38.Advantages and Disadvantages of Various Plasticizers In Different Applications-Mr. Juergen Tri.pdf

Advantages and Disadvantages of various Plasticizers in different Applications Jürgen Trimbach Hansen & Rosenthal

IRE 2011 Chennai, India 26.01.2010

Agenda


H&R – a short Introduction
Plasticizers – some Basics
Plasticizers in different Applications > PC Tyres > Truck Tyres > Transmission Belts > Profiles
Conclusion

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Introduction of H&R – the Highlights 1919 - Foundation of H&R in Hamburg, Germany 1956 - Tudapetrol, the H&R production site 1985 - First production of TDAE under the control of H&R 1994 - Merge of the Salzbergen refinery (BASF) 1996 - First production of MES under the control of H&R 2004 - Merge of the Hamburg refinery (BP) Investment in a large plasticizer production 2005 - Start of the new TDAE production Enlargement of the international production (Thailand, China, Australia, South Africa, …) 2009 - First H&R production in North America H&R, 2011, TRJ

Introduction of Hansen & Rosenthal – the Assets

Production and Tank farm for Process oils

Tank farm for Process oils

Blend plant

Sales office

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Introduction of H&R – the Highlights

Today, H&R is producing more than 350.000 mt label free plasticizers for rubber applications … plus Anti Ozone Waxes. From the top 10 of the tyre industry 10 are on H&R´s customer list. From the top 10 of the technical rubber good producers 10 are on H&R´s customer list.

H&R, 2011, TRJ

Introduction of H&R – the Product Portfolio

Viscosity @ 100 °C [mm²/s]

90 80 70

DAE

60

TDAE

50

MES

40

PAR

30

NAP

20

Plus Anti Ozone Waxes

10 0 0

10

20

30

40

50

Aromatic content [wt. %] H&R, 2011, TRJ

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Basics

Aromatic content [%]

50

DAE 40

TDAE 30

MES

20

NAP

10

RAE PAR

0 100

200

500

1.000

2.000

5.000

10.000

Molecular weight [g/mol] H&R, 2011, TRJ

Basics

PAR

NAP

AR

HAR

Synth.

BR NR/IR SBR IIR EPDM CR NBR PVC 0,80

0,85

0,90

0,95

1,00

Viskosität-Dichte-Konstante (VDK) H&R, 2011, TRJ

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Basics paraffinic

naphthenic

aromatic

highly aromatic

synthetic

BR NR/IR

EPDM CR NBR

DAE

MES

NAP

IIR

TDAE

SBR

RAE

PVC 0,80

0,85

0,90

0,95

1,00

constant of density and viscosity (VGC) H&R, 2011, TRJ

Plasticizers in different Applications

FILLER

RUBBER

CHEMICALS

OIL

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Performance of PC Tyres (Silica filled, SSBR/NdBR/NR)

H&R, 2011, TRJ

Performance of PC Tyres Productivity 110

DAE

100 90

Driving Comfort (after 30.000 miles)

80

Rolling Resistance 70 60

Braking wet and dry

Abrasion Loss (after 30.000 miles) H&R, 2011, TRJ

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Performance of PC Tyres Commission Regulation (EC) 1907/2006 (formerly EU Directive 2005/69/EC) „The ban of Polycyclic Aromatic Hydrocarbons“ starting 01.01.2010 Similar regulations in Japan and other countries This regulation affects more and more the production of technical rubber goods because more and more auto manufacturers require also „cancer free TRG“. H&R, 2011, TRJ

Performance of PC Tyres

EU Tyre Labelling Regulation 1222/2009 starting 01.11.2012 Similar regulations in North America, Japan and other countries

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Performance of PC Tyres Productivity 110

DAE NAP

100 90

Driving Comfort (after 30.000 miles)

TDAE RAE

80

Rolling Resistance 70 60

Braking wet and dry Januar 11

Abrasion Loss (after 30.000 miles) © 2010 •H&R, Hansen 2011, & Rosenthal TRJ KG

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Performance of Truck Tyres (CB, NR/NdBR/ESBR)

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Performance of Truck Tyres Productivity

DAE

105

NAP/MES 100

TDAE RAE

95 90

Retreadability

Rolling Resistance 85 80

Braking wet and dry

Abrasion Loss (after 40.000 miles) H&R, 2011, TRJ

Transmission Belts (CR based, CB)

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Performance of Transmission Belts Productivity

DAE

110

NAP 100

TDAE RAE

90

Heat Dissipation

80

Tear Resistance 70 60

Life Time

Tear Propagation rate H&R, 2011, TRJ

Profiles (EPDM based, Sulfur System)

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Profiles Productivity

PAR

110

NAP (low CA) 100

MES TDAE RAE

90 80

Aging Properties

Compression Set 70 60

Abrasion Loss

Fatigue to Failure H&R, 2011, TRJ

Conclusion paraffinic

naphthenic

aromatic

highly aromatic

synthetic

BR NR/IR

CR NBR

DAE

EPDM

MES

NAP

IIR

TDAE

SBR

RAE

PVC 0,80

0,85

0,90

0,95

1,00

constant of density and viscosity (VGC) H&R, 2011, TRJ

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Plasticizers, Compatibility with Rubbers

DAE TDAE MES RAE NAP Veg. Oils Synth. WM PAR

EPDM

IIR

(X)IIR

BR

NR

SBR

CR

NBR

+ 0 +

+ 0 +

+ 0 0 0 0

+ + + 0 + 0 +

+ + + 0 + 0 +

+ + 0 0 0 0 -

+ + 0 0/+ -

0 0/+ -

H&R, 2011, TRJ

Last but not least

Do you have questions? Thank youany forfurther your attention

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