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CHM 403 Advanced Inorganic Chemistry Welcome to the course website for fall 2011.

Course Documents and Notes        

Lecture Syllabus Lab Syllabus Peer Review Forms Magnetic Suceptibility Handout Point Group Flow Chart Diamagnetic Corrections Inorganic References Nomenclature of Inorganic Compounds

Lecture Notes             

Lecture Notes 1 Lecture Notes 3 Lecture Notes 4 Lecture Notes 5 Lecture Notes 6 Lecture Notes 7 Lecture Notes 8 HSAB Lecture Lecture Notes 9 Jahn-Teller Exercise Molecular Orbitals of Oh Complexes Lecture Notes 10 Lecture Notes 11

Lab Experiments Experiment 1 Preparation and Properties of Hexamminechromium(III) Nitrate Experiment 2 The Synthesis and Characterization of Nickel(II) Complexes Experiment 3 Nickel(II) Complexes of Schiff-Based Ligands Experiment 4 Tris-bipyridine and 1,10-phenanthroline complexes of Iron(II) and Ruthenium(II) Experiment 5 Reaction Rates in Transition Metal Complexes Experiment 6 Synthesis and Characterization of a metal-arene complex: (Mestylene)tricarbonylmolbdenum(0),    

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Exercises  

What you remember from general chemistry? Crystal Field Theory Problem Set

Homework Problems Chapter 1: 6,7,19,21,28,29,30; Chapter 3: 8,14,15,22,23; Chapter 4: 10, 14, 16, 18, 22, 24 Chapter 7: 19, 20, 24; Chapter 19: 7,12,13,14,16,17,18,19; Chapter 20: 3,5,8,9,11,12,15,16,18,20,24

Articles How to Read an Inorganic Chemistry Article - Assignment Article 1. The Lanthanide Contraction Revisited (J. Am. Chem. Soc., 129 (36), 11153 -11160, 2007) Article 2. High-Energy-Density Materials: Synthesis and Characterization of N5+[P(N3)6],etc... (Angew. Chem. Int. Ed. Engl. 2004, 43, 4919-4924) Article 3. Multiple Mixed-Valence Behavior in trans,trans-[(tpy)(Cl)2OsIII(-1,3N3)OsIII(Cl)2(tpy)]+. An Azido Bridge from the Reaction between trans-[OsVI(tpy)(Cl)2(N)]+ and NH3 (J. Am. Chem. Soc., 125 (10), 2828 -2829, 2003)

Article 4. Synthesis of a Stable Compound with Fivefold Bonding Between Two Chromium(I) Centers (Science, 2005, 310, 844-847) Article 5. Synthesis of the P-cluster inorganic core of nitrogenases (J Am Chem Soc. 2003 Apr 9;125(14):4052-3) Article 6. Synthesis, characterization and reactivity of a trinuclear copper(II) thiocyanurate complex: A spin-frustrated molecular propeller. (Inorganic Chemistry Communications 10 (2007) 631 – 635)

General Links CHEMINFO Chemical Information Sources, is designed to help people find and learn how to use chemical information resources MDB: the Metalloprotein Database and Browser at The Scripps Research Institute

RasMol - Viewer program for proteins Reciprocal Net - The Reciprocal Net Site Network is a distributed database for crystallographic information Bioinorganic Systems Metal Complex Formula Finder - enter the metal and ligands and the finder calculates possible formulas. NMR Coupling Constant Calculator

Links Useful Chemistry Calculators Click the link below if you don't have Adobe Reader

Click on the textbook to go to the publisher's site for Chemistry

Course Topic Links Quantum Mechanics The Orbitron Effect of Nuclear Charge on Radial functions - Excel

Simple Bonding Theory Shapes of Molecules - nice site with animations VSEPR Page - with practice problems VSEPR Tutorial Molecular Geometry Tutorial VSEPR examples

Symmetry and Group Theory Group-Theory Tutorial - Illustrates Groups and Tests Knowledge 3D Molecular Symmetry - Probably the best site for illustrating symmetry elements.  Requires Shock Wave Symmetry - nicely illustrated symmetry operations and pt. groups Molecular Symmetry - This site is really helpful in learning about symmetry elements (need to download plug-in) Point Group Form - Answer the Questions about your molecule and you are lead to the Point Group. Spreadsheet to Reduce Representations 3D Excercises in Point Group Symmetry - great site for visualizing symmetry operations Symmetry and Point Groups Tutorial - well constructed site Character Tables and others A Nice Symmetry Site

Assigning Spectra - Tutorial on Using Group Theory to explain IR and Raman Spectroscopies

Copyright (c) Michael Prushan 2009

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Bioinorganic Chemistry of Other Metals

Apr 2, 2000 ... Bioinorganic Chemistry of Oxygen; Nitrogen Compounds; Sulfur Compounds ... Chapter 5 The Frontier of  Bioinorganic Chemistry ... http://www.chemistry.fudan.edu.cn/m_netteacher/bioinorganic/d.ppt - Cached  Download

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1.1.1 Bioinorganic Chemistry is a leading discipline at the interface of  ... The first symposium on bioinorganic chemistry was initiated by inorganic ... http://www.chemistry.fudan.edu.cn/m_netteacher/bioinorganic/a.ppt - Cached  Download

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Chemistry Subject POSTs - Slide 1

Biological catalysis, biosynthesis, protein switching, receptors, carbohydrate chemistry, genetic regulation, bioinorganic chemistry, chemical genetics, ... http://www.chem.toronto.edu/undergrad/student/Chemistry%2520Programs.ppt - Cached 

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Chemistry / Biochemistry Curriculum Powerpoint Presentation - Slide 1

Introductory chemistry, bioinorganic chemistry, advanced inorganic chemistry; Patrice B., sabbatical replacement for 06-07. Sara Winget, Visiting Professor ... http://ecademy.agnesscott.edu/~dfantz/FantzAdvisingFair06.ppt - Cached  Download

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What Does a Chemist Do? 

What is Inorganic Chemistry? Deals with the properties of elements ranging from metals to non metals. Organometallic Chemistry. Bioinorganic Chemistry ... http://www.columbia.edu/itc/chemistry/s0001/presentations/01chemistry_2004.ppt - Cached  Download

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Drug Design and Development 

Organometallic Chemistry. Bioinorganic Chemistry. Ceramics and Glass. Semiconductors. What is Inorganic Chemistry? Inorganic Chemist at Behrend ... http://chemistry.bd.psu.edu/justik/CHEM%2520449/Chem%2520Day%2520Talk.ppt - Cached 

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Nice presentation about Bioinorganic chemistry (ppt) - European ... http://www.ebi.ac.uk/~kirill/biometal/SABIC20041206.ppt - Cached  Download

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Chemistry Subject POSTs - Slide 1

Biological catalysis, biosynthesis, protein switching, receptors, carbohydrate chemistry, genetic regulation, bioinorganic chemistry, chemical genetics, ... http://www.chem.utoronto.ca/undergrad/student/Chemistry%2520Programs.ppt - Cached  Download

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www.hatz.hr 

Basics of Environmental Protection, Nanotechnology and Colloid Chemistry, Genetics, General Chemistry, Analytical Chemistry, Bioinorganic Chemistry, ... http://www.hatz.hr/engineeringeducation/ppd/Jutro/Salgo.ppt - Cached  Download

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Chemistry / Biochemistry Curriculum Powerpoint Presentation - Slide 1

Introductory chemistry, bioinorganic chemistry, advanced inorganic chemistry; Patrice B., sabbatical replacement for 06-07. Sara Winget, Visiting Professor ... http://ecademy.agnesscott.edu/~dfantz/FantzAdvisingFair06.ppt - Cached  Download

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BSc in Chemistry - Biochemistry - Info slajd Nastajanje ...

B302 Bioinorganic chemistry. 2 hours per week in V semester. ... The basic principles of coordinative chemistry in bioinorganic science. ... http://www.campuseuropae.org/en/support/docs/guides/other_guides/Biochemistry_UNS.ppt Cached  Download

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Le cycle du fer 

Wolfgang Kaim and Brigitte Schwederski « Bioinorganic Chemistry: Inorganic Element in the Chemistry of Life. An Introduction and Guide. », Wiley (1993) ... http://www.nsa.univ-cezanne.fr/UE21_files/Chap1.ppt - Cached  Download

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