Ejercicos Cinetica Quimica
March 4, 2023 | Author: Anonymous | Category: N/A
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Ekericils Icjetcig quchcig ̇ Icjėtcig tcig Wuchcig y Igtġfcscs fcscs (Ujcverscdgd Hciblgigjg de Ygj Jcilfçs de Bcdgfal)
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De tg`fgs def Yhctb _gj Jess l`tuvchls fls scaucejtes dgtls;
∏¾092731.5079>.? 00>.1 ∏¾092731.50 Ejtljies;
∏ 322>5.505 (00>.1 ) 520.75 03?14.32
^PL@FEHG 3.-
Fls resuftgdls ilhpfetls reoerejtes gf prl`fehg 7.2 slj ilhl scaue; 7>>>/ T, M-7 Fla M 7>>> / T-7 Fla M
7.??
7.19
7.10
7.15
7.20
7.27
7.20
7.20
-4.75 7.29
-9.15 7.22
-9.?5 7.37
-9.9> 7.37
-9.7> 7.30
-9.0> 0.>5
-9.>> 0.>5
-0.3> 0.>5
-0.35
-0.?>
-0.1>
-9.>>
-0.9>
-0.9>
-0.75
-0.95
YLFUICLJ;
G trgvãs deffls hãtldl de fls hèjchls pgrg iugdrgdls regfcz regfczgdl gdl ej fg igfiufgdlrg se l`tuvcerlj scaucejtes resuftgdls l`tejer fg fcjegfczgicùj de fg scaucejte exprescùj;
fj 7 G8 447>.2319 @8 -77.752
Desigragdl plr Fgrg Pcil (jfrNblthgcf.ilh)
fLHlGP^D ?53 2
^PL@FEHG 7>.-
Fg deterhcjgicùj de M ej ef ^rl`fehg 2 se `gsg ej fg hedcicùj dcreitg de ilhplscicljes de equcfc`rcl. Use fls scaucejtes dgtls igflrchãtrcils y fg terierg fey pgrg prepgrgr ujg arçocig de fla M ej oujicùj de 7/ T pgrg fg sèjtescs de hetgjlf. Cjifuyg uj cjtervgfl de tehpergturg de 032 g 2>> M. Ilhpgre fg arçocig ilj ef resuftgdl l`tejcdl ej ef ^rl`fehg 3. Fg ejtrlpèg def IL agselsl g 032.7? M ej estgdl de ags cdegf g 7 gth es 41.9> igf/hlf a)(M). Ef vgflr pgrg ef bcdrùaejl es 97.07. Ef igflr de vgplrczgicùj def hetgjl7 g 032.7? M es 2 349.1 a, y fg prescùj de vgplr g 032.7? M es >.7?90 gth. gth. Ef igflr de olrhgicùj def IB9LB ej estgdl de ags cdegf g 7 gth es -42 43> igf/hlf a. Fls dgtls de igflr espeièocil y de igflr de trgjscicùj pgrg ef hetgjl7 `gkgs tehpergturgs slj ilhl scaue;
T,M Ip, igf (hlf a) (lI)
T,M Ip
72.7>
07.55
04.49
01.05
9>.10
94.99
91.?4
4>.1
49.39
7.7>3 42.>1 5.4>4 23.03 3.?39 703.92 70.02 725.7> 7?.?1
7.570 5?.>9 ?.405 39.72 3.393 799.17 70.?4 723.>? 7?.11
7.353 53.59 ?.245 31.00 7>.09 741.2? 70.31 73?.11 7?.12
0.030 ?9.03 1.050 777.74 77.09 750.03 79.?3 07>.94 7?.31
0.203 ?3.35 2.>>7 777.20 77.42 759.32 74.70 095.24 71.47
9.491 19.35 2.930 771.31 77.?4 7?4.74 77.03 05?.94 71.1>
9.3?0 11.?7 2.195 772.13 77.?4 7??.09 77.?9 019.52 72.9>
4.401 27.42 3.>>7 707.44 77.14 7?1.15 77.?2 025.75 72.1>
4.24> 25.50 3.035 705.>1 70.72 727.>3 7?.?> 030.>7 73.77
Fls ircstgfes de hetgjl7 presejtgj ujg trgjscicùj de ogse g 751.4 M pgrg fg iugf ΔB 8 754.9 igf/hlf a. Ef pujtl de ouscùj es 715.00 M y ef igflr de ouscùj es 151.> igf/hlf a. Fls dgtls de igflr espeièocil g tehpergturgs superclres g 032.7? M slj ilhl scaue; T, M Ip, IB9LB, igf/( hlf a) ( lI) T, lI Ip, IL, igf/( hlf a) ( lI) Ip, B0, igf/( hlf a) ( lI)
032.7?
9>>
4>>
5>>
?>>
1>>
2>>
7>.2
7>.2
70.1
74.5
7?.9
71.2
73.0
05 >.043
7>> >.05>
0>> >.059
9>> >.052
4>> >.0?4
5>> >.017
?>> >.01?
9.40
9.45
9.41
9.41
9.42
9.5>
9.59
Desigragdl plr Fgrg Pcil (jfrNblthgcf.ilh)
fLHlGP^D ?53 2
^PL@FEHG 77.-
Fg pcedrg igfczg (IgIL9) se desilhplje gf igfejtgr prlduicejdl igf (IgL) y `cùxcdl de igr`ljl. Deterhcje fg tehpergturg g fg iugf fg pcedrg igfczg desgrrlffg ujg prescùj de desilhplscicùj de 7 gth.
YLFUICLJ; IgIL 9 9 IgL+ IL 0
-9 p85.451 + IL0; I IgIL ; Ip870.510
5 0
7.>45 x 7> + >+ + 0.?91 x 7>T-9T + >-7.751 9.70>x x7>7>T5T 0 IgIL9; Ip; 5.451 + 7.>45 x 7> -9T ’ 7.751 x 7>-?T0
∏
∏ 7 7..>7777 7.743 x 7>∐T >.337?7? x 7>T De tg`fgs l`tuvchls fls scaucejtes dgtls;
8 8 ∏ ∏A .8 ^lr fl que;
∏ ∏ 77032. 032.75 ∐.Ñ 032. 7 5 ∏ . 7.>77 .Ñ 007>2. >2.>>?2 >?244 . 007 79>4>7 ̀ ∏ fj fj 50.?>?>312 2.974 ∐032. ∐. 7.4092Ñ7> 75
Desigragdl plr Fgrg Pcil (jfrNblthgcf.ilh)
fLHlGP^D ?53 2
∏ ∏ 8 . .50. 032. 0? Ñ j755∐. ∏ ∏ ? >?>312 fjfj 032.ffj 77 Ñ 7 5 ?>2. 25 7.>77 . 0?..3?> fj ∏ ∏ ∏ Peslfvcejdl fg eiugicùj l`tejehls;
77775>5>.3.3?? ^PL@FEHG 70.-
Fg ejeraèg fc`re pgrg fgs hezifgs ej ogse agselsg de j-pejtgjl y jel pejtgjl g 7 gth y 4>> M estç dgdg plr fg exprescùj
3?>> 233> 233> 2>> 2>> fj fj
…. (7)
Dljde fls su`èjdcies 7 y 0 se reocerej gf j-pejtgjl y gf jel pejtgjl, respeitcvghejte, y O es es fg ejeraèg fc`re ej igf/ (hlf a de fg hezifg). g) Deterhcje fg ilhplscicùj de equcfc`rcl g 7 gth y 4>> M pgrg fg regiicùj de cslherczgicùj ejtre ef y ef jel . `) Trgie ujg iurvg de O ej oujicùj de y7 pgrg fg hezifg g 7 gth y 4>> M y fg fligfczgicùj def pujtl de equcfc`rcl de fg regiicùj deterhcjgdl ej
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YLFUICLJ;
g)
fj ∏
…. (0) ….
←
….. (9)
Gpfcigjdl flagrcthl g gh`ls fgdls;
fjfj
fjfj fj
…(9)
∏ de fg ei. (0) y sustctuyejdl fg ei. (9) ej fg ei. ei . (0), tejehls; ∏ fj fj Yc; 7 7 Ejtljies; Despekgjdl
Desigragdl plr Fgrg Pcil (jfrNblthgcf.ilh)
fLHlGP^D ?53 2
∏ ffj fj fj7 7
…(5)
Caugfgjdl fg eiugicùj (5) y fg eiugicùj (7) pgrg igfiufgr fg
; ]]fj fj fj fj7 7X 3?>>7233> 2>>7fj7 fjfj Peslfvcejdl fg eiugicùj pgrg ; 5.?2>1x7>∐ De`cdl g que; 7 75.?2>1x7>∐ >.333334
>.333334 `)
ΔA vs Orgiicùj j-^ejgtjl 3?>> 35>> s 34>> ` ` c A39>> e d e r 30>> ` c F g è 37>> a r e j E e 3>>>
d l c ` 23>> h g I
22>> 21>> 2?>> >
>.0
>.4
>.?
>.2
7
7.0
Orgiicùj de j-^ejtgjl ΔA
Desigragdl plr Fgrg Pcil (jfrNblthgcf.ilh)
fLHlGP^D ?53 2
^PL@FEHG 79.-
Ef `utgdcejl se prlduie plr hedcl de fg desbcdrlaejgicùj igtgfètcig ej ogse agselsg def f-`utejl;
←
^grg reduicr gf hèjchl fgs regiicljes seiujdgrcgs y hgjtejer ef jcvef de tehpergturg, fg gfchejtgicùj de `utejl se hezifg ilj vgplr de gftg tehpergturg gjtes de ejtrgr gf regitlr. Estche fg tehpergturg def eofuejte def regitlr, iugjdl se gfigjzg ef equcfc`rcl de fg regiicùj, que se requcere pgrg iljvertcr 9>% def `utejl ej `utgdcejl. Fg prescùj ef regitlr es 0 gth y fg gfchejtgicùj iljscste ej 70 hlfes de vgplr plr hlf de `utejl. Fls dgtl de ejeraèg fc`re, Δ ej igf/(hlf a) slj;
7,9-`utgdcejl 7-`utejl 9?>1>
[G8>.9>
?>>M
1>>M
2>>M
3>>M
4?12> 40>1>
5> ?>> 4091>
5442> 4345>
524>> 5?05>
^8 0 gth
@gse de içfiufl; jG>87 hlf
∐
jDL8 70 hlf
∐ 8 ∐∐ .8 >.9
Gdehçs;
Dljde; jl8
∗ 79
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