Informe 3 - Lixiviación en Montón

 

 

_EISORWIMFM EFGINEFL HFYNR MO WFE HFRGNW Cfgult Cf gult fm mo Iekoeiorèf Ko Konl÷k nl÷k igf, Hieorf, Hotflúrk Ho tflúrk igf y Konkræcigf

O.F.P. IEKOEIORÈF IEKOEIORÈF HO]FLÚRKIGF Lfbnrftnrin Lfbnrftnr in Eº 7

LITISIFGINE OE HNE]NE •

  PRNCOWNR: Gfbfllorn Rèns Hfeuol Prumoegin 

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  G_RWN: Lfbnrftnrin mo Dimrnhotflurkif

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   F  FL L _HEN:  Mol Pien Gfhfe Aovie 6=630222 Jnrko Gugdulf Hfrin 6;63004? Pfetnjf Gdævoz Gneenr [flmir 6;630236

 

 

IE]RNM_GGI×E   IE]RNM_GGI×E

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NBJO]ISN   NBJO]ISN

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C_EMFHOE]N ]O×RIGN  ]O×RIGN 

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OV_IPNW Y HF]ORIFLOW  HF]ORIFLOW 

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GNEMIGINE GNEM IGINEOW OW MO ]RFBFJ ]RFB FJN N 

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PRNGOMIHIOE]N OTPORIHOE]FL  OTPORIHOE]FL  

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GÆLG_LNW OTPO OTPORIHO RIHOE]FLOW E]FLOW  

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GNEGL_WINEOW   GNEGL_WINEOW

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BIBLINKRFCÈF

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IE]RNM_GGI×E Lf lixivifgi÷e quo so trfbfjf so trftf mo uef gnestruggi÷e mo uens hnetneos bioe mocieimns y gnetrnlfmns mo ue hieorfl, gne uef krfeulnhotrèf yf motorhiefmf, fsè nbtoeor uef roguporfgi÷e ÷ptihf. Wu prngosn os mo uef murfgi÷e mo fprnxihfmfhoeto uef sohfef, rovisfemn tfhbiée ol gfumfl mo flihoetfgi÷e mo rofgtivn y pntoegifl mo nximfgi÷e f ln lfrkn mo tnmns lns mèfs. Osto tipn mo lixivifgi÷e ostæ sioemn hæs gnesimorfmf yf quo so puomo fprnvogdfr hftoriflos quo fetos en so gnesimorfbf gnhn roetfblos pfrf su oxtrfggi÷e fetos mo lf oxistoegif mo oso hétnmn. Lf gieétigf mo lixivifgi÷e os lf bfso cuemfhoetfl pfrf motorhiefr lfs rofggineos dimrnhotflúrkigfs, trftæemnso hæs mo uef cfso. Lfs rofggineos sne prngosns loetns, ue feælisis motfllfmn mo lf soguoegif mo rofggi÷e, su volngimfm ntnrkf motorhiefr ol hogfeishn mo lf rofggi÷e y to ntnrkf mftns gieétigns, ietrèesogns eogosfrins pfrf ol misoön mol oquipn fmogufmn,  pfrf usns gnhorgiflos prægtigfs. Oe osto trfbfjn prosoetfhns lf lixivifgi÷e mo ue hieorfl nximfmn mo gnbro y ol hétnmn pfrf motorhiefrln.

NBJO]ISN Lf lixivifgi÷e os ue prngosn dimrnhotflúrkign guyn cie os nbtoeor ol gnbro mo lns hieorflos nximfmns quo ln gnetioeoe, fpligfemn uef misnlugi3e mo ægimn sulcúrign. Lns hieorflos nximfmns sne soesiblos fl ftfquo mo snlugineos ægimfs, mopoemioemn mo su porhofbilimfm, ol hieorfl so vf duhomogioemn.

C_EMFHOE]N ]O×RIGN

Lf lixivifgi÷e oe pilfs pfrf lns hieorflos mopoemo mo lf nximfgi÷e efturfl mo ostns sulcurns homifeto ol gnetfgtn gnetieun gne ol firo y ol fkuf. Lns ÷ximns, sulcurns y lns hieorflos hixtns quo so oxtrfoe oxtr foe oe lf clntfgi÷e mo hieorflos mo fltf loy, porn gufemn lf loy os mohfsifmn bfjf gnhn pfrf justicigfr su boeocigin y trftfhioetn  pirnhotflúrkign, so trftfe pnr lixivifgi÷e oe pilfs, gnesistioemn ol prngosn oe fpilfr prihorn ol hieorfl oe ue ærof quo tioeo osgurrihioetn dfgif uef pnzf provifhoeto propfrfmf. Luokn so rngèf snbro lfs pilfs lf snlugi÷e lixivifeto quo gnetioeo ægimn sulcúrign y so mojf  porgnlfr mosgoemoetohoeto f trfvés mol hieorfl pfrf pfrf quo so m misuolvf isuolvf priegipflhoeto lns ÷ximns ÷ximns y mohæs ospogios quo so dfe cnrhfmn pnr lf nximfgi÷e mol sulcurn mo gnbro. Lns hieorflos quo gnetioeoe 6% mo gnbro so puomoe trftfr ogne÷higfhoeto oe pilfs gne lfs snlugineos proöfmfs quo vfe f progipitfgi÷e lfs guflos gnetioeoe mo 6,? kr/lt mo gnbro.

 

  Ol prngosn os bfstfeto loetn y ol hieorfl mo tfhfön mo guftrn f sois pulk. Puomoe roquorir mo hugdns hosos pfrf quo lnkro uef oxtrfggi÷e fmogufmf. Lf prnmuggi÷e mo gnbro mosmo hoefs nximfmfs df imn mishieuyoemn.

Lfs rofggineos quo knbiorefe ol prngosn mo lixivifgi÷e. Gu2N + D2WN=  ä GuWN= + Gu + D2N Gu + Co7+ ä Gu2+ + Co2+ GuN + D2WN= ä GuWN= + D2N

Rofggineos sihultfeofs f lf mol gnbro. Co7+ + D2WN= ä Co7WN= + 2D+ Co2+ + D2WN= ä Co WN= + 2D+ GfGN7 + D2WN=ä GfWN= + GN2 +D2N Fl2Wi2N; + D2WN=ä Fl2 (WN=)7 + WiN2 + D2N

OV_IPNW Y HF]ORIFLOW            

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2 bflmos 6 joriekf mo voenglisis. Yuto. Oquipn mo lixivifgi÷e (gnluhefs). 6 prnbotf. Homimnr mo pD

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  Homimnr mo pntoegifl mo nximfgi÷e.

GNEMIGINEOW MO ]RFBFJN              

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Moesimfm fpfroeto mol hieorfl8 6=30 k/L 62;?4 Ak mo hieorfl nximfmn mo Gu 4L mo D2WN= t lixivifgi÷e86 sohfef Gfumfl: =; kntfs/hie pD: (6.6”6.2) Od: 7;0hv

 

 

PRNGOMIHIOE]N PRNGOMI HIOE]N OTPORIHO OTPORIHOE]FL E]FL 6) Lf huostrf mo hieorfl pfrf lf prægtigf mo lfbnrftnrin ostæ gnestituimn oe hfynr pnrgoetfjo pnr ÷ximns mo Gu gne uef loy mo gfbozf mo ?.9%(GuN), so tioeo tfhbiée lf prosoegif mo ineos hotæligns mo Co7+, GN72-, Fl 2) Wo tnhfe trnzns mo hieorfl mo ue tfhfön oet ro 2‘ y =‘,luokn so pfs÷ pnr lf gdfegfmnrf quijfmf mol mo lfbnrftnrin guyn sot orf mo ;hh, mo mo ostnprihfrif so tnhfmouef huostrf 62 ak fprnxihfmfhoeto, f ostf huostrf so 7) Mospués

=) ?) 3) ;)

lo roflizf ue feælisis krfeulnhétrign, Luokn os dnhnkoeoizfmn y gnlngfmn moetrn mo lf gnluhef mo lixivifgi÷e fgnemiginefmf gnevoeioetohoeto pfrf ol ostumin mo hieorflos f eivol mo lfbnrftnrin. Wo guoetf gne uef snlugi÷e vflnrfmf mo D2WN= guyf gnegoetrfgi÷e os mo 2? kr/L, f ue vnluhoe mo 4 L, ol gufl so fmiginef f ue gfumfl mo ?0 kntfs/hie f lf gnluhef gfrkfmf gne ol hieorfl. Ol prngosn mo lixivifgi÷e tioeo uef murfgi÷e mo uef sohfef, tnhæemnso gfumfl mo flihoetfgi÷e mo rofgtivn y pntoegifl mo nximfgi÷e f ln lfrkn mo tnmns lns mèfs. Fl gfbn mo lns ; mèfs so gflgul÷ ol vnluhoe mo snlugi÷e gfrkfmf (snl. Hfmro) ;200 hL y uef gnegoetrfgi÷e mo 63.2 k/L ol gnesuhn mo snlugi÷e mo lfvfmn 7000 hL. Gne uef gnegoetrfgi÷e gnegoetrfgi÷ e mo 9.? k/L.

GÆLG_LNW GÆL G_LNW OTP OTPORI ORIHOE HOE]FL ]FLOW OW Lixivifgi÷e oe hnet÷e Huostrf % Gu Hieorfl Gu 2.;

% Co 66.4;

# Huostrf 4-env 9-env 66-env 62-env 67-env 6=-env 6?-env 63-env 64-env 69-env

pph Gu 0,?9 0,74 76?9 =377 30?? 4003 4727 9626 9777 60293

pph Co 0,03 0,07 2274 6;0 =?; 60=3 297 923 6639 64?4

]iohpn (mèfs) 0 6 7 = ? 3 ; 4 60 66

QGuX (H/L) 0,0000 0,0000 0,0=9; 0,0;70 0,09?= 0,6236 0,6766 0,6=73 0,6=;0 0,6326

QGuX-QGuXi 0,0000 0,0000 0,0=9; 0,0;70 0,09?7 0,6236 0,6766 0,6=73 0,6=;0 0,6326

20-env

9=;=

6644

62

0,6=92

0,6=92

 

 

GNEGL_WINEOW pnmohns vor vor quo ln lnss mns pri prihorns horns mftns oe lns mns prihorns prihorns mèfs ◎  Mol prihor kræcign pnmohns tioeoe vflnros huy bfjns mobimn f quo ol clujn mol lixivifeto df simn bfjn. ◎  Lf snlugi÷e lo lixivifeto ohplofmf os huy sologtivf. ◎  Oe ol puetn 7 mol Co pnmohns nbsorvfr quo dfy ue orrnr, yf quo en puomo mispfrfrso ol vflnr mol gnetoeimn Co. Pnr ostf rfz÷e ol puetn 7 mo Co mobo sor mosgfrtfmn pfrf nbtoeor uef kræcigf hæs progisf.

 

 

BIBLINKRFCÈF   Kuèf mo lfbnrftnrin mo dimrnhotflurkif - Iek. Gfbfllorn Rèns   dttp://rovistfmohotflurkif.rovistfs.gsig.os/iemox.pdp/rovistfmohotflurkif/frtiglo/mnwel

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nfm/464/429 dttp://tosis.usne.hx/mikitfl/tosis/mngs/220?3/Gfpituln2.pmc dttps://sisbib.uehsh.omu.po/bibvirtufl/publigfgineos/konlnkif/v07^e?/oxtrfgg^lixiv.d th#:~:toxt8Ol%20h%G7%F9tnmn%20mo%20lixivifgi%G7%B7e%20oe,nporfgineos %20mo%20gifeurfgi%G7%B7e%20pnr%20fkitfgi%G7%B7e.