13 i 14-11-2013 Puferi
December 20, 2018 | Author: bilinda_butcher | Category: N/A
Short Description
d...
Description
a r e f u p a j i c i n i f e D . 1
i l i u j n e ž a l b z a r i r p t s o n d e r v H p u n . l a a t s z a b o i n l ž i i l a b i n i r l p e s i u j k a a v n a i ž r č i l d o o k i j h o i k n i e r č o i v n t a s r a g r o u u s k i t r e a f u d o P d
i l a , u j u g a e r e n o n . b a o r s o u v đ e z m e g j u o r k , z u t e n e n n o o p m o k u n z a u b i a r u t l u e s e i k n e a ž r t d s a s o a n u d e g o j v m o u l s U u s
a n z a b - a , k a m a j o m i n i z o , a a m b a m m i a j l o i i k c n a a r j o j t n i m e n t o t c a a n d o t e o k c a d m a a i s n n i j e l j a e u č s g a i n a k z a r e u n t a , e t r n ć a r n e p i s i . . o n r p m z p a m o n o b n ( i k l o e e k k l a i s i s t e n s k s i i i l r e m e K o t s i . k ) k k r a n j a i o a n j a k m v e m t o o n u a g j e d u d i j n o e n o d o v a m a K n a s
2
�
] A H [ g o l −
a
) a z a b a n a v o g u j : u n o k e ( m o s s e u r n e j a n s i r u o n i v l t s e s a i r k u s b r a e l u s •
] ] A A H [ [
) a n i l e s i k a n a v o g u j n o k ( o s u n e j n i u z a b u b a l s
a
K = ] H [
+
K g o l −
=
] H [ g o l -
+
] ] A A [ H [ g o l +
a
K p =
H p
: ] u ] k i H l A [ b o ] H [ m A [ e t š = p a o U K
: a n i č a n d e j h c l a b l e s s a H n o s r e d n e H
] a z a b ] a a n n a i l ] v e a s ] n o i g k o i u [ s l e j s [ i n o k k [ [ g g o o l l +
a
i t s o n d e r v H p i r o t a l u g e r i r e f u P
a j n a v a d e r p j a ž r d a S
a
K p
K p
=
=
H p
H p
+
•
1
a r e f u p g a r o a e k a n f s r t u e u p f a e t u n e c a p a t i e r c m H e a i r f p r a p e f j c u a a f p a a k u g n e a p ć v i i v t e a u a n s a s v j j r a n j s t r a e a e s a r f e č u d j a f u e č a v u a p n m d n p r o z a o a z g g j i a i z i s e d i i r k c n p s o m r i e e a o š n e h r r o o i l f n p m o b i e e e H i r i r z D M p B I P P . . 3 . 4 . 5 . 6 . 7 . 8 . 1
+
3 1 0 2 1 1 4 1 , 3 1
3
a n i č a n d e j h c l a b l e s s a H n o s r e d n e H . 2
e n i l e s i k e b a l s o s a n i l e s i k a b a l S
O O C 3 H C a N H O O C 3 H C u r e m i r p a n
o s a c a c o s a n u p t o p
) a j i c k a e r a n l i b i z r e v e r (
-
-
3
a → 3
a
O O C 3 H C + + H ⇄
H O O C 3 H C
] ] H H [ ] O O O O C 3 C 3 H H C [ C [
+
� � � � � � � ) � � � � � � � � � � � � � � � � č � � � � � � � � � � � � � � � � � � � � � � � � � � ( � � � �
=
) H O O C 3 H C ( a
K
i H O O C 3 H C l o m 5 0 , 0 i ž r d a s . l 5 m 0 1 0 × 0 5 8 , u 1 = i j o H O k O C a 3 r e H C f a u p K a . r o O v O t s a 3 r C H H p C a i t N a l n o u č m a r 1 , z 0 I . 1 r e m i r P
�
] ] B [ H B [ g o l ]
�
+
] ] H B ] [ B ] [ g B [ H − o B l [ b H − g B K ] o l g [ g H b ] o + o O K B l l ) [ H B − p p + [ H − b = B b ( w ] w a K K p K K K p p = H p = ] O = = = [ H H H g H O H o p p p p O l [ +
+
+
,
4 0 , 5
=
] a ] ] a z a a i n n ] i b l o . l e j s e s [ s n i i o k k [ k [ [ g g o o l l +
a
+
a
K p
K p
=
=
H p
H p
l l / / l l o o m m 1 2 , , 0 0 = = l o l l o l m 5 m 5 , , 5 0 1 , 0 0 , 0 0 = = ] ] H O O O C 3 O H C 3 C H a C [ N [
: a n i č a n d e j H H
g o
2
=
4 7 , 4 = a K g o l = a K p
2 , , 1 0 0 g o
2 g o l
=
1 , 5 , 0 0 0 g o l +
4 7 , 4
=
a
p =
p
O O C 3 H C a N
] H ] O [ ] B [ H B [ −
+
=
H O O C 3 H C
: a v o n n l g o o m l + a j a o r K b p o = k e H r p p i l I
! ! ! a j i c a r t n e c n o k o t s e m u , H p e a j a z a z a a n n a n i b i l a b l . e . j j V e s v s V n i n i a o k o k k k n n u n n n č g a g r : o o ) z l l i a + + v a z l o a a i o n K K i m p č p j a = o = n r d b H e ( H j p p u e n i e s č i l a o r e k f i t u p i t s d r o k v u o u g m a o S m
−
4 7 , 2 4
,
+
−
+
+
O ] O H C O O H C 3 C a H N C [ g o
+
=
+
,
+
=
) B ( b
: a n i č a n d e j h c l a b l e s s a H n o s r e d n e H
] a n i l ] e a s z i a k b j . [ n o k [ g o l
] a ] z o a [ s b [ g o l
+
+
a n i l e s i k / a z a : b . d o n i o s k i v a z a s a a o n r e K f p d o u • • p H p
I
a
K p
K p
=
=
H p
H p
K
: u k i l b o m e t š p o U
�
c c A a A a N N l l / / l o l o m m 2 , 4 , 0 0 – – c c : A t A s H H o n l l / d / l e o l o r v m m 1 , 2 H , p 0 0 u . I . t s I I i r r e f e u f j a P u u m P
a
�
e z l a b C 4 e H b a N l s - 3 o s H - N u a z r a e m b i p a r b a a n l S
) i l o s a j i c a j i c o s i d a n u p t o p (
) a j i c k a e r a n l i b i z r e v e r (
] 3 H 4 N [
+
=
-
l
H O +
C + 4 + H + 4 N H ⇄ N O 2 → H l C 4 + 3 H H N N
� � � � ) � � � � � � � � � � � � � � � č � � � � � � � � � � � � � � � � � � � � � � � � � � � ( � � �
) 3 H N ( b
K
0 1
i 3 H N l o m 1 , 0 i ž r d a s l m ] 0 a 0 n i 5 . ] l e a u 5 s z i i 0 a k j 1 b o . × [ j k 8 n a , o r 1 k e [ = f ) g u o p 3 H l N a ( + r b o a K v t K . s p a r l C = 4 H H H p N p i t l a o n u m č 5 a r , z 0 I 0 . 2 r e m i r P
] l ] 3 C H 4 N H [ N [
l / l o m 2 , 0 = l o l m 5 , 1 , 0 0 = ] 3 H N [
) 4
H N ( a
=
l / l o m 1 , 0 = l o l m , 5 5 0 , 0 0 = ] l C 4 H N [
4 7 4 ,
=
b
K g o l − =
) 3 H N ( b
K p
a r e f u p a v t s j e d m a z i n a h e M . 3
6 2 9 ,
=
b
K p − 4 1 =
)
+
4
H N ( a
K p
a m o e v e s a r e f u p t s H p o n a d z a e r b v h i H k a p j u i n l i l a t a s n i o l n e s ž i i k l b i h r i p k a a j v a a n ž i r č d i l o a z k r e h f i l a u p m a u j k n t a e d o m o d l i r a P m
e t e a k d a o j d e a t a m d i o n o d j - a m H i O n o a j s + e H j u a g s a ) e r a z a a r b a p a n g a o v n o a g v u o j g n u k o j n ( o a k t n ) e a n n i o l p e s i m k o ( k a a t g n e u r n d o p a , m e o z k a e n b i a l n e e d s k i e a J j k
o k s n i l e s u z i a k i n u a v a o g u j u n n o k e i n s t u s u i r p a o u t š t o a k a o t e i t s o a n t r d u e e r v n H p i n e m o r p e r i p o r e s a p r e n f u z P a
�
: a n i č a n d e j h c l a b l e s s a H n o s r e d n e H
] a n i l ] e a s z i a k b j . [ n o k [ g o l
] a ] z a a i n b l . j e s n i o k k [ [ g o l
+
+
a
a
K p
K p
=
=
H p
H p
u ) t i s d o o n v d a e n r v e K n = a n e č s K i l o u b r n K e a č e t i f i ( c b u a o l p u r ( e u e u f r r e u z e n i p f i l e u e m s p s o i n m a k t v a a o a t t n n e n č u c a a č t a j i s r u n a n z o i o H , k m a O a a k O u m s a + 4 l C n e 3 i l b H H e a s C N t i k - , a K
1 1
2 =
2 =
2 , , 1 0 0 g o l + 6 2 , 9 = ] l ] 3 C 4 H H N [ N [ g o l
, 5 0 , 0 g o l
+
)
+
: i o t š o t s I
2 1
4
H N ( a
K p =
H p
+
6 2 , 9
= 3
H N
: a v o l o m a j o r b o k e r p i l i
l C 4 H N
n g o l +
)
+
4
H N ( a
K p =
H p
6 5 , 9
= 3 , 0 + 6 2 , 9 = 2 g o l + 6 2 , 9 = H p
� � � � � � � � � � � � � , � � � � � � � � � � � � � � � � � � � � � � � � � � . � � � � � � � � � � � � � � � � � � � � �
! ! ! e z a b e k a j i l i e n i l e s i k e k a j a k t a d o d e l s o p a r e f u p u v a t s a s u e n e m o r P
i t i l n i l e C n o H p m h i o t k a d a o j i d . c a c r t n n o k e c n d o o k e a ć e e . v n e m a r j i o e r f n j p a h u p č i a l H n z a m p u u o j s d a j a i r n e z e f a l u o m p e d i n t a n o g e n e i t n č o b p g e o j m b o o z k k , . H a r c e n O f o a u K N p
-
+ � � � � � � � � � � � � � � � � � �
A A H l C H
� � � � � � � � � � � � � � � . � � � � � � . � � � � � � � � � �
�
� � � � � � � � � � � � � � � � � � �
� 1
-
A A H
A H → -
A + + H -
H O a N
H O + A H
-
-
A A H
←
A + O 2 H
� � � � � � � � � � � � � � , � � � � � � � � � � � � � � � � � � � � � � � � � � � � . � � � � � � � � � � � � � � � � � �
u d o v u e n j a n v e o đ l e i r t s o e p d e j u u r H t s u O l a i N e j i l l i o l b j C a n H i e t s n i o č n i l d o e r v k e t s H i p u e k j t o a v d s o i d n a r r i p b i d t o s u o n a d r e e r f v u p H t p s o e r e n n f s e u a m p k i o f r u E p i
� 1
a c i n H p i d e a j n e H p m o r 5 P ±
u d o v u n a v o l i t s e d u H O a N i l C H k a t a d o D
7 = H
a d o v a n a v o l i t s e D a
l C H l o m 1 0 , 0 + e d o v e n a v o l i t s e d l 1 ) b
M 1 0 , l C 0 + = l C + H H c = 2 → ] l = C + H H H [ p
3 1
: i ž e t o n v a r a n e s a v i n s a z a r e f u p g o n t a t e c a o v t s j e D
) � � � � � � ( . - � � O � � O � C 3 � � � H � C �
+ +
H ⇄ . H � � O � O � � C 3 � � � H � C �
a j i c a a r j t i n c e a r c t n n o e k c n e s o k e j e l u s j C n a e j a N u j m + s n ( a H H o m O n s : O ( O s O : e ) ) C C o 3 d 3 v H a O e H O H l C n O C a a C n O 3 → r C e H 3 → a r H O m C O o . l H e O C m p c C . C O O : 3 a o u n e H N C p c H n o n C ž 3 i o e k u k H č a t ž a e a C a n N o v t n d a v o v + + e ć a j l a n + e ć r v C e v i H k a l v o H r H b p l o o O p a i C a a k s H N H l u k O k O k a a O e O t t l a C a C o d 3 d 3 M o H o H D C D C
O 2 H + O O C 3 H C →
-
O 2 H + O O C 3 H C a N
H O : e + i n č H a n O d e O j C 3 k i H l b o C i
→
H O a N + H O O C 3 H C k s l u k e l o M
) � � � � � � ( � � � � � � � � � �
: i ž e t o n v a r a n e s a v i n s a z a r e f u p g � o � � n � č a � j � i � � n � o � m a o v t s j e D
-
H O +
+ 4
H N l H ⇄ C O a H N
O 2 H + 3 H N
, H N a i c a r t n e c n o k e s e u n a m + 4 s H o N n s e → d 3 a H n a N r e + + m o H : u + ) ž 4 e t H o n N v . a r c n l o C k H a v k ć a a t a e d v o o p D a
H O a N l o m 1 0 , M 0 2 + H 1 0 1 , O 0 = e d + = H o p + v a H O a e N N n c a → = 2 v o H ] l = i t H O s H e a O O d l N [ p 1 ) c
� 1
, 4
l C 4 H N → 3
H N + l C H : e n i č a n d e j k i l b o i k s l u k e l o M
a c a r t n e c n o e s e u O n 2 a H m s + 3 o H v N e a → n a H r e O m + o + 4 p u H e : N t ) o 3 n H v a r N . c n o a k a v ć a a a e v o o p a
l C a N + O 2 H + 3 H N →
: e n i č a n d e j k i l b o i k s l u k e l o M
H O a N + l C 4 H N
� 1
l C H l o m 1 0 , 0 + a r e f u p r a t i l 1 ) b
O O C 3 H C a N o n s o n d o - , O O C 3 H C e j u g a e r l C H m o t a d o d a S
) O O C 3 H C a N l / l o m 1 , 0 / H O O C 3 H C l / l o m 1 , 0 . r p n (
r e f u p i n t a t e c a u H O a N i l C H k a t a d o D
l C a N + H O 1 O 1 , 0 , C 3 0 0 + H C
2 8 , 0 g o l +
4 7 , 4
1 1 , 0
=
9 1 0 , , 1 0 0 g o l
⇄
O O 1 C 3 1 , , 0 H 0 0 C a N + 1 l 1 0 , C 0 , H 0 0 ) l / l l / l o o m m ( a k a n e t e m č o o r P P
r e f u p i n č a j i n o m a u H O a N i l C H k a t a d o D
+
4 7 , 4 = ] ] O H O O C 3 O H C 3 C a H C N [ [ g o l
9 0 , 0
0 ) l / l o m ( a ž e t o n v a R
+
a
K p =
H p
5 6 , 4 = 9 0 , 0 4 7 , 4 = H p
0 2
) l C 4 H N l / l o m 1 , 0 / 3 H N l / l o m 1 , 0 . r p n (
+ 4
H 3 N H N a n - i l a e z s a i b k
] ] a a z a i n b l . j e s n i o k [ k [ g o l +
a
a r e f u p H p ) a
a r e f u p H p ) a
K p =
H p
0 1 × 8 , 1 = a K
+
a
K p =
H p
K p =
H p
+
=
5 H N 4 0 1 a 1 t 0 × n 1 8 a t 1 s n = o ) k a w H N k b s K ( n K i l e = 6 s i ) 2 , k 9 H – = N ( a a a K K K p p −
−
,
3
6 2 , 9 = ] l ] 3 C 4 H H N [ N [ g o l
+
4
O 2 H + O O 1 C 3 , 0 , H 0 C a + N
4 7 , 4 = ] O H O O C 3 O H C C a H C N [ g o l
4 7 , 4 = a K p
1 , 1 , 0 0 g o l
+
a
K p =
H p
1 1 , 0
⇄
4 7 , 4 = H p
6 2 , 9 = H p
� 1
+
a
−
+ 4
1 , 1 , 0 0 g o l
+
=
0 1 × 6 5 5 ,
=
5 -
0 1
� 1
1 g o l + 4 7 , 4
] a z a b . j n o k [ g o l
1 g o l + 6 2 , 9
H O a N l o m 1 0 , 0 + a r e f u p r a t i l 1 ) c
H O O C 3 H C e j u g a e r H O a N m i t a d o d a S
H O O 1 , , 0 C 3 0 H C + H 1 O a , 0 , N 0 -
2 2 , 1 g o l + 4 7 , 4 =
1 9 1 , 0 , 0 0 g o l +
9 0 , 0
0
a ž a e n e t o n m v o r a P R
4 7 , 4 = ] ] O H O O C 3 O H C C a H C N [ [ g o l +
a
K p =
H p
3 8 , 4 = 9 0 , 0 + 4 7 , 4 = H p
2 2
H O a N l o m 1 0 , 0 + a r e f u p r a t i l 1 ) c
l C 4 H N o n s o n d o ,
+ 4
H N e j u g a e r H O a N m i t a d o d a S
l C a N + O 2 H + 3 1 H , 0 , N 0 + ⇄
l 1 C 4 , 0 , H 0 N + H 1 O a , 0 , N 0 -
1 1 , 0 9 0 , 0
0
a ž a e n e t o n m v o r a P R
r e f u p i u d o v u n a v o l i t s e d u a t a d o d l C H
2 2 , 1 g o l + 6 2 , 9 =
1 9 1 , 0 , 0 0 g o l +
6 2 , 9 = ] l ] 3 C 4 H H N [ N [ g o l +
a
K p =
H p
� 2
5 3 , 9 = 9 0 , 0 + 6 2 , 9 = H p
s v
1 -
0 1
2 -
l C H + r e f u P
l C H + a d o V
0 l 1 1 u i 3 - t 0 a 1 d o d 4 - l 0 C 1 H i 5 - l 0 o 1 m 6 -
0 1
7
6 5 4 3
H p
2 1
H p
? r e f u p u l C H l o m 1 , 0 u k t a d o d i r p H p a j n e ž i n s g o k i l e v a d o l š o d e j o t š a Z
: r e f u p i u d o v u l C H u k t a d o d i r p H p u n e m o r p a z r a t n e m o K
1 2
3 2
H 0 , p 5 ∆
9 , 0 , - 0 -
0 0 , 2
7 1 , 9
2 8 , 0 g o l
l 1 C 4 , 0 , H 0 N +
+
1 1 , 0
⇄
l C H l o m 1 0 , 0 + a r e f u p r a t i l 1 ) b
3
H N e j u g a e r l C H m o t a d o d a s
3 1 H , 0 , N 0 + l 1 C , 0 , H 0 -
9 0 , 0 0
a ž a e n e t o n m v o r a P R
6 2 , 9
→ → → 6 0 0 , , 2 , 9 7 H H p p p
=
9 1 0 , , 1 0 0 g o l +
6 2 , 9 = ] l ] 3 C 4 H H N [ N [ g o l +
a
K p =
H p
,
7 1 , 9 = 9 0 , 0 6 2 , 9 = H p
: o n r a m u S
: r a t i l 1 u l C H l o m 1 0 , 0 k a t a d o D
O 2 H e n a v o l i t s e d
a r e u p g o n t a t e c a
a r e f u p g o n č a j i n o m a
0 , 5 +
9 0 , 0 +
9 0 , 0 +
0 5 3 0 3 8 , , , 2 9 4 1
: r a t i l 1 u H O a N l o m 1 0 , 0 k a t a d o D
→ 0 0 , 7 H p
O 2 H e n a v o l i t s e d
→ 4 7 , 4 H p
→ 6 2 , 9 H p
a r e f u p g o n t a t e c a
a r e f u p g o n č a j i n o m a
i t s o n d e r v H p i n e m o r p e r i p o e s a d a r e f u p t s o n b o s o p s ) β ( t e t i c a p a k i k s r e f u P
a r e f u p t e t i c a p a k i a v t s j e d g e s p o H p . 4
� � 2 2
c H p ∆ ∆ a
− =
c H p ∆ ∆ b
=
β
� � � � � � � � � � � � � � � � �
1 / 0 1 o d 0 a r 1 / e f 1 u = p g a o n i n l d e e s j i k a a v / t K s j p a e = z a d H b a . p g n e s o p k o t a s s o o 1 n n = d d e o ] r a v i n a m l H a e p i c s i u k n n [ a l / r ] a r a t z n a u e n c b a . j e n s j a u o k i z k f a [ e k e o p r a e f K u p P
, e z a b e k a j e t a d o d e e j i n c i a l r e t s n i e k c e n k o a k j a o n e n s o m n o r d p o – a c ∆ , b c ∆
) ) m o m k o a k n a z n d z e r d p e r p ” ” “ + s “ a a H s p H ( p ∆ ∆ ( H p H j p e u j a v a a n ć m e s v e o n p i l e e z s a i b k e k e k H a j a p j a k k n a t a e t a a m d d o o o r p d d – H p ∆
t e t i c a p a k i ć e v → H p ∆ t s o n d e r e v a j n a M
� 2
a r e f u . p j e i a v c a d r u t e H n c O a n o N k ) e l o t i č m i l z 1 a 0 , r 0 ( a ,
e n ) ] i a č i n i l l o e k i s e k t s [ / i ] a u z k t a a b d . j o n d o i k r p [ ) s o H n p d o ∆ ( i t s H ( p i a H n e p g m o o r t s P i
H p ∆
,
4 0 , 0
a k H t a O d a o d N l e o l s m o p 1 0 , H p 0
,
8 7 , 4
c c c c a H A k O t a A a A A a N a H N H d N o l / l / l / l / d o l l l l l o o o o e m l s m m m m o 1 9 1 9 , 1 P 0 1 0 2 1 0 , , , , 0 0 0 0 a r e H f p u p ; 4 7 , 4 = H p r r a e t f l u i P 1
=
,
4 7 , 4
c c c c A a A A a A N H N H l l / / l / l / l o l o l o l o m m m m 1 , 1 , 2 , 2 , 0 0 0 0
� 2
] a ] z a a n b i l . j e s n i o k [ k [ g o l
1
g 7 , s 5 ± e p – o a - 7 , K H p p 3
: a v 1 1 t + s + a – j a a a e K K K K d p p p p g = = = = o H H k H H s p p p p r e f u p g e s p o ] H ] a p z a a n i b . l e j s n i o k k [ [ 1
1 / 0 1
0 1 / 1
3 , 2 , 8 0 1 – – 2 , 3 , 6 8
) H O ) O - 4 + ) C 4 3 O 2 H H P N C ( H ( ( 4 1 6
a K 7 , 2 , 2 , p 4 7 9
i n č i a i n t n j i t a f a n r e t e f s o u c o m P A F A
] ] a a z a i n b l . j e s n i o k k [ [ g o l + 4 7 , 4 H p
: a r e f u p t e t i c a p a k i H p a z r a t n e m o K
� 2
) ] a ) n i ] l a e n i s i l k e [ s / i ] k [ a z a + b ] . a j z n a o b . k [ j ( n i t o k [ n e n = o r e p f u p m o c ( : k a d a j i o r e c i a s f i u t v p r n a e e z j c i a n c r o a e r k f t a u n s p e c o t n n e o d t i k o c a • • p a K
e j i c a r t n e c n o k m e j n e j n a m s i l i i t s a o n t K d p e e t = r i v c H a a p 1 = K p a a ] n a p k i i n d ć i o k l s e r e a v r s e j i f e a f u n k [ u p e / ] p j e a s t z H e a e t b p j i u c . m j a e j n n p j o n a a k k a m [ s i v k a a j s r l r → e a e f f d u u U p P
) 1 2 , 7 = 2 a K p (
0 3
a r e f u p t e t i c a p a k i H p a n a j n e ž a l b z a r j a c i t U
e t s i a r e f u ] p a a n v i l d e s u i k [ H / ] O a a N z a ) b l . o j m n o 1 k [ 0 , 0 ( a s o e n n d i č o i l g o o k t i e t i s č l i z u a k r t a d a ,
o ) l / d l i o r p m ) 2 , H p 0 ( ∆ e ( j i c H p a r a t n e n e c m o r n o P k
] ] a a z a i n b l . j e s n i o k k [ [ g o l +
a
K p =
H p
] a n i l e s i k [ / ] a * z a a j b . n e j m n o e k : n [ a r s s e o e f n a u d r e o f m e p e s u a H n j e n p ž a e l m → b z a e n R •
. � � � � � � � � � � � � � � � � � , � + � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � č � � � � � � � � � � � � � � � � , � . � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � ć � � � � � � � � � � � � � � � � � � � , č � � � � � � � � � č � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � ć � � . � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � � č � � � � � � � � � � � � � � � � � �
a r a e r f e u f p u t p e a t i j i c c a a r p a t n k e e c s n e o j k j u e s n e a j s u m j n a → m s •
3 -
8 -
0 0 1 1 × × 2 5 , , 4 7 6 O = = P 3 1 a 2 a H K K
) 2 4
O P H 4
O P 2 H ( r e f u p i n t a f s o F
: 4 O P H 2 a N i 4 O P 2 H a N e š e m s r o v t s a r i n e d o V
� � � � � � � �
� � � � � � � � � � � � � � �
- 4
2 4
O P H + + a a N 2 → → 4 4 O P 2 H 2 a a N 2
] - ] 4 4 O O P P 2 H [ H [ g o l
2
+
)
a k H t a O d a o N d e l o l s m o p 1 0 , H p 0
,
,
a r e H f p u p ; l / l o m 2 , 0 = r r a e t f i u p l c 1
,
4 1 , 4
c c c c A A a A a A N H N H l / l / l l l l / / l l o o o o m m m m 4 6 1 , 1 , 0 , 1 , 0 0 0 0
+
4 7 , 4
=
H p
: a r e f u p t e t i c a p a k i H p a z r a t n e m o K
] ] 4 4 O O P P 2 H 2 H a a N [ [ N g o l +
)
4
K p
K p
O P 2 H ( a
=
H p
4 , 7 o n ž i l b i r p t o v H i p ž
6 2 , 4
c c c a H A c k O a A A t a A a N a d N H N H o l / l / l d l o l / / l l l e m l l o o o o s m m m m o 1 0 , 1 9 5 5 P 0 1 , 0 , 0 , 1 , 0 0 0 0
0 1 × 8 , 4 = 3 a K
O P 2 H ( a
=
H p
1 3
2 1 , 0
] ] a z a a i n b l . j e s n i o k k [ [ g o l
3 1 -
4
� 2
H p ∆
2 3
i r e f u p i n j a č a n z i k š o l o i B . 5
) - 3 O C u e : u j s z H a / o v r q a m g ž e a u t 2 e s O d a o d s C i ( j g o u - 3 r k o s e O e m u C m 8 , p e 7 H t / 3 s > i n O s e H o C 2 k p r s i r H r l p i e i f n 9 t u , a n p 6 e n e o g < ž o b r H r d a a n p k s e i n t i t e s s o g n o n e o n r d č d e i e p r t u h v t e s o n a v s i e v z l e n a T I
2 4
O P H / - 4 O P 2 H i n t a f s o f -
e p u r g e n l a n o i c k n u f i ž r d a s e z a a b n i i e l i t o e r n p i l e e n i s i l k e s e i b k a l o s n i o a m a k ( u i u k l s e n i d e e t o o r p k -
� 3
a z a H b + a - 3 n a O v C o g u H j n o ⇄ k
� 3
e t n e n o p m o k e g u r d r o v t s a r u e t n e n o p m o k e t s - ) r a v č k a j e i n n d o e j m a k a r o t v a . t d a o s r d
+
- 3
O C H 3 O – 3 C O H C 2 – H q a i 2 l i O - 3 C ( O r e C f H u – p q a i 2 n t O a C n o b r a k n e g o r d i H
) -
n o k a z v e j i r n e H
3
O % C 2 1 H O 2 H + ) q a ( a 2 n % i l O 9 e C 9 i s k
→
a z a f a t i v o s a
⇄
] 2 3 O p C x H [ H g o l +
K p =
H p
2
t O i C s o a v ) k t i a j n l s r a i t t o i s r v n t p s o i a k r a n t l a n v j i e e j j c i i r c r a n p i f e – e H o 2 k ( O – C H p k
a r e f u p a m e r p i r P . 7
→
r o v t s a r i n e d o v
i t n e n o p m o ) k r e a f a n u r p e i č f i i u l n o t p k a f i s t h o i n f n e b a n e z o t 4 p r O o P m p o H 2 k i d a o N m e v u i 4 j n m O a e P š 2 e j n H a m r a o a . v N n t r t p s k n a r ( e r i • • D . 1
m o n i l e s i l k ) C m o H i k a a j k a a r a e i s j f n u o e p z m i a a ) t b n k m e š e a o b n i j i a o v c l p k ; s ; H m a o e O a k r m o ( z N a a r i m b e o o v j n t i m i l s c o e a s r a k i z a k i h j l a e i a n n r s t e t e d ć e u o r e n i v n i s l e k m s a e m š j i o i k n n e v a l . r š a b p e j a l n m i s ( c r a • • P . 2
m o z a b m o ) k a H j O a a s N i e a z d a i b r o e l h b a l s m u i j l i n o s ; o m a m o k a n š i i l v e s l ; i k C H m i o a k a t a j t e a s c a e m n i u l j i e r s t i k a n e k b a a š i l s v . i r l p o n s ( •
a r e f u p g e ć e j o t s o p ć e v d O . 3
3 3
: 2 4
O P H o n s o n d o , 4 O P H 2 a N e j u g a e r l C H a S
l C a N + 4 O P 2 H a N → l C H + 4 O P H 2 a N : u k i l - 4 b O o P m 2 o H k s → l u k + e H l o + m 2 4 U O P H
: O P 2 H o n s o n d o , 4 O P 2 H a N e j u g a e r H O a N a S - 4
O 2 H + -
2 4
O P H → H O + - 4 O P 2 H
O 2 H + 4 O P H 2 a N → H O a N + 4 O P 2 H a N : u k i l b o m o k s l u k e l o m U
� 3
a r e f u p g o k s t u e c a m r a f g e ć u j a r a v o g d o r o b z I . 6
) u k s a j n i o c j a t r a t k n i e l c i n u o k k s s n o o j n n d a o , i t u H a k s p n l o u t u č a a k d e a r l z o z i e m ≈ ( n p a i o t u č a a n K p i n l a d e s e z i j a k H z u b H a n a l m s e o s i t n a e r b m a i a r z z I P a •
•
] a ] z a a n b i l . j e s n i o k [ k [ g o l +
a
K p =
H p
t e ) l t / i l c o a p m a 5 k , i 0 ć o u d j a r 5 a 0 , v 0 o g d d o o a a r z f e a u r e p f e u i p j a u c r j t i c n a e r c t n n o e k c n o e n k e j i t a a č i r b b a o z u I ( •
a n e s a z a . n o = r
e f u p
c
, i n i t e s c o , n ) č o i n s b k e o r a t t , r o i t e p f s e u o p n j l o i g b a o a k n ( t e s t j s o o l a n v a l r n i p r u a e č t a s r , n i a H ć p e m i t d a i j r o v i c e v k e a o k r r j e p o t t n s i m a o s r m t i i t e ć a r u m b g a o H z I m p •
•
� 3
0 �
4
O P 2 H a N g 8 8 3 , 0
l m 6 1 , 2 1 = l 6 1 2 1 0 , 0
0 2 1 = r M ×
) l 4 o O m P 2 5 H 0 a 0 , 0 N ( n g o l =
9 1 , 0
l o m 3 0 1 × ) ) l 4 l 4 3 o O o O 2 , 3 m P P m 2 2 = 5 H 5 0 a 0 H ) 4 0 a 0 , , N O 0 N ( 0 ( P n n 2 = H = a 9 1 5 , N 0 5 ( , 0 1 n 1
=
l o m l / 6 l 1 o 2 m 1 1 0 , 0
H O = a N n c n V l / = l = o c V m 1
4
4
a r e f u p i t n e n o p m o k m e j n a š e m o n t k e r i d a r e f u p a m e r p i r P . 1
O P H 2 a N a r o v t s a r l 8 / l o 0 1 × m 2 , 5 6 0 , 0 = l 2 a m K 0 : 0 a 1 i n u l e i t s i a k d o a d n r o o n f s b o e r F t o ? p 4 0 , O 4 7 P 2 = H a H p N r e a f u m p a r o g t a e j s o a n k i i l b o a K d
� 3
l o m 5 0 0 , 0 = ) O P H a N ( n
) a ) z a a i n b l . j e s n i o k ( k ( n n g o l +
a
) ) 4 4 O O P P 2 H 2 H a a N ( ( N n n g o l +
)
4
O P 2 H ( a
K p
K p
=
=
H p
H p
1 2 , 7 = 8 0 1 × 2 , 6 g o l = a K p
) l 4 o O m P 2 5 H 0 a 0 , 0 N ( n g o l +
1 2 , 7
=
0 4 , 7
m o j i c a z i l a r t u e n m o n l a j i c r a p a r e f u p a m e r p i r P . 2
O P 2 H a N 1 2 a , r 7 o v = t 2 s a a r K l p m : 4 0 0 1 O P 3 u i H t a . d o 0 4 d , 7 a b e r H p t r u e j f o k u p H o a O s a t a N n l i / l o b a m d l 1 / l u o n i m m 2 , e r 0 p e a j i z c i a t r a t n u n e č c a n r o z k I ) a
� 3
O 2 H + 4 O P H 2 0 x x + a N → H O a x x - 0 N + 4 O x P 2 2 2 0 0 l , x , o H a 0 - 0 m N 2 0 , 0 ) l ) o = l ) l ) m 4 o o ( m O m ( a ( P ž 2 a e k n H a e t o a t n e N m v č ( o a o r n P P R
) x ) x 2 ( 0 , 0 ( =
5 5 , 1
) 4 4 O O P P 2 H 2 H a a N ( N n n o l +
1 2 , 7
=
0 4 , 7
) ) 4 4 O O P P 2 H 2 H a a N ( ( N n n =
5 5 , 1
) H O a N ( l o m 6 1 2 1 0 , 0 = x
2 �
l m 4 8 , 7 = l 4 8 7 0 0 , 0
x x x x - + - + 2 1 2 1 0 , 0 , 0 , 0 , 0 0 0 0
=
=
1 2 , 0
l C H = l / l c n n V o = = m V c 1
0 1 −
4
1 �
) l C H (
l o m 2 0 , 0 = ) 4 O P H 2 a N ( n
O 2 H + 4 O P 2 0 x x + H a N → l C x x 0 H + 4 O 2 x P 0 2 0 , x H , 2 0 - 0 a N ) ) l o l o ( m l o ( m m a ž a e k n a e t o t n e m v č o o r a P P R
l C H M 1 l m 5 5 , 8 = l 3 0 1 × 5 5 , 8 −
l o m l l 4 / 8 o 7 m 0 1 0 , 0
O P H 2 1 2 a , N 7 = a r 2 a o v K t s p a r : 4 l m O P 3 0 0 1 H . u 0 i 4 t , a 7 d o H d p a a r b e e f r t u u p j o u k l m r C e p H i r l p / l o a m z 1 l / l u o n i m m 2 , e r 0 p e a j i z c i a t r a t n n u e č c a n r o z k I ) b
� �
- ) x , ( =
5 5 , 1
) ) 4 4 O O P P 2 H 2 H a a N ( ( N n n g o l + 1 2 , 7 =
0 4 , 7
) 4 O P 2 2 H a N ( n 4
=
5 5 , 1
l o m 4 8 7 0 0 , 0 = x
1 2 , l 7 o = m a K 1 p 0 , : 4 0 i ž O r P d 3 a H s i j o ? 0 k 0 , a 7 r e H f u p p r l f e m u p 0 0 o 1 i g b e u o ć i d e t j a e o s d t i o s d b o p a a d b ć e 4 e t r v l O d C P o 2 H H a a r e N f M u 1 l o p a m r e o 2 j v n t 0 , a s 0 a r m i 4 e r l m p i o O P r k 2 P i l H o a . 3 K N
=
7 1 6 0 ,
) l C H ( l o m 3 0 1 × 5 5 , 8 = x
3
=
0 1 × 1 5 5 , 8 −
=
n c =
V
3 �
O 2 H + 4 x O + P 1 2 , x 0 , H a + 0 N → l C x x - 0 H + 4 O x P 2 x H , - 0 2 , a 0 N ) l ) o l o ( m o ( m a m ž a e t a n e o t e m n v o o r a P R
) a ) a z a i n b . l e j s n i o k k ( ( n n g o l +
a
K p =
H p
) ) 4 4 O O P P 2 H 2 H a a N ( ( N n n g o l +
1 2 , 7
=
0 0 7 ,
x x - + 2 1 0 , 0 , 0 0 g o l =
1 2 0 ,
−
l m 0 4 i 4 O P 2 H a N l / l o m 2 , 0 l m 0 0 1 m e . j n a 1 2 , š e 7 m = 2 a g K o l a p t : s 4 a O n P a 3 r H o v t s . a r H O H a p N i t l / a l n o u č m a r 2 , z 0 I . 2
a r e f u p u r o v t s a r u H p e j n a v a n u č a r z I . 8
� �
O 2 H + 4 8 O 8 0 P 0 0 0 , , 0 H 0 0 2 a + N → 8 H 8 0 0 O 0 , 0 , 0 a 0 N 0 + 4 O 8 2 P 0 1 2 2 0 0 0 , , , H a 0 0 - 0 N 4
O H P 2 O a H a N N l l o o m m 8 2 0 0 0 , , 0 0
l m 0 0 1 i 4 O P 2 H a N l / l o m 2 , 0 l m 0 0 1 . m e 1 2 j , n 7 a = š a e 2 m K p g : 4 o l a O t s P a 3 n H a r o v . 4 t O s a r P H 2 H a p N i t l / a l n o u č m a r 1 , z 0 I . 1
) l ) l ) o o l m o m ( m ( a ( ž a e k t n a e o t n e m v č o o r a P P R
i j i c k a e r u e j a t s a n r e f u P
) 4 3 O O 0 , P P 7 = H 2 2 a 8 a H 0 1 N N 0 ( , 0 , n n 0 0 g g o o l l + + 1 1 2 2 , , 7 7 =
H p
=
H p
r e f u 4
4
O O P 2 P H H 2 a a N N l o l o m m 2 1 0 0 , , 0 0
=
H p
� �
l C a N + 4 O 5 5 P 0 4 2 4 0 0 0 , , , H 0 a 0 0 N + → 5 l 5 0 C 0 0 0 , 0 , H 0 0 + 4 O 5 5 P 2 0 1 0 H , 0 , 0 , 2 0 0 a 0 N 4 4
O O P 2 P H H 2 a a N N l o l o o m m m 4 2 0 0 , , , 0 0
) 3 4 , O O 7 6 P P 2 = H 2 5 a 5 a H 1 4 N N 0 ( , 0 , n n 0 0 g g o o l l + + 1 1 2 2 , , 7 7 4
) l ) l ) o o l m o m ( m ( a ( ž a e k t n a e o t n e m v č o o r a P P R
=
H p
=
H p
. 4
� �
) ) 4 4 O O P P 2 H 2 H a a N ( ( N n n g o l + 1 2 , 7
l m 0 0 2 u a d o d l C H . 4 l / l o O P m H 2 1 a , 0 N l l m o m 0 5 2 e , s 0 0 a i d 4 a k O e P 2 j a H t a s a N n l i o j o m k 4 a 0 r , . o 0 1 v t 2 i , s ž a r r d 7 = 2 a a H s p K i j i t o p a k : 4 n a u r č e O a f P r 3 z u I p H
l l o o m m 1 2 0 , 0 , 0 0 g o l + 1 2 , 7 =
H p
1 9 , 6 = 0 3 , 0 1 2 , 7 = H p
l m 0 5 i 4 O P H 2 a N l / l o m 2 , 0 l m 0 0 1 m e j . n a 1 2 š , e 7 m = 2 a g o K l a p t s : a 4 n O a P r 3 o v H t s a r l . H C p H i t l / a l n o u m č a 1 r , z 0 I . 3
� �
l C a N + 4 O 5 P 5 2 0 0 0 H , 0 , a 0 0 N + 0 → 5 l 5 0 C 0 0 0 , 0 , H 0 0 + 4 O 5 5 P 2 0 1 0 H , 0 , 0 , 2 0 0 a - 0 N 4
O P l H 2 C a N H l l o o m m 5 2 0 0 0 , , 0 0
) l ) o l ) l m o o ( m m ( a ( ž a e k n a e t o t n e m v č o o r a P P R
i j i c k a e r u e j a t s a n r e f u P
) 4 O P H 2 a N ( n g o l + 1 2 , 7 =
H p
9 6 , 7 =
5 5 1 0 0 , 0 , 0 0 g o l + 1 2 , 7 =
H p
0 �
: e ž r d a s l m 0 0 1 u i j o k l a r e C 4 l f u C 4 p H N H e l t e o N t i m l o c 5 a m 0 p , 5 a 0 , k i 0 i 3 i i t 3 H H s o N n l N d o l e r m o v 5 m 0 5 H , , p 0 0 i t ) ) i d B A e r r r e e o f p f u u U P P . 8
l : l C 4 C a 4 r e H H f N N u l p l / l l e / t o o e t m m i c 5 7 a 0 0 , , p 0 a k i 0 i i 3 3 i H H t s N N o l l n / / l l d o o e r m v m 5 3 H 0 , 0 , p 0 i t ) 0 ) i d B A e r r r e e o f p f u u U P P . 9
? 5 , 6 H p a n a v t s j e d g H H o k O O s r 2 s f e i H r N T u p c a l i O s o H n e j r a p i H H n O O z a + 3 b H H s i + N r o s T k n i l e O s i H k i j o K . . 1 1
) ) ) 1 a 2 a 3 a K K K p p p ( ( ( 6 4 a , 0 2 3 K , 1 , 2 , 2 , p , 9 2 7 1 8 a n i l e s i K
4 + 3 4 O P H 3
o a
3
e j n a b ž e v a Z
3
a . a r e f u p t s o n d e r v H p i s i v a z a g e č d O . 1
. a r e f u p t e t i c a p a k i s i v a z a g e č d O . 2
a e m o p a e r a v o o m u s o n o m o .
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