution is 1.6 10x. The value of ‘x’ is : (A) 3 (B) 5 (C) 7 (D) 9

VMC/Ionic Equilibrium

20

HWT/Chemistry

Vidyamandir Classes

DATE :

IITJEE :

NAME :

  MARKS :    10 

TIME : 25 MINUTES

TEST CODE : ION-EQ [4]

ROLL NO.

START TIME :

STUDENT’S SIGNATURE :

END TIME :

TIME TAKEN:

PARENT’S SIGNATURE :

 This test contains a total of 10 Objective Type Questions.  Each question carries 1 mark. There is NO NEGATIVE marking. Choose the correct alternative. Only one choice is correct. 1.

2.

The Ksp for Cr (OH)3 is 1.6 × 10–30. the molar solubility of this compound in water is : (A)

2 1.6  1030

(B)

4 1.6  1030

(C)

4 1.6  1030 / 27

(D)

1.6 ×10–30 / 27

4.

5.

H2S is passed into one dm3 of a solution containing 0.1 mole Zn3 and 0.01 mole Cu2 till the sulphide ion concentration reaches 8.1 × 1010 moles. Which one of the following statements is true ? [Ksp or ZnS and CuS are 3 × 10–22 and 8 × 10–36 respectively] (A) Only ZnS precipitaes (B) Both CuS and ZnS precipitates (C) Only CuS precipitates (D) No precipitation occurs The solubility of Ca3 (PO4)2 is water is y moles/litre. Its solubility product is : (A) 6y4 (B) 36 y4 5 (C) 64 y (D) 108 y5

[Ksp Ag 2 CrO4  4  1012 ] ; [Ksp AgCl  1  1010] (A) Precipitation does not occur (B) Silver chromate gets precipitated first (C) Silver chloride gets precipitated first (D) Both silver chromate and silver chloride start, precipitating simultaneously 7.

The molar solubility (in mol L1 ) of a sparingly soluble salt MX4 is ‘s’. The corresponding solubility product is Ksp ‘s’ is given in terms of Ksp by the relation. (A) s = (Ksp/128)1/4 (B) s = (128 Ksp)1/4 (C) s = (256 ksp)1/5 (D) s = (Ksp/256)1/5

8.

The solubility product of Hg2I2 is equal to :  Hg 2    I    Hg 2    I   (A) (B)  2         Hg 2    I    2   

(C) 9.

Solid

Ba(NO3)2

is

2

 Hg 2    I      

(D) gradually

dissolved

2

in

a

4

1.0 10 M Na 2CO3 solution. At what concentration of Ba2+ will a precipitate begin to form ? (Ksp for BaCO3 = 5.1  109 )

10.

(A)

4.1  105 M

(B)

5.1  105 M

(C)

8.1  108 M

(D)

8.1  107 M

The solubility product of iron (III) hydroxide is

1.6  1019 . If X is the solubility of iron (III)

At 25C , the solubility product of Mg(OH)2 is precipitating in the form of Mg(OH)2 from a solution of 0.001 M Mg2 ions ? (A) 9 (B) 10 (C) 11 (D) 8

VMC/Ionic Equilibrium

1 dm3 solution containing 105 moles each of Cl ions and CrO 24 ions is treated with 104 moles of silver nitrate. Which one of the following observation is made?

The solubility product (Ksp) of the following compound are given at 25C Compound Ksp I. AgCl (i) 1.1 × 10–10 II. AgI (ii) 1.0 × 10–16 III. PbCrO4 (iii) 4.0 × 10–14 IV. Ag2CO3 (iv) 8.0 × 10–12 The most soluble and least soluble compound are : (A) AgCl & PbCrO4 (B) AgI & Ag2CO3 (C) Ag2Cl & Ag2CO3 (D) Ag2CO3 & AgI (E) Ag2Co3 & PbCrO4

3.

6.

hydroxide, which one of the following expression can be used to calculate X ? (A) Ksp = X4 (B) Ksp = 9X4 3 (C) Ksp = 27 X (D) Ksp = 27 X4

21

HWT/Chemistry

Vidyamandir Classes

DATE :

  MARKS :    10 

IITJEE :

NAME :

TIME : 25 MINUTES

TEST CODE : ION-EQ [5]

ROLL NO.

START TIME :

END TIME :

STUDENT’S SIGNATURE :

TIME TAKEN:

PARENT’S SIGNATURE :

 This test contains a total of 10 Objective Type Questions.  Each question carries 1 mark. There is NO NEGATIVE marking. Choose the correct alternative. Only one choice is correct. 1.

If K sp of Ag 2S is 1017 , the solubility of Ag2S in 0.1 M solution of Na2S will be : (A) (C)

2.

108

10

15

5  109

(B) (D)

10

(A) (C) 7.

16

Solubility product constant [Ksp] of salts of types MX,

4.

of sodium acetate to 0.1 M acetic acid will

If the solubility product constant Ksp of AgIO3 at a

given temperature is 1.0  108 , what is the mass of AgIO3 contained in 100 mL of its saturated solution?

8.

solution in which the concentration A+ ions is 103 M . The salt will precipitate when the concentration of B ions is kept. (A) between 10–8 to 10–7 M (B) between 10–7 M to 10–8 M (C) >10–5 M (D)

6.

2+

(B)

2.83  103 g

(C)

1.0  107 g

(D)

1.0  104 g

At 30C the solubility of Ag 2 CO3 (Ksp  8  1012 ) 0.05 M AgNO3 0.05 M NH3

The value of the ionic product of water depends (A) on volume of water (B) on temperature (C) changes adding acid or alkali (D) always remain constant

10.

Some chemists at ISRO wished to prepare a saturated solution of a silver compound and they wanted it to have the highest concentration of silver ion possible. Which of the following compounds, would they use?

K sp  AgCl   1.8 1010 ; MX2 > M3X (B) M3X > MX2 > MX (C) MX2 > M3X > MX (D) MX > M3X > MX2 Addition cause : (A) (C) (D)

(B) (D)

In a saturated solution of the sparingly soluble strong electrolyte AgIO3 (molecular mass = 283) the equilibrium which sets in is

MX2 and M3X at temperature ‘T’ are 4.0  108 ,

3.

NiS and PbS CoS and NiS

(A) (C)

22

K sp  Ag 2CrO 4   2.4  1012 AgCl (B) AgBr Ag2CrO4 (D) None of these

HWT/Chemistry

Vidyamandir Classes

DATE :

IITJEE :

NAME :

  MARKS :    10 

TIME : 25 MINUTES

TEST CODE : ION-EQ [6]

ROLL NO.

START TIME :

STUDENT’S SIGNATURE :

END TIME :

TIME TAKEN:

PARENT’S SIGNATURE :

 This test contains a total of 10 Objective Type Questions.  Each question carries 1 mark. There is NO NEGATIVE marking. Choose the correct alternative. Only one choice is correct. 1.

The solubility of Pb(OH)2 in water is 6.7 106 M . Its solubility in a buffer solution of pH = 8 would be 26  106 . (A)

2.

4.

(B)

1.6  103

(C)

1.6  102

 K sp BaSO4  1011 , K sp CaSO4  105 , K sp Ag 2SO 4  105    Ag2SO4 (B) BaSO4 (C) CaSO4

1.2  103

(D)

All of these

A precipitate of AgCl is formed when equal volumes of the following are mixed  K sp for AgCl  1010    (A)

104 M AgNO3 and107 M HCl

(B)

105 M AgNO3 and106 M HCl

(C)

104 M AgNO3 and104 M HCl

(D)

106 M AgNO3 and106 M HCl

A solution which is 103 M each in Mn2+, Fe2+, Zn2+ and Hg2+ is treated with 1016 M sulphide ion. If Ksp of Mns, FeS, ZnS and HgS are 1015 , 1023 , 1020 and 1054 respectively, which one will precipitate first ? (A) FeS (B) MgS (C) HgS

5.

(D)

On adding 0.1 M solution each of [Ag+], [Ba2+], [Ca2+] in a Na2SO4 solution, species first precipitated is :

(A) 3.

1.2  102

(D)

Zns

  In the following reaction, AgCl  KI   KCl  AgI

As KI is added, the equilibrium is shifted towards right giving more AgI precipitate, because : (A) both AgCl and AgI are sparingly soluble (B) the Ksp of AgI is lower than Ksp of AgCl (C) the Ksp of AgI is higher than Ksp of AgCl (D) both AgCl and AgI have same solubility product 6.

A buffer solution contains 0.1 mole of sodium acetate dissolved in 1000 cm3 of 0.1 M acetic acid. To the above buffer solution, 0.1 mole of sodium acetate is further added and dissolved. The pH of the resulting buffer is : (A) pKa (B) pKa + 2 (C) (D) pK a  log 2 pK a  log 2

7.

The pH of an aqueous solution of CH3COONa of concentration C(M) is given by : 1 1 pK a  log C 2 2

(A)

7

(C)

1 1 1 pK w  pK b  log C 2 2 2

(B)

1 1 1 pK w  pK b  log C 2 2 2

(D)

1 1 1 pK w  pK a  log C 2 2 2

8.

Which buffer solution comprising of the following has its pH value greater than 7? (A) CH3COOH + CH3COONa (B) HCOOH + HCOOK (C) CH3COONH4 (D) NH4OH + NH4Cl

9.

The buffering action of an acidic buffer is maximum when its pH is equal to : (A) 5 (B) 7 (C) 1

(D)

pKa

A strong acid is titrated with weak base. At equivalence point, pH will be : (A) 7 (C) =0

(D)

Cannot predict

10.

VMC/Ionic Equilibrium

23

HWT/Chemistry

Vidyamandir Classes

DATE :

  MARKS :    10 

IITJEE :

NAME :

TIME : 25 MINUTES

TEST CODE : ION-EQ [7]

ROLL NO.

START TIME :

END TIME :

STUDENT’S SIGNATURE :

TIME TAKEN:

PARENT’S SIGNATURE :

 This test contains a total of 10 Objective Type Questions.  Each question carries 1 mark. There is NO NEGATIVE marking. Choose the correct alternative. Only one choice is correct. 1.





2 2 M weak monoacidic base K b  1  1012 at 25 C is titrated with M HCl in water at 25 C . The concentration 5 15

2.5 mL of



of H+ at equivalence point is : K w  1  1014 at 25 C (A)

3.7  1013 M

(B)

3.2  107 M



(C)

3.2  102 M

(D)

2.7  102 M

2.

The pKa of a weak acid, HA, is 4.80. The pKb of a weak base, BOH is 4.78. The pH of an aqueous solution of the corresponding salt, BA, will be : (A) 9.58 (B) 4.79 (C) 7.01 (D) 9.22

3.

A buffer solution is prepared by mixing 0.1 M ammonia and 1.0 M ammonium chloride. At 298 K, the pKb of NH4OH is 5.0. The pH of buffer is : (A) 10.0 (B) 9.0 (C) 6.0 (D) 8.0

4.

The solubility of mercurous chloride in water will be given as : (A)

5.

Ksp(Hg2Cl2)

Ksp (Hg 2 Cl 2 ) / 4 (C)

(B)

[Ksp (Hg 2 Cl 2 ) / 4]1/ 3 (D)

Which one of the following salts will produce an alkaline solution while dissolving in water ? (A) NH4Cl (B) Na2CO3 (C) NaNO3 (D)

[Ksp(Hg2Cl2)]1/3

Na2SO4

6.

The aqueous solutions of HCOONa, C6H5NH3Cl and KCN are respectively. (A) acidic, acidic, basic (B) acidic, basic, neutral (C) basic, neutral, neutral (D) basic, acidic, basic

7.

The pKa of a weak acid (Ha) is 4.5. The pOH of an aqueous buffered solution of HA in which 50% of the acid ionised is : (A) 4.5 (B) 2.5 (C) 9.5 (D) 7.0

8.

Which one of the following salts give an acidic solution in water ? (A) CH3COONa (B) NH4Cl (C)

9.

(D)

CH3COONH4

A certain buffer solution contains equal concentration of X and HX . The Kb for X is 1010 . The pH of the buffer is : (A)

10.

NaCl

4

(B)

7

(C)

10

(D)

14

(D)

None of these

Degree of hydrolysis (h) of a salt of weak acid and a strong base is given by : (A)

h  Kh

VMC/Ionic Equilibrium

(B)

h

C Kh

(C)

24

h

Kh C

HWT/Chemistry

Vidyamandir Classes

DATE :

  MARKS :    10 

IITJEE :

NAME :

TIME : 25 MINUTES

TEST CODE : ION-EQ [8]

ROLL NO.

START TIME :

END TIME :

STUDENT’S SIGNATURE :

TIME TAKEN:

PARENT’S SIGNATURE :

 This test contains a total of 10 Objective Type Questions.  Each question carries 1 mark. There is NO NEGATIVE marking. Choose the correct alternative. Only one choice is correct. 1.

2.

(A)

sodium ion & water (B)

Na  and OH 

(C)

CO32 and water

CO32 and H 

(D)

(B)

[In  ]  pK In  pH [HIn] [HIn] log  pK In  pH [In  ] [HIn]

 pH  pK In

log

(D)

[In  ] log  pH  pK In [HIn]

[In  ]

In a mixture of acetic acid and sodium acetate the ratio of concentration of the salt to the acid is increased ten times. Then, the pH of the solution : (A) increases by one (B) decreases by one (C) decreases ten fold (D) increased ten fold

4.

A solution of FeCl3 in water acts as acidic solution due to : (A) hydrolysis of Fe3+ (B) acidic impurities (C) dissociation (D) ionisation Relation between hydrolysis constant and dissociation constant are given. Which is the correct formula for MgCl2 ? K K (A) Kh  w (B) Kh  w Ka Kb (C)

7.

8.

3.

6.

(A) (C)

Kh 

Consider the concentrations:

Kw Ka  Kb following

VMC/Ionic Equilibrium

(D)

Kw 

solutions

(B) (D)

A and B C and D

(A)

8  102M

(B)

8  1011M

(C)

1.6  1011M

(D)

8  105M

Statement 1: The pH of a buffer solution containing equal moles of acetic acid and sodium acetate is 4.8 (pKa of acetic acid is 4.8) Statement 2: The ionic product of water at 25C is 10–14 mol2 L–2. (A) Statement-1 is True, Statement-2 is True and Statement-2 is a correct explanation for Statement-1 (B) Statement-1 is True, Statement-2 is True and Statement-2 is NOT a correct explanation for Statement-1 (C) Statement-1 is True, Statement-2 is False (D) Statement-1 is False, Statement-2 is True

9.

10.

HX is a weak acid (K a  105 ) . It forms a salt NaX 0.1 M on reacting with caustic soda. The degree of hydrolysis of NaX is : (A) 0.01 % (B) 0.0001% (C) 0.1 % (D) 0.5 % The degree of hydrolysis in hydrolytic equilibrium    A   H 2 O   HA  OH at salt concentration of

0.001 M is (K a  1  105 )

Kh Kb

of

C and D A and C

0.1 mole of CH 3 NH 2 (K b  5  104 ) is mixed with 0.08 mole of HCl and diluted to 1L. What will be the H+ concentration in the solution ?

log

(C)

B = CH3COONa ; D = CH3COOH

A buffer solution can be obtained by mixture by mixing equal volume of :



The rapid change of OH near the stoichiometric point of an acid base titration is the basis of indicator detection. pH of the solution is related to the ratio of the concentrations of the conjugate acid (HIn) and base – (In ) forms of the indicator given by the expression. (A)

5.

A = NH4Cl ; C = NH4OH ;

The hydrolysis of sodium carbonate involves the reaction between :

equal

25

(A)

1  103

(B)

1  104

(C)

5  104

(D)

1  106

HWT/Chemistry

Vidyamandir Classes

DATE :

  MARKS :    10 

IITJEE :

NAME :

TIME : 25 MINUTES

TEST CODE : ION-EQ [9]

ROLL NO.

START TIME :

END TIME :

STUDENT’S SIGNATURE :

TIME TAKEN:

PARENT’S SIGNATURE :

 This test contains a total of 10 Objective Type Questions.  Each question carries 1 mark. There is NO NEGATIVE marking. Choose the correct alternative. Only one choice is correct. 1.

The pKb value of NH3 is 5. Calculate the pH of the buffer solution, 1 L of which contains 0.01 M NH4Cl and 0.10 M NH4OH (A) 4 (B) 6 (C) 8 (D) 10

2.

Study the following table. Buffer Solution

I

II

III

IV

Volume (in mL) of 1 M weak acid

4.0

4.0

40.0

0.1

Volume (in mL) of 0.1 M sodium salt of weak acid

4.0

40.0

4.0

10.0

II and III

(D)

Which of the two sets of buffer solution have least pH ? (A) I and II (B) I and III

(C)

II and IV

3.

The pH of 0.1 M solution of the following salts increases in the order. (A) NaCl < NH4Cl < NaCN < HCl (B) HCl < NH4Cl < NaCl < NaCN (C) NaCN < NH4Cl < NaCl < HCl (D) HCl < NaCl < NaCN < NH4Cl

4.

A mixture of sodium oxide and calcium oxide are dissolved in water and saturated with excess carbon dioxide gas. The resulting solution is….. . It contains : (A) basic; NaOH and Ca(OH)2 (B) neutral; Na2CO3 and CaCO3 (C) basic; Na2CO3 and CaCO3 (D) acidic; NaOH and CaCO3

5.

6.

7.

8.

9.

An amphoteric buffer solution in which conc. of H+ and HX is same. The value of Ka of HX is 108 , then pH of buffer solution is : (A) 3 (B) 8 (C) 10 (D) 14 An electrolyte. (A) gives complex ions in solution (C) is ionised in the solid state

(B) (D)

dissolves in water to give ions generates ions on passing electric current

Which one is strongest electrolyte in the following ? (A) NaCl (B) CH3COOH

(C)

NH4OH

(D)

C6H12O6

Which will not affect the degree of ionisation? (A) Temperature (B) Concentration

(C)

Type of solvent

(D)

Current

The degree of dissociation of 0.1 M HCN solution is 0.01% its ionisation constant would be : (A)

10.

103

(B)

105

(C)

107

(D)

109

(D)

102

Degree of dissociation of 0.1 N CH3COOH is (dissociation constant = 1  105 ) (A)

105

VMC/Ionic Equilibrium

(B)

104

(C)

26

103

HWT/Chemistry

Vidyamandir Classes

DATE :

IITJEE :

NAME :

  MARKS :    10 

TIME : 25 MINUTES

TEST CODE : ION-EQ [10]

ROLL NO.

START TIME :

STUDENT’S SIGNATURE :

END TIME :

TIME TAKEN:

PARENT’S SIGNATURE :

 This test contains a total of 10 Objective Type Questions.  Each question carries 1 mark. There is NO NEGATIVE marking. Choose the correct alternative. Only one choice is correct. 1.

2. 3.

Which of the following will suppress the ionisation of acetic acid is aqueous solution? (A) NaCl (B) HCl (C) KCl

(D)

Unpredictable

In which of the following, dissociation of NH4OH will be minimum? (A) NaOH (B) H2O (C) NH4Cl

(D)

NaCl

(D)

N3

The conjugate base of NH 2 is : (A)

4.

5.

9.

NH 4

(B)

Cl  is the conjugate base of HCl acid

(C)

Cl1 is the conjugate acid of H2O base

(D)

H3O+ is the conjugate base of HCl

NH 4

(C)

N2H4

(D)

NH2OH

(B)

P2O5

(C)

PO34

(D)

HPO 24

(B)

H2SO4

(C)

H 2SO 4

(D)

None of these

Sorensen

(C)

Lewis

(D)

Lowry

(C)

8

(D)

between 6 and 7

(C)

between 7 and 8

(D)

between 6 and 7

The conjugate acid of NH3 is : NH3

(B)

The conjugate base of H 2PO 4 is : H3PO4

Conjugate base of HSO 4 is :

SO 24 

pH scale was introduced by : (A) Arrhenius (B) What is the pH value of (A)

10.

(C)

H2O is the conjugate base of HCl acid

(A) 8.

NH 2 

(A)

(A) 7.

(B)

    In the reaction HCl  H 2 O   H 3O  Cl

(A) 6.

NH3

7

N 107

KOH solutions? (B)

between 7 and 8

The pH of a 109 M solution of HCl in water is : (A)

8

VMC/Ionic Equilibrium

(B)

8

27

HWT/Chemistry

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