Diagrama Hierro Carbono
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Diagrama Hierro Carbono...
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El estado actual del diagrama de equilibrio de las aleaciones hierro-carbono fue establecido como resultado de las investigaciones hechas por varios científicos. La elaboración de este diagrama fue empezada por D. Chernov, quien estableció en 1968 los puntos críticos del acero.
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Más tarde volvió a estudiar reiteradamente este diagrama. N. Gutovski, M. Wittorft, Roberts Austen, Roozebom hicieron una gran aportación al estudio de este diagrama. Los últimos datos acerca del diagrama están expuestos en las obras de I. Kornilov.
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En el diagrama de equilibrio o de fases, Fe-C se representan las transformaciones que sufren los aceros al carbono con la temperatura, admitiendo que el calentamiento (o enfriamiento) de la mezcla se realiza muy lentamente de modo que los procesos de difusión (homogeneización) tienen tiempo para completarse. Dicho diagrama se obtiene experimentalmente
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El acero se obtiene cuando se mezcla hierro con carbono. El acero es un acero al que se le añaden elementos de aleación adicionales al carbono. Al acero que está formado simplemente por hierro y carbono se le
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Las aleaciones hierro-carbono pertenecen al tipo de aleaciones que forman una composición química. El carbono se puede encontrar en las aleaciones hierro-carbono, tanto en estado ligado (Fe3C), como en estado libre (C, es decir, grafito.
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Para estudiar las transformaciones que tienen lugar en aceros y fundiciones blancas se emplea el diagrama Fe-Fe3C, y para estudiar fundiciones grises, ambos diagramas (Fe-Fe3C y Fe-C). Este diagrama comprende dos sistemas: 0
Fe-Fe3C (metal estable); este sistema está representado en el diagrama con líneas llenas gruesas y comprende aceros y fundiciones blancas, o sea, las aleaciones con el carbono ligado, sin carbono libre
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El carbono puede presentarse en
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El hierro cristaliza en la variedad alfa hasta la temperatura de 768ºC. La red espacial a la que pertenece es la red cúbica centrada en el cuerpo (BCC). La distancia entre átomos es de 2.86 Å. El hierro alfa no disuelve prácticamente en
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La variedad delta se inicia a los 1400ºC, observándose, entonces una reducción en el parámetro hasta 2.93Å, y un retorno a la estructura BCC. Su máxima solubilidad de carbono es 0.007% a 1487ºC. Esta variedad es poco interesante desde el punto de vista industrial. A partir de 1537ºC se inicia la fusión del Fe puro.
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Alta Dureza
CEMENTITA
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La austenita es una forma de ordenamiento distinta de los átomos de hierro y carbono. Ésta es la forma estable del hierro puro a temperaturas que oscilan entre los 900 a 1400 ºC. Está formado por una disolución sólida del carbono de hierro, lo que supone un porcentaje máximo de C del 2,11%. Es dúctil, blanda y tenaz. Es la forma cúbica centrada en las caras (FCC) del hierro. También se le conoce como austerita. Admite el temple, pero no es magnético.
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La estructura cristalina de la austenita es del tipo cúbica, de caras centradas, en donde se diluyen en solución sólida los átomos de carbono en los intersticios, hasta un máximo tal como lo muestra el diagrama de fase Fe-C. Esta estructura permite una mejor difusión con el carbono, acelerando así el proceso de carburación del acero. La solubilidad máxima es sólo del 1,67%. Hay que recordar que por definición los aceros contienen menos de 1,67% de carbono y pueden tener disuelto el carbono completamente a altas temperaturas.
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No es magnética
Baja temperatura de fusión.
FERRITA
Excelente soldabilidad.
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La ledeburita no es un constituyente de los aceros, sino de las fundiciones. Se encuentra en las aleaciones Fe-C cuando el porcentaje de carbono en hierro aleado es superior al 25%, es decir, decir, un contenido total de 1.76% de carbono. La ledeburita se forma al enfriar una fundición líquida de carbono (de composición alrededor del 4.3% de C) desde 1130ºC, siendo estable hasta 723ºC, descomponiéndose a partir de esta temperatura en ferrita y cementita. Está formada por 52% de cementita y 48% de austenita. La ledeburita no existe a temperatura ambiente en las fundiciones ordinarias debido a que en el enfriamiento se transforma en cementita y perlita; sin embargo en las fundiciones se puede conocer las zonas donde existió la ledeburita por el aspecto eutéctico con que quedan las agrupaciones de perlita y cementita.
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Es un agregado muy fino de cementita y ferrita, se produce por un enfriamiento de la austenita con una velocidad de enfriamiento ligeramente inferior a la crítica de temple o por transformación isotérmica de la austenita en el rango de temperatura de 500 a 600C, o
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Es la resultante de la transformación isotérmica de la austenita entre los 500°C y los 600°C; es decir, enfriando rápidamente la austenita hasta la temperatura indicada anteriormente y manteniéndola a esa temperatura hasta la transformación total, ver Se produce también la troostita cuando se enfría la
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La bainita es una mezcla de fases de ferrita y cementita y en su formación intervienen procesos de difusión. La bainita forma agujas o placas, dependiendo de la temperatura de transformación. Los detalles microestructurales de la bainita son tan finos que su resolución sólo es posible mediante el microscopio electrónico. Está compuesta de una matriz ferrítica y de partículas alargadas de cementita.
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Sin embargo, a diferencia de la perlita, la ferrita y la cementita no están presentes en formas que dependen de la aleación y la temperatura de transformación. La microestructura depende de la temperatura y se distinguen dos morfologías:
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BAINITA SUPERIOR: Se forma en rangos de temperatura inmediatamentE inferiores a los de perlita. se compone de agujas o bastones de ferrita con cementita entre ellas.
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Después de la cementita es el constituyente más duro de los aceros. La martensita se presenta en forma de agujas y cristaliza en la red tetragonal. La proporción de carbono en la martensita no es constante, sino que varía hasta un máximo de 0.89% aumentando su dureza, resistencia mecánica y
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Existe una gran variedad en la forma de identificar y clasificar a los aceros. Sin embargo, la mayoría mayoría de los aceros utilizados industrialmente presentan una designación normalizada expresada por medio de cifras, letras y signos. Hay dos tipos de designaciones para cada tipo de material, una simbólica y otra numérica. La designación simbólica expresa normalmente las características físicas, químicas o tecnológicas del material y, en muchos casos, otras características suplementarias que permitan su identificación de una forma más precisa. Por otro lado, la designación numérica expresa una codificación
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La alta variedad de aceros ha hecho surgir una alta gama de normatividad que puede cambiar de un país a otro algunas de estas son: 0
0 0 0 0
ANSI (American National Standards Institute) ACI (American National Standards Institute), AWS AWS (American Welding Society), ASME (American Society of Mechanical Engineers CENIM (Centro Nacional de Investigaciones Metalúrgicas)
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Al igual que los aceros, las fundiciones son básicamente aleaciones hierro- carbono, con una alto porcentaje de carbono mayor que los aceros. Su concentración esta entre 1.76% y 6.67% de carbono. La mayoría de las fundiciones que se manufacturan comercialmente están entre entre 2,5% 2,5% y 4% de de carbono. El máximo porcentaje de carbono que es posible obtener en las aleaciones ferrosas es 6.67%. El mejor método para clasificar las fundiciones es de acuerdo con su estructura metalográfica.
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Las variables para definir los tipos de fundiciones son: 0 0
El porcentaje de carbono. El contenido de aleación y de impurezas.
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La fundición blanca son aleaciones hipoeutécticas y las transformaciones que tienen lugar durante su enfriamiento son análogas a las de la aleación de 2,5 % de carbono. carbono. Se forma forma al enfriar rápidamente la fundición de hierro desde el estado líquido, durante el enfriamiento la austenita solidifica a partir de la aleación fundida en forma de dendritas. Se distinguen por que al fracturarse presenta un
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Esta fundición apareció del afán de ablandar la fundición blanca y convertirla convertirla en un material tenaz. La fundición maleable se obtiene a partir de la fundición blanca por calentamiento prolongado prolongado en atmósfera atmósfera inerte (para prevenir la oxidación) a
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Es una aleación hierro-carbono hipoeutéctica con un porcentaje entre 2.5 y 4.0 % y de silicio entre 1 y 3 %. El grafito suele aparecer como hilos dentro de una matriz de ferrita o perlita. Desde un punto de vista mecánico las fundiciones fundiciones grises grises son frágiles y poco resistentes resistentes a la
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Cuando no se requieren unas características mecánicas muy exigentes, las condiciones más interesantes que en general conviene que cumplan estas fundiciones son: 0 Que tengan buena colabilidad.
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