Compilation of Henry’s Law Constants for Inorganic and Organic Species of Potential Importance in Environmental Chemistry http://www.mpch-mainz.mpg.de/~sander/res/henry.html Rolf Sander Air Chemis Chemistry try Departme Department nt Max-Planck Institute of Chemistry PO Box 3060 55020 Mainz Germany e-mail:
[email protected] Version 3 (April 8, 1999) c Rolf Sander (non-commercial reproduction permitted)
Contents 1 Intro duction
3
2 The physical quantity of solubility
3
3 Temperature dependence
3
4 Unit conversions
3
5 How to use the Tables
4
6 Further Sources of Information
4
7 Data Table (Inorganic)
6
oxygen (O) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
6
hydrogen (H) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
6
nitrogen (N) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
7
fluorine (F) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
8
chlorine (Cl) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
9
bromine (Br) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
10
iodine (I) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
11
sulfur (S) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
12
rare gases . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
13
other elements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
13
2
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8 Data Table (Organic)
14
alkanes (C and H only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
14
cycloalkanes (C and H only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
27
aliphatic alkenes and cycloalkenes (C and H only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
28
aliphatic alkynes (C and H only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
30
mononuclear aromatics (C and H only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
31
terpe pen nes and po pollynuclear aromatics (C and H only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . alcohols (ROH) (C, H, and O only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
35 37
polyols (R(OH)n ) (C, H, and O only)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
41
per peroxi xide dess (R (ROO OOH) H) and per peroxy rad adic icaals (ROO (ROO)) (C, H, and O on only ly)) . . . . . . . . . . . . . . . . . . . . . . . . . .
43
aldehydes (RCHO) (C, H, and O only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
44
ketones (RCOR) (C, H, and O only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
46
carbo carboxy xyli licc acid acidss (RCO (RCOOH OH)) and and per perox oxy y carbo carboxy xyli licc aci acids ds (R (RCOOO COOOH) H) (C, (C, H, H, and and O onl only) y) . . . . . . . . . . . . . .
48
esters (RCOOR) (C, H, and O only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
50
ethers (ROR) (C, H, and O only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
54
misc miscel ella lan neo eous us,, ee.g .g.. mul multtiple iple func functi tioona nall ggrrou oups ps (C, H, aand nd O oonl nly) y) . . . . . . . . . . . . . . . . . . . . . . . . . . .
55
compounds with nitrogen: amines (RNH2 ) (C, H, O, and N only) . . . . . . . . . . . . . . . . . . . . . . . . . . . compounds compoun ds with nitrogen: nitrogen: amino acids (RCHNH2 COOH) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
58 59
co comp mpou ound ndss wit with h nit nitro roge gen: n: het heteero roccyc ycle less (C (C, H, H, O, O, aan nd N on only ly)) . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
59
compounds with nitrogen: nitrates (RONO2 ) (C, H, O, and N only) . . . . . . . . . . . . . . . . . . . . . . . . .
61
co comp mpou ound ndss wit ith h nit nitroge rogen: n: n nit itri rile less (R (RCN CN)) (C, H, O, an and d N on only ly)) . . . . . . . . . . . . . . . . . . . . . . . . . . .
65
compounds with nitrogen: nitro (RNO2 ) (C, H, O, and N only) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
66
compounds with fluorine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
68
aliphatic compou pounds with chlorine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
71
aromatic compounds with chlorine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
82
compou pounds with chlorine and fluorine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
84
compounds with bromine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
86
compounds with iodine
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
89
compounds with sulfur . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
90
po pollychlorobiphenyls (PCB’s), pe pessticides, etc. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
92
9 Notes
96
10 Acknowledgements
99
References
99
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1
3
Intr Introdu oduct ctio ion n
Henry’s law constants (solubilities) of trace gases of potential importance in environmental chemistry (atmospheric chemistry,, waste istry waste water treat treatmen ment, t, . . . ) have have been collected collected and converte converted d into a uniform uniform format. Disclaimer:: Although Disclaimer Although this compilation compilation has been b een edited with greatest greatest care the possibilit possibility y of errors errors cannot be excluded. excluded. If you use data from this table it is recommended recommended that you also check check the original original literature. literature. If you find an error in this table, table, please tell me about it!
2
The phys physica icall quan quantity tity of solu solubil bilit ity y
There are several ways of describing the solubility of a gas in water. Usually the Henry’s law constant k H is defined as: def
kH = ca /pg
(1)
Here, c a is the concentration of a species in the aqueous phase and pg is the partial Here, c partial pressure of that species in the gas phase. phase. as k H . (T = 298.15 K) it will be denoted as k If k k H refers to standard conditions (T Henry’s law constant can also be expressed as the dimensionless ratio between the aqueous-phase concentration ca of a species and its gas-phase concentration c concentration c g : def
cc kH = ca /cg = kH × RT
(2)
where R = gas constant and T where temperature.. To distinguish distinguish these different different physical physical quant quantities ities,, this constant constant has been b een T = temperature cc named k named k H here. Sometimes the reciprocal value k value k px H,inv is used, representing the volatility instead of the solubility. The usual definition is: def
k px H,inv = pg /xa =
H O M H O × kH 2
(3)
2
where x where x a = molar mixing ratio in the aqueous phase, H
2
3
O =
density of water, and M and M H
2
O =
molar mass of water.
Temperat emperature ure dependen dependence ce
A simple way to describe Henry’s law as a function of temperature is:
kH = kH × exp
−∆soln H
R
1
1 − T T
(4)
where ∆soln H = = enthalpy of solution. Here, the temperature dependence is: −d ln kH
d(1/T d(1 /T ))
4
=
∆soln H R
(5)
Unit Unit con conversi ersion onss
Detailed information about the conversion between different units and definitions of Henry’s law constants is given by Sander [1999]. [1999]. Here is a short summary: 3 molaq/dm3aq molaq /maq The commonly used unit for k for k H is [M/ [M/atm] = [ ]. The official official SI uni unitt is is [ ]. The conver conversion sion is: atm Pa
kH kH = 101. 101.325 × [(molaq /m3aq )/Pa] [M [M//atm] cc The relation between k between k H and k and k H is:
kH T cc = 12 12..2 × kH × [M//atm] [K] [M
(6)
(7)
4
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
At T At T = = 298.15 K this leads to:
kH cc = 0.0409 × kH [M [M//atm]
(8)
The commonly used unit for k px k H and and k k px H,inv is [atm]. The product of k H,inv is constant: k px kH H,inv × = 55 55..3 [M [M//atm] [atm]
5
(9)
How How tto ou use se the the Tab Table less
Inorganic substances are sorted according to the elements they contain. The order chosen is: O, H, N, F, Cl, Br, I, S, rare gases, others. Organic substances (i.e. everything with carbon, including CO and CO 2 ) are sorted somewhat arbitrarily by increasing chain cha in length and complexity complexity. Hetero Hetero atoms (N, F, Cl, Br, I, and S) are sorted sorted in the same way as for inorganic compounds. compounds. The column labeled ‘substance’ gives the systematic name, the chemical formula, trivial names (if any), and in several cases the CAS registry number (in square brackets). The column labeled ‘k ‘kH ’ contains the Henry’s law constants as defined in equation (1), rounded to two significant digits and given in the unit [M/ [M/atm].
The column labeled ‘−d ln kH /d(1 d(1/T /T )’ )’ contains the temperature dependence of the Henry’s law constants as defined in equations (4) and (5), rounded to two significant digits and given in the unit [K]. For each table entry the column labeled ‘type’ denotes how the Henry’s law constant was obtained in the given reference. Literature reviews are usually most reliable, followed by original publications of experimental determinations of k of k H . Other data has to be treated more carefully. The types listed here are roughly ordered by decreasing reliability: ‘L’ The cited cited pape paperr is a literatu literature re review. review. ‘M’ Original publication of a measured value (e.g. head-space or bubble column technique as explained by Betterton [1992]). ‘V’ Vapor pres pressur suree of the pure pure substa substance nce is used used to determi determine ne the Henry’s law constant (c/p (c/p for for a saturated solution). ‘R’ The cited paper presents presents a recalculatio recalculation n of previously previously published published material (e.g. extrapolation to a different temperature or concentration range). ‘T’ Thermodynamical calculation (∆solnG = −RT ln ln kH , see Sander [1999] for details). ‘C’ IThe paper is (e.g. cited cited here refers refer s to another anoth eron, referenc refer encee theses, which which could not that obtain personal persona l communicati communi cation, Ph.D. internal papers etc.). ‘X’ I haven’t haven’t seen seen the paper that that I cite here. I found it referen referenced ced by another paper or I know about it through others. ‘?’ The cited paper doesn’t clearly state state how the value value was obtained. ‘E’ The valu valuee is estima estimated ted.. Estima Estimates tes are only only listed listed if no reliabl reliablee measurements are available for that compound. In some cases there might be good agreement between different authors. However, if the original work they refer to is not known one has to be careful when evaluating the reliability. It is possible that they were recalculating data from the same source. The similarity in that case would not be due to independent investigations.
6
Further urther Source Sourcess of of Info Informa rmatio tion n
Further important references: • monoaromatic hydrocarbons, chlorobenzenes, and PCBs: Mackay et al. [1992a]
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
5
• polynuclear aromatic hydrocarbons, polychlorinated dioxins, and dibenzofuranes: Mackay et al. [1992b] • volatile organic chemicals: Mackay et al. [1993] • oxygen, nitrogen, and sulfur containing compounds: Mackay et al. [1995] • pestizides, PCB’s, etc.: Westcott et al. [1981]; Burkhard et al. [1985]; Hassett and Milicic [1985]; Yin and Hassett [1986]; Murphy et al. [1987]; Shiu et al. [1988]; Rice et al. [1997]; Fendinger and Glotfelty [1988]; Fendinger et al. [1989]; De Maagd et al. [1998]; Duce et al. [1991] • additional references that are not (yet) included: Lide and Frederikse [1995]; Shiu et al. [1994]; Watts and Brimblecombe [1987]; Wright et al. [1992a]; Tse et al. [1992]; Kolb et al. [1992]; Ettre et al. [1993]; Gan and Yates [1996]; Peng and Wan [1997]; Roberts and D¨ andliker [1983]; Economou et al. [1997]; Wong and Wang [1997]; Suleimenov and Krupp [1994]; Heron et al. [1998]; Becker et al. [1998]; Leuenberger et al. [1985] • predictive methods for Henrys law coefficients (QSPRs): Russell et al. [1992]; Nirmalakhandan et al. [1997]; Brennan et al. [1998]
On the Internet: • The NIST Chemistry WebBook at http://webbook.n http://webbook.nist.gov/chemistr ist.gov/chemistry y • The Pesticide Properties Database (PPD) at http://www.arsu http://www.arsusda.gov/rsml/ppd sda.gov/rsml/ppdb2.html b2.html
6
7
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Data Data Table able (Ino (Inorg rgan anic ic))
substance
−d ln kH
kH [M [M//atm]
d(1/T )
[K]
ref efeerenc rencee
type
no note te
oxygen (O) oxygen O2 [7782-44-7]
ozone O3 [10028-15-6]
hydrogen H2 [1333-74-0]
−3
1.3×10 1.2×10−3 1.3×10−3 1.3×10−3 1.3×10−3 1.2×10−3 1.2×10−2 1.3×10−2 1.3×10−2 1.2×10−2 1.1×10−2 1.2×10−2 9.4×10−3 1.1×10−2 9.4×10−3 8.9×10−3
2300 2700 2500 2400 2400 2900
490 640 500 3100
Loomis [1928] Briner and Perrottet Perrottet [1939] Wilhe Wilhelm lm et al. [1977] Durham et al. [1981] Kosak-Chann Kosak-Channing ing and Helz [1983] Chameides [1984] Hoffmann and Jacob [1984] Jacob [1986] Seinfeld [1986] Kavanaugh and Trussell [1980]
4500 4800
6600
5300
9.0×103
hydrogen peroxide H2 O2 [7722-84-1]
Loomis [1928] Carpenter [1966] Wilhe Wilhelm lm et al. [1977] Dean [1992] Lide and Frederikse rederikse [1995] Kavanaugh and Trussell [1980]
hydrogen (H)
7.8×10−4 7.8×10−4 7.8×10−4 7.8×10−4 2.9×101 3.2×101 2.5×101 2.5×101 2.0×102 9.0×103 3.0×101 4.6×103 9.0×103 1.2×103
hydroxyl radical OH [3352-57-6]
hydroperoxy radical HO2 [3170-83-0]
1700 1800 1500 1700 1500 1700 2300 2000 2000
4.0×103 5.7×103 7.1×104 7.1×104 1.4×105 9.7×104 6.9×104 1.0×105 8.3×104 1.1×105
5900
8.6×104
6500
7000 7300 6600 7900 6300 7400 7500
Hine and Weimar [1965] Wilhe Wilhelm lm et al. [1977] Dean [1992] Lide and Frederikse rederikse [1995]
Berdn Berdnikov ikov and Bazhin [1970] Mozurkewich [1986] Jacob [1986] Lelieveld and Crutzen [1991] Lelieveld and Crutzen [1991] Lelieveld and Crutzen [1991] Hanson Hanson et al. [1992]
Berdn Berdnikov ikov and Bazhin [1970] Chameides [1984] Schwartz [1984] Jacob [1986] Weinstein-Lloyd and Schwartz [1991] Hanson Hanson et al. [1992] R´ eegimbal gim bal a and nd Mozurkew Mozu rkewich ich [1997]
Martin and Damschen [1981] Hoffmann and Jacob [1984] Yoshizumi et al. [1984] Chameides [1984] Hwang and Dasgupta [1985] Lind and Kok [1994] O’Sulliva O’Sullivan n et al. [1996] Staffelbach Staffelbach and Kok [1993]
Zhou and Lee Lee [1992]
X M L ? L X X M L C M T ? C C X R L ? L T T C C C C T T T T E T T R T ? M T M M M M M
1
2 3 1
4
3
2 5 6
5 7
4 8
9 10
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substance
kH [M [M//atm]
7
−d ln kH
d(1/T )
[K]
reference
type
note
nitrogen (N) ammonia NH3 [7664-41-7]
hydrazoic acid HN3 [7782-79-8]
5.9×101 5.7×101 1.0×101 6.1×101 7.6×101
4100 4100 1500 4200 3400
5.8×101 7.8×101 5.8×101 5.6×101 5.6×101 6.1×101 2.7×101 6.2×101 5.4×101 6.0×101 9.9
4100
Sillen and Martell Martell [1964] Robin Robinson son and Stokes [1970] Wilhelm Wilhelm et al. [1977] Edwar Edwards ds et al. [1978] Hales and Drewes Drewes [1979]
Chameides [1984] Holzwarth et al. [1984] 4100 Hoffmann and Jacob [1984] 4100 Dasgupta Dasgupta and Dong [1986] 4200 Dasgupta Dasgupta and Dong [1986] 4200 Clegg and Brimblecombe Brimblecombe [1989] 2100 Dean [1992] Van Krevelen et al. [1949] Bone et al. [1983] 4400 Kavanaugh and Trussell [1980]
3100
Wilhelm Wilhelm et al. [1977]
X X L L M T M ? M T M ? X ? X L
1 1
4
2 11 12 3
−2
d itrogen monoxide Ni2nO (nitrous oxide, laughing gas) [10024-97-2]
nitrogen N2 [7727-37-9] nitrogen monoxide NO (nitric oxide) [10102-43-9]
nitrogen dioxide NO2 [10102-44-0]
nitrogen trioxide NO3 (nitrate radical) [12033-49-7]
× −2 22..65×10 10 2.4×10−2 2.5×10−2 2.4×10−2 2.5×10−2 2.4×10−2
6.5×10−4 6.1×10−4
7.9×10−7 1.4×10−3 1.9×10−3 1.9×10−3
1.9×10−3 1.9×10−3 3.4×10−2 7.0×10−3 4.0×10−2 2.4×10−2 1.2×10−2 4.1×10−2 1.2×10−2 3.4×10−2 1.2×101 2.0 6.0×10−1 see 1.8 note
Loomis [1928] Liss and Slater [1974] Wilhelm Wilhelm et al. [1977] Seinfeld [1986] Dean [1992] Lide and Frederikse rederikse [1995] Perry [1963]
2600
2800 2600 2700 1300 Wilhelm Wilhelm et al. [1977] 1300 Kavanaugh and Trussell [1980] 3800 1500 1700 1400 1800
2500 2000 1900 2000
X ? L ? ? L X L X
1 13 2 14
3
Wilhelm Wilhelm et al. [1977] Zafiriou and McFarland [1980] Schwartz Schwartz and White [1981] Durham et al. [1981]
L M L C
Dean [1992] Lide and Frederikse rederikse [1995]
2
17
Berdnikov Berdnikov and Bazhin [1970] Lee and Schwartz [1981] Lee and Schwartz [1981] Lee and Schwartz [1981] Schwartz and White [1981] Durham et al. [1981] Chameides [1984]
Berdnikov Berdnikov and Bazhin [1970] Chameides [1986] Thom Thomas as et al. [1993] Rudich et al. [1996]
? L T M C C L C T T T M M
Seinfeld Seinfeld and Pandis Pandis [1998] Thomas Thomas et al. [1998]
M M
5 15
5
16
8
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kH [M [M//atm] 6.0×10−1 2.6×101
1.4 1.6
substance dinitrogen trioxide N2 O3 [10544-73-7] dinitrogen tetroxide N2 O4 [10544-72-6] dinitrogen pentoxide N2 O5 (nitric anhydride) [10102-03-1] nitrous acid HNO2 [7782-77-6]
nitric acid HNO3 [7697-37-2]
d(1/T )
[K]
Schwartz Schwartz and White [1981] Durh Durham am et al. [1981]
L C
Jacob [1986] Fried et al. [1994] Sander and Crutzen [1996]
E E E
4800 4700 4900 4900
Schwartz Schwartz and White [1981] Durham et al. [1981] Chameides [1984] Martin [1984] Park and Lee Lee [1988] Becker Becker et al. [1996]
8700
Schwartz and White [1981] Durham et al. [1981] Chameides [1984]
L C T T M M T C T
∞
3400
4.9×101 3.7×101 4.9×101 4.8×101 4.9×101 5.0×101 2.1×105 8.9×104 2.6×106
typ ypee L C
∞
ref efeerenc rencee
Schwartz and White [1981] Durham et al. [1981]
2.1
−d ln kH
4800
no notte
18 19 18
5
pernitric acid HNO4 [26404-66-0]
3.5×10 /K A 2.4×106 /K A 2.1×105 2.0×104 1.0×105 1.2×104 4.0×103
8700 8700 8700 0
Hoffmann and Jacob [1984] Brimblecombe Brimblecombe and Clegg [1989] Lelieveld and Crutzen [1991]
? T R C E T M
20, 4 20, 21 22
Berdnikov Berdnikov and Bazhin [1970]
T
5
Brimblecombe Brimblecombe and Clegg [1989]
T
20, 21
Jacob Jacob et al. [1989] M¨ oller and Mauersberger [1992] 6900 R´eegimbal gi mbal and Mozurkew Mozu rkewich ich [1997] Amels et al. [1996]
23
fluorine (F) fluorine atom F [14762-94-8] hydrogen fluoride HF [7664-39-3] nitrogen trifluoride NF3 [7783-54-2] dinitrogen tetrafluoride N2 F4 (tetrafluorohydrazine) [10036-47-2]
2.1×10
−2
9.6/K A
400
7400
7.9×10−4
1900
Wilhelm Wilhelm et al. [1977]
L
8.5×10−4
2500
Wilhelm Wilhelm et al. [1977]
L
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substance
9
−d ln kH
kH [M [M//atm]
d(1/T )
typ ypee
no notte
X X X C T
1 1,20 1
2000
Loomis [1928] Loomis [1928] Chen et al. [1979] Graedel and Goldberg [1983] Marsh and McElroy [1985]
9000 600 9000
Seinfeld [1986] Brimblecomb Brimblecombee and Clegg [1989] Dean [1992] Wagman Wagman et al. [1982]
13 20, 21 2
[K]
refe refere renc ncee
chlorine (Cl) 1
hydrogen chloride HCl [7647-01-0]
1.9×10 1.7×105 /K A 1.5×103 2.0×101 1.1
hypochlorous acid HOCl [7790-92-3]
nitrosyl chloride NOCl [2696-92-6] nitryl chloride
2.5×103 2.0×106 /K A 1.9×101 2.0×106 /K A 7.3×102 4.8×102 9.3×102 6.6×102 2.6×102 > 0.05
9000
5900 5100
Holzwarth et al. [1984] Hanson and Ravishankara [1991] Blatchley et al. [1992] Huth Huthwelke welkerr et al. [1995] Wagman Wagman et al. [1982]
Scheer Scheer et al. [1997]
? T ? T M M M L T M
Behnke et al. [1997]
E
Frenzel et al. [1998]
E
Sander and Crutzen [1996]
E
18
Kruis Kruis and May [1962] Wilhelm Wilhelm et al. [1977] Wagman Wagman et al. [1982] Dean [1992] Brian et al. [1962] Lide and Frederikse rederikse [1995] Kavanaugh and Trussell [1980]
26
2.4×10−2
24
25
−2
ClNO2 [13444-90-1] chlorine nitrate ClNO3 [14545-72-3] molecular chlorine Cl2 [7782-50-5]
dichlorine monoxide Cl2 O [7791-21-1] chlorine dioxide ClO2 [10049-04-4] chlorine atom Cl [22537-15-1] chloramide NH2 Cl [10599-90-3] dichloroamine NHCl2 (chlorimide) [3400-09-7] nitrogen trichloride NCl3 [10025-85-1]
4.6×10
∞
see note 9.1×10−2 6.2×10−2 9.3×10−2 6.3×10−2 9.5×10−2 8.6×10−2 1.7×101 1.7×101
2500 2800 2300 3200 2100 2000 1800 1700
Wilhelm Wilhelm et al. [1977] Lide and Frederikse rederikse [1995]
? L T ? L L X L L
1.0 1.0 8.5×10−1 1.5×10−2 2.0×10−1
3300 Wilhelm Wilhelm et al. [1977] 3300 Lide and Frederikse rederikse [1995] 3400 Kavanaugh and Trussell [1980] 1500 Berdnikov Berdnikov and Bazhin [1970] Mozurkewich [1986]
L L X T T
9.4×101
4800
Holzwarth Holzwarth et al. [1984]
M
2.9×101
4200
Holzwarth Holzwarth et al. [1984]
M
1.0×10−1
4100
Holzwarth Holzwarth et al. [1984]
M
2
3
14 3 5
10
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
−d ln kH
kH [M [M//atm]
d(1/T )
[K]
reference
type
note
bromine (Br) 9
hydrogen bromide HBr [10035-10-6] hypobromous acid
HOBr [13517-11-8]
nitryl bromide BrNO2 [13536-70-4] bromine nitrate BrNO3 [40423-14-1] molecular bromine Br2 [7726-95-6]
1.3×10 /K A 7.2×10−1 2.5×101 7.2×108 /K A >1.9×103
10000 Brimblec Brimblecombe ombe and Clegg [1989] 6100 Chameides and Stelson [1992] 370 Dean [1992] 10000 Wagman Wagman et al. [1982] Blatchley et al. [1992]
7.9×10−1 7.1×10−1 9.7×10−1
28 29
Frenzel et al. [1998]
T E M E E
Sander and Crutzen [1996]
E
18
Winkler [1899] Kelley and Tartar [1956] Jenkins and King [1965]
X M M
30
Jenk Jenkins ins and King [1965] Hill et al. [1968] Wagman Wagman et al. [1982] Dean [1992] Dubik et al. [1987]
R M T ? M M T T M M E T T
Mozurkewich [1995] Vogt et al. [1996] Fickert [1998] Frenzel et al. [1998]
∞
20, 21 27 2
1.8 9.3×101 see note 6.1×103 3.0×10−1
T C ? T M
3600 4100
8
−1
bromine chloride BrCl [13863-41-7]
bromine atom Br [10097-32-2]
8.0×10 6.9×10−1 7.3×10−1 7.6×10−1 1.8 4.2 1.1 7.4×10−1 5.2 9.4×10−1 5.9×10−1 3.4×10−2 1.2
3900 4000 4100 3300 3700
Dubik et al. [1987]
see note see note Disselkamp Disselkamp et al. [1998] 5600 Bartlett and Margerum Margerum [1998] Frenzel et al. [1998] 1800 Berdnikov Berdnikov and Bazhin [1970] Mozurkewich [1986]
2 31 31 32 33 34
5
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
11
−d ln kH
kH [M [M//atm]
d(1/T )
[K]
reference
type
note
iodine (I) hydrogen iodide HI [10034-85-2] hypoiodous acid HOI [14332-21-9] molecular iodine I2 [7553-56-2] iodine atom I [14362-44-8] iodine chloride ICl [7790-99-0] iodine bromide IBr [7789-33-5]
9
2.5×10 /K A 2.2×109 /K A
9800 Brimblec Brimblecombe ombe and Clegg [1989] 9800 Wagman Wagman et al. [1982]
T T
Thompson and Zafiriou [1983] Thompson and Zafiriou [1983]
Ber Berdnikov dnikov and Bazhin [1970] Mozurkewich [1986]
E E C R T C R T T
1.1×102
Wagman et al. [1982]
T
2.4×101
Wagman et al. [1982]
T
>4.5×101 4.1×102 3.1 3.3 1.1 3.0 6.3×10−3 8.0×10−2
4600 4800
4400 2300
Palmer et al. [1985] Ber Berdnikov dnikov and Bazhin [1970] Wagman Wagman et al. [1982] Thompson and Zafiriou [1983] Palmer Palmer et al. [1985]
20, 21
35 5
12
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
kH [M [M//atm]
substance
−d ln kH
d(1/T )
[K]
reference
type
note
sulfur (S) −3
hydrogen sulfide H2 S [7783-06-4]
sulfur dioxide SO2 [7446-09-5]
sulfur trioxide SO3 [7446-11-9] sulfuric acid H2 SO4 [7664-93-9] sulfur hexafluoride SF6 [2551-62-4]
1.0×10 1.0×10−1 1.0×10−1 1.0×10−1 1.0×10−1
2300
Loomis [1928] Hine and Weimar [1965] Wilhelm Wilhelm et al. [1977] Edwa Edward rdss et al. [1978] Carr Carroll oll and Mather Mather [1989]
X R L L L
1
1.0×10−1 1.0×10−1 8.7×10−2 9.8×10−2 1.2 1.2 1.1 1.2 1.4 1.2 1.2 1.2 1.2
Dean [1992] 2300 2000 Lide and Frederikse rederikse [1995] 2100 De Bruy Bruyn n et al. [1995] 2200 Kavanaugh and Trussell [1980] 3200 Sillen and Martell Martell [1964] 3100 Hales and Sutter Sutter [1973] Liss and Slater Slater [1974] 3100 Smith and Martell Martell [1976] 2800 Wilhelm Wilhelm et al. [1977] 3000 Edwa Edward rdss et al. [1978] Durham Durham et al. [1981] 3100 Chameides [1984] 3100 Hoffmann and Jacob [1984]
? L M X X c c X L L C T ?
2
11..22 1.5 1.2 1.2 1.4 1.3
Jacob [1986] Pandis Pandis and Seinfeld Seinfeld [1989] Dean [1992] Maahs [1982] 3200 Maahs [1982] 2900 Lide and Frederikse rederikse [1995] 2800 Kavanaugh and Trussell [1980] Sander and Crutzen [1996]
C C ? X X L X E
Gmitro and Vermeulen [1964]
M
Wilhelm Wilhelm et al. [1977]
L
∞
2100 2100 2200
33210000 2900
see note
2.4×10−4
2400
3 1
1
4
2 11 1 3 18
36
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
kH [M [M//atm]
13
−d ln kH
d(1/T )
[K]
reference
type
note
rare gases helium He [7440-59-7] neon Ne [7440-01-9] argon Ar [7440-37-1] krypton Kr [7439-90-9] xenon Xe [7440-63-3] radon Rn [10043-92-2] selenium hydride H2 Se [7783-07-5] phosphorus trihydride PH3 (phosphine) [7803-51-2] arsenic hydride AsH3 (arsine) [7784-42-1] mercury Hg [7439-97-6]
3.7×10−4 3.8×10−4
360 Morrison and Johnstone [1954] 92 Wilhelm Wilhelm et al. [1977]
M L
37
4.5×10−4 4.5×10−4
530 Morrison and Johnstone [1954] 450 Wilhelm Wilhelm et al. [1977]
M L
37
1.4×10−3 1.4×10−3
1100 Morrison and Johnstone [1954] 1500 Wilhelm Wilhelm et al. [1977]
M L
2.4×10−3 2.5×10−3
1500 Morrison and Johnstone [1954] 1900 Wilhelm Wilhelm et al. [1977]
M L
4.3×10−3 4.3×10−3
1900 Morrison and Johnstone [1954] 2200 Wilhelm Wilhelm et al. [1977]
M L
9.3×10−3
2600
other elements 1900
8.4×10−2
Wilhelm Wilhelm et al. [1977]
L
Wilhelm Wilhelm et al. [1977]
L
8.1×10−3
2000
Wilhelm Wilhelm et al. [1977]
L
8.9×10−3
2100
Wilhelm Wilhelm et al. [1977]
L
Brimblecombe [1986]
?
9.3×10−2
38
14
8
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
Data Data Table able (O (Org rgan anic ic))
substance
kH [M [M//atm]
−d ln kH
d(1/T )
[K]
reference
type
note
alkanes (C and H only) methane CH4
ethane C2 H6
propane C3 H8
butane C4 H10
9.2×10−3 1.4×10−3 9.7×10−4 1.5×10−3 1.4×10−3 1.3×10−3 1.3×10−3 1.4×10−3 1.5×10−3 1.3×10−3 1.1×10−2 2.0×10−3 1.8×10−3 2.0×10−3 1.9×10−3 2.0×10−3
2-methylpropane HC(CH3 )3 (isobutane)
dimethylpropane C(CH3 )4 (neopentane) pentane C5 H12 2-methylbutane C5 H12 (isopentane) 2,2-dimethylpropane C5 H12
1.4×10−3 1.5×10−3 1.4×10−3 1.5×10−3 1.4×10−3 4.9×10−3 1.1×10−3 1.2×10−3 1.1×10−3 1.1×10−3 8.5×10−4 8.1×10−4 8.4×10−4 8.7×10−4 4.6×10−4 5.9×10−4 2.7×10−4
1700 1900 1600 1800
2400 2300
Butler and Ramchandani [1935] Hine and Weimar [1965] Liss and Slater [1974] Hine and Mookerjee [1975] Wilhe Wilhelm lm et al. [1977] Mackay and Shiu [1981] Dean [1992] Lide and Frederikse rederikse [1995] Yaws and Yang [1992] Kavanaugh and Trussell [1980] Butler and Ramchandani [1935] Hine and Mookerjee [1975] Wilhe Wilhelm lm et al. [1977] Mackay and Shiu [1981] Lide and Frederikse rederikse [1995] Yaws and Yang [1992]
2700 2700
3100
2700
3400
Hine and Mookerjee [1975] Wilhe Wilhelm lm et al. [1977] Mackay and Shiu [1981] Lide and Frederikse rederikse [1995] Yaws and Yang [1992]
Butler and Ramchandani [1935] Hine and Mookerjee [1975] Wilhe Wilhelm lm et al. [1977] Mackay and Shiu [1981] Yaws and Yang [1992] Hine and Mookerjee [1975] Wilhe Wilhelm lm et al. [1977] Mackay and Shiu [1981] Yaws and Yang [1992] Hine and Mookerjee [1975] Wilhe Wilhelm lm et al. [1977] Mackay and Shiu [1981]
8.0×10−4 8.1×10−4 7.9×10−4 7.3×10−4 7.3×10−4
Hine and Mookerjee [1975] Mackay and Shiu [1981] Yaws and Yang [1992]
4.7×10−4
V R C V L L ? L ? X V V L L L ? V L L L ? V V L L ? V L L ? V L L
2 14 39 3
39
39
39
39
Mackay and Shiu [1981] Yaws and Yang [1992]
V L ? L ?
39
Yaws and Yang [1992]
?
39
39
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
kH [M [M//atm] 5.5×10−4 6.0×10−4 7.7×10−4 1.0×10−3 5.8×10−4 6.0×10−4 5.8×10−4 1.3×10−1 5.9×10−4 5.9×10−4 8.9×10−4 5.1×10−4 5.9×10−4 6.6×10−4 7.8×10−4 7.7×10−4
4.9×10−4 4.4×10−4
substance hexane C6 H14
2-methylpentane C6 H14 (isohexane) [107-83-5] 3-methylpentane C6 H14 2,2-dimethylbutane C6 H14 2,3-dimethylbutane C6 H14 heptane C7 H16
15
−d ln kH
d(1/T )
[K]
reference
Mackay and Shiu [1981] Yaws and Yang [1992]
V L ? X V L ? X V L ? V L ? L ?
Hine and Mookerjee [1975] Mackay and Shiu [1981]
V L
3700
3700
Mackay and Shiu [1981] Yaws and Yang [1992]
L ? X L M ? X L ?
7500
Hine and Mookerjee [1975] Mackay and Shiu [1981] Yaws and Yang [1992] Ashworth Ashworth et al. [1988]
type
Hine and Mookerjee [1975] Mackay and Shiu [1981]
960
Yaws and Yang [1992] Ashworth Ashworth et al. [1988]
Hine and Mookerjee [1975] Mackay and Shiu [1981] Yaws and Yang [1992] Hine and Mookerjee [1975] Mackay and Shiu [1981] Yaws and Yang [1992]
note
39 3
39 3
39
39 39
−3
1.2×10−4 3.7×10 1.2×10−3 2.9×10−4 1.9×10−3 2.9×10−4 1.9×10−3 4.2×10−4 3.2×10−4
3.2×10−4 3.1×10−4
Mackay and Shiu [1981] Yaws and Yang [1992]
L ?
39
5.8×10−4 5.8×10−4
Mackay and Shiu [1981] Yaws and Yang [1992]
L ?
39
3.2×10−4 3.4×10−4 3.4×10−4 5.4×10−4 5.5×10−4
Hine and Mookerjee [1975] Mackay and Shiu [1981] Yaws and Yang [1992]
39
Mackay and Shiu [1981] Yaws and Yang [1992]
V L ? L ?
3-ethylpentane C7 H16
3.9×10−4
Yaws and Yang [1992]
?
39
2,2,3-trimethylbutane C7 H16
4.1×10−4
Yaws and Yang [1992]
?
39
2-methylhexane C7 H16
3-methylhexane C7 H16 2,2-dimethylpentane C7 H16 2,3-dimethylpentane C7 H16 2,4-dimethylpentane C7 H16 3,3-dimethylpentane C7 H16
-3600 -3500
Hansen Hansen et al. [1995] Yaws and Yang [1992] Hansen Hansen et al. [1993]
Mackay and Shiu [1981] Hansen Hansen et al. [1995] Yaws and Yang [1992] Hansen Hansen et al. [1993]
39 3 40 39 3 39
39
16
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html) −d ln kH
kH [M [M//atm] 3.1×10−4 3.4×10−4 2.0×10−4 2.9×10−3 2.7×10−4 2.7×10−4
2.7×10−4 2.7×10−4
Mackay and Shiu [1981] Yaws and Yang [1992]
L ?
39
4-methylheptane C8 H18
2.7×10−4
Yaws and Yang [1992]
?
39
2,2-dimethylhexane C8 H18
2.9×10−4
Yaws and Yang [1992]
?
39
2,3-dimethylhexane C8 H18
2.6×10−4
Yaws and Yang [1992]
?
39
2,4-dimethylhexane C8 H18
2.8×10
Yaws and Yang [1992]
?
39
2,5-dimethylhexane C8 H18
3.0×10−4
Yaws and Yang [1992]
?
39
3,3-dimethylhexane C8 H18
2.6×10−4
Yaws and Yang [1992]
?
39
3,4-dimethylhexane C8 H18
2.4×10−4
Yaws and Yang [1992]
?
39
substance octane C8 H18
2-methylheptane C8 H18 3-methylheptane C8 H18
d(1/T )
[K]
7800
reference
Hine and Mookerjee [1975] Mackay and Shiu [1981] Yaws and Yang [1992] Hansen Hansen et al. [1993]
type
note
Hoff et al. [1993] Yaws and Yang [1992]
V L ? X ? ?
39 3 13 39
−4
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance 3-ethylhexane C8 H18
kH [M [M//atm] 2.6×10−4
17
−d ln kH
d(1/T )
[K]
reference
type
note
Yaws and Yang [1992]
?
39
2,2,3-trimethylpentane C8 H18
2.6×10−4
Yaws and Yang [1992]
?
39
2,2,4-trimethylpentane C8 H18
3.3×10−4 3.1×10−4 3.0×10−4 2.4×10−4
Hine and Mookerjee [1975] Mackay and Shiu [1981] Yaws and Yang [1992] Yaws and Yang [1992]
V L ? ?
39 39
5.3×10−4 5.7×10−4
Mackay and Shiu [1981] Yaws and Yang [1992]
L ?
39
3-ethyl-2-methylpentane C8 H18
2.6×10−4
Yaws and Yang [1992]
?
39
3-ethyl-3-methylpentane
2.3×10−4
Yaws and Yang [1992]
?
39
2.6×10−4
Yaws and Yang [1992]
?
39
2,3,3-trimethylpentane C8 H18 2,3,4-trimethylpentane C8 H18
C8 H18 2,2,3,3-tetramethylbutane C8 H18
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance 2,2,3-trimethylhexane C9 H20
kH [M [M//atm] 1.9×10−4
19
−d ln kH
d(1/T )
[K]
reference
type
note
Yaws and Yang [1992]
?
39
2,2,4-trimethylhexane C9 H20
2.1×10−4
Yaws and Yang [1992]
?
39
2,2,5-trimethylhexane C9 H20
2.9×10−4 1.9×10−4
Mackay and Shiu [1981] Yaws and Yang [1992]
L ?
39
2,3,3-trimethylhexane C9 H20
1.7×10−4
Yaws and Yang [1992]
?
39
2,3,4-trimethylhexane C9 H20
1.8×10−4
Yaws and Yang [1992]
?
39
2,3,5-trimethylhexane C9 H20
2.0×10−4
Yaws and Yang [1992]
?
39
2,4,4-trimethylhexane
1.9×10−4
Yaws and Yang [1992]
?
39
3,3,4-trimethylhexane C9 H20
1.7×10−4
Yaws and Yang [1992]
?
39
3-ethyl-2-methylhexane C9 H20
1.9×10−4
Yaws and Yang [1992]
?
39
4-ethyl-2-methylhexane C9 H20
2.1×10−4
Yaws and Yang [1992]
?
39
3-ethyl-3-methylhexane C9 H20
1.7×10−4
Yaws and Yang [1992]
?
39
3-ethyl-4-methylhexane C9 H20
1.8×10−4
Yaws and Yang [1992]
?
39
2,2,3,3-tetramethylpentane C9 H20
1.6×10−4
Yaws and Yang [1992]
?
39
2,2,3,4-tetramethylpentane C9 H20
1.7×10−4
Yaws and Yang [1992]
?
39
2,2,4,4-tetramethylpentane C9 H20
1.9×10−4
Yaws and Yang [1992]
?
39
2,3,3,4-tetramethylpentane
1.6×10−4
Yaws and Yang [1992]
?
39
C9 H20
C9 H20
20
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance 3-ethyl-2,2-dimethylpentane C9 H20
kH [M [M//atm] 1.8×10−4
−d ln kH
d(1/T )
[K]
reference
type
note
Yaws and Yang [1992]
?
39
3-ethyl-2,3-dimethylpentane C9 H20
1.5×10−4
Yaws and Yang [1992]
?
39
3-ethyl-2,4-dimethylpentane C9 H20
1.8×10−4
Yaws and Yang [1992]
?
39
3,3-diethylpentane C9 H20
1.5×10−4
Yaws and Yang [1992]
?
39
decane C10 H22
1.4×10−4 2.1×10−4
Mackay and Shiu [1981] Yaws and Yang [1992]
L ?
39
2-methylnonane C10 H22
1.8×10−4
Yaws and Yang [1992]
?
39
3-methylnonane
1.7×10−4
Yaws and Yang [1992]
?
39
4-methylnonane C10 H22
1.7×10−4
Yaws and Yang [1992]
?
39
5-methylnonane C10 H22
1.7×10−4
Yaws and Yang [1992]
?
39
2,2-dimethyloctane C10 H22
1.7×10−4
Yaws and Yang [1992]
?
39
2,3-dimethyloctane C10 H22
1.5×10−4
Yaws and Yang [1992]
?
39
2,4-dimethyloctane C10 H22
1.7×10−4
Yaws and Yang [1992]
?
39
2,5-dimethyloctane C10 H22
1.6×10−4
Yaws and Yang [1992]
?
39
2,6-dimethyloctane C10 H22
1.6×10−4
Yaws and Yang [1992]
?
39
C10 H22
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance 2,7-dimethyloctane C10 H22
kH [M [M//atm] 1.7×10−4
21
−d ln kH
d(1/T )
[K]
reference
type
note
Yaws and Yang [1992]
?
39
3,3-dimethyloctane C10 H22
1.5×10−4
Yaws and Yang [1992]
?
39
3,4-dimethyloctane C10 H22
1.5×10−4
Yaws and Yang [1992]
?
39
3,5-dimethyloctane C10 H22
1.6×10−4
Yaws and Yang [1992]
?
39
3,6-dimethyloctane C10 H22
1.6×10−4
Yaws and Yang [1992]
?
39
4,4-dimethyloctane C10 H22
1.5×10−4
Yaws and Yang [1992]
?
39
4,5-dimethyloctane
1.5×10−4
Yaws and Yang [1992]
?
39
3-ethyloctane C10 H22
1.6×10−4
Yaws and Yang [1992]
?
39
4-ethyloctane C10 H22
1.6×10−4
Yaws and Yang [1992]
?
39
2,2,3-trimethylheptane C10 H22
1.5×10−4
Yaws and Yang [1992]
?
39
2,2,4-trimethylheptane C10 H22
1.6×10−4
Yaws and Yang [1992]
?
39
C10 H22
22
substance 2,2,5-trimethylheptane C10 H22
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
kH [M [M//atm] 1.6×10−4
−d ln kH
d(1/T )
[K]
reference
tty ype
no note
Yaws and Yang [1992]
?
39
2,2,6-trimethylheptane C10 H22
1.7×10−4
Yaws and Yang [1992]
?
39
2,3,3-trimethylheptane C10 H22
1.4×10−4
Yaws and Yang [1992]
?
39
2,3,4-trimethylheptane C10 H22
1.4×10−4
Yaws and Yang [1992]
?
39
2,3,5-trimethylheptane C10 H22
1.4×10−4
Yaws and Yang [1992]
?
39
2,3,6-trimethylheptane C10 H22
1.6×10−4
Yaws and Yang [1992]
?
39
2,4,4-trimethylheptane
1.5×10−4
Yaws and Yang [1992]
?
39
2,4,5-trimethylheptane C10 H22
1.5×10−4
Yaws and Yang [1992]
?
39
2,4,6-trimethylheptane C10 H22
1.8×10−4
Yaws and Yang [1992]
?
39
2,5,5-trimethylheptane C10 H22
1.5×10−4
Yaws and Yang [1992]
?
39
3,3,4-trimethylheptane C10 H22
1.3×10−4
Yaws and Yang [1992]
?
39
3,3,5-trimethylheptane C10 H22
1.4×10−4
Yaws and Yang [1992]
?
39
3,4,4-trimethylheptane C10 H22
1.3×10−4
Yaws and Yang [1992]
?
39
3,4,5-trimethylheptane C10 H22
1.4×10−4
Yaws and Yang [1992]
?
39
C10 H22
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance 3-ethyl-2-methylheptane C10 H22
kH [M [M//atm] 1.5×10−4
23
−d ln kH
d(1/T )
[K]
reference
type
note
Yaws and Yang [1992]
?
39
4-ethyl-2-methylheptane C10 H22
1.6×10−4
Yaws and Yang [1992]
?
39
5-ethyl-2-methylheptane C10 H22
1.6×10−4
Yaws and Yang [1992]
?
39
3-ethyl-3-methylheptane C10 H22
1.4×10−4
Yaws and Yang [1992]
?
39
4-ethyl-3-methylheptane C10 H22
1.4×10−4
Yaws and Yang [1992]
?
39
3-ethyl-5-methylheptane C10 H22
1.6×10−4
Yaws and Yang [1992]
?
39
3-ethyl-4-methylheptane
1.4×10−4
Yaws and Yang [1992]
?
39
4-ethyl-4-methylheptane C10 H22
1.4×10−4
Yaws and Yang [1992]
?
39
4-propylheptane C10 H22
1.7×10−4
Yaws and Yang [1992]
?
39
4-isopropylheptane C10 H22
1.5×10−4
Yaws and Yang [1992]
?
39
2,2,3,3-tetramethylhexane C10 H22
1.2×10−4
Yaws and Yang [1992]
?
39
2,2,3,4-tetramethylhexane C10 H22
1.2×10−4
Yaws and Yang [1992]
?
39
C10 H22
24
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance 2,2,3,5-tetramethylhexane C10 H22
kH [M [M//atm] 1.6×10−4
−d ln kH
d(1/T )
[K]
reference
tty ype
no note
Yaws and Yang [1992]
?
39
2,2,4,4-tetramethylhexane C10 H22
1.2×10−4
Yaws and Yang [1992]
?
39
2,2,4,5-tetramethylhexane C10 H22
1.5×10−4
Yaws and Yang [1992]
?
39
2,2,5,5-tetramethylhexane C10 H22
1.8×10−4
Yaws and Yang [1992]
?
39
2,3,3,4-tetramethylhexane C10 H22
1.2×10−4
Yaws and Yang [1992]
?
39
2,3,3,5-tetramethylhexane C10 H22
1.4×10−4
Yaws and Yang [1992]
?
39
2,3,4,4-tetramethylhexane
1.2×10−4
Yaws and Yang [1992]
?
39
2,3,4,5-tetramethylhexane C10 H22
1.4×10−4
Yaws and Yang [1992]
?
39
3,3,4,4-tetramethylhexane C10 H22
1.0×10−4
Yaws and Yang [1992]
?
39
3-ethyl-2,2-dimethylhexane C10 H22
1.4×10−4
Yaws and Yang [1992]
?
39
4-ethyl-2,2-dimethylhexane C10 H22
1.6×10−4
Yaws and Yang [1992]
?
39
3-ethyl-2,3-dimethylhexane C10 H22
1.3×10−4
Yaws and Yang [1992]
?
39
4-ethyl-2,3-dimethylhexane C10 H22
1.4×10−4
Yaws and Yang [1992]
?
39
3-ethyl-2,4-dimethylhexane C10 H22
1.4×10−4
Yaws and Yang [1992]
?
39
4-ethyl-2,4-dimethylhexane C10 H22
1.3×10−4
Yaws and Yang [1992]
?
39
3-ethyl-2,5-dimethylhexane
1.5×10−4
Yaws and Yang [1992]
?
39
C10 H22
C10 H22
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
4-ethyl-3,3-dimethylhexane C10 H22
kH [M [M//atm] 1.3×10−4
25
−d ln kH
d(1/T )
[K]
reference
type
note
Yaws and Yang [1992]
?
39
3-ethyl-3,4-dimethylhexane C10 H22
1.3×10−4
Yaws and Yang [1992]
?
39
3,3-diethylhexane C10 H22
1.3×10−4
Yaws and Yang [1992]
?
39
3,4-diethylhexane C10 H22
1.4×10−4
Yaws and Yang [1992]
?
39
3-isopropyl-2-methylhexane C10 H22
1.1×10−4
Yaws and Yang [1992]
?
39
2,2,3,3,4-pentamethylpentane C10 H22
1.0×10−4
Yaws and Yang [1992]
?
39
2,2,3,4,4-pentamethylpentane
1.0×10−4
Yaws and Yang [1992]
?
39
3-ethyl-2,2,3-trimethylpentane C10 H22
1.0×10−4
Yaws and Yang [1992]
?
39
3-ethyl-2,2,4-trimethylpentane C10 H22
1.3×10−4
Yaws and Yang [1992]
?
39
3-ethyl-2,3,4-trimethylpentane C10 H22
1.1×10−4
Yaws and Yang [1992]
?
39
3,3-diethyl-2-methylpentane C10 H22
1.1×10−4
Yaws and Yang [1992]
?
39
2,4-dimethyl-3-isopropylpen pentane C10 H22
1.3×10−4
Yaws and Yang [1992]
?
39
C10 H22
26
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html) −d ln kH
kH [M [M//atm] 5.5×10−5 5.5×10−4
1.4×10−4 1.4×10−4
Mackay and Shiu [1981] Yaws and Yang [1992]
L ?
39
tridecane C13 H28
4.3×10−4
Yaws and Yang [1992]
?
39
tetradecane C14 H30
8.8×10−4
Yaws and Yang [1992]
?
39
pentadecane C15 H32
2.1×10−3
Yaws and Yang [1992]
?
39
hexadecane C16 H34
4.3×10−3
Yaws and Yang [1992]
?
39
heptadecane
1.8×10−2
Yaws and Yang [1992]
?
39
octadecane C18 H38
1.1×10−1
Yaws and Yang [1992]
?
39
nonadecane C19 H40
3.4×10−1
Yaws and Yang [1992]
?
39
eicosane C20 H42
3.1
Yaws and Yang [1992]
?
39
substance undecane C11 H24 dodecane C12 H26
d(1/T )
[K]
reference
type
note
Mackay and Shiu [1981] Yaws and Yang [1992]
L ?
39
C17 H36
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
kH [M [M//atm]
27
−d ln kH
d(1/T )
[K]
reference
typ e
note
cycloalkanes (C and H only) cyclopropane C3 H6
1.1×10−2 1.3×10−2
1700
Wilhe Wilhelm lm et al. [1977] Yaws and Yang [1992]
L ?
3300
Hine and Mookerjee [1975] Mackay and Shiu [1981] Hansen Hansen et al. [1995] Yaws and Yang [1992] Hansen Hansen et al. [1993]
3200 710
Hine and Mookerjee [1975] Mackay and Shiu [1981] Yaws and Yang [1992] Ashworth Ashworth et al. [1988] USEPA [1982] Hoff et al. [1993] Yaws and Yang [1992]
V L M ? X V L ? X X ? ?
39 3 3 13 39 13 39
39, 41
5.4×10−3 5.5×10−3 6.6×10−3 5.4×10−3 6.6×10−3 5.1×10−3 5.6×10−3 5.2×10−3 5.6×10−3 6.3×10−3 1.6×10−1 1.1×10−2
9.9×10−3 9.6×10−3
Hoff et al. [1993] Yaws and Yang [1992]
? ?
2.8×10−3 2.8×10−3 2.8×10−3 2.3×10−3 2.5×10−3 9.7×10−3 2.3×10−3 9.4×10−3 2.8×10−3 2.8×10−3 2.8×10−3 2.1×10−3
Hine and Mookerjee [1975] Mackay and Shiu [1981] Yaws and Yang [1992]
Yaws and Yang [1992]
V L ? V L M ? X V L ? ?
39 39
1.1×10−3 1.1×10−3
Mackay and Shiu [1981] Yaws and Yang [1992]
L ?
39
1,1,3-trimethylcyclopentane C5 H7 (CH3 )3
6.4×10−4
Mackay and Shiu [1981]
L
propylcyclopentane C5 H9 C3 H7
1.1×10−3 1.1×10−3
Mackay and Shiu [1981] Yaws and Yang [1992]
L ?
39
5.5×10−4 5.5×10−4
Mackay and Shiu [1981] Yaws and Yang [1992]
L ?
39
Ashworth Ashworth et al. [1988]
X
3
cyclopentane C5 H10
cyclohexane C6 H12
cycloheptane C7 H14 cyclooctane C8 H16 methylcyclopentane C5 H9 CH3
methylcyclohexane C6 H11CH3
cis -1,2-dimethylcyclohexane
C6 H10(CH3 )2
trans -1,2-dimethylcyclohexane
3400
9400 9100
Hine and Mookerjee [1975] Mackay and Shiu [1981] Hansen Hansen et al. [1995] Yaws and Yang [1992] Hansen Hansen et al. [1993] Hine and Mookerjee [1975] Mackay and Shiu [1981] Yaws and Yang [1992]
39 3
39
39 3
C6 H10(CH3 )2 trans -1,4-dimethylcyclohexane
C6 H10(CH3 )2
pentylcyclopentane C5 H9 C5 H11 decahydronaphthalene C10 H18 (decalin) [91-17-8]
7.3×10−3
4100
28
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
kH [M [M//atm]
−d ln kH
d(1/T )
[K]
reference
type
note
aliphatic alkenes and cycloalkenes (C and H only) ethene C2 H4 (ethylene)
4.9×10−3 4.7×10−3 4.7×10−3 4.7×10−3 4.9×10−3 4.8×10−3 4.8×10−3 7.4×10−3 4.8×10−3 4.8×10−3 4.0×10−3 1.3×10−2 1.4×10−3 4.0×10−3 4.3×10−3
Irrmann [1965]
X V L L ? ? V L L ? V L L ? X
39 42
4.4×10−3
Irrmann [1965]
X
42
Hine and Mookerjee [1975] Wilhelm Wilhelm et al. [1977] Mackay and Shiu [1981] Yaws and Yang [1992]
4.7×10−3 5.7×10−3 1.6×10−3 4.8×10−3 2.5×10−3 2.5×10−3 2.5×10−3 4.4×10−3 4.4×10−3
Mackay and Shiu [1981] Yaws and Yang [1992]
V L L ? V L ? L ?
4.3×10−3 4.3×10−3
Hine and Mookerjee [1975] Yaws and Yang [1992]
V ?
2-methyl-2-butene C5 H10
4.5×10−3
Hine and Mookerjee [1975]
V
3-methyl-1-butene C5 H10
1.9×10−3 1.9×10−3 1.9×10−3
Hine and Mookerjee [1975] Mackay and Shiu [1981] Yaws and Yang [1992]
V L ?
propene C3 H6 (propylene) 1-butene C4 H8
cis -2-butene
1800
3400
6400
Loomis [1928] Hine and Mookerjee [1975] Wilhelm Wilhelm et al. [1977] Mackay and Shiu [1981] Seinfeld [1986] Yaws and Yang [1992] Hine and Mookerjee [1975] Wilhelm Wilhelm et al. [1977] Mackay and Shiu [1981] Yaws and Yang [1992] Hine and Mookerjee [1975] Wilhelm Wilhelm et al. [1977] Mackay and Shiu [1981] Yaws and Yang [1992]
1
13 39
39
C4 H8 trans -2-butene
C4 H8 2-methylpropene C4 H8 (isobutene) 1-pentene C5 H10
cis -2-pentene
C5 H10 trans -2-pentene
C5 H10
3000
Hine and Mookerjee [1975] Mackay and Shiu [1981] Yaws and Yang [1992]
39
39 39
39
39
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance 1-hexene C6 H12 2-methyl-1-pentene C6 H12 4-methyl-1-pentene C6 H12
1-heptene C7 H14 trans -2-heptene
C7 H14 1-octene C8 H16
1-nonene
kH [M [M//atm] 2.4×10−3 2.4×10−3 3.3×10−3 3.6×10−3 3.6×10−3
29
−d ln kH
d(1/T )
[K]
reference
Hine and Mookerjee [1975] Mackay and Shiu [1981] Yaws and Yang [1992] Mackay and Shiu [1981] Yaws and Yang [1992]
type V L ? L ?
1.6×10−3 1.6×10−3 1.6×10−3 2.5×10−3
Hine and Mookerjee [1975] Mackay and Shiu [1981] Yaws and Yang [1992] Yaws and Yang [1992]
V L ? ?
2.5×10−3 2.4×10−3
Hine and Mookerjee [1975] Mackay and Shiu [1981]
V L
1.1×10−3 1.1×10−3 1.6×10−3 1.2×10−3
Hine and Mookerjee [1975] Mackay and Shiu [1981] Yaws and Yang [1992]
V L ? ?
1.6×10−2 1.4×10−2 1.4×10−2 1.4×10−2 1.3×10−2 1.3×10−2 2.8×10−2 1.3×10−2 8.3×10−3 8.4×10−3 8.5×10−3 7.4×10−3
Hine and Mookerjee [1975] Wilhelm Wilhelm et al. [1977] Mackay and Shiu [1981] Yaws and Yang [1992]
Yaws and Yang [1992]
note
39 39
39 39
39 39
C9 H18 1,3-butadiene C4 H6
methylbutadiene C5 H8 (isoprene) 1,4-pentadiene C5 H8
1,5-hexadiene C6 H10
4500
Hine and Mookerjee [1975]
V L L ? V L M ? V L ? V
Hine and Mookerjee [1975] Mackay and Shiu [1981] Karl and Lindinger [1997] Yaws and Yang [1992] Hine and Mookerjee [1975] Mackay and Shiu [1981] Yaws and Yang [1992]
2,3-dimethyl-1,3-butadiene C6 H10
2.1×10−2
Hine and Mookerjee [1975]
V
cyclopentene C5 H8
1.6×10−2 1.5×10−2
Hine and Mookerjee [1975] Yaws and Yang [1992]
V ?
2.2×10−2 2.6×10−2 2.2×10−2 1.3×10−2
Hine and Mookerjee [1975] Nielsen et al. [1994] Yaws and Yang [1992] Hine and Mookerjee [1975]
V M ? V
2.1×10−1
Yaws and Yang [1992]
?
cyclohexene C6 H10 1-methylcyclohexene C6 H9 CH3 1,3,5-cycloheptatriene C7 H8
39
43 39
39
39
39
39
30
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
kH [M [M//atm]
−d ln kH
d(1/T )
[K]
reference
type
note
aliphatic alkynes (C and H only) ethyne C2 H2 (acetylene)
4.2×10−2 4.1×10−2 3.9×10−2
1800
Hine and Mookerjee [1975] Wilhelm Wilhelm et al. [1977] Yaws and Yang [1992]
V L ?
Hine and Mookerjee [1975] Mackay and Shiu [1981] Yaws and Yang [1992] Wilhel Wilhelm m et al. [1977]
Hine and Mookerjee [1975] Yaws and Yang [1992]
V L ? ? V L L ? V L ? V ?
39
1-hexyne C4 H9 CCH
9.2×10−2 9.1×10−2 9.4×10−2 see note 5.4×10−2 7.6×10−2 5.3×10−2 5.5×10−2 4.0×10−2 4.1×10−2 2.0×10−2 2.5×10−2 4.6×10−2
1-heptyne C5 H11 CCH
1.5×10 2 1.4×10−2
Hine and Mookerjee [1975] Yaws and Yang [1992]
V ?
39
1-octyne C6 H13 CCH
1.2×10−2 1.2×10−2
Hine and Mookerjee [1975] Yaws and Yang [1992]
V ?
39
1-nonyne C7 H15 CCH
6.9×10−3 7.0×10−3
Hine and Mookerjee [1975] Yaws and Yang [1992]
V ?
39
3-buten-1-yne CH2 CHCCH (vinylacetylene)
3.8×10−2
Wilhelm Wilhelm et al. [1977]
L
butadiyne C4 H2 (biacetylene)
1.9×10−1
Yaws and Yang [1992]
?
propyne CH3 CCH (methylacetylene) 1-butyne C2 H5 CCH (ethylacetylene) 1-pentyne C3 H7 CCH
1900
Hine and Mookerjee [1975] Wilhelm Wilhelm et al. [1977] Mackay and Shiu [1981] Yaws and Yang [1992] Hine and Mookerjee [1975] Mackay and Shiu [1981] Yaws and Yang [1992]
−
1700
39 44
39
39 39
39
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
kH [M [M//atm]
31
−d ln kH
d(1/T )
[K]
reference
type
note
mononuclear aromatics (C and H only) benzene C6 H6 [71-43-2]
1.8×10−1 1.8×10−1 1.8×10−1 1.8×10−1 1.8×10−1 1.9×10−1 2.1×10−1 2.1×10−1 1.8×10−1 1.6×10−1 1.8×10−1 1.7×10−1 2.2×10−1 1.8×10−1 1.8×10−1 1.7×10−1 1.8×10−1 1.9×10−1
3800 3600 4500
4200
3900 2200 4300
Hine and Mookerjee [1975] Mackay et al. [1979] Mackay et al. [1979] Mackay and Shiu [1981] Ettre et al. [1993] Robbins obbins et al. [1993] Nielsen et al. [1994] Dewulf Dewulf et al. [1995] Vitenberg et al. [1975] Wasik and Tsang Tsang [1970] Bohon and Claussen [1951] Hoff et al. [1993] Hartkopf and Karger Karger [1973] Karl and Lindinger [1997] Yaws and Yang [1992] Co Cooling oling et al. [1992] USEPA [1982] Kavanaugh and Trussell [1980]
V M T L X M M M M M V M M M ? X X X
Ervin et al. [1980] Staudinger and Roberts Roberts [1996] Bissonette Bissonette et al. [1990] Ashworth Ashworth et al. [1988] Leighton Leighton and Calo [1981] Allen et al. [1998]
3
McAuliffe [1971] Hine and Mookerjee [1975] Mackay et al. [1979] Mackay et al. [1979] Mackay and Shiu [1981] Kolb et al. [1992] Ettre et al. [1993] Robbins obbins et al. [1993] Nielsen et al. [1994] Dewulf Dewulf et al. [1995] Vitenberg et al. [1975] Wasik and Tsang Tsang [1970] Bohon and Claussen [1951] Hoff et al. [1993] Hartkopf and Karger Karger [1973] Yaws and Yang [1992] USEPA [1982] Staudinger and Roberts Roberts [1996] Bissonette Bissonette et al. [1990] Ashworth Ashworth et al. [1988] Leighton Leighton and Calo [1981]
X L X X X E X V M T L X X M M M M M V M M ? X L X X X
Ervin et al. [1980] Lamarche Lamarche and Droste [1989] Allen et al. [1998]
X X E
3 3
45
43 39 3 3 3
−1
methylbenzene C6 H5 CH3 (toluene) [108-88-3]
1.2×10−1 1.6×10 1.6×10−1 1.8×10−1 1.8×10−1 1.8×10−1 1.5×10−1 1.5×10−1 1.5×10−1 1.5×10−1 1.5×10−1 1.6×10−1 1.6×10−1 1.5×10−1 1.6×10−1 1.8×10−1 1.9×10−1 1.7×10−1 1.8×10−1 1.3×10−1 2.1×10−1 1.6×10−1 1.5×10−1 1.5×10−1 1.4×10−1 1.5×10−1 1.5×10−1
5300 4100 4300 3200 4000
3400 4100 5900
4600 1900 4000 5000 3000 3700
3 3 3 45
45 45
39 3 3 3 3
−1
1.5×10−1 1.7×10 1.6×10−1
4900 8400
32
substance 1,2-dimethylbenzene C6 H4 (CH3 )2 (o-xylene) [95-47-6]
1,3-dimethylbenzene C6 H4 (CH3 )2 (m-xylene) [108-38-3]
1,4-dimethylbenzene C6 H4 (CH3 )2
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
kH [M [M//atm] 1.9×10−1 2.0×10−1 1.9×10−1 2.5×10−1 2.9×10−1 2.4×10−1 1.9×10−1 1.9×10−1 2.1×10−1 1.6×10−1 1.4×10−1 1.6×10−1 1.7×10−1 1.5×10−1 1.3×10−1 1.3×10−1 1.4×10−1 1.6×10−1 1.4×10−1
1.7×10−1 1.6×10 2.3×10−1 1.6×10−1 1.2×10−1 1.2×10−1 1.3×10−1 1.3×10−1 3.1×10−1 2.7×10−1
−d ln kH
d(1/T )
[K]
reference
Hine and Mookerjee [1975] Mackay and Shiu [1981] 3400 Robbins obbins et al. [1993] 4200 Dewu Dewulf lf et al. [1995] 5400 Wasik and Tsang Tsang [1970] Yaws and Yang [1992] 3200 Ashworth Ashworth et al. [1988] 4000 Staudinger and Roberts Roberts [1996] 5600 Bissonette Bissonette et al. [1990] Hine and Mookerjee [1975] Mackay and Shiu [1981] 4000 Dewu Dewulf lf et al. [1995] Bohon and Claussen [1951] Yaws and Yang [1992] 3300 Ashworth Ashworth et al. [1988] 4200 Staudinger and Roberts Roberts [1996] 6000 Bissonette Bissonette et al. [1990] Hine and Mookerjee [1975] Mackay and Shiu [1981]
type V L M M M ? X L X V L M V ? X L X V L
note
39 3 3
39 3 3
−1
(p-xylene) [106-42-3]
1,2,3-trimethylbenzene C6 H3 (CH3 )3 [526-73-8] 1,2,4-trimethylbenzene C6 H3 (CH3 )3 [95-63-6]
1,3,5-trimethylbenzene C6 H3 (CH3 )3 (mesitylene) [108-67-8] 1,2,4,5-tetramethylbenzene C6 H2 (CH3 )4
1.7×10−1 1.7×10−1 1.5×10−1 1.8×10−1 1.5×10−1 1.7×10−1 1.2×10−1 1.4×10−1 4.0×10−2 3.9×10−2
4500 5400 3000 5300 3500 3800
Dewu Dewulf lf et al. [1995] Bohon and Claussen [1951] Wasik and Tsang Tsang [1970] Yaws and Yang [1992] Hansen Hansen et al. [1993] Bissonette Bissonette et al. [1990] Ashworth Ashworth et al. [1988] Staudinger and Roberts Roberts [1996] Mackay and Shiu [1981] Yaws and Yang [1992]
M V M ? X X X L L ?
4200
Hine and Mookerjee [1975] Mackay and Shiu [1981] Hansen Hansen et al. [1995] Yaws and Yang [1992] Hansen Hansen et al. [1993]
3600
Mackay and Shiu [1981] Yaws and Yang [1992] Ashworth Ashworth et al. [1988]
V L M ? X L ? X
Mackay and Shiu [1981] Yaws and Yang [1992]
L ?
4300
39 3 3 3
39
39 3 39 3
39
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance ethylbenzene C6 H5 C2 H5 [100-41-4]
propylbenzene C6 H5 C3 H7 [103-65-1]
kH [M [M//atm] 1.2×10−1 1.2×10−1 1.1×10−1 1.3×10−1 1.3×10−1 1.5×10−1 1.5×10−1 1.1×10−1 1.7×10−1 1.2×10−1 1.2×10−1 1.6×10−1 1.1×10−1 1.2×10−1 1.4×10−1 1.3×10−1 1.0×10−1 1.4×10−1 9.8×10−2
33
−d ln kH
d(1/T )
[K]
reference
Hine and Mookerjee [1975] Mackay et al. [1979] Mackay et al. [1979] Mackay and Shiu [1981] 4600 Robbins obbins et al. [1993] 4600 Dewu Dewulf lf et al. [1995] Bohon and Claussen [1951] Hoff et al. [1993] 6100 Hartkopf and Karger Karger [1973] Yaws and Yang [1992] 5100 Staudinger and Ro Roberts berts [1996] 1700 USEPA [1982] 5500 Bissonette Bissonette et al. [1990] 5000 Ashworth Ashworth et al. [1988] 5500 Ervin et al. [1980] Allen et al. [1998] Hine and Mookerjee [1975] Mackay and Shiu [1981] Yaws and Yang [1992]
type V M T L M M V ? M ? L X X X X E V L ?
note
13 39 3 3 3 3
39
−2
(2-propyl)-benzene C6 H5 C3 H7 (isopropylbenzene, cumene) [98-82-8] 1-ethyl-2-methylbenzene C6 H4 CH3 C2 H5 (o-ethyltoluene) [611-14-3] 1-ethyl-4-methylbenzene C6 H4 CH3 C2 H5 (p-ethyltoluene) [622-96-8] butylbenzene C6 H5 C4 H9 [104-51-8] 2-methylpropylbenzene C6 H5 C4 H9 [538-93-2] sec -butylbenzene C6 H5 C4 H9 [135-98-8] tert -butylbenzene C6 H5 C4 H9 [98-06-6] 1-isopropyl-4-methylbenzene C6 H4 CH3 C3 H7
9.1×10−2 6.8×10 7.8×10−1 6.9×10−2 6.9×10−2 8.8×10−2 2.4×10−1 2.3×10−1
3700
Ashworth Ashworth et al. [1988] Hine and Mookerjee [1975] Mackay and Shiu [1981] Hoff et al. [1993] Yaws and Yang [1992] Hansen Hansen et al. [1993] Mackay and Shiu [1981] Yaws and Yang [1992]
X V L ? ? X L ?
2.0×10−1 2.0×10−1
Mackay and Shiu [1981] Yaws and Yang [1992]
L ?
8.0×10−2 7.8×10−2 7.6×10−2 3.1×10−2
Hine and Mookerjee [1975] Mackay and Shiu [1981] Yaws and Yang [1992] Mackay and Shiu [1981]
V L ? L
8.7×10−2 7.2×10−2
Hine and Mookerjee [1975] Mackay and Shiu [1981]
V L
8.5×10−2 8.4×10−2
Hine and Mookerjee [1975] Mackay and Shiu [1981]
V L
1.3×10−1
Mackay and Shiu [1981]
L
3200
3
13 39 3 39
39
39
34
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance pentylbenzene C6 H5 C5 H11
hexylbenzene C6 H5 C6 H13 C6 H5 C5 H11 (tert -amylbenzene) -amylbenzene) ethenylbenzene C8 H8 (styrene)
kH [M [M//atm] 1.7×10−1 6.0×10−2
−d ln kH
d(1/T )
[K]
reference
type
note
Mackay and Shiu [1981] Yaws and Yang [1992]
L ?
39
4.6×10−2
Yaws and Yang [1992]
?
39
5.5×10−2
Hine and Mookerjee [1975]
V
3.7×10−1 2.9×10−1 3.8×10−1
Yaws and Yang [1992] Bissonette Bissonette et al. [1990] USEPA [1982]
? X X
39 3 3
4800 4200
1-ethenyl-3-methylbenzene C9 H10 (m-methylstyrene)
2.6×10−1
Yaws and Yang [1992]
?
39
1-ethenyl-4-methylbenzene C9 H10
3.5×10−1
Yaws and Yang [1992]
?
39
(p-methylstyrene)
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
kH [M [M//atm]
35
−d ln kH
d(1/T )
[K]
reference
type
note
terpenes and polynuclear aromatics (C and H only) pinene C10 H16 [127-91-3] naphthalene C10 H8
4.9×10−2
2.4 2.1 2.1 2.4 1.9 8.1×10−1 2.0 2.1 2.3 3.9 2.7 2.5 5.1×10−3 2.0 5.1×10−3
1-methylnaphthalene C10 H7 CH3
2-methylnaphthalene C10 H7 CH3
1-ethylnaphthalene C10 H7 C2 H5 2-ethylnaphthalene C10 H7 C2 H5
Karl and Lindinger [1997]
M
Hine and Mookerjee Mookerjee [1975] Mackay Mackay et al. [1979] Mackay Mackay et al. [1979] Mackay Mackay and Shiu [1981] Bohon and Claussen [1951] Yaws and Yang [1992] Meylan and Howard Howard [1991] USEPA [1982]
Mackay Mackay and Shiu [1981] Hansen Hansen et al. [1995] Yaws and Yang [1992] Hansen Hansen et al. [1993]
V M T L V ? X X L M ? L M ? X
39 3
Mackay Mackay and Shiu [1981] Yaws and Yang [1992]
L ?
39
Mackay Mackay and Shiu [1981] Yaws and Yang [1992]
L ?
39
3600
Mackay Mackay and Shiu [1981] Mackay Mackay and Shiu [1981] Yaws and Yang [1992]
1200
1200
2.7 2.7
1.2 1.6
43
39 3 3
39
1,3-dimethylnaphthalene C12 H12
1.4
Yaws and Yang [1992]
?
39
1,4-dimethylnaphthalene C12 H12
2.0
Yaws and Yang [1992]
?
39
1,5-dimethylnaphthalene C H
1.6
Yaws and Yang [1992]
?
39
2,3-dimethylnaphthalene C12 H12
1.7
Yaws and Yang [1992]
?
39
2,6-dimethylnaphthalene C12 H12
8.3×10−1
Yaws and Yang [1992]
?
39
biphenyl (C6 H5 )2
2.5 3.6 3.3 1.2 1.2
Mackay Mackay et al. [1979] Mackay Mackay and Shiu [1981] Mackay Mackay and Shiu [1981] Bohon and Claussen [1951] Yaws and Yang [1992]
M L M V ?
39
12
12
36
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance acenaphthene C12 H10 [83-32-9]
phenanthrene C14 H10
2,3-benzindene C13 H10 (fluorene) [86-73-7] anthracene C14 H10 [120-12-7]
kH [M [M//atm] 1.3×101 6.8 4.2 6.5×10−1 4.1 6.5 3.9×101 2.5×101 2.5×101 2.8×101 2.8×101 9.5 1.2×101 1.0×101 8.5 1.0×101 5.6×101 1.7×101 1.4
−d ln kH
d(1/T )
[K]
reference
Hine and Mookerjee [1975] Mackay Mackay et al. [1979] Mackay Mackay and Shiu [1981] Mackay and Shiu [1981] USEPA [1982] Meylan and Howard Howard [1991]
2800
Hine and Mookerjee [1975] Mackay et al. [1979] Mackay and Shiu [1981] Mackay and Shiu [1981] Meylan and Howard [1991] USEPA [1982]
4700
Mackay and Shiu [1981] Mackay and Shiu [1981] USEPA [1982] Meylan and Howard [1991]
3000
Hine and Mookerjee [1975] Mackay and Shiu [1981] Mackay Mackay and Shiu [1981]
type V M L M X X V M L M X X L M X X V L M
note
3 3
3 3
3 3
1.5×101 3.5×101 8.4×101 9.2×101
4.6×10−1 1.1×102
6900
5900 1900 5500
tenHulsche tenHulscherr et al. [1992] USEPA [1982]
benzo[b]fluoranthene
1.7×103 9.7×10−1 1.5×103
tenHulsche tenHulscherr et al. [1992]
X X X
benzo[k]fluoranthene
1.7×103
5900
tenHulsche tenHulscherr et al. [1992]
X
3
indeno[1,2,3-cd]pyrene
2.9×103
3600
tenHulsche tenHulscherr et al. [1992]
X
3
benzo[a]pyrene C20 H12 [50-32-8] benzo[ghi]perylene C22 H12 [191-24-2] 1,2,3,4-tetrahydronaphthalene C10 H12 (tetralin) [119-64-2]
1.6×10−1 2.2×103
110 4700
USEPA [1982] tenHulsche tenHulscherr et al. [1992]
X X
3 3
3.0×103
3200
tenHulsche tenHulscherr et al. [1992]
X
3
5.3×10−1
5400
Ashw Ashworth orth et al. [1988]
X
3
pyrene C16 H10 [129-00-0] fluoranthene C16 H10 [206-44-0] benzo[a]fluoranthene
Meylan and Howard [1991] USEPA [1982]
4000
Mackay and Shiu [1981] Mackay and Shiu [1981]
X X L M
3 3
Mackay and Shiu [1981] tenHulsche tenHulscherr et al. [1992]
L X
3 3 3 3
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
kH [M [M//atm]
37
−d ln kH
d(1/T )
reference
type
note
Butler et al. [1935] Burnett [1963] Timmermans [1960] Gaffney and Senum [1984] Snide Sniderr and Dawson Dawson [1985] Yaws and Yang [1992] Schaffer and Daubert Daubert [1969] Meylan and Howard [1991]
M M M,X X M ? X X M M M,X X M M ? X X M
46
[K]
alcohols (ROH) (C, H, and O only) methanol CH3 OH
ethanol C2 H5 OH
1-propanol C3 H7 OH [71-23-8]
2-propanol C3 H7 OH (isopropanol) [67-63-0] 1-butanol C4 H9 OH [71-36-3]
2-butanol C4 H10O (sec -butanol) [78-92-2] 2-methyl-1-propanol C4 H10O (isobutanol) [78-83-1] 2-methyl-2-propanol C4 H10O (tert -butanol) [75-65-0]
2.3×102 2.3×102 2.1×102 2.2×102 2.2×102 1.4×102 1.6×102 2.2×102 1.9×102 2.2×102 1.6×102 2.0×102 1.9×102 2.3×102 1.2×102 1.5×102 2.0×102 1.4×102 1.6×102 1.3×102 1.5×102 1.1×102 1.2×102 1.7×102 1.3×102 8.9×101 1.2×102 1.1×102 1.4×102 1.3×102 1.2×102 5.4×101 9.8×101 9.8×101 1.1×102
5200 5600
6600
6400
Butler et al. [1935] Burnett [1963] Timmermans [1960] Gaffney and Senum [1984] Snide Sniderr and Dawson Dawson [1985] Rohrschneider [1973] Yaws and Yang [1992] Schaffer and Daubert Daubert [1969] Meylan and Howard [1991] Butler et al. [1935] Burnett [1963] Snide Sniderr and Dawson Dawson [1985] Snider and Dawson [1985] Yaws and Yang [1992]
Butler et al. [1935] Butler et al. [1935] Snide Sniderr and Dawson Dawson [1985]
M M C ? M R M ? M M M M C M M V M
8.4×101 1.0×102
Butler et al. [1935] Snider and Dawson [1985]
M M
8.4×101 7.0×101 see note
Butler et al. [1935] Snide Sniderr and Dawson Dawson [1985] Koga [1995]
M M M
7500
7500
7200
7300
8300
Butler et al. [1935] Hine and Weimar [1965] Snide Sniderr and Dawson Dawson [1985] Yaws and Yang [1992] Butler et al. [1935] Buttery et al. [1969] Burnett [1963] Snide Sniderr and Dawson Dawson [1985] Snider and Dawson [1985] Friant and Suffet [1979]
47 48 39 3 3
47 48
39 3 3 46
39
39 46
49
50
38
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance 1-pentanol C5 H11 OH (amylalcohol) [71-41-0] 2-pentanol C5 H12 O (sec -pentanol) -pentanol) [6032-29-7] 2-methyl-1-butanol C5 H12 O (isopentanol) [137-32-6] 2-methyl-2-butanol C5 H12 O (tert -pentanol) -pentanol) [75-85-4] 2,2-dimethyl-1-propanol C5 H12 O [75-84-3] 1-hexanol C6 H13 OH [111-27-3] 3-hexanol C6 H14 O [623-37-0] 2-methyl-2-pentanol C6 H14 O [590-36-3] 4-methyl-2-pentanol C6 H14 O [108-11-2] 2-methyl-3-pentanol C6 H14 O [565-67-3] 2,3-dimethyl-2-butanol C6 H14 O [594-60-5] 1-heptanol C7 H15 OH [110-70-6] 1-octanol C8 H17 OH [111-87-5]
kH [M [M//atm] 7.7×101 7.9×101 8.2×101
−d ln kH
d(1/T )
[K]
reference
type
Butler et al. [1935] Butler et al. [1935] Yaws and Yang [1992]
M V ?
6.8×101
Butler et al. [1935]
M
7.1×101
Butler et al. [1935]
M
7.3×101
Butler et al. [1935]
M
5.0×101
Saxena and Hildemann [1996]
E
6.5×101 5.9×101 6.5×101 5.4×101 2.0×101
Butler et al. [1935] Buttery et al. [1969] Hine and Mookerjee [1975] Yaws and Yang [1992] Hine and Mookerjee [1975]
V M V ? V
3.1×101
Hine and Mookerjee [1975]
V
2.2×101
Hine and Mookerjee [1975]
V
2.9×101
Hine and Mookerjee [1975]
V
3.0×101
Hine and Mookerjee [1975]
V
5.3×101 5.4×101 8.6×101 4.1×101 4.2×101 4.0×101 6.3×101
Butler et al. [1935] Hine and Mookerjee [1975] Yaws and Yang [1992]
V V ? V V M ?
Butler et al. [1935] Hine and Mookerjee [1975] Buttery et al. [1969] Yaws and Yang [1992]
note
39
51
39
39
39
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance 1-nonanol C9 H19OH
kH [M [M//atm] 6.1×101
39
−d ln kH
d(1/T )
[K]
reference
type
note
Yaws and Yang [1992]
?
39
1-decanol C10 H21 OH
3.7×101
Yaws and Yang [1992]
?
39
1-dodecanol C12 H25 OH
1.1×101
Yaws and Yang [1992]
?
39
1-tetradecanol C14 H29 OH
3.9×105
Yaws and Yang [1992]
?
39
1-pentadecanol C15 H31 OH
3.0×105
Yaws and Yang [1992]
?
39
1-hexadecanol C16 H33 OH
6.0×101
Yaws and Yang [1992]
?
39
1-heptadecanol
1.2×103
Yaws and Yang [1992]
?
39
1-octadecanol C18 H37 OH
9.2×101
Yaws and Yang [1992]
?
39, 52
cyclohexanol C6 H11OH [108-93-0] 2-propen-1-ol C3 H5 OH (allyl alcohol) [107-18-6] 2-buten-1-ol
1.7×102
Hine and Mookerjee [1975]
V
2.0×102 1.8×102 2.0×102 4.4×102 3.0×102
Pierotti et al. [1957] Yaws and Yang [1992] Meylan and Howard [1991] USEPA [1982] Saxena and Hildemann [1996]
X ? X X E
53 39 3 3 51
Iraci et al. [1998]
M
49
C17 H35 OH
7200
CH3 CHCHCH2 OH 2-methyl-3-buten-2-ol [115-18-4]
6.5×101
40
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
hydroxybenzene C6 H5 OH (phenol)
(hydroxymethyl)benzene C6 H5 CH2 OH (benzyl alcohol) [100-51-6] 4-tert -butylphenol (CH3 )3 CC6 H4 OH 1-hydroxy-2-methylbenzene HOC6 H4 CH3 (2-cresol, o (2-cresol, o--cresol) [95-48-7] 1-hydroxy-3-methylbenzene HOC6 H4 CH3 (3-cresol, m (3-cresol, m-cresol) -cresol) [108-39-4] 1-hydroxy-4-methylbenzene HOC6 H4 CH3 (4-cresol, p (4-cresol, p--cresol) [106-44-5] 1,3-dimethyl-4-hydroxyben benzene C8 H10 O (2,4-dimethylphenol) [105-67-9]
kH [M [M//atm] 4.9×102 3.0×103 2.9×103 7.8×10−2 1.9×102 3.0×103 1.9×103 1.6×103 9.0×103
9.0×102
8.3×102 8.3×102 1.2×103 2.6×102 8.3×102 1.4×103 6.3×102
1.0×103 1.3×103 2.5×103 1.1×103 5.3×102 1.9×10−1 4.1×102
−d ln kH
d(1/T )
type
note
Saxena and Hildemann [1996]
R X M X X X X X E
48 54 11 3 3 3 55,8 51
Parsons Parsons et al. [1972]
M
56
Gaffney and Senum [1984] Parsons Parsons et al. [1972] Yaws and Yang [1992] Janini and Quaddora Quaddora [1986]
X M ? X
48 56 39, 8 3
Meylan and Howard [1991] Yaws and Yang [1992] Janini and Quaddora Quaddora [1986]
X ? X
3 39, 8 3
Gaffney and Senum [1984] Parsons Parsons et al. [1972] Yaws and Yang [1992] Meylan and Howard [1991] Janini and Quaddora Quaddora [1986]
X M ? X X X X
48 56 39, 8 3 3 3 3
[K]
6800 3600
7300
Hine and Weimar [1965] Gaffney and Senum [1984] Parsons Parsons et al. [1971] Howe et al. [1987] Janini and Quaddora Quaddora [1986] Meylan and Howard [1991] USEPA [1982] Tremp et al. [1993]
7700
7300 4600
7700
7200
4600 -3300 6600
reference
Ashworth Ashworth et al. [1988] USEPA [1982]
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
kH [M [M//atm]
substance
41
−d ln kH
d(1/T )
[K]
reference
type
note
polyols (R(OH)n) (C, H, and O only) 1,2-ethanediol HO(CH2 )2 OH (ethylene glycol) [107-21-1] 1,2-propanediol C3 H8 O2
1.7×104 4.0×106
Butler and Ramchandani [1935] Bone et al. [1983]
M M
57 8
Saxena and Hildemann [1996] Saxena and Hildemann [1996]
E E
51 51
Bone et al. [1983]
M
8
Butler and Ramchandani [1935] Saxena and Hildemann [1996] Saxena and Hildemann [1996]
M E E
57 51 51
5.0×106
Saxena and Hildemann [1996]
E
51
> 1.0 ×105
Saxena and Hildemann [1996]
E
51
< 5.0 ×106
Saxena and Hildemann [1996]
E
51
> 4.0 ×104 < 4.0 ×106
Saxena and Hildemann [1996] Saxena and Hildemann [1996]
E E
51 51
1,2,3-butanetriol C4 H10O3
3.0×1011
Saxena and Hildemann [1996]
E
51
1,2,4-butanetriol C4 H10O3
3.0×1011
Saxena and Hildemann [1996]
E
51
1,2,3,4-tetrahydroxy butane C4 H10O4
2.0×1016
Saxena and Hildemann [1996]
E
51
1,5-pentanediol C5 H12O2
4.0×106
Saxena and Hildemann [1996]
E
51
2,3-pentanediol C5 H12O2
3.0×106
Saxena and Hildemann [1996]
E
51
2,4-pentanediol C5 H12O2
3.0×106
Saxena and Hildemann [1996]
E
51
1,2,3,4,5-pe pen ntahydroxy pe pen ntane C5 H12O5
9.0×1020
Saxena and Hildemann [1996]
E
51
1,6-hexanediol C6 H14O2
3.0×106
Saxena and Hildemann [1996]
E
51
> 1.0 ×105 < 6.0 ×106
1,3-propanediol C3 H8 O2
9.2×105
1,2,3-propanetriol C3 H8 O3 (glycerol)
6.0×104 > 6.0 ×108 < 4.0 ×1011
1,3-butanediol C4 H10O2 1,4-butanediol C4 H10O2 2,3-butanediol C4 H10O2
42
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
2,5-hexanediol C6 H14 O2
kH [M [M//atm] 2.0×106
−d ln kH
d(1/T )
[K]
reference
type
note
Saxena and Hildemann [1996]
E
51
2-methyl-1,3-pentanediol C6 H14 O2
3.0×106
Saxena and Hildemann [1996]
E
51
2-methyl-2,4-pentanediol C6 H14 O2
2.0×106
Saxena and Hildemann [1996]
E
51
1,2,6-hexanetriol C6 H14 O3
2.0×1011
Saxena and Hildemann [1996]
E
51
1,2,3,4,5,6-hexahydroxy hexane C6 H14 O6
4.0×1025
Saxena and Hildemann [1996]
E
51
1,2,4,5-tetrahydroxy cyclohexane C6 H12 O4
4.0×1016
Saxena and Hildemann [1996]
E
51
1, 1,2, 2,3, 3,4, 4,5, 5,66-he hexa xah hydro ydroxy xy cycl cycloh ohex exan anee
1. 1.00×1026
Saxena and Hildemann [1996]
E
51
1,7-heptanediol C7 H16 O2
2.0×106
Saxena and Hildemann [1996]
E
51
2,4-heptanediol C7 H16 O2
2.0×106
Saxena and Hildemann [1996]
E
51
2,3-diethyl-1,3-propanediol C7 H16 O2
2.0×106
Saxena and Hildemann [1996]
E
51
2-ethyl-1,3-hexanediol C8 H18 O2
2.0×106
Saxena and Hildemann [1996]
E
51
1,2,3,4,5-pen pentahydroxy heptane C7 H16 O5
5.0×1020
Saxena and Hildemann [1996]
E
51
1,2,3,4,6-pen pentahydroxy heptane C7 H16 O5
4.0×1020
Saxena and Hildemann [1996]
E
51
1,2,3,5,7-pen pentahydroxy heptane C7 H16 O5
5.0×1020
Saxena and Hildemann [1996]
E
51
1,2,3,4,5,6-hexahydroxy heptane C7 H16 O6
3.0×1025
Saxena and Hildemann [1996]
E
51
C6 H12 O6
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
kH [M [M//atm] 4.6×103
substance 1,2-dihydroxybenzene C6 H4 (OH)2 (pyrocatechol) [120-80-9] 1,3-dihydroxybenzene C6 H4 (OH)2 (resorcinol) [108-46-3] 1,4-dihydroxybenzene C6 H4 (OH)2 (hydroquinone) [123-31-9]
8.3×106
43
−d ln kH
d(1/T )
[K]
reference
type
note
Mackay et al. [1995]
V
USEPA [1982]
X
3
Meylan and Howard [1991] Meylan and Howard [1991] Mackay et al. [1995]
X X V
58 58
M M
9
6300
2.6×107 1.7×107 2.5×107
peroxides (ROOH) and peroxy radicals (ROO) (C, H, and O only) methyl hydroperoxide CH3 OOH (methylperoxide) [3031-73-0] ethyl hydroperoxide C2 H5 OOH
3.0×102 3.1×102
5300 5200
Lind and Kok [1994] O’Sulliva O’Sullivan n et al. [1996]
3.4×102
6000
O’Sulliva O’Sullivan n et al. [1996]
M
1.7×106 1.6×106 4.8×105
9700 10000 1500
O’Sulliva O’Sullivan n et al. [1996] Staffelbach Staffelbach and Kok [1993] Zhou and Lee Lee [1992]
M M M
(ethylperoxide) hydroxymethyl hydroperoxide HOCH2 OOH (HMHP,HMP) [15932-89-5] bis(hydroxymethyl)peroxide HOCH2 OOCH2 OH (BHMP) [17088-73-2] methylperoxy radical CH3 OO
peroxyacet peroxyacetyl radical CH3 C(O)Oyl 2 [36709-10-1]
>1.0×107 4.5×105
8400
Staffelbach and Kok [1993] Zhou and Lee Lee [1992]
M M
6.0 2.0×103
5600 Jacob [1986] 6600 Lelieveld and Crutzen [1991]
E E
< 0.1
Villalta et al. [1996]
M
59 60
44
substance
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
kH [M [M//atm]
−d ln kH
d(1/T )
[K]
reference
type
note
aldehydes (RCHO) (C, H, and O only) methanal HCHO (formaldehyde) [50-50-0]
ethanal CH3 CHO (acetaldehyde) [75-07-0]
propanal C2 H5 CHO (propionaldehyde) [123-38-6] butanal C3 H7 CHO (butyraldehyde) [123-72-8] pentanal C4 H9 CHO (valeraldehyde) [110-62-3] hexanal C5 H11 CHO heptanal C6 H13 CHO octanal C7 H15 CHO nonanal C8 H17 CHO decanal C9 H19 CHO
see note 6.0×103 7.0×103 see note 6.3×103 3.0×103 1.4×104 3.1×103 3.0×103 3.2×103 1.5×101 1.5×101 1.3×101 1.1×101 1.7×101 1.3×101 1.5×101 9.9
Ledbury Ledbury and Blair [1925] Gaffney and Senum [1984] 6400 Chameides [1984] Dong and Dasgupta Dasgupta [1986] Seinfeld [1986] 7200 Betterton and Hoffmann [1988] Warneck [1988] 6500 Zhou and Mopper [1990] 7200 M¨ oller and Mauersberger [1992] 6800 Staudinger and Roberts Roberts [1996]
1.7×101 1.7 1.4×101 1.3×101 1.3×101 1.3×101 2.8 5.3 9.6 8.7 5.5
4700 4500 5600
6.4 6.8 4.4
6300
4.9 4.7 1.9 3.3 3.7 2.3 2.1 1.9 2.1×102 1.0 1.3
6500
7.0×10−1 6.1×10−1
Buttery et al. [1969] Gaffney and Senum [1984] 5800 Snide Sniderr and Dawson Dawson [1985] 6300 Betterton and Hoffmann [1988] 5000 Zhou and Mopper [1990] 5700 Benkelberg Benkelberg et al. [1995] Pierotti et al. [1957] Yaws and Yang [1992]
5700 24 2400 5600 6200
USEPA [1982] Janini and Quaddora Quaddora [1986] Staudinger and Roberts Roberts [1996]
4000
7500
7400
6700
8700
61 48 62 13 63 64
48 63 64 65 39 3 3
Zhou and Mopper [1990] Butt Buttery ery et al. [1969] Janini and Quaddora Quaddora [1986]
X X L M C M X X M M X
Zhou and Mopper [1990] Butt Buttery ery et al. [1969] Yaws and Yang [1992]
M M ?
64
Zhou and Mopper [1990] Butt Buttery ery et al. [1969] Yaws and Yang [1992]
64
Zhou and Mopper [1990] Butt Buttery ery et al. [1969]
M M ? M M ? M M ? M M
Yaws and Yang [1992] Zhou and Mopper [1990]
? M
Buttery et al. [1969] Snider and Dawson [1985] Zhou and Mopper [1990] Janini and Quaddora Quaddora [1986] Schaffer and Daubert Daubert [1969]
M X T M ? M C M c L M X M M M M X ?
Zhou and Mopper [1990] Butt Buttery ery et al. [1969] Yaws and Yang [1992] Zhou and Mopper [1990] Butt Buttery ery et al. [1969] Yaws and Yang [1992]
64 3 3 64 3
39, 49
39, 49 64 39, 49 64 39, 49 64 39, 49 64
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance propenal CH2 CHCHO (acrolein) [107-02-8] 2-methylpropenal C4 H6 O (methacrolein) [78-85-3] trans -2-butenal CH3 CHCHCHO (crotonaldehyde)
kH [M [M//atm] 8.2 7.4 1.0×101 8.2 4.3 6.5
5.2×101 5.1×101 5.1×101 6.0×101 2.0×101
45
−d ln kH
d(1/T )
[K]
Gaffney and Senum [1984] Snider Snider and Dawson Dawson [1985] USEPA [1982] Meylan and Howard Howard [1991]
5100 3800
reference
5300
Alle Allen n et al. [1998] Iraci Iraci et al. [1998]
3600
Buttery et al. [1971] Gaffney and Senum [1984] Meylan and Howard [1991] USEPA [1982]
type X M X X E M
Buttery et al. [1971]
M X X X M
1.0×102
Buttery et al. [1971]
M
trans -2-octenal
1.3×101
Buttery et al. [1971]
M
C5 H11CHCHCHO
see note
see note
?
benzaldehyde C6 H5 CHO [100-52-7]
3.6×101 3.6×101 3.7×101 4.2×101 3.9×101 3.5×101 4.0×105
Hine and Mookerjee [1975] Gaffney and Senum [1984] 5100 Betterton and Hoffmann [1988] 4600 Zhou and Mopper Mopper [1990] 4800 Staudinger and Roberts Roberts [1996] 7000 Alle Allen n et al. [1998] Gaffney and Senum [1984]
V X M M L E X
1.9×106
8600
Pars Parsons ons et al. [1971]
M
Graedel and Goldberg [1983]
C
Betterton and Hoffmann [1988] Zhou and Mopper [1990]
M M
trans -2-hexenal
note 48 3 3
48 3 3
C3 H7 CHCHCHO trans -trans -2,4-hexadienal
CH3 CHCHCHCHCHO
3-hydroxybenzaldehyde C6 H4 (OH)CHO (3-formylphenol) 4-hydroxybenzaldehyde
66
48 63 64
48
54
C6 H4 (OH)CHO (4-formylphenol) 4.2×103
generic aldehyde RCHO ethanedial OHCCHO (glyoxal)
>3.0×105 3.6×105
63
46
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
kH [M [M//atm]
substance
−d ln kH
d(1/T )
[K]
reference
type
note
ketones (RCOR) (C, H, and O only) propanone CH3 COCH3 (acetone) [67-64-1]
2-butanone C2 H5 COCH3
(methyl ethyl ketone, MEK) [78-93-3]
2-pentanone C3 H7 COCH3 [107-87-9] 3-pentanone C2 H5 COC2 H5 2-heptanone C5 H11 COCH3 [110-43-0]
3.0×101 2.8×101 3.1 2.5×101 3.0×101 2.6×101 3.5×101 3.2×101 2.7×101 2.5×101 2.5×101 2.7×101 2.3×101 2.2×101 3.0 3.0×101 7.1 1.8×101 2.1×101 7.7 2.0×101 4.1...7.7 1.8×101 1.9×101 1.7×101 1.0×101 2.0×101 6.9 7.2 1.6×101 1.2×101 9.2 2.0×101
7.0 3.5×101 6.3
4800 3800 5800 5300
5000 3300 4600
Butler and Ramchandani [1935] Burnett [1963] Hine and Weimar Weimar [1965] Buttery et al. [1969] Gaffney and Senum [1984] Snider and Dawson [1985] Zhou and Mopper [1990] Betterton [1991] Benkelberg Benkelberg et al. [1995] Vitenberg et al. [1975] Vitenberg et al. [1974] Hoff et al. [1993] Yaws and Yang [1992] Schaffer and Daubert Daubert [1969] Janini and Quaddora Quaddora [1986] Staudinger and Roberts Roberts [1996]
5700
5000
5000 -5200 5800
4600 9200
Buttery et al. [1969] Ashworth Ashworth et al. [1988] Zhou and Mopper [1990] Howe et al. [1987] Vitenberg et al. [1975] Rohrschneider [1973] Vitenberg et al. [1974] Friant and Suffet [1979] Staudinger and Roberts Roberts [1996] Ashworth Ashworth et al. [1988] Janini and Quaddora Quaddora [1986]
Buttery et al. [1969] Meylan and Howard [1991] Janini and Quaddora Quaddora [1986]
Janini and Quaddora Quaddora [1986]
M X M X M M X M L X X M X X X
Buttery Buttery et al. [1969] Janini and Quaddora Quaddora [1986] Meylan and Howard Howard [1991]
M X X
4500
Hine and Weimar Weimar [1965] Snider and Dawson [1985]
R M R M X M M M M M X M ? X X L R M
48 64
67 39 3 3
68 64 11
67 49 3 3 3 3 3
3 3
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
2-octanone C6 H13COCH3
kH [M [M//atm] 5.4
−d ln kH
d(1/T )
[K]
reference
type
Butte Buttery ry et al. [1969]
M
2-nonanone C7 H15COCH3
2.7
Butte Buttery ry et al. [1969]
M
2-undecanone C9 H19COCH3
1.6
Butte Buttery ry et al. [1969]
M
4-methyl-2-pentanone (CH3 )2 CHCH2 COCH3 (methyl isobutyl ketone, MIBK) [108-10-1] 3-buten-2-one C4 H6 O (methyl vinyl ketone, MVK) [78-94-4] 1-phenylethanone C6 H5 COCH3
2.6. . .5 . 5.2 2.2
Howe et al. [1987] Ashw Ashworth orth et al. [1988]
X X
Allen et al. [1998] Betterton [1991] Iraci et al. [1998]
E ? M
Hine and Mookerjee [1975] Betterton [1991]
V M
(acetophenone) [98-86-2] 3,5,5 ,5,5-t -tri rime meth thyl yl-2 -2-c -cyc yclo lohe hexe xenn-11-one -one C9 H14O (isophorone) [78-59-1] 2,3-butanedione CH3 COCOCH3 (biacetyl, dimethylglycol)
2.1×101 4.4×101 4.1×101
170
7800
9.4×101 1.1×102
6000
9.8×101
12000
1. 1.77×102
3900
1.9×102 5.7×101 7.4×101
47
5700
note
11 3
Allen et al. [1998]
E
USEPA [1982]
X
3
Gaffney and Senum [1984] Snider and Dawson [1985] Betterton [1991]
X M M
48
48
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
kH [M [M//atm]
−d ln kH
d(1/T )
[K]
reference
type
note
carboxylic acids (RCOOH) and peroxy carboxylic acids (RCOOOH) (C, H, and O only) methanoic acid HCOOH (formic acid) [64-18-6]
6.0×103 3.7×103 3.7×103 5.6×103
5700 5700
3
5700 5700 5700
ethanoic acid CH3 COOH
3.5×10 3.7×103 1.3×104 7.6×103 5.2×103 5.5×103 5.4×103 8.9×103 5.2×103 9.0×102 5.4×103 3.4×103 3.3×103
(acetic acid) [64-19-7]
1.0×104 8.8×103 8.8×103
propanoic acid C2 H5 COOH (propionic acid) [79-09-4] butanoic acid C3 H7 COOH (butyric acid) [107-92-6] 2-methyl propanoic acid (CH3 )2 CHCOOH pentanoic acid C4 H9 COOH [109-52-4]
9.3×103 5.5×103 5.2×103 8.6×103 4.1×103 5.2×103 8.3×102 5.5×103 9.8×102 2.3×103 2.2×103 6.2×103 5.7×103 1.9×103 1.9×103 4.7×103
6100
5700
Gaffney and Senum [1984] Chameides [1984] Jacob [1986] Keene and Galloway [1986] Winiwarter Winiwarter et al. [1988] Pandis Pandis and Seinfeld Seinfeld [1989] Lelieveld and Crutzen [1991] Servant et al. [1991] Johnson [1990] Keene et al. [1995] Khan et al. [1995] Keene et al. [1995] Johnson Johnson et al. [1996] Johnson et al. [1996] Yaws and Yang [1992] Staudinger and Roberts Roberts [1996] Butler and Ramchandani [1935] Hine and Mookerjee [1975]
6400 6400
6300
6300 4900
Butler and Ramchandani [1935] Hine and Mookerjee [1975] Khan et al. [1995]
X T T T M M C C M C ? ? X M ? M M M ? M
Servant et al. [1991] Khan et al. [1995]
M M
Khan et al. [1995] Staudinger and Roberts Roberts [1996]
M ?
Butler and Ramchandani [1935] Hine and Mookerjee [1975] Servant et al. [1991] Khan et al. [1995]
5.7×103 1.1×103 2.2×103 2.2×103
Gaffney and Senum [1984] Keene and Galloway [1986] Winiwarter Winiwarter et al. [1988] Jacob Jacob et al. [1989] Servant et al. [1991] Khan et al. [1995] Keene et al. [1995] Keene et al. [1995] Johnson Johnson et al. [1996] Johnson et al. [1996] Yaws and Yang [1992] Staudinger and Roberts Roberts [1996] USEPA [1982]
6583 6900
X T C T T C C M X C M C M C ? ? c ?
48
69 11
39 70
48
69
39 70 3
69
69
70
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance 3-methyl butanoic acid (CH3 )2 CHCH2 COOH
kH [M [M//atm] 1.2×103
49
−d ln kH
d(1/T )
[K]
reference
type
Khan et al. [1995]
M
note
2,2-dimethyl propanoic acid (CH3 )3 CCOOH
3.5×102
Khan et al. [1995]
M
hexanoic acid C5 H11COOH [142-62-1] propenoic acid C3 H4 O2 (acrylic acid) [79-10-7] 2-Methyl-2-propenoic acid C4 H6 O2 (methacrylic acid) [79-41-4] benzoic acid C6 H5 COOH
1.4×103 1.2×103
6304 Khan et al. [1995] 5900 Staudinger and Roberts Roberts [1996]
M ?
70
2.4×103
Yaws and Yang [1992]
?
39
2.6×103
Khan et al. [1992]
M
2.4×104 1.4×104
Yaws and Yang [1992] USEPA [1982]
? X
39 3
6500
ethanedioic acid HOOCCOOH (oxalic acid)
7.0×106 5.0×108
Gaffney and Senum [1984] Saxena and Hildemann [1996]
X E
48 51
propanedioic acid HOOCCH2 COOH (malonic acid)
4.0×108
Saxena and Hildemann [1996]
E
51
butanedioic acid HOOC(CH2 )2 COOH (succinic acid)
3.0×108
Saxena and Hildemann [1996]
E
51
pentanedioic) aCOOH cid HOOC(CH 2 3 (glutaric acid)
2.0×10
Saxena and Hildemann [1996]
E
51
hexanedioic acid HOOC(CH2 )4 COOH (adipic acid)
2.0×108 1.8×107
Saxena and Hildemann [1996] USEPA [1982]
E X
51 3
cis -butenedioic acid
1.0×109
Saxena and Hildemann [1996]
E
51
Lind and Kok [1994] O’Sulliva O’Sullivan n et al. [1996]
M M
9
8
11000
HOOC(CH)2 COOH (maleic acid) ethanoic peroxyacid CH3 COOOH (peroxyacetic acid)
6.7×102 8.4×102
5900 5300
50
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
kH [M [M//atm]
substance
−d ln kH
d(1/T )
[K]
reference
type
note
esters (RCOOR) (C, H, and O only) methyl methanoate HCOOCH3 (methyl formate)
4.5 4.5 4.1 4.1
3800
Hine and Mookerjee Mookerjee [1975] Betterton [1992] Hoff et al. [1993] Hartkopf and Karger Karger [1973]
? ? M M
71..81 10 8.7
5000
Butler and Ramchandani Kieck Kieckbusch busch and King [[1 1993759]] Buttery Buttery et al. [1969]
M M M
6.2 5.8
Hine and Mookerjee Mookerjee [1975] Buttery Buttery et al. [1969]
V M
×
methCOOCH yl ethanoate CH 3 3 (methyl acetate) methyl propanoate C2 H5 COOCH3 (methyl propionate)
1
methyl butanoate C3 H7 COOCH3 (methyl butyrate)
4.8
Buttery Buttery et al. [1969]
M
methyl pentanoate C4 H9 COOCH3
3.1
Buttery Buttery et al. [1969]
M
methyl hexanoate C5 H11 COOCH3
2.7
Buttery Buttery et al. [1969]
M
methyl octanoate C6 H13 COOCH3
1.3
Buttery Buttery et al. [1969]
M
methyl decanoate C11 H22 O2 (methyl caprate) [110-42-9] methyl dodecanoate C13 H26 O2
1.4
Kr Krop op et al. [1997]
V
8.4×10−1
Krop et al. [1997]
V
5.1×10−1
Krop et al. [1997]
V
3.0×10−1
Krop et al. [1997]
V
1.7×10−1
Krop et al. [1997]
V
(methyl laurate) [111-82-0] methyl tetradecanoate C15 H30 O2 (methyl myristate) [124-10-7] methyl hexadecanoate C17 H34 O2 (methyl palmitate) [112-39-0] methyl octadecanoate C19 H38 O2 (methyl stearate) [112-61-8]
71 71
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
methyl arachidate
kH [M [M//atm] 1.0×10−1
methyl behenate (Z,Z,Z)-9 (Z,Z,Z )-9,12 ,12,15 ,15-oct -octade adecat catrie rienoi noicc acid acid methyl ester C19 H32 O2 (methyl linolenate) [301-00-8] (Z,Z)-9,12(Z,Z) -9,12-octade octadecadie cadienoic noic acid methyl methyl ester C19 H34 O2 (methyl linolate) [112-63-0] (Z (Z))-99-oc octa tade dece ceno noic ic ac acid id me meth thyl yl es este terr C19 H36 O2 (methyl oleate) [112-62-9] (Z (Z))-13 13-d -doc ocos osen enoi oicc ac acid id meth methyl yl es este terr
substance
C23 H44 O2 (methyl erucate) [1120-34-9] methyl benzoate C6 H5 COOCH3 ethyl methanoate HCOOC2 H5 (ethyl formate) ethyl ethanoate CH3 COOC2 H5 (ethyl acetate)
ethyl propanoate C2 H5 COOC2 H5 (ethyl propionate)
d(1/T )
[K]
reference
type
Krop et al. [1997]
V
6.0×10−2
Krop et al. [1997]
V
2.8×101
Krop et al. [1997]
V
6.3
Kr Krop op et al. [1997]
V
1. 1.33
Kr Krop op et al. [1997]
V
Krop et al. [1997]
V
Hine and Mookerjee [1975]
V
Hine and Mookerjee Mookerjee [1975] Hoff et al. [1993] Hartkopf and Karger Karger [1973]
V ? M
Butler and Ra Ramchandani mchandani [1935] Kieckbusch Kieckbusch and King [1979] Hoff et al. [1993] Janini and Quaddora Quaddora [1986] Meylan and Howard Howard [1991]
Hine and Mookerjee Mookerjee [1975]
M M ? X X V
5. 5.33×10−1
3.6 1.4×10−1 2.0×10−1
51
−d ln kH
5.6×101
7.6 5.9 9.0 4.7 6.5 4.6
4300
5300
5700
ethyl butanoate C3 H7 COOC2 H5 (ethyl butyrate)
2.8
Hine and Mookerjee Mookerjee [1975]
V
ethyl pentanoate C4 H9 COOC2 H5
2.9
Hine and Mookerjee Mookerjee [1975]
V
note
13
13 3 3
52
substance
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
kH [M [M//atm] 2.0
ethyl heptanoate C6 H13 COOC2 H5
d(1/T )
[K]
(ethyl laurate) [106-33-2] propyl methanoate HCOOC3 H7 (propyl formate)
2.7
propyl propanoate C2 H5 COOC3 H7 (propyl propionate)
5.0 5.0 4.6 4.4 4.5 2.6
propyl butanoate C3 H7 COOC3 H7 (propyl butyrate)
1.9
propyl dodecanoate C15 H30 O2 (propyl laurate) [3681-78-5] isopropyl methanoate HCOOC3 H7 (isopropyl formate)
7.8×10−1
reference
type
Hine and Mookerjee Mookerjee [1975]
V
Krop et al. [1997]
V
Hine and Mookerjee Mookerjee [1975]
V
Butler and Ramchandani Ramchandani [1935] Hine and Mookerjee Mookerjee [1975] Kieck Kieckbusch busch and King [1979] Janini and Quaddora Quaddora [1986] Meylan and Howard Howard [1991]
Hine and Mookerjee Mookerjee [1975]
V V M X X V
Hine and Mookerjee Mookerjee [1975]
V
Krop et al. [1997]
V
Hine and Mookerjee Mookerjee [1975]
V
Hine and Mookerjee Mookerjee [1975] Janini and Quaddora Quaddora [1986]
V X
7.8×10−1
ethyl dodecanoate C14 H28 O2
propyl ethanoate CH3 COOC3 H7 (propyl acetate)
−d ln kH
5500 6000
1.2
23..96
isopropyl propanoate C2 H5 COOC3 H7 (isopropyl propionate)
1.7
Hine and Mookerjee Mookerjee [1975]
V
butyl ethanoate CH3 COOC4 H9 (butyl acetate)
3.0 3.6 3.5 3.5 2.1 7.2×10−1
Hine and Mookerjee Mookerjee [1975] Kieck Kieckbusch busch and King [1979] Meylan and Howard Howard [1991] Janini and Quaddora Quaddora [1986] USEPA [1982]
V M X X X V
iCH soprCOOC opyl ethHanoate 3 3 7 (isopropyl acetate)
butyl dodecanoate C16 H32 O2 (butyl laurate) [106-18-3]
5500
6000
7500 3200
Krop et al. [1997]
note
3 3
3
3 3 3
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
kH [M [M//atm] 1.7
2-methylpropyl methanoate HCOOC4 H9 (isobutyl formate)
53
−d ln kH
d(1/T )
[K]
reference
type
note
Hine and Mookerjee Mookerjee [1975]
V
2.2
Hine and Mookerjee Mookerjee [1975]
V
2.6 2.8
Hine and Mookerjee Mookerjee [1975] Kieckbu Kieckbusch sch and King [1979]
V M
pentyl propanoate C2 H5 COOC5 H11 (amyyl propionate)
1.2
Hine and Mookerjee Mookerjee [1975]
V
isopentyl methanoate HCOOC5 H11 (isoamyyl formate)
1.5
Hine and Mookerjee Mookerjee [1975]
V
isopentyl ethanoate CH3 COOC5 H11 (isoamyyl acetate)
1.7 2.4
Hine and Mookerjee Mookerjee [1975] USEPA [1982]
V X
hexyl ethanoate CH3 COOC6 H13 (hexyl acetate)
1.9
Hine and Mookerjee Mookerjee [1975]
V
2-ethylhexyl dodecanoate (2-ethylhexyl laurate)
3.1×10−1
Krop et al. [1997]
V
ethenyl ethanoate
1.7
2600
USEPA [1982]
X
3
3.0×103
5700
USEPA [1982]
X
3
1.2×103
5600
USEPA [1982]
X
3
2-methylpropyl ethanoate 3 COOC4 H9 CH (isobutyl acetate) [110-19-0] pentyl ethanoate CH3 COOC5 H11 (amyyl acetate)
6500
5000
3
CH3 COOCHCH2 (vinyl acetate) dimethyl phthalate C10 H10 O4 [131-11-3] diethyl phthalate C12 H14 O4 [84-66-2]
54
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
kH [M [M//atm]
substance
−d ln kH
d(1/T )
[K]
reference
type
note
ethers (ROR) (C, H, and O only) dimethyl ether CH3 OCH3
9.9×10−1 1.0
Hine and Weimar [1965] Hine and Mookerjee Mookerjee [1975]
R V
Saxena and Hildemann [1996]
E
Butler and Ramchandani Ramchandani [1935] Hine and Weimar Weimar [1965] Signer et al. [1969] Nielsen Nielsen et al. [1994] Hoff et al. [1993] Lamarche Lamarche and Droste Droste [1989] Hine and Mookerjee [1975]
V V M M ? X V
Hine and Mookerjee Mookerjee [1975]
V
Guthrie [1973] Robbins Robbins et al. [1993]
V M
8.7×10−1 8.7×10−1
Butler and Ramchandani [1935] Hine and Mookerjee [1975]
V V
2.8×10−1 2.9×10−1 1.9×10−1 2.3×10−1 4.5×10−1 9.9×10−2 1.0×10−1
Butler and Ramchandani [1935] Hine and Mookerjee [1975] Hoff et al. [1993] Hartkopf and Karger Karger [1973] Yaws and Yang [1992]
V V ? M ? V V
9.0×10−1
ethyl methyl ether
51
C2 H5 OCH3 diethyl ether C2 H5 OC2 H5
1.1 1.1 8.0×10−1 1.2 7.8×10−1 7.9×10−1 6.8×10−1
methyl propyl ether CH3 OC3 H7 methyl 2-propyl ether CH3 OC3 H7
1.2
methyl tert -butyl ether CH3 OC(CH3 )3
1.7 1.6
ethyl propyl ether C2 H5 OC3 H7
dipropyl ether C3 H7 OC3 H7
diisopropyl ether C3 H7 OC3 H7
5300
7700
8900
Hine and Weimar [1965] Hine and Mookerjee [1975]
13 3
13 39
−1
dibutyl ether C4 H9 OC4 H9 methoxybenzene C6 H5 OCH3 (anisole) [100-66-3]
4.9×10−1 5.8×10 1.7×10−1
Nielsen et al. [1994] Yaws and Yang [1992] Pierotti et al. [1957]
M ? X
2.4×10−1 2.4×10−1
Hine and Weimar [1965] Hine and Mookerjee [1975]
R V
39 53
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
kH [M [M//atm]
55
−d ln kH
d(1/T )
[K]
reference
type
note
miscellaneous, e.g. multiple functional groups (C, H, and O only) 1,2-epoxypropane C3 H6 O (propyleneoxide) [75-56-9]
5.3
3500
USEPA [1982]
X
3
Ashworth Ashworth et al. [1988]
X
3
Pierotti Pierotti et al. [1957]
X
53
−2
2C-mHetO hoxyethanol 3 8 2 [109-86-4] dimethoxymethane CH3 OCH2 OCH3
2.2×10
trimethoxymethane HC(OCH3 )3
7.0×101
Guthrie [1973]
V
1,1-diethoxyethane (C2 H5 O)2 CHCH3
1.0×101
Hine and Mookerjee [1975]
V
1,2-diethoxyethane C2 H5 OC2 H4 OC2 H5
1.6×101
Hine and Mookerjee [1975]
V
1,1,1-trimethoxyethane CH3 C(OCH3 )3
6.5×101
Guthrie [1973]
V
3-oxapentane-1,5-diol HO(CH2 )2 O(CH2 )2 OH (diethylene glycol) [111-46-6] 3,6-dioxaoctane-1,8-diol HO(CH2 CH2 O)3 H (triethylene glycol) [112-27-6] propanonal
2.0×109
Saxena and Hildemann [1996]
E
51
9.0×1011
Saxena and Hildemann [1996]
E
51
7500 Betterton and Hoffmann [1988]
M
63
Zhou and Mopper [1990]
M
5.8
-870
3.7×103 4
CH3 COCHO (methylglyoxal, pyruvaldehyde)
3.2×10
2-hydroxyethanal HOCH2 CHO (hydroxyacetaldehyde)
4.1×104
4600 Betterton and Hoffmann [1988]
M
63
oxoethanoic acid OHCCOOH (glyoxylic acid) [298-12-4] 2-oxopropanoic acid CH3 COCOOH (pyruvic acid)
9.0×103
Saxena and Hildemann [1996]
E
51
Khan et al. [1995] Staudinger and Roberts Roberts [1996] Khan et al. [1992]
M ? M
70
3.1×105 3.0×105 3.1×105
5100 5200
56
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance 3-oxopropanoic acid OHCCH2 COOH
kH [M [M//atm] 7.0×103
−d ln kH
d(1/T )
[K]
reference
type
note
Saxena and Hildemann [1996]
E
51
4-oxobutanoic acid OHC(CH2 )2 COOH
5.0×103
Saxena and Hildemann [1996]
E
51
5-oxopentanoic acid OHC(CH2 )3 COOH
4.0×103
Saxena and Hildemann [1996]
E
51
oxacyclopentadiene C4 H4 O (furan, furfuran) [110-00-9] tetrahydrofurane C4 H8 O (THF)
1.8×10−1
Yaws and Yang [1992]
?
39
1.4×101 2.2×101
5700
Cabani Cabani et al. [1971a] Signer et al. [1969]
M M
2-methyltetrahydrofurane CH3 C4 H7 O
1.1×101
6200
Cabani Cabani et al. [1971a]
M
2,5-dimethyltetrahydrofurane (CH3 )2 C4 H6 O
5.7
6800
Cabani Cabani et al. [1971a]
M
tetrahydropyran C5 H10 O (THP)
8.0
5900
Cabani Cabani et al. [1971a]
M
1,3-dioxolane C3 H6 O2
4.0×101
4800
Cabani Cabani et al. [1971a]
M
1,4-dioxane C4 H8 O2
2.1×102 2.2×102
Cabani et al. [1971a] Rohrschneider [1973]
X M
11
Friant and Suffet [1979] Cabani Cabani et al. [1971a] Yaws and Yang [1992]
49
2
(dioxane) 1,3-dimethoxy-2-hydroxybe ben nzene C8 H10 O3 (2,6-dimethoxyphenol) [91-10-1] 1-hydroxy-2-methoxybenzene C7 H8 O2 (guaicol) [90-05-1] 4-methyl-2-methoxyphenol hydroxybutanedioic acid HOOCCH2 CHOHCOOH (malic acid)
1.4×102 2.0×10 1.4×102 4.9×103
6700
Sagebiel Sagebiel et al. [1992]
M M ? X
9.1×102
7500
Sagebiel Sagebiel et al. [1992]
X
3
7.2×102
7400
Sagebiel Sagebiel et al. [1992]
X
3
Saxena and Hildemann [1996]
E
51
2.0×1013
5800
39 3
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
2-hydroxy-1,2,3-propanetricarboxylic acid C6 H8 O7 (citric acid) [77-92-9] 2-oxopentanedioic acid HOOC(CH2 )2 COCOOH (α-keto glutaric acid) [328-50-7] 2-hydroxypropanoic acid CH3 CHOHCOOH (lactic acid) 2,3-dihydroxybutanedioic acid HOOCCHOHCHOHCOOH (tartaric acid) [87-69-4] 2,3-dihydroxypropanal C3 H6 O3
kH [M [M//atm] 3.0×1018
57
−d ln kH
d(1/T )
[K]
reference
type
note
Saxena and Hildemann [1996]
E
51
1.0×109
Saxena and Hildemann [1996]
E
51
7.0×107
Saxena and Hildemann [1996]
E
51
1.0×1018
Saxena and Hildemann [1996]
E
51
2.0×1010
Saxena and Hildemann [1996]
E
51
7.4×10−3 8.2×10−4 9.5×10−4 9.5×10−4 9.9×10−4 8.7×10−4 3.4×10−2 3.4×10−2 3.4×10−2 3.5×10−2 3.4×10−2 3.1×10−2 3.4×10−2 3.4×10−2 3.4×10−2 3.4×10−2 3.5×10−2 3.4×10−2 3.5×10−2 4.5×10−2 3.2×10−2 3.6×10−2
Meadows and Spedding [1974] Liss and Slater [1974] Wilhelm Wilhelm et al. [1977] Dean [1992] Lide and Frederikse rederikse [1995] Yaws and Yang [1992]
M c L ? L ? M X L L C T ? C C C L ? L ? X M
(glyceraldehyde) carbon monoxide CO
carbon dioxide CO2
1300 1600 1300 2400 2400 2400 2400
Morgan Morgan and Maass [1931] Sillen and Martell Martell [1964] Wilhelm Wilhelm et al. [1977] Edwar Edwards ds et al. [1978] Durham et al. [1981] 2400 Chameides [1984] 2400 Hoffmann and Jacob [1984] 2400 Jacob [1986] 2400 Pandis Pandis and Seinfeld Seinfeld [1989] 2400 Lelieveld and Crutzen [1991] 2300 Carroll Carroll et al. [1991] 2600 Dean [1992] 2400 Lide and Frederikse rederikse [1995] Yaws and Yang [1992] 2400 Kavanaugh and Trussell [1980] 2200 Zheng Zheng et al. [1997]
2 39 1
4
2 39 3
58
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
kH [M [M//atm]
−d ln kH
d(1/T )
[K]
reference
type
note
compounds with nitrogen: amines (RNH2 ) (C, H, O, and N only) methylamine CH3 NH2
3.6×101 9.0×101 1.4×102 1.0×102
ethylamine
2600
Wilhe Wilhelm lm et al. [1977] Christie and Crisp [1967] Bone et al. [1983]
Butler and Ramchandani [1935]
L M ? M
12
1
3.5×10 8.1×101 8.0×101 6.7×101
6.6×101 5.8×101
Butler and Ramchandani [1935] Christie and Crisp [1967]
M M
4.1×101
Christie and Crisp [1967]
M
hexylamine C6 H13 NH2
3.7×101
Christie and Crisp [1967]
M
dimethylamine (CH3 )2 NH [124-40-3] diethylamine (C2 H5 )2 NH [109-89-7]
3.1×101 5.7×101
Wilhe Wilhelm lm et al. [1977] Christie and Crisp [1967]
L M
Christie and Crisp [1967] Yaws and Yang [1992] USEPA [1982] Meylan and Howard [1991]
see note
M ? X X M ?
Christie and Crisp [1967]
M
C2 H5 NH2 [75-04-7] propylamine C3 H7 NH2 [107-10-8] butylamine C4 H9 NH2 [109-73-9] pentylamine C5 H11 NH2
dipropylamine (C3 H7 )2 NH
3.9×101 1.5×101 1.3×102 3.9×101 1.9×101 see note
3600
4000
Wilhe Wilhelm lm et al. [1977] Christie and Crisp [1967]
Butler and Ramchandani [1935] Christie and Crisp [1967]
L M M M
10000
Christie and Crisp [1967]
dibutylamine (C4 H9 )2 NH
1.1×101
trimethylamine (CH3 )3 N [75-50-3] triethylamine (C2 H5 )3 N
9.6
Chris Christie tie and Crisp [1967]
M
6.7
Chris Christie tie and Crisp [1967]
M
ethylenediamine H2 NCH2 CH2 NH2
5.9×105
Westheimer and Ingraham [1956]
M
hexamethyleneimine (CH2 )6 NH
1.6×102
Cabani Cabani et al. [1971b]
M
ethanolamine HOC2 H4 NH2 [141-43-5]
6.2×106
Bone et al. [1983]
M
8200
39 3 3 66
8
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
kH [M [M//atm]
59
−d ln kH
d(1/T )
[K]
reference
type
note
compounds with nitrogen: amino acids (RCHNH2 COOH) glutamic acid
1.0×1013
Saxena and Hildemann [1996]
E
51
asparagine
1.0×1013
Saxena and Hildemann [1996]
E
51
serine
4.0×10
Saxena and Hildemann [1996]
E
51
glutamine
1.0×1013
Saxena and Hildemann [1996]
E
51
glycine
9.0×107
Saxena and Hildemann [1996]
E
51
arginine
1.0×1017
Saxena and Hildemann [1996]
E
51
alanine
6.0×107
Saxena and Hildemann [1996]
E
51
leucine
2.0×107
Saxena and Hildemann [1996]
E
51
12
compounds with nitrogen: heterocycles (C, H, O, and N only) pyrrolidine C4 H8 NH
4.2×102
7600
Cabani Cabani et al. [1971b]
M
N-methyl-pyrrolidine C4 H8 NCH3
3.3×101
7600
Cabani Cabani et al. [1971b]
M
piperidine C5 H10NH
2.2×102
7900
Cabani Cabani et al. [1971b]
M
N-methyl-piperidine C5 H10NCH3
2.9×101
7900
Cabani Cabani et al. [1971b]
M
pyridine C5 H5 N
1.1×102 9.0×101
5900
Andon Andon et al. [1954] Yaws and Yang [1992]
M ? ? M
39
Yaws and Yang [1992] Andon Andon et al. [1954]
? M
39
[110-86-1] 2-methylpyridine C5 H4 NCH3 (2-picoline, α-picoline) (2-picoline, [109-06-8] 3-methylpyridine C5 H4 NCH3 (3-picoline, β -picoline) (3-picoline, -picoline) [108-99-6] 4-methylpyridine C5 H4 NCH3 2-ethylpyridine C5 H4 NC2 H5
3.4×101 1.0×102
5.5×101 1.3×102
6400
Yaws and Yang [1992] Andon Andon et al. [1954]
1.7×102
6600
Andon Andon et al. [1954]
M
6.1×101
6700
Andon Andon et al. [1954]
M
6400
39
60
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
kH [M [M//atm] 9.6×101
3-ethylpyridine C5 H4 NC2 H5
−d ln kH
d(1/T )
reference
type
[K] 6500
Andon Andon et al. [1954]
M
note
4-ethylpyridine C5 H4 NC2 H5
1.2×102
6300
Andon Andon et al. [1954]
M
2,3-dimethylpyridine C5 H3 N(CH3 )2 [583-61-9] 2,4-dimethylpyridine C5 H3 N(CH3 )2
1.4×102
700
Andon Andon et al. [1954]
M
1.5×102
7100
Andon Andon et al. [1954]
M
2,5-dimethylpyridine C5 H3 N(CH3 )2
1.2×102
7100
Andon Andon et al. [1954]
M
2,6-dimethylpyridine C5 H3 N(CH3 )2
9.5×101
7300
Andon Andon et al. [1954]
M
3,4-dimethylpyridine C5 H3 N(CH3 )2
2.7×102
6900
Andon Andon et al. [1954]
M
3,5-dimethylpyridine C5 H3 N(CH3 )2
1.4×102
6800
Andon Andon et al. [1954]
M
2-methylpyrazine C4 N2 H3 CH3
4.5×102
Buttery et al. [1971]
M
2-ethylpyrazine C4 N2 H3 (C2 H5 )
4.0×102
Buttery et al. [1971]
M
2-isobutylpyrazine C4 N2 H3 C4 H9
2.0×102
Buttery et al. [1971]
M
2-ethyl-3-methoxypyrazine C4 N2 H3 (C2 H5 )OCH3
6.8×101
Buttery et al. [1971]
M
2-isobutyl-3-methoxypyrazine C4 N2 H3 (C4 H9 )OCH3
2.0×101 1.3×101
Buttery et al. [1971] Karl and Lindinger [1997]
M M
43
USEPA [1982]
X
3
benzo[b]pyridine C9 H7 N (quinoline) [91-22-5]
3.7×103
5400
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
kH [M [M//atm]
61
−d ln kH
d(1/T )
[K]
reference
type
note
compoundss with nitro compound nitrogen: gen: nitra nitrates tes (RONO2 ) (C, H, O, and N only) methyl nitrate CH3 ONO2
2.0
4700
Kames and Schurath Schurath [1992]
M
ethyl nitrate
1.6
5400
Kames and Schurath Schurath [1992]
M
1.1 1.1 7.9×10−1 7.9×10−1 6.2×10−1 8.3×10−1 1.0 1.0 6.5×10−1 8.6×10−1 6.5×10−1 6.5×10−1 4.4×10−1 6.5×10−1 7.0×10−1
5500
Kames and Schurath Schurath [1992] Hauff et al. [1998] Hauff et al. [1998]
Kames and Schurath Schurath [1992] Hauff et al. [1998] Hauff et al. [1998]
Kames and Schurath Schurath [1992]
M V M M M V M M M V M M M V M
Kames and Schurath Schurath [1992] Hauff et al. [1998] Hauff et al. [1998]
M V M
Kames and Schurath Schurath [1992] Hauff et al. [1998] Hauff et al. [1998] Hauff et al. [1998]
M M V M
4.9×10
Hauff et al. [1998]
V
4.5×10−1
Hauff et al. [1998]
M
3.7×10−1 6.7×10−1
Hauff et al. [1998] Hauff et al. [1998]
V M
C2 H5 ONO2 1-propyl nitrate C3 H7 ONO2 [627-13-4] 2-propyl nitrate C3 H7 ONO2 1-butyl nitrate C4 H9 ONO2 [928-45-0] 2-butyl nitrate C4 H9 ONO2 (isobutyl nitrate) [543-29-3] tert -butyl nitrate C4 H9 ONO2 1-pentyl nitrate C5 H11ONO2 (amyl nitrate) [1002-16-0] 2-pentyl nitrate C5 H11ONO2 [21981-48-6] 3-pentyl nitrate
1.2 4.1×10−1 6.0×10−1 3.7×10−1 3.4×10−1 4.9×10−1 3.7×10−1
5400
6000 5800
5600 5400
Luke et al. [1989] Kames and Schurath Schurath [1992] Hauff et al. [1998] Hauff et al. [1998] Luke et al. [1989] Kames and Schurath Schurath [1992] Hauff et al. [1998] Hauff et al. [1998]
5200
6300
−1
C5 H13ONO2
3-methyl-1-butanol nitrate C5 H11ONO2 (isoamyl nitrate) [543-87-3] 1-hexyl nitrate C6 H13ONO2
8
62
substance 2-nitrooxy ethanol HOC2 H4 ONO2 nitrooxy propanol C3 H7 O4 N
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
kH [M [M//atm] 4.0×104 3.9×104
−d ln kH
d(1/T )
[K] 8600
7.3×103 6.7×103
reference
type
note
Kames and Schurath [1992] Shepson Shepson et al. [1996]
M M
8
Kames and Schurath [1992] Kames and Schurath [1992]
M M
8, 72 8, 72
(1,2 and 2,1) 1-nitrooxy-2-propanol C3 H7 O4 N
1.1×104
10000
Shepson Shepson et al. [1996]
M
2-nitrooxy-1-propanol C3 H7 O4 N
4.5×103
8800
Shepson Shepson et al. [1996]
M
2-nitrooxy-3-butanol C4 H9 O4 N
1.0×104
9500
Shepson Shepson et al. [1996]
M
1-nitrooxy-2-butanol C4 H9 O4 N
5.8×103
9200
Shepson Shepson et al. [1996]
M
2-nitrooxy-1-butanol C4 H9 O4 N
6.0×103
9600
Shepson Shepson et al. [1996]
M
nitrooxyacetone CH3 COCH2 ONO2
1.0×103
Kames and Schurath [1992]
M
8
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
1,2-ethanediol dinitrate O3 NCH2 CH2 ONO2 (1,2-ethane dinitrate) [628-96-6] 1,2-propanediol dinitrate
kH [M [M//atm] 6.4×102 7.9×101
63
−d ln kH
d(1/T )
[K]
reference
type
note
Kames and Schurath [1992] Fischer and Ballschmiter [1998b]
M M
8 73
Kames and Schurath [1992]
M
8
3.2×10
Fischer and Ballschmiter [1998b]
M
73
1,3-propanediol dinitrate C3 H6 N2 O6 [3457-90-7] 1,2-butanediol dinitrate
1.3×102
Fischer and Ballschmiter [1998b]
M
73
2.1×101
Fischer and Ballschmiter [1998b]
M
73
1,3-butanediol dinitrate
5.8×101
Fischer and Ballschmiter [1998b]
M
73
1,4-butanediol dinitrate
1.6×102
Fischer and Ballschmiter [1998b]
M
73
2,3-butanediol dinitrate
1.2×101
Fischer and Ballschmiter [1998b]
M
73
1,2-pentanediol dinitrate
1.3×101
Fischer and Ballschmiter [1998b]
M
73
1,4-pentanediol dinitrate
3.9×101
Fischer and Ballschmiter [1998b]
M
73
1,5-pentanediol dinitrate
1.2×102
Fischer and Ballschmiter [1998b]
M
73
c-2,4-pentanediol dinitrate
2.2×101
Fischer and Ballschmiter [1998b]
M
73
t-2,4-pentanediol dinitrate
1.5×101
Fischer and Ballschmiter [1998b]
M
73
1,2-hexanediol dinitrate
9.7×100
Fischer and Ballschmiter [1998b]
M
73
1,5-hexanediol dinitrate
2.8×101
Fischer and Ballschmiter [1998b]
M
73
1,6-hexanediol dinitrate
1.5×102
Fischer and Ballschmiter [1998b]
M
73
2,5-hexanediol dinitrate
3.2×101
Fischer and Ballschmiter [1998b]
M
73
1.8×102 1
C3 H6 (ONO2 )2 (1,2-propane dinitrate) [6423-43-4] 1,2-propanediol dinitrate
64
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
cis -1,2-cyclohexanediol dinitrate
kH [M [M//atm] 1.3×102
trans -1,2 - 1,2-c -cyc yclo loh hexan exaneediol diol dini dinittra rate te
substance
−d ln kH
d(1/T )
[K]
reference
type
note
Fischer and Ballschmiter [1998b]
M
73
5. 5.22×101
Fischer and Ballschmiter [1998b]
M
73
cis -1,3-cyclohexanediol dinitrate
3.5×102
Fischer and Ballschmiter [1998b]
M
73
trans -1,3 - 1,3-c -cyc yclo loh hexan exaneediol diol dini dinittra rate te
6. 6.99×101
Fischer and Ballschmiter [1998b]
M
73
1,7-heptanediol dinitrate
1.2×102
Fischer and Ballschmiter [1998b]
M
73
trans --1,2 1,2-c -cyc yclo lohe hept ptan aned edio ioll dini dinitr trat atee
8. 8.99×101
Fischer and Ballschmiter [1998b]
M
73
1,2-octanediol dinitrate
5.3×100
Fischer and Ballschmiter [1998b]
M
73
1,8-octanediol dinitrate
7.9×101
Fischer and Ballschmiter [1998b]
M
73
1,2-decanediol dinitrate
2.0×100
Fischer and Ballschmiter [1998b]
M
73
1,10-decanediol dinitrate
4.3×101
Fischer and Ballschmiter [1998b]
M
73
peroxyacetyl nitrate CH3 COOONO2 (PAN)
3.6 5.0 2.9 2.8 4.1 see note see note 2.9 see note see note
Kames and Schurath Schurath [1995] Warnec Warneckk et al. [1996] Schurath Schurath et al. [1996]
X M C M M ? ? M ? ?
48 74
Gaffney Gaffney and Senum Senum [1984] Holdren Holdren et al. [1984] Pandis Pandis and Seinfeld Seinfeld [1989] Kames Kames et al. [1991] Kames and Schurath Schurath [1995] Warnec Warneckk et al. [1996] Schurath Schurath et al. [1996]
8 75 76 8 75 76
Kames and Schurath Schurath [1995]
M
8
Warnec Warneckk et al. [1996] Schurath Schurath et al. [1996]
? ?
75 76
Kames and Schurath Schurath [1995] Warnec Warneckk et al. [1996] Schurath Schurath et al. [1996]
M ? ?
8 75 76
Kames and Schurath Schurath [1995] Warnec Warneckk et al. [1996] Schurath Schurath et al. [1996]
M ? ?
8 75 76
peroxypropionyl nitrate C2 H5 COOONO2 (PPN)
peroxy-n-butyryl nitrate C3 H7 COOONO2 (PnBN)
2.3
5900 6500
see note see note
peroxy-2-propenoyl nitrate CH2 C(CH3 )COOONO2 (pero (pe roxy xyme meth thac acry rylo loyl yl ni nitr trat ate, e, MPAN MPAN))
1.7 see note se seee no note te
peroxy-isobutyryl nitrate C3 H7 COOONO2 (PiBN)
1.0 see note see note
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
kH [M [M//atm]
65
−d ln kH
d(1/T )
[K]
reference
type
note
compounds with nitrogen: nitriles (RCN) (C, H, O, and N only) cyanide radical CN
8.0×10−2
1400
hydrocyanic acid
9.3
Berd Berdnikov nikov and Bazhin [1970]
T
5
Hine and Weimar Weimar [1965]
R
Edward Edwardss et al. [1978] Gaffney and Senum [1984]
Butler and Ramchandani [1935]
L X R X M M L M ? M
Butler and Ramchandani [1935]
M
Yaws and Yang [1992]
?
39, 77
Yaws and Yang [1992]
?
39, 8
USEPA [1982] Meylan and Howard Howard [1991]
X X
3 3
1
HCN ethane nitrile CH3 CN (acetonitrile) [75-05-8]
propane nitrile C2 H5 CN (propionitrile) [107-12-0] butane nitrile C3 H7 CN (butyronitrile) benzenenitrile C6 H5 CN (benzonitrile) [100-47-0] ethanedinitrile C2 N2 (cyanogen) [460-19-5] 2-propenenitrile C3 H3 N (acrylonitrile) [107-13-1]
1.2×10 7.5 2.9×101 2.9×101 5.4×101 4.9×101 4.8×101 5.3×101 4.9×101 2.7×101
5000
4100 4000 3500 4100
1.9×101
1.8
1.9×10−1
1.1×101 7.3
2800
Hine and Weimar [1965] Gaffney and Senum [1984] Hamm Hamm et al. [1984] Snide Sniderr and Dawson Dawson [1985] Arijs and Brasseur Brasseur [1986] Benkelberg Benkelberg et al. [1995] Yaws and Yang [1992]
48 48
39
66
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
kH [M [M//atm]
substance
−d ln kH
d(1/T )
[K]
reference
type
note
compoundss with nitrogen: nitro (RNO2 ) (C, H, O, and N only) compound nitromethane CH3 NO2
3.5×101 4.5×101 3.6 2.1×101
nitroethane
Gaffney and Senum [1984] Rohrschneider [1973] Yaws and Yang [1992] Hine and Mookerjee [1975]
X M ? V
48 39
1
C2 H5 NO2 1-nitropropane C3 H7 NO2
2.1×10 1.4×102 1.2×101 1.6×101
2-nitropropane CH3 CH(NO2 )CH3
8.2 1.1×101
Gaffney and Senum [1984] Friant and Suffet [1979] Hine and Mookerjee [1975] Yaws and Yang [1992]
X M V ?
Hine and Mookerjee Mookerjee [1975] Yaws and Yang [1992]
V ?
4500
Hine and Mookerjee [1975] Meylan and Howard [1991] USEPA [1982]
2900
Hine and Mookerjee [1975] USEPA [1982]
V X X V X
Hine and Mookerjee [1975] USEPA [1982]
V X
3
48 49 39, 8
39, 8
4.3×101 4.1×101 4.7×101 1.7×101 7.8
1.4×101 1.4×101
3200
4-nitrotoluene C6 H4 (NO2 )CH3
1.6×101
3100
USEPA [1982]
X
3
1-methyl-2,4-dinitrobenzene C7 H6 N2 O4 (DNT) [121-14-2]
2.1×101
2900
USEPA [1982]
X
3
nitrobenzene C6 H5 NO2 [98-95-3] 2-nitrotoluene C6 H4 (NO2 )CH3 [88-72-2] 3-nitrotoluene C6 H4 (NO2 )CH3
3 3 3
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
2-nitrophenol HOC6 H4 (NO2 ) [88-75-5] 3-nitrophenol HOC6 H4 (NO2 ) 4-nitrophenol HOC6 H4 (NO2 ) [100-02-7] 3-methyl-2-nitrophenol C7 H7 NO3 [4920-77-8] 4-methyl-2-nitrophenol C7 H7 NO3 [119-33-5] 5-methyl-2-nitrophenol C7 H7 NO3 [700-38-9] 4-(1-methylpropyl)-2 -2--nitrophenol C10 H13 NO3 [3555-18-8] 4-methoxy-2-nitrophenol C7 H7 NO4 [1568-70-3] 4-hydroxy-3-nitro-ben benzaldehyde C7 H5 NO4 [3011-34-5] 2,4-dinitrophenol C6 H4 N2 O5 [51-28-5] 2,5-dinitrophenol C6 H4 N2 O5 [329-71-5] 2-methyl-4,6-dinitrophenol C7 H6 N2 O5 (dinitro-o-cresol,DNOC) [534-52-1]
kH [M [M//atm] 7.0×101 7.4×101 7.9×101 5.0×105
67
−d ln kH
d(1/T )
type
note
X V X X
3 8 55,8 48
Schwarzenbach et al. [1988]
M X V X V
54 3 8 55,8 8
6.2×101
Schwarzenbach et al. [1988]
V
8
6.8×101
Schwarzenbach et al. [1988]
V
8
2.4×101
Schwarzenbach et al. [1988]
V
8
2.3×101
Schwarzenbach et al. [1988]
V
8
9.5×102
Schwarzenbach et al. [1988]
V
8
3.5×103 1.2×104
Schwarzenbach et al. [1988] Tremp et al. [1993]
V X
8 55,8
1.5×103
Schwarzenbach et al. [1988]
V
8
2.3×103 4.6×103
Schwarzenbach et al. [1988] Tremp et al. [1993]
V X
8 55,8
2.6×106 9.9×102 3.0×104 7.9×104 2.5×102
[K] 4600
reference
USEPA [1982] Schwarzenbach et al. [1988] Tremp et al. [1993] Gaffney and Senum [1984]
9100 6000
Parsons Parsons et al. [1971] USEPA [1982] Schwarzenbach et al. [1988] Tremp et al. [1993]
68
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
kH [M [M//atm]
−d ln kH
d(1/T )
[K]
reference
type
note
compounds with fluorine 5.9×10−2 5.9×10−2 5.2×10−2 7.2×10−2
fluoromethane CH3 F
2200
Hine and Mookerjee [1975] Wilhelm Wilhelm et al. [1977] Mackay and Shiu [1981] Yaws and Yang [1992]
V L L ?
39, 38
Yaws and Yang [1992]
?
39
Hine and Mookerjee [1975] Wilhelm Wilhelm et al. [1977] Yaws and Yang [1992] Zheng Zheng et al. [1997]
Yaws and Yang [1992]
V L ? M V M L ? ?
V ? M
Zheng Zheng et al. [1997]
M
−2
difluoromethane CH2 F2
8.7×10
trifluoromethane CHF3 (R23)
1.1×10−2 1.3×10−2 1.3×10−2 1.4×10−2 2.0×10−4 2.0×10−4 2.1×10−4 1.9×10−4 4.4×10−2
tetrafluoromethane CF4 (carbontetrafluoride)
fluoroethane C2 H5 F
3200 2200
Hine and Mookerjee [1975] 1500 Morrison and Johnstone [1954] 1800 Wilhelm Wilhelm et al. [1977] Yaws and Yang [1992]
39
39 39
4.9×10−2 3.7×10−2 5.4×10−2
2600
Hine and Mookerjee [1975] Yaws and Yang [1992] Zheng Zheng et al. [1997]
1,1,1,2-tetrafluoroethane C2 H2 F4 (R134a)
1.8×10−2
2700
hexafluoroethane C2 F6
5.9×10−5
Yaws and Yang [1992]
?
39
1-fluoropropane C3 H7 F
6.2×10−2
Yaws and Yang [1992]
?
39, 79
2-fluoropropane C3 H7 F
5.9×10−2
Yaws and Yang [1992]
?
39, 38
octafluorocyclobutane C4 F8
2.5×10−4
Yaws and Yang [1992]
?
39
1,1-difluoroethene C2 H2 F2
2.5×10−3
Yaws and Yang [1992]
?
39
tetrafluoroethene C2 F4
1.6×10−3 1.6×10−3
2100
Wilhelm Wilhelm et al. [1977] Yaws and Yang [1992]
L ?
39
2.9×10−4
2400
Wilhelm Wilhelm et al. [1977]
L
1,1-difluoroethane C2 H4 F2 (R152a)
hexafluoropropene C3 F6
39, 78
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance carbonyl fluoride COF2
kH [M [M//atm] 2.0×101 3.5×101
69
−d ln kH
d(1/T )
[K]
reference
type
Kanakidou et al. [1995] Mirabel et al. [1996]
C M
Kanakidou Kanakidou et al. [1995]
E
formyl fluoride FCHO
3.0
2,2,2-trifluoroethanol CF3 CH2 OH
5.9×101
5900 Ro Rochester chester and Symonds [1973]
M
1,1,1-trifluoro-2-propanol CF3 CHOHCH3
4.5×101
6300 Ro Rochester chester and Symonds [1973]
M
2,2,3,3-tetrafluoro-1-propanol CHF2 CF2 CH2 OH
1.6×102
6700 Ro Rochester chester and Symonds [1973]
M
2,2,3,3,3-pe pen ntafluoro-1-propanol CF3 CF2 CH2 OH
4.5×101
6000 Ro Rochester chester and Symonds [1973]
M
1,1,1,3,3,3-hexafluoro-2-propanol CF3 CHOHCF3
2.4×101
6700 Ro Rochester chester and Symonds [1973]
M
trifluoroacetylfluoride CF3 COF
3.0 3.0
Kanakidou Kanakidou et al. [1995] Mirabel Mirabel et al. [1996]
C M
1,1,1-trifluoro-2-propanone CF3 COCH3
1.4×102
Betterton [1991]
M
fluoroethanoic acid CH2 FCOOH (fluoroacetic acid) [144-49-0] difluoroethanoic acid
8.1×104
Bowden et al. [1998b]
M
Bowden Bowden et al. [1998b]
M
Bowden Bowden et al. [1996]
M
Kanakidou et al. [1995]
E
CHF2 COOH (difluoroacetic acid) [381-73-7] trifluoroethanoic acid CF3 COOH (trifluoroacetic acid) [76-05-1] generic peroxide with fluorine ROOH
8900
3.0×104
6900
8.9×103
9300
3.0×101
note
80
70
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance fluorobenzene C6 H5 F
1,2-difluorobenzene
kH [M [M//atm] 1.6×10−1 1.2×10−1 1.6×10−1 1.6×10−1 1.4×10−1
−d ln kH
d(1/T )
[K]
4100
reference
Mackay and Shiu [1981] Hoff et al. [1993] Hartkopf and Karger Karger [1973] Yaws and Yang [1992]
type
Yaws and Yang [1992]
L ? M ? ?
note 13 39 39
C6 H4 F2 (o-difluorobenzene) 1,3-difluorobenzene C6 H4 F2 (m-difluorobenzene)
1.3×10−2
Yaws and Yang [1992]
?
39
1,4-difluorobenzene C6 H4 F2 (p-difluorobenzene)
1.3×10−1
Yaws and Yang [1992]
?
39
(trifluoromethyl)-benzene C6 H5 CF3 (α,α,α-trifluorotoluene)
6.3×10−2 6.2×10−2
Mackay and Shiu [1981] Yaws and Yang [1992]
L ?
39
5-fluoro-2-nitrophenol C6 H4 FNO3 [446-36-6]
5.9×102
Schwarzenbach et al. [1988]
V
8
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
kH [M [M//atm]
71
−d ln kH
d(1/T )
[K]
reference
type
note
M V L L
81,8
aliphatic compounds with chlorine 1.3×10−1 1.0×10−1 1.0×10−1 1.1×10−1
chloromethane CH3 Cl (methylchloride)
Pearson and McConnell [1975] Hine and Mookerjee [1975] Wilhelm Wilhelm et al. [1977] Mackay and Shiu [1981]
2800
−1
dichloromethane CH2 Cl2 [75-09-2]
1.2×10 9.4×10−2 1.1×10−1 1.2×10−1 1.2×10−1 2.9×10−2 1.0×10−1 3.3×10−1 4.4×10−1 3.9×10−1 3.5×10−1 4.7×10−1 4.0×10−1 4.0×10−1 1.2 3.7×10−1 4.1×10−1 4.4×10−1 4.0×10−1 3.1×10−1 3.6×10−1 8.6×10−1 3.1×10−1 3.4×10−1 3.5×10−1 3.8×10−1 3.9×10−1
Gossett [1987] Moore Moore et al. [1995] Dilling [1977] Dilling [1977] Yaws and Yang [1992] -630 USEPA [1982] 2900 Kavanaugh and Trussell [1980]
4200 3000
Pearson and McConnell [1975] Hine and Mookerjee [1975] Mackay and Shiu [1981] Lincoff and Gossett [1984] Gossett [1987] Wright Wright et al. [1992b] Dilling [1977]
4200 3800 3800
Dilling [1977] Dilling [1977] Hoff et al. [1993] 4100 Hartkopf and Karger Karger [1973] Yaws and Yang [1992] 3600 USEPA [1982] 4100 Staudinger and Roberts Roberts [1996] 4200 Kavanaugh and Trussell [1980] 3700 Leighton Leighton and Calo [1981] 4300 Ashworth Ashworth et al. [1988] 4200 Gossett Gossett et al. [1985] 3500 Tse et al. [1992] 4500 Gossett Gossett et al. [1985]
M M V V ? X X M V L M M M V V C M M ? X L X X X X X X
8 39 3 3 81,8
82
39 3 3 3 3 3 3 3
−1
4.0×10
3900
Wright Wright et al. [1992a]
X
3
72
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance trichloromethane CHCl3 (chloroform) [67-66-3]
kH [M [M//atm] 3.5×10−1 2.3×10−1 2.7×10−1 2.0×10−1 3.3×10−1
−d ln kH
d(1/T )
type
note
Pearson and McConnell [1975] Hine and Mookerjee [1975] Mackay and Shiu [1981] Hunt Hunter-Sm er-Smith ith et al. [1983] Nicholson et al. [1984]
M V L M M
81,8
2.8×10−1 3.2×10 2.1×10−1 2.4×10−1 2.8×10−1 4.9×10−1 2.6×10−1 2.7×10−1 2.3×10−1 2.5×10−1 9.1×10−1 3.1×10−1 2.5×10−1 2.9×10−1
Nicholson et al. [1984] Nicholson et al. [1984] Nicholson et al. [1984] 4200 Lincoff and Gossett [1984] 4600 Gossett [1987] 7300 Tancr`ede ede and Yanagisawa Yanagisa wa [1990] 3900 Wright Wright et al. [1992b] 4100 Dewu Dewulf lf et al. [1995] 3800 Moore Moore et al. [1995] Dilling [1977] Dilling [1977] Dilling [1977] Hoff et al. [1993] 4800 Hartkopf and Karger Karger [1973]
C C C M M M M M M V V C M M
2.4×10−1 2.5×10−1 2.5×10−1 2.6×10−1 3.0×10−1 1.5×10−1 2.3×10−1 2.3×10−1 2.4×10−1 2.5×10−1 2.5×10−1 2.5×10−1 2.6×10−1
Yaws and Yang [1992] Barr and Newsham Newsham [1987] Kavanaugh and Trussell [1980] Wrigh Wrightt et al. [1992a] USEPA [1982] Ervin et al. [1980] Gossett Gossett et al. [1985] Ashworth Ashworth et al. [1988] Lam Lamarche arche and Droste Droste [1989] Leighton Leighton and Calo [1981] Gossett Gossett et al. [1985] Staudinger and Roberts Roberts [1996] Munz and Roberts Roberts [1987]
? X X X X X X X X X X L X
[K]
3900
reference
83
−1
4100 4600 4000 4400 5600 4200 5000 2200 4100 4300 4500 4300
82
39 3 3 3 3 3 3 3 3 3 3 3
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance tetrachloromethane CCl4 (carbontetrachloride) [56-23-5]
kH [M [M//atm] 3.8×10−2 4.5×10−2 3.5×10−2 5.1×10−2 4.2×10−2
73
−d ln kH
d(1/T )
[K]
reference
type
Liss and Slater [1974] Pearson and McConnell [1975] Hine and Mookerjee [1975] Mackay and Shiu [1981] Hunter-Sm Hunter-Smith ith et al. [1983]
C M V L M
3.3×10 3.5×10−2 3.0×10−2 3.8×10−2 3.4×10−2 3.4×10−2 4.7×10−2 3.6×10−2 3.9×10−2 3.4×10−2 3.1×10−2 3.3×10−2 3.3×10−2 3.8×10−2
Gossett [1987] 4400 4100 Tancr`ede ede and Yanagisawa Yanagis awa [1990] 4200 Wright Wright et al. [1992b] 4100 Dewulf Dewulf et al. [1995] 3600 Hansen Hansen et al. [1995] Dilling [1977] Dilling [1977] Hoff et al. [1993] 4900 Hartkopf and Karger Karger [1973] Yaws and Yang [1992] 4200 Wright Wright et al. [1992a] 1100 USEPA [1982] 4700 Kavanaugh and Trussell [1980] 3600 Tse et al. [1992]
M M M M M V C M M ? X X X X
2.8×10−2 3.2×10−2 3.3×10−2 3.3×10−2 3.4×10−2 3.6×10−2 1.2×10−1 5.1×10−1 8.9×10−2 8.9×10−2 1.4×10−1 6.9×10−2 8.5×10−2
5600 3400 4000 4300 4200 4400
3200
note 81,8
−2
chloroethane C2 H5 Cl [75-00-3]
Bissonette Bissonette et al. [1990] Hansen Hansen et al. [1993] Ashw Ashworth orth et al. [1988] Munz and Roberts Roberts [1987] Staudinger and Roberts Roberts [1996] Leighto Leighton n and Calo [1981]
X X X X L X V L M V ? X L
3 3 3 3
Ashw Ashworth orth et al. [1988] Hine and Mookerjee [1975] Mackay and Shiu [1981] Gossett [1987] Wright Wright et al. [1992b] Dewulf Dewulf et al. [1995] Dilling [1977] Yaws and Yang [1992] Wright Wright et al. [1992a] Barr and Newsham Newsham [1987] USEPA [1982] Tse et al. [1992] Kavanaugh and Trussell [1980] Ervin et al. [1980]
X V L M M M V ? X X X X X X
3
Ashw Ashworth orth et al. [1988] Staudinger and Roberts Roberts [1996] Lamarche Lamarche and Droste Droste [1989]
X L X
3
Hine and Mookerjee [1975] Mackay and Shiu [1981] Gossett [1987] Dilling [1977] Yaws and Yang [1992] USEPA [1982] Staudinger and Roberts Roberts [1996]
3100
750 2900
39 3 3 3 3
3
39, 8 3
−2
1,1-dichloroethane CHCl2 CH3 [75-34-3]
8.1×10−1 1.7×10 1.7×10−1 1.8×10−1 1.7×10−1 2.0×10−1 1.7×10−1 1.7×10−1 1.6×10−1 1.7×10−1 1.8×10−1 1.8×10−1 1.8×10−1 1.3×10−1
2600
1.5×10−1 1.6×10−1 1.7×10−1
3100 3600 2100
4100 3600 4000
3600 3800 1700 3300 4400 4900
39 3 3 3 3 3 3
3
74
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance 1,2-dichloroethane CH2 ClCH2 Cl [107-06-2]
kH [M [M//atm] 1.1 7.6×10−1 9.2×10−1 8.7×10−1 9.5×10−1
−d ln kH
d(1/T )
type
note
Pearson Pearson and McConnell [1975] Hine and Mookerjee [1975] Mackay and Shiu [1981] Wright Wright et al. [1992b] Dewulf Dewulf et al. [1995]
M V L M M
81,8
Dilling [1977] Dilling [1977] Hoff et al. [1993] Hartkopf and Karger Karger [1973] Yaws and Yang [1992] Tse et al. [1992] Wright Wright et al. [1992a] Barr and Newsham [1987] USEPA [1982] Ashworth Ashworth et al. [1988] Bissonette Bissonette et al. [1990] Lamarche Lamarche and Droste [1989] Staudinger and Ro Roberts berts [1996] Leighton and Calo [1981] Pearson and McConnell [1975] Hine and Mookerjee [1975] Mackay and Shiu [1981] Hunter-Sm Hunter-Smith ith et al. [1983] Linco Lincoff ff and Gossett [1984] Gossett [1987] Kolb et al. [1992] Wright Wright et al. [1992b] Robbins obbins et al. [1993] Kana Kanakidou kidou et al. [1995] Dewulf Dewulf et al. [1995] Hansen Hansen et al. [1995] Dilling [1977]
V C M M ? X X X X X X X L X M V L M M M X M M C M M V
4.0×10−1 1.1×10 5.4×10−2 1.1×10−1 2.2×10−1 5.9×10−2 5.9×10−2 6.4×10−2 2.7×10−2 5.1×10−2 5.2×10−2 5.8×10−2 5.9×10−2 5.9×10−2
Dilling [1977] Dilling [1977] Hoff et al. [1993] 4600 Kavanaugh and Trussell [1980] 1700 USEPA [1982] 3400 Wright Wright et al. [1992a] 4000 Barr and Newsham [1987] 3700 Tse et al. [1992] 7000 Ervin et al. [1980] 4400 Leighton and Calo [1981] 5200 Bissonette Bissonette et al. [1990] 3400 Ashworth Ashworth et al. [1988] 3900 Staudinger and Ro Roberts berts [1996] 4200 Gossett Gossett et al. [1985]
V V M X X X X X X X X X L X
8 82
6.0×10−2 6.0×10−2 6.0×10−2
3200 4100 4300
X X X
3 3 3
[K]
3900 4300
reference
−1
1,1,1-trichloroethane CH3 CCl3 (methylchloroform, MCF) [71-55-6]
8.2×10 1.0 8.4×10−1 8.4×10−1 8.5×10−1 8.3×10−1 8.6×10−1 8.7×10−1 9.1×10−1 6.5×10−1 6.5×10−1 7.0×10−1 7.3×10−1 8.5×10−1 2.9×10−2 6.2×10−2 3.6×10−2 7.7×10−2 5.9×10−2 5.9×10−2 8.7×10−2 6.1×10−2 5.7×10−2 7.1×10−2 6.8×10−2 6.0×10−2 3.4×10−2
4100 3800 3900 3700 2400 1500 4500 4700 4200 3500
3200 4300 4100 3500 3200 4700 3800 3100
39 3 3 3 3 3 3 3 3 81,8
45
−2
Hansen Hansen et al. [1993] Munz and Ro Roberts berts [1987] Gossett Gossett et al. [1985]
3 3 3 3 3 3 3 3 3 3
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance 1,1,2-trichloroethane CHCl2 CH2 Cl [79-00-5]
1,1,1,2-tetrachloroethane CCl3 CH2 Cl [630-20-6]
1,1,2,2-tetrachloroethane CHCl2 CHCl2 [79-34-5]
pentachloroethane
kH [M [M//atm] 1.1 8.4×10−1 1.2 1.3 1.1
1.0 1.2 1.2 1.2 1.2 1.0 1.1 1.2 1.3 2.2 3.6×10−1 4.0×10−1 3.7×10−1 3.4×10−1 4.5×10−1 2.1 2.0 2.1 3.0 1.8 1.9 2.2 2.3 2.4 2.4 2.8 4.1×10−1
75
−d ln kH
d(1/T )
[K]
reference
type
Hine and Mookerjee Mookerjee [1975] Mackay and Shiu [1981] Wrigh Wrightt et al. [1992b] Hansen Hansen et al. [1995] Dilling [1977]
V L M M V
Yaws and Yang [1992] 2700 USEPA [1982] 3800 Wright Wright et al. [1992a] 4000 Tse et al. [1992] 4300 Barr and Newsham [1987] 4800 Ashworth Ashworth et al. [1988] 4900 Staudinger and Ro Roberts berts [1996] 3700 Leighton and Calo [1981] 6100 Hansen Hansen et al. [1993] Hine and Mookerjee Mookerjee [1975] Mackay and Shiu [1981] 4800 Wrigh Wrightt et al. [1992b] Dilling [1977] 4500 Wright Wright et al. [1992a] Tse et al. [1992] 4600 Mackay Mackay and Shiu [1981] 5000 Wrigh Wrightt et al. [1992b] Dilling [1977] Yaws and Yang [1992] 4200 Barr and Newsham [1987] 4700 Wright Wright et al. [1992a] 2800 Ashworth Ashworth et al. [1988] 3000 USEPA [1982] 3200 Staudinger and Ro Roberts berts [1996] 4800 Tse et al. [1992] 3600 Leighton and Calo [1981] Hine and Mookerjee [1975]
? X X X X X L X X V L M V X X L M V ? X X X X L X X V
Mackay and Shiu [1981] Dilling [1977] Yaws and Yang [1992]
L V ? V L V ? X L X X
39 3900 5900
note
39 3 3 3 3 3 3 3
3 3
39 3 3 3 3 3 3
−1
CHCl2 CCl3 [76-01-7] hexachloroethane C2 Cl6 [67-72-1]
4.6×10−1 4.0×10 5.5×10−1 4.4×10−1 7.8×10−2 8.2×10−1 4.4×10−2 1.0×10−1 2.5×10−1 1.2×10−1 2.5×10−1
Hine and Mookerjee [1975] Mackay and Shiu [1981] Dilling [1977] Yaws and Yang [1992] 2100 USEPA [1982] 5600 Staudinger and Ro Roberts berts [1996] 2600 Ashworth Ashworth et al. [1988] 5600 Munz and Ro Roberts berts [1987]
39
39 3 3 3
76
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance 1-chloropropane C3 H7 Cl [540-54-5] 2-chloropropane C3 H7 Cl [75-29-6] 1,2-dichloropropane C3 H6 Cl2 [78-87-5]
1,3-dichloropropane C3 H6 Cl2 [142-28-9] 1,2,3-trichloropropane C3 H5 Cl3 [96-18-4]
1-chloro-2-methylpropane C4 H9 Cl [513-36-0] 1-chlorobutane C4 H9 Cl [109-69-3] 2-chlorobutane
kH [M [M//atm] 7.4×10−2 9.2×10−2 9.3×10−2 6.2×10−2 6.9×10−2
3.4×10−1 3.7×10−1 3.7×10−1 3.4×10−1 3.4×10−1 4.0×10−1 3.0×10−1 3.4×10−1 3.5×10−1 3.8×10−1 1.0 1.0 1.0 4.4 3.1 2.9 2.8 3.4 8.4×10−1 6.4×10−2 5.1×10−2 5.7×10−2 5.9×10−2 6.0×10−2 5.4×10−2
−d ln kH
d(1/T )
[K]
reference
Hine and Mookerjee [1975] Mackay and Shiu [1981] Yaws and Yang [1992] Hine and Mookerjee [1975] Yaws and Yang [1992]
3800 2100 3600 3700 3800 4300 4300 4700
Hine and Mookerjee [1975] Wright Wright et al. [1992b] Yaws and Yang [1992] USEPA [1982] Wright Wright et al. [1992a] Tse et al. [1992] Bissonette Bissonette et al. [1990] Staudinger and Roberts Roberts [1996] Leigh Leighton ton and Calo [1981] Ashworth Ashworth et al. [1988] Hine and Mookerjee Mookerjee [1975] Yaws and Yang [1992] Leigh Leighton ton and Calo [1981]
39 3900 4000 Tancr`ede ede and Yanagisawa Yanagisa wa [1990] Dilling [1977] Yaws and Yang [1992] 3500 Leigh Leighton ton and Calo [1981] 3700 Staudinger and Roberts Roberts [1996] Mackay and Shiu [1981] Yaws and Yang [1992]
3500
note
V L ? V ?
39, 8
V M ? X X X X L X X V ? X M V ? X L L ?
39, 8
39 3 3 3 3 3 3 39 3
39 3
39, 8
Yaws and Yang [1992]
V ? ? X ?
13 39 3 39
Leigh Leighton ton and Calo [1981]
X
3
Hine and Mookerjee [1975]
V
Leigh Leighton ton and Calo [1981]
X
3
Hine and Mookerjee [1975] Yaws and Yang [1992] Leigh Leighton ton and Calo [1981]
V ? X V
39 3
Hine and Mookerjee [1975] Hoff et al. [1993] Yaws and Yang [1992] Leigh Leighton ton and Calo [1981]
type
−2
C4 H9 Cl [78-86-4] 1,1-dichlorobutane C4 H8 Cl2 [541-33-3] 1,4-dichlorobutane C4 H8 Cl2 1-chloropentane C5 H11 Cl [543-59-9] 2-chloropentane C5 H11 Cl [625-29-6]
4.1×10
4500
1.3×10−1
2.0
4.6×10−2 2.0×10−2 4.2×10−2 3.6×10−2
3100
4700
Hine and Mookerjee [1975]
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
3-chloropentane C5 H11Cl [616-20-6] 1,5-dichloropentane C5 H10Cl2 2-chloro-2-methylbutane C5 H11Cl [594-36-5] 1-chlorohexane C6 H13Cl
kH [M [M//atm] 3.8×10−2
77
−d ln kH
d(1/T )
[K]
1.8
1600
3.1×10−1
4.1×10−2
4500
reference
type
Hine and Mookerjee [1975]
V
Leighto Leighton n and Calo [1981]
X
3
Yaws and Yang [1992]
?
39
Leighto Leighton n and Calo [1981]
X
3
Drouillard et al. [1998]
V
Drouillard Drouillard et al. [1998]
M
1,10-dichlorodecane C10 H20 Cl2
2.0×10−1
1,2,9,10-tetrachlorodecane C10 H18 Cl4
5.7
pentachlorodecane isomers C10 H17 Cl5
2.1×101 3.9×101
Drouillard et al. [1998] Drouillard et al. [1998]
M M
1,2,10,11-tetrachloroundecane C11 H20 Cl4
1.6×101
Drouillard et al. [1998]
M
pentachloroundecane isomers C11 H19 Cl5
6.9×101 1.5×102
Drouillard et al. [1998] Drouillard et al. [1998]
M M
1,12-dichlorododecane C12 H24 Cl2
1.6×10−1
Drouillard et al. [1998]
V
po pollychlorinated dode odecane isomers C12 Hx Cly
7.4×101
Drouillard et al. [1998]
M
note
78
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance chloroethene CH2 CHCl (vinyl chloride) [75-01-4]
kH [M [M//atm] 8.2×10−4 1.8×10−2 4.6×10−2 3.8×10−2 9.5×10−4
−d ln kH
d(1/T )
type
note
Pearson and McConnell [1975] Hine and Mookerjee [1975] Wilhelm Wilhelm et al. [1977] Gossett [1987] Dilling [1977]
M V L M V
81,74
Dilling [1977] Yaws and Yang [1992] Staudinger and Roberts Roberts [1996] Ashw Ashworth orth et al. [1988]
V ? L X M L M V V ? X X X X L X X V L M M V ? X X X L
[K]
3000 3300
reference
−2
1,1-dichloroethene CH2 CCl2 [75-35-4]
(Z)-1,2-dichloroethene CHClCHCl (cis -1,2-dichloroethene) [156-59-2]
4.3×10−2 4.4×10 3.9×10−2 4.0×10−2 6.5×10−3 7.6×10−3 3.9×10−2 5.3×10−3 6.2×10−3 4.3×10−2 3.7×10−2 6.6×10−2 1.4×10−2 2.7×10−2 3.4×10−2 3.4×10−2 3.7×10−2 3.0×10−1 1.3×10−1 2.7×10−1 2.4×10−1 1.3×10−1 1.3×10−1 2.1×10−1 2.2×10−1 2.3×10−1 2.4×10−1
3100 2900
3700
3100 1200 6600 4600 4000 4500 2900
Pearson and McConnell [1975] Mackay and Shiu [1981] Gossett [1987] Dilling [1977] Dilling [1977] Yaws and Yang [1992] Tse et al. [1992] USEPA [1982] Ervin et al. [1980] Leigh Leighton ton and Calo [1981] Staudinger and Roberts Roberts [1996] Bisso Bissonette nette et al. [1990] Ashw Ashworth orth et al. [1988]
4200 3800
3100 4100 4000 3900
Hine and Mookerjee [1975] Mackay and Shiu [1981] Gossett [1987] Wrigh Wrightt et al. [1992b] Dilling [1977] Yaws and Yang [1992] Ashw Ashworth orth et al. [1988] Ervin et al. [1980] Wrigh Wrightt et al. [1992a] Staudinger and Roberts Roberts [1996]
39 3 81,8
8 39 3 3 3 3 3 3
39 3 3 3
−1
2.5×10 2.6×10−1
4200 3400
Bisso Bissonette nette et al. [1990] Tse et al. [1992]
X X
3 3
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance (E)-1,2-dichloroethene CHClCHCl (trans -1,2-dichloroethene) [156-60-5]
kH [M [M//atm] 1.5×10−1 1.5×10−1 1.1×10−1 1.0×10−1 9.9×10−2
79
−d ln kH
d(1/T )
[K]
reference
type
4200 4000 3400
Hine and Mookerjee [1975] Mackay and Shiu [1981] Gossett [1987] Wright Wright et al. [1992b] Hans Hansen en et al. [1995]
V L M M M
3000 3400 4300 1700 5400 4800 4100 4100 3300
Dilling [1977] Yaws and Yang [1992] Ashworth Ashworth et al. [1988] Tse et al. [1992] Wright Wright et al. [1992a] USEPA [1982] Ervin Ervin et al. [1980] Bissonette Bissonette et al. [1990] Staudinger and Roberts Roberts [1996] Co Cooling oling et al. [1992] Hans Hansen en et al. [1993]
V ? X X X X X X L X X M V L M M M M M M M V V V M ? X
note
−1
trichloroethene C2 HCl3 (trichloroethylene) [79-01-6]
1.5×10−1 1.5×10 1.0×10−1 1.1×10−1 1.1×10−1 1.9×10−1 7.1×10−2 8.6×10−2 9.1×10−2 9.8×10−2 9.9×10−2 1.1×10−1 8.5×10−2 8.2×10−2 9.9×10−2 1.1×10−1 1.3×10−1 1.1×10−1 9.7×10−2 1.3×10−1 1.2×10−1 8.4×10−2 1.0×10−1 2.4×10−1 1.1×10−1 8.6×10−2 1.0×10−1
Pearson and McConnell [1975] Hine and Mookerjee [1975] Mackay and Shiu [1981] Lincoff Lincoff and Gossett [1984] 4900 4800 Gossett [1987] 5200 Tancr`ede ede and Yanagisawa Yanagis awa [1990] 4200 Wright Wright et al. [1992b] 3500 Robbins obbins et al. [1993] Nielsen et al. [1994] 3600 Dewu Dewulf lf et al. [1995] Dilling [1977] Dilling [1977] Dilling [1977] Hoff et al. [1993] Yaws and Yang [1992] 4100 Wright Wright et al. [1992a]
39 3 3 3 3 3 3 3 3 81,8
8 82 39 3
−1
1.1×10−1 1.2×10 8.2×10−2 8.9×10−2 1.0×10−1 1.0×10−1 1.0×10−1 1.1×10−1 7.5×10−2 9.7×10−2 9.7×10−2 9.9×10−2 9.9×10−2
4400 3900 4000 1600 4600 4700 5200 4300 4800 3700 4700 2100 4900
Co Cooling oling et al. [1992] Tse et al. [1992] Kavanaugh and Trussell [1980] USEPA [1982] Staudinger and Roberts Roberts [1996] Leighton Leighton and Calo [1981] Bissonette Bissonette et al. [1990] Gosse Gossett tt et al. [1985] Ervin Ervin et al. [1980] Ashworth Ashworth et al. [1988] Munz and Roberts Roberts [1987] Lama Lamarche rche and Droste Droste [1989] Gosse Gossett tt et al. [1985]
X X X X L X X X X X X X X
3 3 3 3 3 3 3 3 3 3 3 3
80
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance tetrachloroethene C2 Cl4 (tetrachloroethylene) [127-18-4]
kH [M [M//atm] 5.0×10−2 3.7×10−2 4.4×10−2 5.7×10−2 5.7×10−2
−d ln kH
d(1/T )
type
note
Pearson and McConnell [1975] Hine and Mookerjee [1975] Mackay and Shiu [1981] Lincoff and Gossett [1984] Gossett [1987]
M V L M M
81,8
ede and Yanagisawa Yanagisa wa [1990] 5500 Tancr`ede Kolb et al. [1992] 3600 Robbins obbins et al. [1993] 4500 Dewu Dewulf lf et al. [1995] Dilling [1977] Dilling [1977] Dilling [1977] Dilling [1977] Hoff et al. [1993] Yaws and Yang [1992] 1500 USEPA [1982] 5000 Kavanaugh and Trussell [1980] 4800 Staudinger and Roberts Roberts [1996] 4400 Ashworth Ashworth et al. [1988] Munz and Roberts Roberts [1987] 4400 5100 Gossett Gossett et al. [1985] 5200 Ervin et al. [1980] 4700 Leighton Leighton and Calo [1981] 5300 Bissonette Bissonette et al. [1990] 4600 Gossett Gossett et al. [1985] Hine and Mookerjee [1975] Dilling [1977] Yaws and Yang [1992] 4200 Wright Wright et al. [1992b] 1500 USEPA [1982] Meylan and Howard [1991] Mackay and Shiu [1981]
M X M M V V V C M ? X X L X X X X X X X V V ? M X X L
Dilling [1977]
V
[K]
5100 4900
reference
−2
6.0×10−2 8.2×10 5.6×10−2 7.0×10−2 3.4×10−2 4.0×10−2 1.2×10−1 8.2×10−2 6.4×10−2 3.7×10−2 3.6×10−2 4.0×10−2 5.9×10−2 5.5×10−2 5.5×10−2 5.8×10−2 5.8×10−2 6.2×10−2 6.3×10−2 6.6×10−2 3-chloro-1-propene C3 H5 Cl [107-05-1] 1,3-dichloropropene C3 H4 Cl2 [542-75-6] cis -1,3-dichloropropene
1.1×10−1 9.3×10−2 1.1×10−1 6.5×10−1 2.8×10−1 5.2×10−1 4.2×10−1
45
8 82
39 3 3 3 3 3 3 3 3 3
39 3 3
−1
4.3×10
C3 H4 Cl2 [10061-01-5] trans -1,3-dichloropropene C3 H4 Cl2
5.6×10−1 5.7×10−1
Mackay and Shiu [1981] Dilling [1977]
L V
2,3-dichloropropene C3 H4 Cl2
2.8×10−1 2.7×10−1
Mackay and Shiu [1981] Dilling [1977]
L V
4.0×10−2 9.7×10−2 9.9×10−2 3.4×105
4700 3500
Pearson and McConnell [1975] Meylan and Howard [1991] USEPA [1982] Betterton and Hoffmann [1988]
M X X M
5.9×101
5400
Betterton [1991]
M
hexachlorobutadiene CCl2 CClCClCCl2 [87-68-3] trichloroethanal CCl3 CHO (trichloroacetaldehyde) chloro-2-propanone CH2 ClCOCH3
81,8 3 3 63
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance chloroethanoic acid CH2 ClCOOH (chloroacetic acid) [79-11-8] dichloroethanoic acid CHCl2 COOH (dichloroacetic acid) [79-43-6] trichloroethanoic acid CCl3 COOH (trichloroacetic acid) [76-03-9] trichloroacetylchloride CCl3 COCl
kH [M [M//atm] 1.1×105
−d ln kH
d(1/T )
reference
tty ype
[K] 9700
Bowden Bowden et al. [1998b]
M
1.2×105
8000
Bowden Bowden et al. [1998b]
M
7.4×104
8700
Bowd Bowden en et al. [1998a]
M
Mirabel Mirabel et al. [1996]
M
2.0
81
no n ote
1-chloro-2,3-epoxypropane
2.8×101
3700
USEPA [1982]
X
3
2-chloroethylvinylether
3.1
2500
USEPA [1982]
X
3
bis(2-chloroethoxy)methane C5 H10Cl2 O2 [111-91-1] 1,5-dichloro-3-oxapentane C4 H8 Cl2 O (bis(2-chloroethyl)ether) [111-44-4] bis(2-chloroisopropyl)ether C6 H12Cl2 O [108-60-1]
2.6×103
5500
USEPA [1982]
X
3
4.7×101
4100
USEPA [1982]
X
3
6.6
2800
USEPA [1982]
X
3
82
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
kH [M [M//atm]
−d ln kH
d(1/T )
[K]
reference
type
note
aromatic compounds with chlorine 2.2×10−1 2.7×10−1 2.7×10−1 2.9×10−1
chlorobenzene C6 H5 Cl [108-90-7]
Hine and Mookerjee [1975] Mackay et al. [1979] Mackay et al. [1979] Mackay and Shiu [1981]
V M T L
Mackay and Shiu [1981] Hoff et al. [1993] 4600 Hartkopf and Karger Karger [1973] Yaws and Yang [1992] 2100 USEPA [1982] 1900 Co Cooling oling et al. [1992] 4700 Bissonette Bissonette et al. [1990] 2700 Ashworth Ashworth et al. [1988] 3800 Staudinger and Roberts Roberts [1996] 4200 Ervin et al. [1980] 3500 Leighton Leighton and Calo [1981]
M M M ? X X X X L X X V L M ? X L X X X V L M ? X X V
−1
1,2-dichlorobenzene C6 H4 Cl2 (o-dichlorobenzene) [95-50-1]
1,3-dichlorobenzene C6 H4 Cl2 (m-dichlorobenzene) [541-73-1]
1,4-dichlorobenzene
3.2×10−1 2.6×10 2.9×10−1 2.2×10−1 2.5×10−1 3.2×10−1 2.4×10−1 2.6×10−1 2.7×10−1 2.9×10−1 3.0×10−1 4.1×10−1 5.3×10−1 5.3×10−1 3.3×10−1 5.3×10−1 5.5×10−1 4.9×10−1 5.4×10−1 6.0×10−1 2.1×10−1 2.8×10−1 3.4×10−1 3.0×10−1 3.9×10−1 3.0×10−1 2.2×10−1
Hine and Mookerjee [1975] Mackay and Shiu [1981] Mackay and Shiu [1981] Yaws and Yang [1992] 2800 USEPA [1982] 5900 Staudinger and Roberts Roberts [1996] 5100 Bissonette Bissonette et al. [1990] 1400 Ashworth Ashworth et al. [1988] 6700 Gossett Gossett et al. [1985]
2400 2600
Hine and Mookerjee [1975] Mackay and Shiu [1981] Hoff et al. [1993] Yaws and Yang [1992] USEPA [1982] Ashworth Ashworth et al. [1988] Hine and Mookerjee [1975]
39 3 3 3 3 3 3
39 3 3 3 3
39 3 3
−1
C6 H4 Cl2 (p-dichlorobenzene) [106-46-7]
1,2,3-trichlorobenzene C6 H3 Cl3 [87-61-6] 1,2,4-trichlorobenzene C6 H3 Cl3 [120-82-1] 1,3,5-trichlorobenzene C6 H3 Cl3 [108-70-3]
6.3×10 4.2×10−1 2.3×10−1 3.1×10−1 3.8×10−1 3.1×10−1 4.3×10−1 8.0×10−1 2.7×10−1 7.1×10−1 4.6×10−1 6.3×10−1
2700 2700 2700
Mackay and Shiu [1981] Mackay and Shiu [1981] Yaws and Yang [1992] Ashworth Ashworth et al. [1988] USEPA [1982] Ashworth Ashworth et al. [1988] Mackay and Shiu [1981] Mackay and Shiu [1981]
2500 4000
Mackay and Shiu [1981] USEPA [1982] Ashworth Ashworth et al. [1988] Mackay and Shiu [1981]
L M ? X X X L M
39 3 3 3
L X X L
3 3
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance 1,2,3,4-tetrachlorobenzene C6 H2 Cl4 [634-66-2] 1,2,3,5-tetrachlorobenzene C6 H2 Cl4 [634-90-2] 1,2,4,5-tetrachlorobenzene C6 H2 Cl4 [95-94-3] pentachlorobenzene C6 HCl5 hexachlorobenzene C6 Cl6
α-chlorotoluene C6 H5 CH2 Cl
kH [M [M//atm] 3.9×10−1 1.3
d(1/T )
[K]
reference
type
note
1.7×10−1 6.4×10−1
Mackay and Shiu [1981] Mackay and Shiu [1981]
L M
3.9×10−1
Mackay and Shiu [1981]
L
1.0×10−1 1.4
Mackay and Shiu [1981] tenH tenHulsch ulscher er et al. [1992]
L X
Mackay and Shiu [1981] Yaws and Yang [1992] tenH tenHulsch ulscher er et al. [1992] USEPA [1982]
39 3 3
Mackay Mackay and Shiu [1981]
L ? X X L
USEPA [1982] Leighton and Calo [1981]
X X
3 3
Mackay and Shiu [1981] Mackay and Shiu [1981]
L M
Mackay Mackay and Shiu [1981] Mackay Mackay and Shiu [1981] USEPA [1982] Meylan and Howard Howard [1991] USEPA [1982] Meylan and Howard [1991]
L M X X X X
3 3 3 3
4800
5200
2.0×101 2.4×10−3 2.1 5.9×10−1 1.6
2-chloronaphthalene C10 H7 Cl
3.2 3.2 1.6 3.1 1.1×101 4.0×104
4-chloro-2-nitrophenol C6 H4 ClNO3 [89-64-5] 4-chloro-5-methyl-2 -2--nitrophenol C7 H6 ClNO3 (4-chloro-6-nitro-m-cresol) [7147-89-9]
−d ln kH
L X
1.9 2.8×10−1
(pentachlorophenol) [87-86-5] 2-hydroxychlorobenzene C6 H5 ClO (2-chlorophenol) [95-57-8] 2.4-dichlorophenol
83
Mackay and Shiu [1981] tenH tenHulsch ulscher er et al. [1992]
1-chloro-2-methylbenzene C7 H7 Cl (o-chlorotoluene) [95-49-8] 1-chloronaphthalene C10 H7 Cl
hydroxypentachlorobenzene C6 HCl5 O
5800 1600
3000 3500
2.9×10−1 2.9×10−1
3800
1300
3
3
1.2×102
4600
USEPA [1982]
X
3
1.5×102
4900
USEPA [1982]
X
3
7.9×101
Schwarzenbach et al. [1988]
V
8
3.6×101
Schwarzenbach et al. [1988]
V
8
84
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
kH [M [M//atm]
−d ln kH
d(1/T )
[K]
reference
type
note
compounds with chlorine and fluorine chlorofluoromethane CH2 FCl (R31)
1.5×10−1 1.5×10−1 1.5×10−1
chlorodifluoromethane CHF2 Cl (R22)
3.4×10−22 3.4×10 2.4×10−1 3.3×10−2 3.1×10−2 3.7×10−2 1.9×10−1
Hine and Mookerjee [1975] Wilhelm Wilhelm et al. [1977] Yaws and Yang [1992]
V L ?
Hine and Mookerjee [1975] Wilhelm Wilhelm et al. [1977] Kanakidou et al. [1995] Yaws and Yang [1992] 3400 Kavanaugh and Trussell [1980] 2700 Zheng Zheng et al. [1997] Yaws and Yang [1992]
V L C ? X M ?
Hine and Mookerjee [1975] Wilhelm Wilhelm et al. [1977] Yaws and Yang [1992]
V L ?
Pearson and McConnell [1975] Hine and Mookerjee [1975] Wilhelm Wilhelm et al. [1977] Mackay and Shiu [1981] Yaws and Yang [1992] Munz and Ro Roberts berts [1987] USEPA [1982]
M V L L ? X X C M L M ? L
81,8
3 3
Hine and Mookerjee [1975]
X X V
Hine and Mookerjee [1975] Yaws and Yang [1992] Ashworth Ashworth et al. [1988]
V ? X
2600
39
−
dichlorofluoromethane CHFCl2 (R21) chlorotrifluoromethane CF3 Cl (R13)
5.8×10−4 9.4×10−4 8.9×10−4
dichlorodifluoromethane CF2 Cl2 (R12)
2.5×10−3 2.4×10−3 2.1×10−3 2.3×10−3 2.5×10−3 3.1×10−3 3.5×10−4 8.2×10−3 1.2×10−3 9.2×10−3 1.1×10−2 8.2×10−3 1.0×10−2
trichlorofluoromethane CFCl3 (R11)
3400
1600
1800
3500 -210
2700 3100
Liss and Slater [1974] Pearson and McConnell [1975] Mackay and Shiu [1981] Hunter-Sm Hunter-Smith ith et al. [1983] Yaws and Yang [1992] Staudinger and Ro Roberts berts [1996]
84 39 3 39
39
39 3 3 81,8
39
−
1,1,2,2-tetrachlorodi odifluoroet oethane C2 F2 Cl4 (R112)
1.7×10−2 1.0×10 2 1.0×10−2
740 3500
USEPA [1982] Ashworth Ashworth et al. [1988]
1,1,2-trichlorotrifluoroethane C2 F3 Cl3 (R113)
2.0×10−3 2.0×10−3 3.4×10−3
1,1-dichlorotetrafluoroethane C2 F4 Cl2 (R114)
5.9×10−4
Hine and Mookerjee [1975]
V
1,2-dichlorotetrafluoroethane C2 F4 Cl2 (R114)
8.2×10−4 8.3×10−4
Hine and Mookerjee [1975] Yaws and Yang [1992]
V ?
3200
39 3
39
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
chloropentafluoroethane C2 F5 Cl (R115) dichlorotrifluoroethane
2.9×10−2
2600
1-chl -chlor oroo-1, 1,2, 2,2, 2,22-ttetra etraflu fluooroe roetha hane ne C2 HF4 Cl (R124)
1. 1.11×10−2
3200
2-chloro-1,1,1-trifluoroethane C2 H2 F3 Cl (R133)
3.7×10−2
1,1-dichloro-1-fluoroethane CH3 CFCl2 (R141B)
7.9×10−3
5200
1-chloro-1,1-difluoroethane CH3 CF2 Cl (R142B)
1.4×10−2
2500
chlorodifluoroethanoic acid CF2 ClCOOH (chlorodifluoroacetic acid) [76-04-0] chlorodi odifluoroet oethanoic pe perroxyacid CClF2 COOOH
2.5×104
dichlorofluoroet oethanoic pe perroxyacid
substance
85
−d ln kH
kH [M [M//atm] 3.2×10−4 3.4×10−4 3.8×10−4
d(1/T )
[K]
reference
type
note
Hine and Mookerjee [1975] Wilhelm Wilhelm et al. [1977] Yaws and Yang [1992]
V L ?
Kanakidou Kanakidou et al. [1995]
C
Kanakidou Kanakidou et al. [1995]
C
Hine and Mookerjee [1975]
V
Kanakidou Kanakidou et al. [1995]
C
Kanakidou Kanakidou et al. [1995]
C
Bowd Bowden en et al. [1998b]
M
3.0×103
Kanakidou et al. [1995]
E
3.0×103
Kanakidou et al. [1995]
E
carbonic chloride fluoride COFCl
1.0×101
Kanakidou et al. [1995]
C
trifluoroacetylchloride CF3 COCl
2.5 2.0
Kana Kanakidou kidou et al. [1995] Mirabel Mirabel et al. [1996]
C M
genericc peroxid generi peroxidee with with fluorin fluorinee and/or and/or chlorine ROOH
3.0×101
Kanakidou et al. [1995]
E
80
chlorodifluoronitrooxymethane CClF2 OONO2
2.9
Kanakidou Kanakidou et al. [1995]
E
85
2800
39
C2 HF3 Cl2 (R123)
10000
CCl2 FCOOOH
5900
86
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
kH [M [M//atm]
−d ln kH
d(1/T )
[K]
reference
type
note
compounds with bromine 1.6×10−1 1.6×10−1 1.9×10−1 1.5×10−1
bromomethane CH3 Br [74-83-9]
3100
Hine and Mookerjee [1975] Wilhe Wilhelm lm et al. [1977] Mackay and Shiu [1981] Yaws and Yang [1992]
V L L ?
USEPA [1982] Hine and Mookerjee Mookerjee [1975] Mackay Mackay and Shiu [1981] Wrigh Wrightt et al. [1992b] Moor Mooree et al. [1995] Wright Wright et al. [1992a] Tse et al. [1992]
X V L M M X X V L M C M M X X X L X V ?
8 39
−
dibromomethane CH2 Br2 [74-95-3]
tribromomethane CHBr3 [75-25-2]
bromoethane C2 H5 Br [74-96-4] 1,2-dibromoethane C2 H4 Br2 [106-93-4]
4.4×10 3 1.1 3.2 1.1 9.3×10−1 1.1 1.1 1.5 1.6 2.3 1.7 2.3 1.4 1.8 1.9 2.0 1.7 1.9 1.3×10−1 1.3×10−1
1-bromopropane C3 H7 Br [106-94-5] 2-bromopropane C3 H7 Br [75-26-3] 1,2-dibromopropane C3 H6 Br2 [78-75-1] 1,3-dibromopropane C3 H6 Br2 [109-64-8]
1.4 1.4 1.1 1.5 1.1×10−1 1.4×10−1
39 3900 4400 3700 4000
Hine and Mookerjee Mookerjee [1975] Mackay Mackay and Shiu [1981] Nicholson Nicholson et al. [1984] Nicholson Nicholson et al. [1984] 5700 Wrigh Wrightt et al. [1992b] 5000 Moor Mooree et al. [1995] 2700 USEPA [1982] 4300 Tse et al. [1992] 5200 Wright Wright et al. [1992a] 5200 Staudinger and Roberts Roberts [1996] 4700 Munz and Roberts Roberts [1987] Hine and Mookerjee [1975] Yaws and Yang [1992]
1900 3900
9.2×10−2 1.0×10−1
360
1.1 6.8×10−1
1.1
Hine and Mookerjee Mookerjee [1975] Yaws and Yang [1992] USEPA [1982] Ashworth Ashworth et al. [1988]
3
3 3
3 3 3 3 39
Hine and Mookerjee [1975] Yaws and Yang [1992]
V ? X X V ?
Hine and Mookerjee [1975] Yaws and Yang [1992]
V ?
39, 8
Hine and Mookerjee Mookerjee [1975] Yaws and Yang [1992]
V ?
39
Hine and Mookerjee Mookerjee [1975]
V
39 3 3 39, 8
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
kH [M [M//atm] 8.2×10−2 4.7×10−2 8.3×10−2 4.3×10−2
87
−d ln kH
d(1/T )
[K]
reference
note
Hine and Mookerjee [1975]
V M ? V
3.1×10−2
Yaws and Yang [1992]
?
2.9×10−2
Hine and Mookerjee [1975]
V
5.1×10−2
Yaws and Yang [1992]
?
39
3-bromo-1-propene C3 H5 Br
1.7×10−1
Yaws and Yang [1992]
?
39
bromoethanoic acid CH2 BrCOOH (bromoacetic acid) [79-08-3] dibromoethanoic acid CHBr2 COOH (dibromoacetic acid) [631-64-1] tribromoethanoic acid CBr3 COOH (tribromoacetic acid) [75-96-7] bromobenzene C6 H5 Br
1.5×105
9300
Bowden Bowden et al. [1998b]
M
2.3×105
8900
Bowden Bowden et al. [1998b]
M
3.0×105
9000
Bowden Bowden et al. [1998b]
M
Hine and Mookerjee [1975] Mackay and Shiu [1981]
V L
[108-86-1]
4.1×10−1 5.4×10−1 4.7×10−1 5.4×10−1 5.1×10−1
Mackay and Shiu [1981] Hansen Hansen et al. [1995] Yaws and Yang [1992] Hansen Hansen et al. [1993] Mackay and Shiu [1981]
M M ? X L
Hine and Mookerjee Mookerjee [1975] Mackay and Shiu [1981]
V L
4.3×10−1
Hine and Mookerjee [1975]
V
3.0×10−1
Hine and Mookerjee [1975]
V
1-bromobutane C4 H9 Br [109-65-9] 1-bromo-2-methylpropane C4 H9 Br [78-77-3] 2-bromo-2-methylpropane C4 H9 Br 1-bromo-3-methylbutane C5 H11Br [107-82-4] 1-bromopentane C5 H11Br
1,3-dibromobenzene C6 H4 Br2 [108-36-1] 1,4-dibromobenzene C6 H4 Br2 [106-37-6] 1-bromo-4-methylbenzene BrC6 H4 CH3 (p-bromotoluene) 1-bromo-2-ethylbenzene BrC6 H4 C2 H5
Hine and Mookerjee [1975] Hoff et al. [1993] Yaws and Yang [1992]
typ e
4.8×10−1 4.8×10−1
2.0 4.9×10−1
5300 5400
39
39, 86
39 3
88
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
1-bromo-2-(2-propyl)-benzene BrC6 H4 C3 H7 (o-bromocumene)
kH [M [M//atm] 1.7×10−1
−d ln kH
d(1/T )
7.0×103
4-bromophenol
[K]
8200
reference
type
Hine and Mookerjee [1975]
V
Parsons Parsons et al. [1971]
M
note
54
HOC6 H4 Br bromotrifluoromethane CHF3 Br
2.0×10−3
Hine and Mookerjee [1975]
V
bromodichloromethane CHCl2 Br
6.3×10−1 4.3×10−1 4.8×10−1 4.0×10−1 4.6×10−1 5.2×10−1 3.5×10−1 4.0×10−1 1.1 1.2 1.1 7.3×10−1 1.2 9.8×10−1 8.6×10−1 8.7×10−1 8.7×10−1 1.1
Nicholson et al. [1984] Nicholson et al. [1984] Nicholson et al. [1984] Moore Moore et al. [1995] USEPA [1982] Tse et al. [1992] Ervin et al. [1980] Staudinger and Roberts Roberts [1996]
Hine and Mookerjee Mookerjee [1975]
M C C M X X X L M C C M X X X X L V
Mackay and Shiu [1981]
L
dibromochloromethane CHClBr2
1-chloro-2-bromoethane C2 H4 BrCl [107-04-0] 1-bromo-4-chlorobenzene ClC6 H4 Br
6.9×10−1
4700 1200 3900 5200 5200
4900 2500 4000 6400 5000 5500
Nich Nicholson olson et al. [1984] Nich Nicholson olson et al. [1984] Nich Nicholson olson et al. [1984] Moore Moore et al. [1995] USEPA [1982] Tse et al. [1992] Ashworth Ashworth et al. [1988] Ervin et al. [1980] Staudinger and Roberts Roberts [1996]
3 3 3
3 3 3 3
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
kH [M [M//atm]
89
−d ln kH
d(1/T )
[K]
reference
type
note
compounds with iodine 1.7×10−1 1.8×10−1 1.9×10−1 1.4×10−1
iodomethane CH3 I [74-88-4]
Liss and Slater [1974] Hine and Mookerjee [1975] Hunter-Sm Hunter-Smith ith et al. [1983] Moor Mooree et al. [1995]
C V M M
Yaws and Yang [1992] Moor Mooree et al. [1995] Yaws and Yang [1992]
? M ?
39
3.4×10−1
Yaws and Yang [1992]
?
39
1.4×10−1 1.8×10−1
Hine and Mookerjee [1975] Yaws and Yang [1992]
V ?
39, 8
1.1×10−1 1.2×10−1
Hine and Mookerjee [1975] Yaws and Yang [1992]
V ?
39
8.9×10−2 1.1×10−1
Hine and Mookerjee [1975] Yaws and Yang [1992]
V ?
39, 8
6.3×10−2
Hine and Mookerjee [1975]
V
7.8×10−1 7.5×10−1
Mackay and Shiu [1981] Yaws and Yang [1992]
L ?
Moor Mooree et al. [1995]
M
3800 4300
−
diiodomethane CH2 I2 [75-11-6] triiodomethane CHI3 (iodoform) [75-47-8] iodoethane C2 H5 I [75-03-6] 1-iodopropane C3 H7 I [107-08-4] 2-iodopropane C3 H7 I [75-30-9] 1-iodobutane C4 H9 I [542-69-8] iodobenzene C6 H5 I [591-50-4] chloroiodomethane CH2 ClI [593-71-5]
3.5×10 2.3 2.8
1
8.9×10−1
5000
4300
39
39
90
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance
kH [M [M//atm]
−d ln kH
d(1/T )
[K]
reference
type
note
compounds with sulfur 3.3×10−1 3.9×10−1 7.1×10−1 2.0×10−1
methanethiol CH3 SH (methyl mercaptan)
3100 2800
Hine and Weimar [1965] Przy Przyjazny jazny et al. [1983] Russell et al. [1992] De Bruyn et al. [1995]
M M E M
USEPA [1982] Hine and Mookerjee [1975] Przy Przyjazny jazny et al. [1983] Vitenberg et al. [1975] Karl and Lindinger [1997] Yaws and Yang [1992]
87
−
2.6×10 1 3.6×10−1 2.8×10−1 2.2×10−1 2.6×10−1 3.4×10−1 2.5×10−1
ethanethiol C2 H5 SH (ethyl mercaptan) [75-08-1] 1-propanethiol C3 H7 SH
3.0 3.0
thioanisole C6 H5 SCH3
4.1 4.1
diethyl sulfide C2 H5 SC2 H5
3600
Przy Przyjazny jazny et al. [1983]
X V M M M ? M
3800
Przy Przyjazny jazny et al. [1983] Yaws and Yang [1992]
M ?
Hine and Weimar Weimar [1965] Hine and Mookerjee Mookerjee [1975]
V V
Hine and Weimar Weimar [1965] Hine and Mookerjee Mookerjee [1975]
V V
Hine and Weimar [1965] Lovelock et al. [1972] Vitenberg et al. [1975] Vitenberg et al. [1975] Przy Przyjazny jazny et al. [1983] Cline and Bates [1983] Gaffney and Senum [1984] Dac Dacey ey et al. [1984] Aneja Aneja and Overton Overton [1990]
V M M R M C X M X
Russell et al. [1992] De Bruyn et al. [1995]
3400
2.2×10−1 1.1×10−1
1-butanethiol C4 H9 SH [109-75-5] thiophenol C6 H5 SH
dimethyl sulfide CH3 SCH3 (DMS)
1600
5.5×10−1 1.6×10−1 6.2×10−1 7.1×10−1 5.6×10−1 4.4×10−1 6.2×10−1 5.6×10−1 4.8×10−1
8.0×10−2 4.8×10−1 4.6×10−1 5.6×10−1
3700
3500 3500 3100
4600
Hine and Mookerjee [1975] Przy Przyjazny jazny et al. [1983]
E M V M
dipropyl sulfide C3 H7 SC3 H7
3.3×10−1
4200
Przy Przyjazny jazny et al. [1983]
M
di-(2-propyl)-sulfide (C3 H7 )2 S
3.0×10−1
4700
Przy Przyjazny jazny et al. [1983]
M
dimethyl disulfide CH3 SSCH3
8.4×10−1 9.2×10−1 9.6×10−1 4.7×10−1 6.5×10−1 5.8×10−1
Vitenberg et al. [1975] Vitenberg et al. [1975] Przy Przyjazny jazny et al. [1983]
M R M M M ?
diethyl disulfide C2 H5 SSC2 H5
4000 4000
Vitenberg et al. [1975] Przy Przyjazny jazny et al. [1983] Yaws and Yang [1992]
3
43 39
39
8 8 88, 83 48 89 87
8 8 8 39, 8
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
kH [M [M//atm] 4.4×10−1 3.4×10−1
substance thiophene C4 H4 S [110-02-1] 2-methyl-thiophene CH3 C4 H3 S
dimethylsulfone CH3 SO2 CH3 (DMSO2)
reference
type
note
1.4×103 >5.0×104
Gmehling et al. [1981] De Bruyn et al. [1994]
X C
>5.0×104
De Bruyn et al. [1994]
E
Brimblecombe Brimblecombe and Clegg [1988]
T
20
Hempel [1901] Winkler [1906] Winkler [1907] Stock and Kuss [1917] Wilhelm Wilhelm et al. [1977] Hoyt [1982] De Bruyn et al. [1995] Yaws and Yang [1992]
X X X X L X M ? X X M ? X V
30, 79 30 90 30, 8
3.3×10−2 2.1×10−2 2.1×10−2 2.2×10−2 2.1×10−2 1.5×10−2 2.2×10−2 1.9×10−2 5.6×10−2 4.4×10−2 5.5×10−2 5.2×10−2 7.6×10−2 3.0×101
(ClCH2 CH2 )2 S (mustard gas)
[K] 3700
M
carbon oxide sulfide OCS (carbonyl sulfide)
2,2’-dichlorodiethylsulfide
d(1/T )
Przyjazny Przyjazny et al. [1983]
6.5×1013 /K A
−d ln kH
M ?
methanesulfonic acid CH3 SO3 H (MSA)
carbon disulfide CS2
91
Przyjazny Przyjazny et al. [1983] Yaws and Yang [1992]
4.2×10−1
dimethylsulfoxide CH3 SOCH3 (DMSO)
4000
3300 3300 3000 3600 2100 4000 4100 2800 1200
Rex [1906] Booth Booth and Jolley [1943] De Bruyn et al. [1995] Yaws and Yang [1992] USEPA [1982] Hine and Mookerjee [1975]
39
11
91, 83 39 30 30 39 3
92
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
kH [M [M//atm]
substance
−d ln kH
d(1/T )
[K]
reference
type
note
polychlorobiphenyls (PCB’s), pesticides, etc. 2, 2,77-di dicchl hlor orod odib iben enzzo[b, o[b,ee][1, ][1,4] 4]di diooxi xin n C12 H6 O2 Cl2 (2,7-DiCDD) [33857-26-0]
1.7×101 1.2×101
Santl et al. [1994] Shiu et al. [1988]
M X
92
1, 1,2, 2,44-tr tric ichl hlor orod odib iben enzo zo[b [b,e ,e][ ][1, 1,4] 4]di diooxi xin n C12 H5 O2 Cl3 (1,2,4-TriCDD)
2. 2.88×101 2.6×101
Santl et al. [1994] Shiu et al. [1988]
M X
92
1,2,3,4-t 1,2,3, 4-tetr etrac achlo hlorodi rodibenz benzo[b o[b,e] ,e][1, [1,4]d 4]dio ioxin xin C12 H4 O2 Cl4 (1,2,3,4-TCDD) [30746-58-8] aroclor1221
5.1×101 2.7×101
Santl et al. [1994] Shiu et al. [1988]
M X
92
4.4
6700
Burkhard Burkhard et al. [1985]
X
3
aroclor1242
2.0 2.4 3.0 2.3
10000 5900 7300 7500
Murphy Murphy et al. [1987] USEPA [1982] Burkhard Burkhard et al. [1985]
Burkhard Burkhard et al. [1985]
X X X X
3 3 3 3
Burkhard Burkhard et al. [1985]
X X X X X X X
3 3 3 3 3 3 3
Murphy Murphy et al. [1983] Burkhard Burkhard et al. [1985] Dunn Dunnivant ivant et al. [1988]
X X M
93, 94 93
Burkhard Burkhard et al. [1985] Dunn Dunnivant ivant et al. [1988] tenH tenHulsch ulscher er et al. [1992]
X M X
93
X M
93
Burkhard Burkhard et al. [1985] Dunn Dunnivant ivant et al. [1988]
X M
93
Burkhard et al. [1985] Dunn Dunnivant ivant et al. [1988]
aroclor1248
1.2×10−1 3.0 3.6 3.1 3.3 8.6×10−2 2.5
aroclor1254
aroclor1260
aroclor1268 2,2’-PCB C12 H8 Cl2 (IUPAC-4) [13029-08-8] 2,5-PCB C12 H8 Cl2 (IUPAC-9) [34883-39-1] 3,3’-PCB C12 H8 Cl2 (IUPAC-11) [2050-67-1] 3,4’-PCB C12 H8 Cl2 (IUPAC-12) [2974-92-7]
4.5 1.8 2.9 3.0 2.6 2.3
7.5 4.2
1.0×101 4.8
4700 9700 8000 8300 9700 4400 8700
Burkhard Burkhard et al. [1985] Murphy Murphy et al. [1987] USEPA [1982]
5700
USEPA [1982] Murphy Murphy et al. [1987] Burkhard Burkhard et al. [1985]
3
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
substance 4,4’-PCB C12 H8 Cl2 (IUPAC-15) [2050-68-2] 2,3’,5-PCB C12 H7 Cl3 (IUPAC-26) [38444-81-4] 2,4,6-PCB C12 H7 Cl3 (IUPAC-30) [35693-92-6] 2,4,4’-PCB C12 H7 Cl3 2,2’,3,3’-PCB C12 H6 Cl4 (IUPAC-40) [38444-93-8] 2,2’,5,5’-PCB C12 H6 Cl4 (IUPAC-52) [35693-99-3]
2,2’,6,6’-PCB C12 H6 Cl4 (IUPAC-54) [15968-05-5] 2,2’,5,6’-PCB C12 H6 Cl4 (IUPAC-53) [41464-41-9] 3,3’,4,4’-PCB C12 H6 Cl4 (IUPAC-77) [32598-13-3] 2,2’,4,5,5’-PCB C12 H5 Cl5 (IUPAC-101) [37680-73-2]
kH [M [M//atm] 3.3 6.9 9.2 5.1 3.5
3.0
2.7 1.5 1.4×102
d(1/T )
2.4
2.3×101 1.1×101
>2.8 1.9 c > 3.8 mM. 51) Value 51) Value obtained by Saxena and Hildemann [1996] using the group contribution method. 52) Value 52) Value at T at T = = 307 K. 53) Value 53) Value given here as quoted by Hine and Mookerjee [1975]. 54) It is assumed here that the thermodynamic data in Parsons et al. [1971] 54) It [1971] refers to the units [mol dm−3 ] and [atm] as standard states. 55) Value 55) Value given here as quoted by L L¨ uttke ¨ and Levsen [1997]. [1997]. 56) It is assumed here that the thermodynamic data in Parsons et al. [1972] 56) It [1972] refers to the units [mol dm−3 ] and [atm] as standard states. 57) Saxena and Hildemann [1996] say that this value is unreliable. 58) Value 58) Value given here as quoted by Mackay et al. [1995]. 59) Jacob [1986] assumes k assumes k H (CH3 OO) = kH (CH3 OOH) × kH (HO2 )/kH (H2 O2 ). 60) Lelieveld and Crutzen [1991] assume k assume k H (CH3 OO) = kH (HO2 ). 61) Ledbury and Blair [1925] (and also Blair and Ledbury [1925]) measured the solubility of HCHO at very high concentratio tra tions ns around around 5 to 15 M. Their Their val value ue of kH increases with HCHO concentration. Lelieveld and Crutzen [1991], Hough [1991], and Pandis Pandis and Seinf Seinfeld eld [1989] all use these solubility data but do not specify how they extrapolated to lower concentr conce ntration ations. s. Since the concentr concentration ation range is far away away from typical typical values values in atmospher atmospheric ic chemistr chemistry y the data is not reproduced here. 62) Dong and Dasgupta [1986] found that the Henry’s law constant for HCHO is not a true constant but increases with increasing concentration. They recommend the expression
[HCHO] = 10(4538/T −11.34) × p(HCHO) p(HCHO)(252.2/T +0.2088)
98
R. Sander: Sander: Henry’s Henry’s law constants constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
with [HCHO] = aqueous-phase concentration in [mol/l], p(HCHO) = partial pressure in [atm], and T T = = temperature in [K]. At T = = 298.15 K and a partial pressure of p(HCHO) = 10 −9 atm, for example, this equation results in kH = 2.5×103 M/atm. It should be noted that this expression does not converge asymptotically to a constant value at infinite dilution. 63) Betterton and Hoffmann [1988] list effective values that take into account hydration of the aldehydes: kH = ([RCHO] + [RCH(OH)2 ]) ])/p /p(RCHO) (RCHO) 64) The data from Table 1 by Zhou and Mopper [1990] was used to redo the regressio 64) The regression n analysis. The data for acetone in their Table 2 is wrong. 65) Value 65) Value given here as quoted by Bone et al. [1983]. 66) The 66) The value citet by Betterton [1992] [1992] is wrong. 67) Value 67) Value given here as quoted by Vitenberg et al. [1975]. 68) Value 68) Value given here as cited in Saxena and Hildemann [1996]. 69) The value given here was measured at a liquid phase volume mixing ratio of 10 −6 . Servant et al. [1991] found that the 69) The Henry’s law constant changes at higher concentrations. 70) Staudinger and Roberts [1996] give ‘Khan & Brimblecombe’ as the reference but don’t include this paper in their list of references. 71) Pecsar and Martin [1966] [1966] is quoted as the source. Howeve However, r, there only activity activity coefficients coefficients and no vapor pressures pressures are listed. 72) Kames and Schurath [1992] couldn’t assign the values to the isomers. 73) The 73) The same data was also published in Fischer and Ballschmiter [1998a]. 74) Value 74) Value at at T = 283 K. T = 75) The 75) The value given by Warneck et al. [1996] is wrong. 76) The 76) The value given by Schurath et al. [1996] is wrong. 77) Value 77) Value at at T T = = 373 K. 78) Value 78) Value at at T T = = 301 K. 79) Value 79) Value at at T T = = 287 K. 80) Estimate 80) Estimate for R = haloalkylgroup. 81) The 81) The same data was also published in McConnell et al. [1975]. 82) Value 82) Value at at T T = = 275 K. 83) Solubility 83) Solubility in sea water. 84) The 84) The temperature dependence (after a unit conversion) is given as: kH = exp(−8.689 + 205. 205.9/(T − 255 255..1)) × 11 11..7 M/atm This can obviously only be valid for T >> 255 255..1 K. 85) Kanakidou et al. [1995] assume k assume k H (CClF2 OONO2 ) = kH (PAN). 86) Value 86) Value at at T T = = 291 K. 87) Calculated 87) Calculated molecular structure relationship. 88) Cline and Bates [1983] [1983] refer to an unpublished manuscript; no details are available. 89) Value 89) Value given here as quoted by De Bruyn et al. [1995]. 90) Value 90) Value given here as quoted by Loomis [1928]. 91) Value given here as quoted by Rasmussen et al. [1982]. 91) Value 92) Value 92) Value given here as quoted by Santl et al. [1994]. 93) Value 93) Value given here as quoted by Dunnivant et al. [1988].
94) Value 94) Value at ‘room temperature’.
R. Sander: Henry’s law constants ( http://www.mpch-mainz.mpg.de/~sander/res/henry.html http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
10
99
Ackno Acknowle wledge dgemen ments ts
Compiling this data set would not have been possible without the help I received. For valuable discussions and for pointing out additional references to me I would like to thank C. Allen, W. Asman, M. Barth, E. Betterton, S. Clegg, N. Couffin, P. J. Crutzen, F. Dentener, D. J. Jacob, H.-W. Jacobi, W. C. Keene, J. Matthijsen, J. Montgomery, R. M. Moore, M. Mozurkewich, F. M¨ u uller, ller, O. Pahl, S. Pandis, J. Perlinger, J.-M. R´ egimbal, egimbal, S. E. Schwartz, W. Y. Shiu, T. A. Staffelbach, G. Tyndall, C. Verlinde, R. Vogt, and P. Warneck.
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