Designation: D 1418 – 01a
Standard Practice for
Rubber and Rubber Latices—Nomenclature1 This standard is issued under the fixed designation D 1418; the number immediately following the designation indicates the year of original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A superscript superscript epsilon epsilon (e) indicates an editorial change since the last revision or reapproval.
INTRODUCTION
The system of designating rubbers and rubber latices in this practice was developed in 1955 to replace replace designatio designations ns GR-A, GR-I, GR-M, GR-S and GR-T (standing (standing for “Government “Government Rubber”: Rubber”: A-acrylontrile, I-isobutylene, S-styrene, M-monochlorobutadiene and T-thiosulfide), T-thiosulfide), used for synthetic thetic rubbers rubbers made made in govern governmen mentt owned owned plants plants.. The system system was design designed ed to be a generi genericc classification of the rubber polymers that would accommodate both existing and future rubbers. The chemical composition of the polymer chain was selected as the best classification proposal to achieve this goal. The rubber polymers were divided into seven classes as described in Section 2 of this practice. The letter symbol for the class was given last in the designation for the rubber. Preceding the class symbol were letter symbols to designate either the monomers used to prepare the polymer or the substituent groups on the polymer chain. The system has been successful both in accommodating the many new polymers developed since 1955 and in conveying to the user certain characteristics of the rubber associated with the chemical composition. 1. Scope Scope
Q—Rubb Q—Rubbers ers having having silico silicon n and oxygen oxygen in the polyme polymerr chain. T—Rubbers having sulfur in the polymer chain. U—Rubb U—Rubbers ers having having carbon carbon,, oxygen oxygen,, and nitrog nitrogen en in the polymer chain. Z—Rubbers having phosphorus and nitrogen in the polymer chain.
1.1 This practice practice covers a system system of general classificati classification on for the basic rubbers both in dry and latex forms determined from the chemical composition of the polymer chain. 1.2 The purpose purpose of this practice practice is to provide provide a standardi standardizazation of terms for use in industry, commerce, and government and and is not not inte intend nded ed to confl conflic ictt with with but but rath rather er to act act as a supplement to existing trade names and trademarks. 1.3 In techni technical cal papers papers or presen presentat tation ionss the name of the polymer should be used if possible. The symbols can follow the chemical name for use in later references.
3. Class Class Designations Designations 3.1 The “M” class includes includes rubbers having a saturated chain of the polymethylene type. The following classification shall be used: ACM—Copolymers of ethyl or other acrylate and a small amount of monomer which facilitates vulcanization. AEM—Copolymers of ethyl or other acrylates and ethylene. ANM—Copolymers of ethyl or other acrylate and acrylonitrile. CM—Chloro-polyethylene. CFM—Polychloro-trifluoro-ethylene. CSM—Chloro-sulfonyl-polyethylene. EOM—Copolymers of ethylene and an octene. EPDM—T EPDM—Terpolymer erpolymer of ethylene, ethylene, propylene, propylene, and a diene with the residual unsaturated portion of the diene in the side chain. EPM—Copolymers of ethylene and propylene. EVM—Copolymers of ethylene and vinyl acetate. FEPM—A FEPM—A fluoro fluoro rubber rubber of the polyme polymethy thylen lenee type type only only containing one or more of the monomeric alkyl, perfluoroalkyl, and/or and/or perfluo perfluoroa roalko lkoxy xy groups groups,, with with or withou withoutt a cure cure site site monomer (having a reactive pendant group). FFKM—Perflu FFKM—Perfluorin orinated ated rubbers rubbers of the polymethyl polymethylene ene type
NOTE 1—For terms related to thermoplastic thermoplastic elastomers, elastomers, see D 5538 Practice for Thermoplastic Elastomers – Terminology and Abbreviations.
2. Rubbers Rubbers 2.1 Rubbers Rubbers in both dry and latex form shall be classified classified and coded from the chemical composition of the polymer chain in the following manner: M—Rubbers having a saturated chain of the polymethylene type. N—Rubbers having nitrogen, but not oxygen or phosphorus, in the polymer chain. O—Rubbers having oxygen in the polymer chain. R—Rubbers R—Rubbers having an unsaturate unsaturated d carbon carbon chain, chain, for example, ample, natural natural rubber rubber and syntheti syntheticc rubbers rubbers derived derived at least partly from diolefins. 1 This practice is under the jurisdiction of ASTM Committee D11 on Rubber Rubber and is the direct responsibility of Subcommittee D11.08 on Terminology. Curren Currentt edition edition approv approved ed May 10, 2001. 2001. Publish Published ed Julyl Julyl 2001. 2001. Original Originally ly published published as D 1418 – 56 T. Last previous edition D 1418 – 00.
Copyright © ASTM, 100 Barr Harbor Drive, West Conshohocken, PA 19428-2959, United States.
1
D 1418 having all fluoro, perfluoroalkyl, or perfluoroalkoxy substituent groups on the polymer chain; a small fraction of these groups may contain functionality to facilitate vulcanization. FKM—Fluoro rubber of the polymethylene type that utilizes vinylidene fluoride as a comonomer and has substituent fluoro, alkyl, perfluoroalkyl or perfluoroalkoxy groups on the polymer chain, with or without a cure site monomer (having a reactive pendant group). Type 1—Dipolymer of hexafluoropropylene and vinylidene fluoride. Type 2—Terpolymer of tetrafluoroethylene, vinylidene fluoride, and hexafluoropropylene. Type 3—T 3—Terpo erpolyme lymerr of tetr tetrafluor afluoroethy oethylene, lene, a fluori fluorinate nated d vinyl ether, and vinylidene fluoride. Type 4—Terpolymer of tetrafluoroethylene, propylene and vinylidene fluoride. Type 5—Pen 5—Pentapo tapolyme lymerr of tetr tetrafluor afluoroeth oethylene ylene,, hexafl hexafluorouoropropylene propy lene,, viny vinyliden lidenee fluori fluoride, de, ethyl ethylene, ene, and a fluor fluorinate inated d vinyl ether. 3.2 The “O” cla class ss inc includ ludes es rub rubber berss hav having ing oxygen oxygen in the polymer chain. The following classification shall be used: CO—Polychloromethyl oxirane (epichlorohydrin polymer). ECO—Ethylene oxide (oxirane) and chloromethyl oxirane (epichlorohydrin copolymer). GECO—Epichlorohydrin-ethylene GECO—Epichlorohydrinethylene oxide-allylgl oxide-allylglycidylether ycidylether terpolymer. GPO—Polypropylene oxide and allyl glycidyl ether. 3.3 The “R” class shall shall be defined by inserting inserting the name of the mon monome omerr or mon monome omers rs bef before ore the wor word d “ru “rubbe bber” r” fro from m which it was prepared (except for natural rubber). The letter immediately preceding the letter R shall signify the diolefin from fr om wh whic ich h th thee ru rubb bber er wa wass pr prep epar ared ed (e (exc xcep eptt fo forr na natu tura rall rubber rub ber). ). Any let letter ter or let letter terss pre preced ceding ing thi thiss dio diolefi lefin n let letter ter signifies the comonomer or comonomers. A parenthetical letter (S),, for solution (S) solution,, or (E) (E),, for emulsion emulsion,, is use used d to ind indica icate te whet wh ethe herr th thee ru rubb bber er or la late tex x wa wass pr prep epar ared ed by so solu luti tion on or emulsion polymerization. The following classification shall be used for rubbers of the “R” class: ABR—Acrylate-butadiene. BIIR—Bromo-isobutene-isoprene BR—Butadiene. CIIR—Chloro-isobutene-isoprene. CR—Chloroprene. ENR—Epoxidized natural rubber. HNBR—Hydrogenated acrylonitrile acrylonitrile-butadiene. -butadiene. IIR—Isobutene-isoprene. IR—Isoprene, synthetic. NBR—Acrylonitrile-butadiene. NIR—Acrylonitrile-isoprene. NR—Natural rubber. PBR—Vinylpyridine-butadiene. PSBR—Vinylpyridine-styr PSBR—Vi nylpyridine-styrene-butadiene. ene-butadiene. SBR—Styrene-butadiene. SIR—Styrene-isoprene rubbers. 3.3.1 Rubbers of the “R” class having substitute substitute carboxylic acid (COOH) groups on the polymer chain shall be identified by the prefix “X”: XBR—Carboxylic-butadiene rubber
XSBR—Carboxylic-styrene-butadiene. XNBR—Carboxylic-acrylonitrile-butadiene. NOTE 2—When designating latex or latices the terminology shall be, for for example,“ SBR latex” or “SBR latices.”
3.4 The “Q” class shall shall be defined by inserting inserting the name of the substituent group on the polymer chain prior to the silicone design des ignati ation. on. The fol follow lowing ing cla classi ssifica ficatio tion n sha shall ll be use used d for members of the“ Q” class. (The M preceding the Q indicates that methyl is one of the substituent groups on the polymer chain.) FMQ—Si FMQ —Silic licone one rub rubber ber hav having ing bot both h met methyl hyl and fluo fluorin rinee substituent groups on the polymer chain. FVMQ—Silicone rubber having fluorine, vinyl, and methyl substitute groups on the polymer chain. PMQ—Si PMQ —Silic licone one rub rubber berss hav having ing bot both h me methy thyll and phe phenyl nyl substituent groups on the polymer chain. PVMQ—Silicone rubbers having methyl, phenyl, and vinyl substituent groups on the polymer chain. MQ—Silic MQ—S ilicone one rubb rubbers ers havi having ng only met methyl hyl subs substit tituent uent groups on the polymer chain, such as dimethyl polysiloxane. VMQ—Silicone rubber having both methyl and vinyl substituent groups on the polymer chain. 3.5 The “U” class includes includes rubbers rubbers having carbon, oxygen, and nitrogen in the polymer chain. The following classification shall be used: AFMU—T AFMU— Terpol erpolymer ymer of tetr tetrafluor afluoroethy oethylene, lene, triflu trifluoron oroniitrosomethane, and nitrosoperfluorobutyric acid. AU—Polyester urethane. EU—Polyether urethane. 3.6 The “T” class includes includes rubbers having having carbo carbon, n, oxygen, and sulfur in the polymer chain. The following classification shall be used for members of the “T” class: OT—A rubber having either a -CH 2-CH2-O-CH 2-O-CH2CH2 group or occasionally an -R-group, where R is an aliphatic hydrocarbon between the polysulfide linkages in the polymer chain. EOT—A EOT —A rubber rubber hav having ing a -CH2-CH2-O-CH 2-O-CH2-CH2 group and R groups that are usually -CH 2-CH2 but occasionally other aliphatic groups between the polysulfide linkages in the polymer chain. 3.7 The “Z” class includes includes rubbers having phosphorus phosphorus and nitrogen nitro gen in the polym polymer er chain chain.. The foll following owing classification classification shall be used: FZ—A rubber having a -P|CxN- chain and having fluoroalkoxy groups attached to the phosphorus atoms in the chain. PZ—A rubber having a -P|CxN- chain and having aryloxy (pheno (ph enoxy xy and sub substi stitut tuted ed phe phenox noxy) y) gro groups ups att attach ached ed to the phosphorus atoms in the chain. 3.8 Mix Mixtur tures es of rub rubber berss are identifie identified d by usi using ng the class design des ignati ations ons for the types of rub rubber berss in the mixture mixture.. If the composition is known, the major component is listed first; for exam ex ampl ple, e, a bl blen end d of NR NR/B /BR R in 60 60/4 /40 0 ra rati tio o is de desi sign gnat ated ed NR/BR. If the rubbers are present in equal amounts or if the proportion is unknown, the rubbers should be designated in alphabetical order; for example, BR/NR is used for a 50/50 ratio, and BR-NR is used for an unknown composition. 2
D 1418 4. Keyw Keywords ords 4.1 acro acronyms nyms for lati latices; ces; acronyms acronyms for rubber; nomenclanomenclature
APPENDIX X1. HISTORICAL NOMENCLATURE NOMENCLATURE
X1.1 X1. 1 The follow following ing terms terms have been been rem remove oved d from the main body of this standard because they are obsolete and no longer commercially available. This appendix will serve as an historical reference.
NCR—Acrylonitrile-chloroprene SCR—Styrene-chloroprene
The American Society for Testing Testing and Materials takes no position respecting the validity of any patent rights asserted in connection with any item mentioned in this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the risk of infringement of such rights, are entirely their own responsibility. This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years and if not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standards and should be addressed to ASTM Headquarters. Your comments will receive careful consideration at a meeting of the responsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you should make your views known to the ASTM Committee on Standards, at the address shown below. This standard is copyrighted by ASTM, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, Conshohocken, PA19428-2959, United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the above address or at 610-832-9585 (phone), 610-832-9555 (fax), or
[email protected] (e-mail); or through the ASTM website (www.astm.org).
3
