38.Advantages and Disadvantages of Various Plasticizers In Different Applications-Mr. Juergen Tri.pdf
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Advantages and Disadvantages of various Plasticizers in different Applications Jürgen Trimbach Hansen & Rosenthal
IRE 2011 Chennai, India 26.01.2010
Agenda
H&R – a short Introduction Plasticizers – some Basics Plasticizers in different Applications > PC Tyres > Truck Tyres > Transmission Belts > Profiles Conclusion
H&R, 2011, TRJ
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Introduction of H&R – the Highlights 1919 - Foundation of H&R in Hamburg, Germany 1956 - Tudapetrol, the H&R production site 1985 - First production of TDAE under the control of H&R 1994 - Merge of the Salzbergen refinery (BASF) 1996 - First production of MES under the control of H&R 2004 - Merge of the Hamburg refinery (BP) Investment in a large plasticizer production 2005 - Start of the new TDAE production Enlargement of the international production (Thailand, China, Australia, South Africa, …) 2009 - First H&R production in North America H&R, 2011, TRJ
Introduction of Hansen & Rosenthal – the Assets
Production and Tank farm for Process oils
Tank farm for Process oils
Blend plant
Sales office
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Introduction of H&R – the Highlights
Today, H&R is producing more than 350.000 mt label free plasticizers for rubber applications … plus Anti Ozone Waxes. From the top 10 of the tyre industry 10 are on H&R´s customer list. From the top 10 of the technical rubber good producers 10 are on H&R´s customer list.
H&R, 2011, TRJ
Introduction of H&R – the Product Portfolio
Viscosity @ 100 °C [mm²/s]
90 80 70
DAE
60
TDAE
50
MES
40
PAR
30
NAP
20
Plus Anti Ozone Waxes
10 0 0
10
20
30
40
50
Aromatic content [wt. %] H&R, 2011, TRJ
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Basics
Aromatic content [%]
50
DAE 40
TDAE 30
MES
20
NAP
10
RAE PAR
0 100
200
500
1.000
2.000
5.000
10.000
Molecular weight [g/mol] H&R, 2011, TRJ
Basics
PAR
NAP
AR
HAR
Synth.
BR NR/IR SBR IIR EPDM CR NBR PVC 0,80
0,85
0,90
0,95
1,00
Viskosität-Dichte-Konstante (VDK) H&R, 2011, TRJ
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Basics paraffinic
naphthenic
aromatic
highly aromatic
synthetic
BR NR/IR
EPDM CR NBR
DAE
MES
NAP
IIR
TDAE
SBR
RAE
PVC 0,80
0,85
0,90
0,95
1,00
constant of density and viscosity (VGC) H&R, 2011, TRJ
Plasticizers in different Applications
FILLER
RUBBER
CHEMICALS
OIL
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Performance of PC Tyres (Silica filled, SSBR/NdBR/NR)
H&R, 2011, TRJ
Performance of PC Tyres Productivity 110
DAE
100 90
Driving Comfort (after 30.000 miles)
80
Rolling Resistance 70 60
Braking wet and dry
Abrasion Loss (after 30.000 miles) H&R, 2011, TRJ
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Performance of PC Tyres Commission Regulation (EC) 1907/2006 (formerly EU Directive 2005/69/EC) „The ban of Polycyclic Aromatic Hydrocarbons“ starting 01.01.2010 Similar regulations in Japan and other countries This regulation affects more and more the production of technical rubber goods because more and more auto manufacturers require also „cancer free TRG“. H&R, 2011, TRJ
Performance of PC Tyres
EU Tyre Labelling Regulation 1222/2009 starting 01.11.2012 Similar regulations in North America, Japan and other countries
H&R, 2011, TRJ
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Performance of PC Tyres Productivity 110
DAE NAP
100 90
Driving Comfort (after 30.000 miles)
TDAE RAE
80
Rolling Resistance 70 60
Braking wet and dry Januar 11
Abrasion Loss (after 30.000 miles) © 2010 •H&R, Hansen 2011, & Rosenthal TRJ KG
15
Performance of Truck Tyres (CB, NR/NdBR/ESBR)
H&R, 2011, TRJ
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Performance of Truck Tyres Productivity
DAE
105
NAP/MES 100
TDAE RAE
95 90
Retreadability
Rolling Resistance 85 80
Braking wet and dry
Abrasion Loss (after 40.000 miles) H&R, 2011, TRJ
Transmission Belts (CR based, CB)
H&R, 2011, TRJ
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Performance of Transmission Belts Productivity
DAE
110
NAP 100
TDAE RAE
90
Heat Dissipation
80
Tear Resistance 70 60
Life Time
Tear Propagation rate H&R, 2011, TRJ
Profiles (EPDM based, Sulfur System)
H&R, 2011, TRJ
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Profiles Productivity
PAR
110
NAP (low CA) 100
MES TDAE RAE
90 80
Aging Properties
Compression Set 70 60
Abrasion Loss
Fatigue to Failure H&R, 2011, TRJ
Conclusion paraffinic
naphthenic
aromatic
highly aromatic
synthetic
BR NR/IR
CR NBR
DAE
EPDM
MES
NAP
IIR
TDAE
SBR
RAE
PVC 0,80
0,85
0,90
0,95
1,00
constant of density and viscosity (VGC) H&R, 2011, TRJ
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Plasticizers, Compatibility with Rubbers
DAE TDAE MES RAE NAP Veg. Oils Synth. WM PAR
EPDM
IIR
(X)IIR
BR
NR
SBR
CR
NBR
+ 0 +
+ 0 +
+ 0 0 0 0
+ + + 0 + 0 +
+ + + 0 + 0 +
+ + 0 0 0 0 -
+ + 0 0/+ -
0 0/+ -
H&R, 2011, TRJ
Last but not least
Do you have questions? Thank youany forfurther your attention
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