Flexible packaging has now become popular in various industries ranging from consumer products to industrial applications. Flexible applications. Both flexographic and gravure printing methods are used for flex flexible ible packaging printing. These two methods share the same raw materials; hence guidelines to select raw materials for the both printing methods are common. Review the guidelines to select raw materials such as waxes, surface additives, various resins as well as pigments for flexible packaging inks. By Terence Kenneth
Flexible Packaging Packaging Inks And Raw Materials Se Materials Selection lection Process
Flexible Packag Flexible Packaging ing Inks And And Raw Materials Materials Selection Selection Process Flexibl e packaging is printe Flexible p rinted d using both f lexographic and gravure printing methods methods and comprises and comprises a number number of different end products. These would include but are not limited to packaging for: Confectionary Confectio nary products Cookies/biscuits Coffee Juice Food
Types of Flexible Packaging Inks From an ink point of view, inks for flexible packa packaging ging can be divided into surface printing inks and inks and lamination inks. inks. For the most part, flexographic and gravure inks share the same raw materials, so for this matrix we will group both printing methods together.
Surface Printing Inks
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Surface printing inks must have reasonably: High gloss Excellent rub resistance and Resistance to a number of different external ele ments, such as Resistance solvents,, detergents and other materials that may come water, solvents into contact with the printed surface These inks typically use a protect protective ive overprint varnish to increase the surface resistance and to impart the desired C.O.F. and gloss. (See formulation example here)
Lamination Inks
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Lamination is the process of combining two or more substrates to form a tough packaging structure to hold and provide barrier protection for the contents. Lamination can be accomplished with adhesives (adhesive lamination) or with molten plastic (extrusion lamination) that acts to adhere the packaging films together. Lamination inks are typically sealed inside the lamination structure so that the ink surface is not exposed to the outside, however the inks must still exhibit excellent adhesion to the film on which they are printed and they must not interfere with the bonding of the lamination films. (See formulation example here)
The differences be tween surface printing inks and lamination inks are slight but important: Surface printing inks are typically formulated with waxes that migrate to the surface of the ink film to provide rub, scuff and other resistance properties. They must also have good gloss, particularly if they are not to be overprinted. Lamination inks do not have the gloss requirements of surface inks but they do require ex cellent bonding ability to ensure that the lamination structure isn't compromised after manufacturing. They typically do not incorporate a lot of waxes or surface active ingredients as these can often interfere with lamination bonding. Common types of flexible packaging substrates include: Biaxially oriented polypropylene (BOPP) Cast polypropylene (CPP) Polyester (treated or coated) Nylon Cellophane Polyethylene (LLDPE/HDPE)
Raw Materials Used for Solvent-based Flexible Packaging Inks Additives and Their Functions
Raw Material
Function
Plasticizer (Phthalate or Benzoate)
Flexibility and some adhesive properties
Metal Chelating Agent
Adhesion, water resistance, heat resistance
Waxes
Rub and scuff resistance
Silicone Oils
Slip and tape release
Check Out More Additives for Solvent-based Inks
Select Waxes for Cold Seal and Hot S eal Flexible Packaging The primary waxes used are Polyethylene , Polypropylene and Erucimide waxes, which are used to impart slip to the i nk surface. Raw Material
PE Wax
Erucimide/stearamide
PP Wax
Silicone
Rub resistance
Scratch
Slip
Water resistance
Gloss
Excellent
Excellent
Excellent
Poor
Moderate
Fair
Excellent
Excellent
Good
Fair
Excellent
Excellent
Excellent
Poor
Fair
Fair
Excellent
Excellent
Moderate
Excellent
PTFE
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Excellent
Excellent
Moderate
Moderate
Poor
Cold Seal Packaging Many temperature sensitive confectionary items (e.g. chocolate) are packaged and sealed using cold seal adhesives. These surface printed constructions consist of a surface printed ink and a cold seal release lacquer (CSRL), which prevents the printed ink from offsetting against the cold seal glue when in the printed roll. Inks for cold seal packaging should not be formulated with any kind of fatty amide (erucimide) or PFE waxes as these can "poison" the cold seal adhesive if left in contact with the adhesive for any length of time in the printed roll.
Heat Seal Packaging Both surface printed inks and lamination inks can also be heat sealed. In this instance a heat sealable film is used or a heat sealable coating is used to combine two films by applying heat to achieve the seal. Sealing temperatures and pressures can vary so when formulating these types of inks, it's important to know and test the inks under these sealing conditions. A typical sealing specification may be 350 degrees Fahrenheit for half a second at 40p.s.i. » Learn How Wax Emulsion Help Improve Properties of Inks
Select Resins for Flexible Packag ing Inks The typical resins used in solvent-based packaging inks are listed in the table below. Each resin type shown can be combined with others to increase the overall performance of the inks, for example nitrocellulose is often combined with polyurethane or polyamide resins. Raw Material Pigment wetting
Adhesion
Usage
Heat Resistance
Gloss
Nitrocellulose resin
Excellent
Very good
Surface & lamination inks
Excellent
Excellent
Polyurethane resin
N/A
Excellent
Surface & lamination inks
Excellent
Very good
Alcohol soluble Polyamide
Unsuitable
Good
Very good
Very good
Hot melt polyamide
Unsuitable
Excellent
Excellent
Excellent
Fair
Good
Excellent
Very good
Poor
Good
Good
Very good
Poor
Fair
Fair
Very good
Fair
Good
Very good
Very good
PVB
Acrylic
Ketone Cellulose Acetate Propionate (CAP)
Surface inks
Lamination inks
Surface & lamination inks
Surface inks
Surface inks
Surface & lamination inks
» View All Commercially Available Resins Suitable for Solvent-based Inks
Pigments & Their Function in Flexible Packaging Inks Raw Mate rial
Usage
Transparency
G loss/Bril liance He at Re si stance
Stabili ty
Organic Pigments
Surface & lamination inks
Excellent
Excellent
Moderate
Excellent
Inorganic Pigments
Surface & lamination inks
Fair
Very Good
Excellent
Excellent
Metallic Pigments
Surface & lamination inks Metallic pigments should be non-leafing types
Poor
Excellent
Moderate
Excellent
» Select Suitable Pigment Grade for your Solvent-based Ink Formulation
Ink Formulations for Flexible Packaging
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1. Flexographic Ink Formulation Surface Printing
Product
Parts by Weight
Nitrocellulose Resin
8.00
Ethyl Alcohol
16.00
Ethyl Acetate
3.00
PE Wax
1.00
Alcohol soluble Polyamide Varnish (40% solids)
22.00
NC Pigment Dispersion
50.00
Total
100.00
2. Gravure Ink Formulation for Lamination Printing:
Product
Parts by Weight
Ethyl Alcohol
13.00
Ethyl Acetate
6.00
Nitrocellulose Resin
3.00
Polyurethane resin
25.00
Benzoate plasticizer
1.00
Adhesion promoter
2.00
*NC based pigment Dispersion
50.00
Total
100.00
External links Find Today's Best Adhesion Promoters and Primers for Adhesives & Coatings Get Insider Knowledge to Better Sel ect your Additives & Solve your Coatings Formulation Issues... See how to f aster replace your solvent -- Video Tutorial
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