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S E C TI O N 1: 1 : I den denti tifi fi c atio ation n of the s ubs tanc tance/ e/mi mixx tur ture e and of the company co mpany / undertaking - 1.1 Product identifier - Trade name: TB 12 1227 27 - 1.2 R el eleva evant nt ide ident ntified ified us es of the subs tance tance or mixture an and d us es advis ed ag ains t - S ector of Us e SU3 Industrial uses: Uses of substances as such or in preparations preparation s at industrial industri al sites - Pr oduct ca cate tegg ory PC1 Adhesives, sealants - A pplicatio ppli cation n of the s ubs tance Silicate sealing / the mixtur mix ture e - 1.3 Details of the s upplier of the s afet afetyy dat data a s heet THREE BOND EUROPE S.A.S - Manufac Manufactur turer/Su er/Su pplier ppli er:: B.P 9105 95073 CERGY PONTOISE FRANCE - Inf Information ormation department: department: - 1.4 Emerg ency teleph telephone one
number:
TEL : 33 (0)1 34 32 39 60 FAX : 33 (0)1 34 32 39 61
Three Bond Europe H&S department : ms : ms
[email protected] [email protected] Site : : http://quickfds.com http://quickfds.com ORFILA (France) - Tel : +33 (0)1 45 42 59 59 (24h) Ireland - Tel : 00 353 1 8092568 - 00 353 1 8379964 (24h/24) EU Tel : 112
S E C TI TION ON 2: 2 : Haza H azard rdss i dentif dentific ic at atii on - 2.1 C lass las s if ifii catio cation n of the ssubs ubs tance or mi xtur e - Class ific ation a according ccording to Reg ula ulattion (E C) No 1272/ 1272/200 2008 8 GHS07 Eye Irrit. 2 H319 Causes serious eye irritation. - 2.2 L abel elements - Labe Labell lling ing according to
R eg ulation ulation (E C ) No 1272/ 1272/2008 2008 The product is classified and labelled according to the CLP - Haza Hazard rd pi ctog rams
regulation.
GHS07 - S ig nal word - Hazard sta s tatem tements ents - P recautiona recautionary ry s tate tatement mentss
- A ddition ddi tional al infor in for mati mati on:
Warning H319 Causes serious eye irritation. irritation. P280 Wear protective gloves / eye protection. protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and an d easy to do. Continue rinsing. EUH208 Contains 3-aminopropyltriethoxysil 3-aminopropyltriethoxysilane. ane. May produce an allergic reaction.
- 2.3 Other Oth er hazards hazar ds - R esul esults ts of PB T a and nd vPvB as s ess me ment nt - PBT : Not applicable. - vPvB: Not applicable.
GB
(Contd. on page 2)
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Trade name: name: TB 1227 (Contd. of page 1)
S E C TI TION ON 3: 3 : C ompos i tion/ tion/ii nfor ma mation tion on ing in g r edi edients ents - 3.2 Mi x tures tur es - Description: - Dangerous comp componen onents: ts:
Mixture of the substances listed below with nonhazardous additions. (**) Liberates methanol on exposure to humid air.
trimethoxyvinylsilane Acute Tox. 4, H332 CAS: 2530-83-8 [3-(2,3-epoxypropoxy)propyl]t [3-(2,3-epoxypr opoxy)propyl]trimethoxysi rimethoxysilane lane EINECS: 219-784-2 Eye Dam. 1, H318; Aquatic Chronic 2, H411 CAS: 919-30-2 3-aminopropyltriethoxysilane EINECS: 213-048-4 Skin Corr. 1B, H314; Acute Tox. 4, H302; Reg.nr.: 01-2119480479-24-XXXX Skin Sens. 1, H317 CAS: 67-56-1 methanol EINECS: 200-659-6 Flam. Liq. 2, H225; Acute Tox. 3, H301; Acute Tox. 3, 3 , H311; Acute Acut e Tox. 3, H331; H33 1; STOT SE 1, H370 CAS: 2768-02-7 EINECS: 220-449-8
- S V HC - A ddition ddi tional al infor in for mati mati on
2.5 –10% ≥1 –2,528 mg/kg (rat)
LD50 17,100 mg/kg (rabbit) Inhalative LC50/4 h 128.2 mg/l (rat) Dermal
- P ri ma mary ry ir ri ta tant nt e effect: ffect: - S k i n corr cor r os i on/ir on/ir ri tati tati on Based on available data, the classification criteria are not met. - S eri ous eye dama damagg e/i e/i rr i tat tatii on Causes serious eye irritation. - R espira espirattory or ski n s ens iti s ation Based on available data, the classification criteria are not met. - C MR effects effects (carcinog enit enity, y, mut muta ag enicity an and d to toxic xic ity for r ep eproduction) roduction) - G erm cel celll m muta utagg enici ty Based on available data, the classification classification criteria are not met. - Carcinogenicity Based on available data, the classification classification criteria are not met. - R ep eproductive roductive toxici toxici ty
Based on available data, the classification classification criteria are not on met. 6) (Contd. page GB
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Trade name: name: TB 1227 - S TO TOT-s T-s ing in g le expos ur ure e - S TO TOT-r T-r epeated expos expo s ur e - A s pir pi r at atio ion n hazard
(Contd. of page 5)
Based on available data, the classification classification criteria are not met. Based on available data, the classification classification criteria are not met. Based on available data, the classification criteria are not met.
S E C TI TION ON 12: 12 : E co colog log i cal infor ma mation tion - 12.1 Toxicity - A quatic tox i ci ty:
67-56-1 methanol LC50/96h 15.4 mg/l (Leopomis macrochirus) CE50/48h >10,000 mg/l (daphnia) CE50/96h 22 mg/l (Selenastrum capricomutum) - 12.2 Pers is tence tence and
degradability No further relevant information available. - 12.3 B ioaccumula ioaccumulative tive No further relevant information available. potential potenti al No further relevant information available. - 12.4 Mobilit Mobilityy in s oil - A ddition ddi tional al eco ecolog log i cal in infor for mati mati on: - General notes: - 12 12.5 .5 Results Results of PB T a and nd vPvB - PBT : - vPvB: - 12.6 Other Other advers e effe effects cts
Generally not hazardous for water.
as ses s me ment nt
Not applicable. Not applicable. No further relevant information available.
S E C TI TION ON 13: 13 : D is pos al con conss i deratio derations ns - 13.1 W aste treatm treatment ent methods - R ecomm Must be specially treated adhering to official regulations. ecommenda endation tion - Uncle Unclea aned pa packag ckag ing s : - R ecomm ecommenda endation: tion: - R ecommended ecommended clea cleans ns ing
agent:
Dispose of packaging according to regulations on the disposal of packagin gs. packagings. Alcohol
S E C TI TION ON 14: 14 : Trans T rans por portt i nfor mat matio ion n - 14.1 UN-N umbe umber r - A D R /R I D /A D N, A D N, I MDG MD G , IA TA
Void
- 14.2 UN proper proper s hipping name name - A D R /R I D /A D N, A D N, I MDG MD G , IA TA
Void
- 14.3 Transport hazard class(es) - A D R /R I D /A D N, A D N, I MDG MD G , IA TA - Class
Void
- 14 14.4 .4 Packing Packing g roup - A D R /R I D /A D N, I MDG MD G , IIA A TA
Void (Contd. on page 7) GB
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Trade name: name: TB 1227 (Contd. of page 6)
- 14.5 E nvir onme onmenta ntall haza hazards rds : - Mari ne pollutant:
No
-
Not applicable.
14.6 Special precautions precautions for us er - 14.7 Transport in bulk bulk according to Annex II of Marpol Marpol a and nd the the IB C C ode Not applicable. - Trans port/A port/A dditiona dditionall infor mation: mation:
Not dangerous specifications.
- UN " Model Model R egula egulation tion"" :
Void
according
to the above
S E C TI TION ON 15: 15 : R eg ulatory infor i nfor ma mation tion - 15.1 S afe afety, ty, hea healt lth h and e envir nvir onmenta onmentall reg ula ulations tions /legi s lation lation s pecifi c for the subs tance tance or
mixture
- Di rectiv e 2012/ 2012/18/ 18/E E U - Nam Named ed dang erous
s ubs tances - A NN E X I
- R EG ULATION ULATION ((EC EC ) N No o
1907/200 1907/ 2006 6 A NNE X XV II - 15.2 C hem hemic ic al s afety afety assessment:
None of the ingredients is listed. Conditions of restriction: 3 A Chemical Safety Saf ety Assessment Assess ment has not n ot been carried ca rried out.
S E C TI TION ON 16: 16 : Other O ther infor i nfor mat matio ion n This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. - R el elevant evant phrases
H225 Highly flammable liquid and vapour. H301 Toxic if swallowed. H302 Harmful if swallowed. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H318 serious eye damage. H331 Causes Toxic if inhaled. H332 Harmful if inhaled. H370 Causes damage to organs. H411 Toxic to aquatic life with long lasting effects.
- A bbrevi bbr evi at atio ions ns and a acr cr ony onyms ms : RID: Règlement international concernant le transport des marchandises
dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) ICAO: International Civil Aviation Organisation ADR: Accord europée n sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) DNEL: Derived No-Effect Level (REACH) LC50: Lethal concentration, 50 percent (Contd. on page 8) GB
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Trade name: name: TB 1227 (Contd. of page 7) LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic SVHC: Substances of Very High Concern vPvB: very Persistent and very Bioaccumulative Flam. Liq. 2: Flammable liquids – Category 2 Acute Tox. 3: Acute toxicity – Category 3 Acute Tox. 4: Acute toxicity – Category 4 Skin Corr. 1B: Skin corrosion/irritation – Category 1B Eye Dam. 1: Serious eye damage/eye irritation – Category 1 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 Skin Sens. 1: Skin sensitisation – Category 1 STOT SE 1: Specific target organ toxicity (single exposure) – Category 1 Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2 GB
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