Innovene Pe Products

Innovene™ PE products: full market coverage now and in the future

Dr. Fabian Siberdt PE Product Manager SPE conference, Houston February 2015

Sustainability

New Products

Sneak peek at

Growth through strategic partnerships JV with PetroChina for refining and trading Former JV with BASF (now fully owned) for the styrene/PS chain Proposed JV with Solvay for the chlorine/PVC chain

INOVYN™ 

Entrepreneurial & Innovative

Our polyolefins licensing successes

384 56

The new leading licensor of polyolefins technology

More than 20 million tonnes of polyolefins capacity awarded since 2005

Our polyolefins technologies

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Innovene™ G

Innovene™ S

Innovene™ PP

Clean loop gas phase Swing LLDPE/HDPE

Bimodal slurry loops HDPE/Bimodal HDPE

Plug flow gas phase PP (homo, RCP, ICP)

Superior mLL and HAO LL products Unique C4-C6-C8 comonomer versatility Clean Loop Process High reliability / Low Maintenance

Superior bimodal HDPE products Unique swing monomodal/bimodal/Cr operations Quick transitions No wax generation

G S PP •

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Superior ICP’s Highest product consistency Unique plug flow process Short transitions

Our future…. « The challenge of our age must be to decouple human progress from resource use & environmental deterioration » © KMPG: expect the unexpected, building business value in a changing world, 2012

Our future… with polyolefins Light weight & durable Recycling solutions Energy recovering

Polyolefins end-use application

Trends in polyethylene

Metallocene LLDPE

Bimodal HDPE 1.5 x AAGR of HDPE

2 x AAGR of LLDPE

Based on

POPS data

Based on

POPS and Towsend Solutions data

Innovene™ G product coverage Application Film

Blow Molding Injection Molding Pipe & Conduits Textile Rotomolding Others

 Commercial

Type LL C4 LL C6 LL C8 mLL C6 or C8 HDPE Medium Mw Cr High Mw Cr LLDPE HDPE Non pressure PE80 Monofilament Tape MDPE mMDPE W&C Geomembrane Extrusion coating  New/improved

2007

2015

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Extension of mLL grade slate New Cr catalyst Extended offer New Cr catalyst

ISO certified black PE80 Improved tenacity

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and delivered

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Metallocene & Ziegler Development

HPLL™  metallocene product line 25

2007 20    )   n    i   m15    /    0    1   g    (    6    1  . 10    2    I    M

5

0 910

915

920

925

930

Density (kg/m³)

935

940

945

HPLL™  metallocene product line 25

2015 20    )   n    i   m15    /    0    1   g    (    6    1  . 10    2    I    M

Injection Extrusion coating

Roto Film

5

0 910

915

920

925

930

Density (kg/m³)

935

940

945

HPLL™ , a unique metallocene product Reverse Comonomer Distribution

LCB Conventional Ziegler

Conventional Metallocene

INEOS HPLL™ 

Broad MWD Comonomer decreases with Mw

Very narrow MWD Comonomer evenly distributed

Narrow MWD Comonomer increases with Mw    h   g    i    t    H   n

  e    t   n   o   c   r   e   m   o   n   o   m   o    C   w

  o    L

Low

High

Low

High

Low

High

HPLL™ , a unique metallocene product

Extrudability

Mechanicals

Bubble Stability INEOS HPLL Solution C8 Metallocene Conventional Gas Phase Metallocene Optics

Sealability

Best processability Best ESCR Best optics High impact Excellent sealability

HPLL™ , downgauging in film applications •

Mono

Better processability with HPLL™  •

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Formulation : monolayer 50µm 95% mLLDPE + 5% LDPE

• Higher stiffness:

Bubble stability comparable to conventional LLDPE HPLL™ was run at 20% higher output

• Outstanding Optics: PF6212KJ formulation

Competitive gas phase metallocene formulation

HPLL™ formulation

Competitive mPE formulation

Haze (%) 7.9 9.7 Best balance of mechanical, optical and sealing Gloss (‰) 71 66 properties available now with unmatched processability and lower energy costs Secant Modulus

Dart impact

HPLL™ , low SIT film based on mVLDPE HPLL6012 (912) HPLL6212 (920) C8 ULDPE (902)

• HPLL™ @ 912 kg/m³ matches solution 902 kg/m³ ULDPE’s • is very close to metallocene plastomers • but is exhibiting better mechanical Extra low SITproperties film

still with superior processability and toughness

HPLL™ , enhanced extrusion coating • Lower seal temperature - broader processing window • Tougher seal - higher seal integrity • Highly increased ESCR

Seal strength

ESCR

Broader processing window and better package integrity & ESCR still with superior processability

Innovene™ S Product Coverage Application Film

Blow Molding

Injection Molding Pipe & Conduits

Textile

Others

 Commercial

Type LLDPE HDPE Bimodal HDPE Medium Mw Cr High Mw Cr Bimodal Monomodal Bimodal Non pressure PE80 PE100 bimodal PE100RC Monofilament Tape Bimodal W&C Geomembrane Rotomolding  New/improved

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2015 

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LL C4 INcrease™  High processability INcrease™  INcrease™  High stiffness, ESCR & swell

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High ESCR INcrease™ 

Low sag PE100 PE100RC

High tenacity

Roto C6

Development

Trends in pressure pipes market

   l   e   v   e    l   e   c   n   a   m   r   o    f   r   e    P

1987: INEOS invented PE100RC the 1st generation of PE100 Low Sag 2.5 m PE100

PE100 PE63 1970

PE80 1980

1990

2000

2010

PE100RC

« PE100 designed for alternative installation techniques »

PE100 Requires sand bed protection

PE100RC Sandless Laying

Sand protection might represent up to 50 % of the total cost !

INpipe™100SR a new PE100RC reference

1 000 000

Superstress™

INEOS’ INpipe™100SR   Limit of testing No break!!

100 000    )    h    ( 10 000   e   r   u    l    i   a    f   o 1 000    t   e   m    i    t  , 100    T    C    N    F

10

NO BREAK !

   R    C    S    E

PE100RC

PE100RC PE100 PE100RC

PE 100

PE 80

Eltex® PE100

PE80

Blow moulding General Purpose HDPE

1

Innovene™ S is a solution provider for all piping systems including PE100RC, today’s most performing HDPE grade

Bimodal Blow Moulding

A

B

ZBM58-30HS, a new reference

ZBM58-30HS Bimodal comp. A Bimodal comp. B Chromium reference

Superior ESCR and processability multiplying opportunities for downgauging

Innovene™ G

Innovene™ S

Clean loop gas phase Swing LLDPE/HDPE

Bimodal slurry loops HDPE/Bimodal HDPE

Première platforms

G

Bimodal HDPE mLLDPE / mVLDPE for all market segments

S

Solutions for the new millenium

© INEOS 2015 - Innovene™, INcat™, INcrease ™, INpipe™, HPLL™ are trademarks of INEOS Technologies