1.pdf

novAA 350 Operator:

Page 1/4

22/04/2016 14:59 Laboratory: De Benikhalled

Mm Farida Karoui

Method Parameters Technique: Flame Name: Created: Comment:

fe04016 22/04/2016 14:18

Version: Operator:

1 Mm Farida Karoui

Lines Line

Elem. Wavel. [nm] Fe 248.3

Fe248

Optic. mode Lamp

Current [mA] 4

Single-beam HCL

Boost [mA] -

Slit [nm] 0.2

Meas time. PMT [V] [s] 3.0 300

Evaluation/Background correction Line Fe248

Background corr. D2 background

Int.mode AZDK Mean off

Smooth strong

D2 cur. [mA] HC/BC rat. -

Flame Parameters Type: Burner type: Line

C2H2/air 50 mm C2H2/air [L/h] 65

Fe248

Ox. control: Burner angle:

off 0 deg

Nebulizer rate:

0 mL/min

Burner height [mm] 6

Sample Transport Autosampler: Dilution if conc. exceeded: Injection switch: Wash:

Yes none

Delay time:

5s

No after sample

Wash time:

5s

std. cal.

Std. prep.:

manual

Mixing cup cycles: 1

Calibration Method:

Calibration Curve Parameters Line Calib.func.. Intercept Fe248 linear calculate Calibration table

Weighting none

No.

Type

Pos

Rec

1 2 3 4

Cal-Zero1 Cal-Std1 Cal-Std2 Cal-Std3

1 2 3 4

-

Check none

Unit mg/L

Fe [mg/L] 0 2 3 4

Statistics Parameters Statistics: Repl./sample: Pre-runs: ASpect LS 1.5.0.0

Mean stat. 3 0

CI calc.: absolute Repl./calib.sample: 3 Grubbs test: off

conf. level: Repl./QC:

95.4% 3

Analytik Jena

novAA 350 Operator:

Page 2/4

22/04/2016 14:59 Mm Farida Karoui

Laboratory: De Benikhalled

QCS Parameters No entries exist

QCC Parameters RSD/RR% check:

ASpect LS 1.5.0.0

Calib. check:

Recal. check:

Analytik Jena

novAA 350 Operator:

Page 3/4

22/04/2016 14:59 Laboratory: De Benikhalled

Mm Farida Karoui

Results Results file: Instrument: Comment: Line Load method

C:\Use...\Results-16-04-22 1426.tps novAA 350 # Technique: Mean fe04016 (1)

SD

Flame

RSD[%]

Flame on

CI

Unit Date:

Rem. 22/04/2016 14:26

Date:

22/04/2016 14:26

Autozero

fe04016(1)

SIM

Date:

22/04/2016 14:27

Fe248 Cal-Zero1

fe04016(1)

SIM

Date:

22/04/2016 14:27

Fe248 Conc.1 Abs.

0 0.00011

mg/L 0.00010

89.4

Single values (Abs.): #1: 0.00001 #2: 0.00012 #3: 0.00021 (SEV: 300V) BG (Abs.): #1: -0.00007 #2: 0.00010 #3: -0.00013 Cal-Zero1 Fe248 0.004 Abs.

0.003 0.002 0.001 0.000 0

1

2

3

Time [s]

Cal-Std1

fe04016(1)

Fe248 Conc.1 Abs.

2 0.47514

SIM

Date:

22/04/2016 14:27

mg/L 0.00039

0.1

Single values (Abs.): #1: 0.47551 #2: 0.47475 #3: 0.47517 (SEV: 300V) BG (Abs.): #1: 0.00010 #2: 0.00016 #3: -0.00010 Cal-Std1 Fe248 0.5

Abs.

0.4 0.3 0.2 0.1 0.0 0

1

2

3

Time [s]

Cal-Std2

fe04016(1)

Fe248 Conc.1 Abs.

3 0.71241

SIM

Date:

22/04/2016 14:27

mg/L 0.00047

0.1

Single values (Abs.): #1: 0.71278 #2: 0.71256 #3: 0.71189 (SEV: 300V) BG (Abs.): #1: -0.00011 #2: -0.00003 #3: 0.00005 0.8

Cal-Std2 Fe248

Abs.

0.6 0.4 0.2 0.0 0

1

2

3

Time [s]

ASpect LS 1.5.0.0

Analytik Jena

novAA 350

Page 4/4

22/04/2016 14:59

Operator:

Laboratory: De Benikhalled

Mm Farida Karoui

Line Cal-Std3

Mean fe04016(1)

Fe248 Conc.1 Abs.

4 0.95036

SD

RSD[%] SIM

CI

Unit Date:

Rem. 22/04/2016 14:28

mg/L 0.00022

0.0

Single values (Abs.): #1: 0.95014 #2: 0.95036 #3: 0.95057 (SEV: 300V) BG (Abs.): #1: -0.00006 #2: 0.00008 #3: 0.00004 Cal-Std3 Fe248 1.00

Abs.

0.75 0.50 0.25 0.00 0

1

2

3

Time [s]

Compute calib.

Fe248

Date:

22/04/2016 14:28

Date:

22/04/2016 14:28

Fe248 R²(adj.): 0.999999442 Slope: 0.23753 Abs./mg/L Char.conc.: 0.01836 mg/L/1%A Method SD: 0.00090 y=a+bx a=0.0000623 b=0.2375303 mg/L Fe248 1.00

3

Abs.

0.75

2

0.50

1

0.25

0.00

Z 0

1

Sample

2 Conc. [mg/L]

3

4

fe04016(1)

Pre-DF: 1 Fe248 Conc.1 Conc.2 Abs.

SIM

Wt.[g]: 2.946 2.946 0.69990

Vol.[mL]: 100 0.0026 0.0026 0.00062

AS-DF: 1.0

0.1 0.1 0.1

0.0028

Blank corr.:

off

mg/L mg/L

Single values (Abs.): #1: 0.70049 #2: 0.69997 #3: 0.69925 (SEV: 300V) BG (Abs.): #1: 0.00025 #2: 0.00009 #3: 0.00004 0.8

Sample Fe248

Abs.

0.6 0.4 0.2 0.0 0

1

2

3

Time [s]

Flame off

Date:

22/04/2016 14:28

Lamp off

Date:

22/04/2016 14:28

Cleaning

Date:

22/04/2016 14:28

Clean system

Date:

22/04/2016 14:28

Clean system

Date:

22/04/2016 14:28

ASpect LS 1.5.0.0

Analytik Jena