45085047 Charles Law Strategic Intervention Material in Chemistry

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GUIDE CARD

Understanding the different concepts governing the behavior of gasses (i.e. Ideal Gas) has always been focused by chemistry as it plays a very important role in our society, in the industry and in the different fields of our lives. In this Strategic Intervention Material, the student is subjected to a deeper understanding of Charles Law. After completing this SIM the learner is expected to: —? State and Define the Charles Law. —? cecognize the key concepts regarding the behavior of ideal gasses at constant pressure. —? Identify the applicability and limitations of Charles Law and its association with other physical concepts (e.g. Ideal Gas Law, Kinetic Theory & Absolute Zero). —? Solve practical problems involving Charles Law. Now you are ready to learn! Let us have the basics of Charles Law!

INTRODUCTION i
 
 (also known as the 
    ) is an experimental gas law which describes how gases tend to expand when heated. It was first published by French natural philosopher Joseph Louis Gay-Lussac in 1802, although he credited the discovery to unpublished work from the 1780s by Jacques Charles. The law was independently discovered by British natural philosopher John Dalton by 1801, although Dalton's description was less thorough than GayLussac's.[2] The basic principles had already been described a century earlier by Guillaume Amontons. Whatever the priority of the discovery, Gay-Lussac was the first to demonstrate that the law applied generally to all gases, and also to the vapours of volatile liquids if the temperature was more than a few degrees above the boiling point. His statement of the law can be expressed mathematically as: where @100 is the volume occupied by a given sample of gas at 100 °C; @0 is the volume occupied by the same sample of gas at 0 °C; and is a constant which is the same for all gases at constant pressure. Gay-Lussac's value for was 1 Ш2.6666, remarkably close to the present-day value of 1Ш2.7315. A modern statement of Charles's law is: ͞At constant pressure, the volume of a given mass of an ideal gas increases or decreases by the same factor as its temperature on the absolute temperature scale (i.e. the gas expands as the temperature increases).͟ which can be written as: where @ is the volume of the gas; and
is the absolute temperature. The law can also be usefully expressed as follows:

The equation shows that, as absolute temperature increases, the volume of the gas also increases in proportion.

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So at constant pressure, if the temperature (K) is doubled, the volume of gas is also (4)_______.

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4. A hypothetical gas which obeys Charles' Law at all temperatures and pressures is called an (5)_____ gas.

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  A. V1=20L, T1=10°C, V2=__L, T2=52°C B. The volume of a gas at a certain temperature is 224L. If a drop of 12°C will reduce the volume by 24L, what is the original temperature? D. V1=____mL, T1=10°C, V2=70L, T2=20°C E. Find the increase in temperature of a gas whose original volume and temperature is 150L and 100°C respectively, if the new volume is equal to 412.5L? F. If after the temperature is tripled the new volume of a gas is 1107L, find the original volume. G. V1=46mL, T1=Ɍ°C, V2=____mL, T2=9Ɍ°C H. V1=___mL, T1=10Ɍ°C, V2=10mL, T2=Ɍ°C L. 147 An ideal gas has a volume of 100L under the temperature of 100°C. If the temperature grows by 47°C, what is the new volume? M.V1=600L, T1=300°C, V2=__L, T2=315°C

j   A. V1=74mL, T1=____°C, V2=200mL, T2=300°C C. The volume of a given mass of gas, at 288K is 400 ml. At what temperature, will it occupy a volume of 600 ml? I. What is the new volume of a gas after the temperature is tripled if the original volume is 21667mL? J. The temperature is reduced by 2/3. If the original volume is 1737mL, what is the new volume? K. The temperature is squared. If the original volume is 20, find the new volume. L. The volume of a gas is 9L under a temperature of 90°C, if after applying heat the volume changes to 10.6L, find the new temperature? N. V1=1080mL, T1=300°C, V2=__mL, T2=200°C

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4. A hypothetical gas which obeys Charles' Law at all temperatures and pressures is called an (5)_____ gas.

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REFERENCE CARD 1.? Gay-Lussac, J. L. (L'An X ʹ 1802), "cecherches sur la dilatation des gaz et des vapeurs", j
    ë: 137. English translation. 2.? http://www.chemistryexplained.com/Fe-Ge/Gay-Lussac-JosephLouis.html 3.? Fullick, P. (1994), ISBN 0435570781.

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Heinemann,

pp. 141ʹ42,

4.? Clapeyron, E. (1834), "Mémoire sur la puissance motrice de la chaleur", è

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 ë$: 153ʹ90. Facsimile at the Bibliothèque nationale de France (pp. 153ʹ90). 5.? Thomson, William (1848), "On an Absolute Thermometric Scale founded on Carnot's Theory of the Motive Power of Heat, and calculated from cegnault's Observations", à    
 

 : 100ʹ6, http://zapatopi.net/kelvin/papers/on_an_absolute_thermomet ric_scale.html. 6.? Thomson, William (1852), "On the Dynamical Theory of Heat, with numerical results deduced from Mr Joule's equivalent of a Thermal Unit, and M. cegnault's Observations on Steam", à    


  ù. 7.? http://www.ausetute.com.au/charslaw.html