BS EN-12285-1

EUROPEAN STANDARD

EN 12285-1

NORME EUROPÉENNE EUROPÄISCHE NORM

March 2003

ICS 13.300; 23.020.10

English version

Workshop fabricated steel tanks - Part 1: Horizontal cylindrical single skin and double skin tanks for the underground storage of flammable and non-flammable water polluting liquids Réservoirs en aciers fabriqués en atelier - Partie 1:Réservoirs horizontaux cylindriques à simple et double paroi pour le stockage enterré de liquides inflammables et non-inflammables polluant l'eau

Werksgefertigte Tanks aus Stahl - Teil 1:Liegende zylindrische ein- und doppelwandige Tanks zur unterirdischen Lagerung von brennbaren und nichtbrennbaren wassergefährdenden Flüssigkeiten

This European Standard was approved by CEN on 4 November 2002. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Czech Republic, Denmark, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Luxembourg, Malta, Netherlands, Norway, Portugal, Slovak Republic, Spain, Sweden, Switzerland and United Kingdom.

EUROPEAN COMMITTEE FOR STANDARDIZATION COMITÉ EUROPÉEN DE NORMALISATION EUROPÄISCHES KOMITEE FÜR NORMUNG

Management Centre: rue de Stassart, 36

© 2003 CEN

All rights of exploitation in any form and by any means reserved worldwide for CEN national Members.

B-1050 Brussels

Ref. No. EN 12285-1:2003 E

EN 12285-1:2003 (E)

Contents page Foreword......................................................................................................................................................................3 1

Scope ..............................................................................................................................................................4

2

Normative references ....................................................................................................................................5

3

Terms and definitions....................................................................................................................................5

4

Symbols and abbreviations ..........................................................................................................................7

5

Designation and purchaser's specification.................................................................................................8

6 6.1 6.2 6.3 6.4 6.5

Materials..........................................................................................................................................................8 General............................................................................................................................................................8 Materials for shell, dished ends and manholes ..........................................................................................9 Materials for tank accessories......................................................................................................................9 Consumable....................................................................................................................................................9 Material inspection documentation .............................................................................................................9

7 7.1 7.2 7.3 7.4 7.5 7.6 7.6.1 7.6.2 7.6.3 7.7 7.8 7.9 7.10 7.11 7.12 7.13

Design .............................................................................................................................................................9 Forms of construction...................................................................................................................................9 Single skin tanks............................................................................................................................................9 Double skin tanks ..........................................................................................................................................9 Dished ends....................................................................................................................................................9 Compartments................................................................................................................................................9 Dimensions...................................................................................................................................................10 Material thickness........................................................................................................................................10 Secondary skin.............................................................................................................................................10 Interstitial space...........................................................................................................................................10 Tolerances ....................................................................................................................................................11 Shell plate arrangement ..............................................................................................................................11 Manholes and inspection covers ...............................................................................................................11 Structural bolts.............................................................................................................................................12 Tank fittings, pipes and nozzles.................................................................................................................12 Stiffening rings.............................................................................................................................................13 Lifting lugs....................................................................................................................................................15

8 8.1 8.2 8.3 8.4 8.5

Fabrication....................................................................................................................................................15 Plate preparation..........................................................................................................................................15 Shell plate forming.......................................................................................................................................15 Types of joints..............................................................................................................................................15 Welding procedures, welders' qualifications............................................................................................15 External coating ...........................................................................................................................................19

9 9.1 9.2 9.3

Testing ..........................................................................................................................................................19 General..........................................................................................................................................................19 Pressure testing ...........................................................................................................................................20 Testing of the external coating...................................................................................................................20

10 10.1 10.2

Handling and installation ............................................................................................................................20 Handling........................................................................................................................................................20 Installation ....................................................................................................................................................20

11 11.1 11.2 11.3

Marking of the tank and manufacturer's statement .................................................................................21 Marking of the tank ......................................................................................................................................21 Manufacturer's statement ...........................................................................................................................21 Drawings .......................................................................................................................................................21

Annex A (informative) Transport, storage and installation procedure ................................................................22 Annex B (informative) Evaluation of liquid-material-combinations for storage tanks according to this standard ........................................................................................................................................................24 Annex C (informative) A-devitations......................................................................................................................155 Bibliography ............................................................................................................................................................159 2

EN 12285-1:2003 (E)

Foreword

This document (EN 12285-1:2003) has been prepared by Technical Committee CEN /TC 221 "Shop fabricated metallic tanks and equipment for storage tanks and for service stations", the secretariat of which is held by DIN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by September 2003, and conflicting national standards shall be withdrawn at the latest by September 2003. This standard is part of a series of standards in the field of shop fabricated metallic tanks. The titles of the standards which are already edited or are under preparation are: 

Workshop fabricated steel tanks; Horizontal cylindrical single skin and double skin tanks for the underground storage of flammable and non-flammable water polluting liquids



Workshop fabricated steel tanks; Horizontal cylindrical single skin and double skin tanks for the aboveground storage of flammable and non-flammable water polluting liquids.

Further standards will be evaluated according to former decisions of CEN/TC 221 and according to the common rules for standard works for CEN-standards. Annexes A, B and C are informative. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Czech Republic, Denmark, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Luxembourg, Malta, Netherlands, Norway, Portugal, Slovak Republic, Spain, Sweden, Switzerland and the United Kingdom.

3

EN 12285-1:2003 (E)

1

Scope

This standard specifies the requirements for shop fabricated cylindrical, horizontal steel tanks, single and double skin for the underground storage of water polluting liquids (both flammable and non-flammable) within the following limits: 

from 800 mm up to 3000 mm nominal diameter and,



up to a maximum overall length of 6 times the nominal diameter and,



for liquids with a maximum density of up to 1,9 kg/l and,



with an operating pressure (po) of maximum 1,5 bar (abs.) and,



for double skin tanks with a vacuum leak detection system where the kinematic viscosity does not exceed -3 2 5 x 10 m /s.

This standard is applicable for normal operating temperature conditions (-20 °C to +50 °C). Where temperatures are outside this range, additional requirements should be taken into account. For guidance on the liquid-material combinations see Annex B. This standard is not applicable to the liquid classes listed in Table 1 because of special dangers involved. This standard does not deal with internal coating. Table 1 — List of dangerous goods not to be considered by this standard UNclassification

Dangerous Good

Class 1

Explosives

Class 4.2

Substances liable to spontaneous combustion

Class 4.3

Substances which in contact with water emit flammable gases

Class 5.2

Organic peroxides

Class 6.2

Infectious substances

Class 7

Radioactive substances, hydrocyanic or hydrocyanic solvent liquids, metalcarbonyls, hydrofluoracid, bromide liquids

The classifications referred to are those adopted by the United Nations Committee of Experts on the Transport of Dangerous Goods (not to be interpreted as tank classes described in 3.4).

4

EN 12285-1:2003 (E)

2

Normative references

This European Standard incorporates by dated or undated reference, provisions from other publications. These normative references are cited at the appropriate places in the text, and the publications are listed hereafter. For dated references, subsequent amendments to or revisions of any of these publications apply to this European Standard only when incorporated in it by amendment or revision. For undated references the latest edition of the publication referred to applies (including amendments). EN 287–1, Approval testing of welders — Fusion welding — Part 1: Steels. EN 288–1, Specification and qualification of welding procedures for metallic materials — Part 1: General rules for fusion welding. EN 288–2, Specification and approval of welding procedures for metallic materials — Part 2: Welding procedure specification for arc welding. EN 288–3, Specification and approval of welding procedures for metallic materials — Part 3: Welding procedure tests for the arc welding of steels. EN 10025, Hot rolled products of non-alloy structural steels — Technical delivery conditions. EN 10051:1991, Continuously hot-rolled uncoated plate, sheet and strip of non-alloy and alloy steels — Tolerances on dimensions and shape. EN 10204:1991, Metallic products — Types of inspection documents. prEN 13160–1, Leak detection systems — Part 1: General principles. prEN 13160–2, Leak detection systems — Part 2: Pressure and vacuum systems. prEN 13160–3, Leak detection systems — Part 3: Liquid systems for tanks. prEN 13160–4, Leak detection systems — Part 4: Liquid and/or vapour sensor systems for use in leakage containments or interstitial spaces. prEN 13160–5, Leak detection systems — Part 5: Tank gauge leak detection systems. prEN 13160–6, Leak detection systems — Part 6: Sensors in monitoring wells. prEN 13160–7, Leak detection systems — Part 7: General requirements and test methods for interstitial spaces, leak protecting linings and leak protecting jackets. EN ISO 898–1, Mechanical properties of fasteners made of carbon steel and alloy steel - Part 1: Bolts, screws and studs (ISO 898-1:1999). EN ISO 8501–1, Preparation of steel substrates before application of paints and related products - Visual assessment of surface cleanliness — Part 1: Rust grades and preparation grades of uncoated steel substrates and of steel substrates after overall removal of previous coatings (ISO 8501-1:1988).

3

Terms and definitions

For the purposes of this European Standard, the following terms and definitions apply. 3.1 tanks workshop fabricated cylindrical containments for the storage of liquids. They are made of steel, equipped with dished ends and consist of one or more compartments

5

EN 12285-1:2003 (E)

3.2 compartment single storage fluid space within a tank 3.3 underground tanks tanks which are totally or partially imbedded in the ground 3.4 tank classes are defined in Table 2 Table 2 — Tank classes Tank class

Description

Class A

For liquids with density up to 1,1 kg/l

Class B

For liquids with density up to 1,9 kg/l

Class C

For liquids with density up to 1,9 kg/l, and explosion pressure shockproof under atmospheric conditions (see also 3.5)

3.5 explosion pressure shockproof tanks are designed to withstand an internal explosion without leakage; permanent deformations are permissible. Where the atmospheric pressure of 1 bar the maximum explosion pressure is measured at 10 bar (abs.) 3.6 tank types for the purpose of this standard two tank types are distinguished: Type S: Single skin Type D: Double skin 3.7 operating pressure (po) pressure inside the tank above the liquid during operating conditions 3.8 test pressure (pt1) pressure to which the tank or compartment is subjected for testing 3.9 interstitial test pressure (pt2) pressure to which the interstitial space between the skins is subjected for testing. It is only applicable for double skin tanks 3.10 nominal volume volume stated on customer's order 3.11 actual volume volume which is equal to or greater than the nominal volume NOTE The safe working capacity of the tank should usually not exceed 97 % of the nominal volume in normal operating temperatures.

6

EN 12285-1:2003 (E)

4

Symbols and abbreviations

For the purpose of this standard the following symbols apply: Dimensions in mm

d1

External nominal diameter of the tank

d2

Inside diameter of the manhole

d3

Diameter of the manhole cover

h1

Length of the straight flange of the dished end

kp

Pitch circle diameter

lc

Length of the compartment of a tank without dished ends

lo

Overall length of the tank

lz

Length of the tank without dished ends

r1

Crown radius of dished ends

r2

Knuckle radius of dished ends

r3

Knuckle radius of the outer dished end

s1

Nominal thickness of inner skin and inner dished ends

s2

Interstitial space

s3

Nominal thickness of outer skin

s4

Nominal thickness of outer dished ends

s5

Nominal thickness of compartment dished ends

s6

Nominal thickness of manhole flange and cover

s7

Plate thickness of manhole body




incline angle for T-joint welding

7

EN 12285-1:2003 (E)

Tank type S

Tank type D

(single skin)

(double skin)

Key 1 nozzle detail see figure 3 2 example for stiffening ring see figure 4 3 lifting lug Figure 1 — Example of tank symbols

5

Designation and purchaser's specification

Example for designation: A tank according to this standard with a nominal volume of 50 m³ and a nominal diameter d1 = 2500 mm, tank class A and type D is designated as follows: Tank EN 1/50/2500/A/D

12285-

The purchaser shall also provide the following information: a)

number of compartments and their volumes,

b)

material specification,

c)

kind of external coating.

6

Materials

6.1 General The manufacturer selects the material in accordance with the customer's instructions either by using the material specified by the purchaser or by nomination of intended liquids to be stored. Annex B provides guidelines on material specifications in relation to storage media.

8

EN 12285-1:2003 (E)

6.2 Materials for shell, dished ends and manholes Carbon steel according to EN 10025 or austenitic stainless steel according to EN 10088-1 may be used if the mechanical properties are at least equal to those of S 235 JR (EN 10025). In areas where low temperatures have to be considered (below -20°C) and in this case wall-thicknesses are 6 mm, at least carbon steel of grade S 235 J2G3 or equal shall be used.

6.3 Materials for tank accessories Materials used for the fabrication of tank accessories if welded to the tank shall be compatible with the tank material.

6.4 Consumable All welding rods/wires and other consumables shall be compatible with the basic material.

6.5 Material inspection documentation Material inspection documentation of shell plates and dished ends shall for carbon steel according to EN 10025 be in accordance with the requirements of 2.2 of EN 10204: 1991 and for all other steel qualities shall be in accordance with 3.1 B of EN 10204: 1991.

7

Design

7.1 Forms of construction Single skin tanks shall form an impermeable containment; they constitute the inner tank of a double skin tank.

7.2 Single skin tanks Single skin tanks shall form an impermeable containment; they constitute the inner tank of a double skin tank.

7.3 Double skin tanks For double skin tanks, a secondary skin is welded around the inner tank, which forms an impermeable self contained tank. The secondary skin shall cover at least 97 % of the nominal volume of the inner tank. There shall be at least two sockets for the leak detection system and these shall be located at the highest point of the interstitial space. The interstitial space shall be connected to a leak detection system in order to monitor the integrity of the tank permanently. For leak detection systems see prEN 13160–1 to –7.

7.4 Dished ends Dished ends shall be used for external ends and to separate compartments. The following dimensions shall apply:

r1 ≤ d1

r2 ≥ d1/30.

7.5 Compartments The nominal wall thicknesses of dished ends separating the compartments (compartment dished ends) are given in Table 3. For classes A and B a different form of dished ends separating the compartments is possible, where r1 = d1, but without knuckle radius r2 and without straight flange. A compartment dished end with a knuckle radius and a straight flange is equivalent to a reinforcement ring at the same position. 9

EN 12285-1:2003 (E)

7.6 Dimensions 7.6.1

Material thickness

The nominal wall thickness of the inner tank shell, outer tank shell and dished ends shall be specified by the manufacturer in rounded millimetres, and shall be at least as given in Table 3. Table 3 — Nominal wall thickness for inner and outer skin of tanks, dished ends and compartment dished ends Tank classes

Class A

Class B

Class C

Nominal diameter of the

Nominal shell thickness

tank d1 in mm

in mm

s1

s3

s1

s3

s1

s3

inner skin

outer skin

inner skin

outer skin

inner skin

outer skin

800 up to 1600

5

3

5

3

5

3

1601 up to 2000

6

3

6

3

6

3

2001 up to 2500

6

4

7

4

7

4

2501 up to 3000

7

4

9

4

9

4

Nominal diameter of the tank

Nominal wall thickness of dished ends

d1 in mm

in mm

s1

s4

s1

s4

s1

s4

inner skin

outer skin

inner skin

outer skin

inner skin

outer skin

800 up to 1600

5

3

5

3

5

3

1601 up to 2000

6

3

6

3

6

3

2001 up to 2500

6

5

7

5

7

5

2501 up to 3000

7

5

9

5

9

5

Nominal diameter of the tank

Nominal wall thickness of compartment dished ends

d1 in mm

in mm

7.6.2

s5

s5

s5

800 up to 1600

5

5

10

1601 up to 2000

6

6

14

2001 up to 2500

6

7

16

2501 up to 3000

7

9

18

Secondary skin – Circumferential angle

The secondary skin shall enclose at least 300 degrees of the circumference of the tank, leaving not more than 60 degrees on the top uncovered. In cases where the manhole diameter exceeds d1/2, the manhole shall be provided with a secondary skin. 7.6.3

Interstitial space

The interstitial space gap should be as small as practically possible but suitable for the leak detection system to function. 10

EN 12285-1:2003 (E)

7.7 Tolerances 7.7.1

The overall length of the inner tank

The tolerance on the overall length of the tank shall be ± 1% of the real length stated by the manufacturer. 7.7.2

Wall thickness

The minimum thicknesses of dished ends after forming and for shell plates shall be at least 92 % of the nominal wall thickness according to Table 3. The thickness of shell plates shall be in accordance with EN 10051:1991, Table 2. 7.7.3

Circumference of dished ends

For the dished ends, the tolerances shall be -0/+6 mm for d1 ≤ 2000 mm, and -0/+10 mm for d1 > 2000 mm based on the calculated circumference of d1.

7.8 Shell plate arrangement Cross seams are not allowed. Longitudinal welds are not allowed in the bottom half of the tank.

Key a minimum distance: 5 x wall thickness but not less than 25 mm.

Figure 2 — Shell-plate arrangement for inner and outer skin

7.9 Manholes and inspection covers Unless otherwise specified by the purchaser, the tanks shall be equipped with at least one inspection cover per compartment. In cases where inspection covers are not allowed, the tanks shall have one manhole of at least d2 = 600 mm. No part of a compartment shall be more than 10 m from a manhole. Single skin tanks shall always have a manhole. The manufacturer shall decide whether manholes (inspection covers, nozzles) shall be of set-through or set-ontype. Nozzles and flanges shall either be welded inside and outside, or by full penetration. For the dimensions of the manholes and their components see Table 4.

11

EN 12285-1:2003 (E)

Table 4 — Dimensions of manhole components Inside diameter

d2 mm

Plate thickness of manhole body

Diameter of cover

Pitch circle diameter

d3

kp

s7

mm

mm

Bolt hole diameter

Flange thickness and cover thickness

s6 mm

Bolts Thread

Number

size

mm

mm Class A 600a

6

720

680

800

7

920

880

1000b

7

1120

1080

18

Class B and C

12

16

12

20

--

20

a

If a manhole is required and no specification is given by the purchaser this diameter shall be used.

b

For tanks of class C inside diameters of the manhole (d2) exceeding 800 mm are not permitted.

32 M 16

44 48

Instead of the manhole covers shown in the figure 3 and dimensioned in Table 4, ribbed or embossed covers may be used in class A tanks with a plate thickness at least equal to the thickness of the inner tank s1. A ribbed or embossed cover shall withstand the test pressure pt1. Inspection covers for tanks of class A with d1 ≤ 1250 mm and tanks of classes B and C with d1 ≤ 1000 mm. The diameter of the inspection cover shall not be larger than 300 mm and not smaller than 120 mm, and the thickness of the inspection cover shall be equal to the minimum thickness of the inner tank.

7.10 Structural bolts Structural bolts used shall be in accordance with EN ISO 898-1, with a property class being at least 4.6. The material chosen shall be compatible with the tank material.

7.11 Tank fittings, pipes and nozzles All tank fittings, pipes and nozzles, shall be situated on the manhole cover or in the single skin top of the tank. For tanks of class C only the set-through nozzles shall be used. A penetration of the double skin is not allowed (exception: nozzles for leak detection system). Fittings and all other openings shall have a minimum distance of 50 mm to welded seams.

12

EN 12285-1:2003 (E)

Key 1 2 3 4 5

Gasket set-through nozzle set-on nozzle vent or pressure relief device of 10 mm diameter surface roughness of facing:

R z • 160

a Gaskets shall be suitable for the purpose. b For set-through-nozzles a vent of 10 mm diameter or equivalent opening shall be provided in the manhole neck at the highest practical point. c Connection for earthing and use for cathodic corrosion protection if required.

Figure 3 — Examples for manhole

7.12 Stiffening rings The following methods of construction may be used:

T 80 x 80 according to EN 10055, or

100 x 12.

13

EN 12285-1:2003 (E)

The number of stiffening rings depends on tan to tan length (lc) of each compartment and shall be in accordance with Table 5. Table 5 — Number of required stiffening rings in accordance with length of each compartment

Length of the compartment in mm

lc ≤ 7800 7800 <

Number of rings ––

lc ≤ 11700

1

11700 < lc ≤ 15600

2

lc

3

15600 <

Key 1 Welding for tank class B and C and for tank calss A with internal coating 2 Welding for tank class A without internal coating

Figure 4 — Examples for design details of stiffening rings Apertures as shown in figure 4 should be located at the top and bottom of the stiffening rings to allow un-obstructed flow of liquids, vapour or gases. Where internal coating is asked for, continuous welding shall be used on stiffening rings. Alternatively, instead of using stiffening rings (lc ≥ 7800 mm), the wall thickness of inner tanks may be increased. In this case the wall thickness of the inner tank shall be the greater of the following: a) nominal wall thickness according to table 3 14

EN 12285-1:2003 (E)

b)

s1 = 0,4 +

1,4 d 1 1(rounded up to full mm) 1000

(rounded up to full mm)

7.13 Lifting lugs 3

Each tank shall be provided with lifting lugs. The number of liftings lugs shall be at least 1 for a tank up to 20 m 3 nominal volume and not less than 2 above 20 m . The lug(s) shall be positioned to enable the tank to be lifted in a horizontal position. Lifting lugs fully welded to the tanks shall be provided in sufficient size and quantity to enable the empty tank to be lifted. The lifting lugs shall be provided with a lifting hole of at least 60 mm minimum diameter. In order to prevent deformation and for maintaining integrity of the coating, a reinforcement plate shall be provided or the lifting lug(s) shall be made of suitable size.

8

Fabrication

8.1 Plate preparation The plate edges shall be visually examined for laminations by the manufacturer. Where such faults are found the plate shall be deemed unsuitable for fabrication of the tank.

8.2 Shell plate forming All plates shall be formed to the required curvature over the full width or length of the plate as might be applicable. The manufacturer shall ensure that there is continuity of curvature at the longitudinal butt welds.

8.3 Types of joints The types of welded joints shall be in accordance with Table 6. All internal attachments shall be continuously welded.

8.4 Welding procedures, welders' qualifications Welding procedures shall be in accordance with EN 288–1, EN 288–2, EN 288–3 and welders' qualifications shall be in accordance with EN 287–1.

15

EN 12285-1:2003 (E)

Table 6 — Types of welded joints No.

Types of welded joints

Class of tanks and liquid (liquid-touched wall)

1

Square butt joint

For class A, B and C and all liquids For inner skin Plate misalignment may not exceed 0,3 s1, 0,3 s3 or 2mm

2a

Joggled butt joint

For class A and hydrocarbon liquids For double and single skin Not permissible with inner coating

2b

Joggled butt joint

For class A, B and C

3a

Overlap joint

For class A, B and C For outer skin

a = 0,7 s3

3b

Overlap joint

For class A, B and C For outer skin

a = 0,7 s3

16

EN 12285-1:2003 (E)

Table 6 — Types of welded joints (continued) No.

Types of welded joints

Class of tanks and liquid (liquid-touched wall)

4

Fillet weld in T-joint

For class A, B and C For nozzles in the outer skin

a = 0,7 smin s min= thickness of the thinner plate

5

Fillet weld (full penetration) in T-joint

For class A, B and C For manholes, nozzles and inspection covers
= 45 °

6

Double fillet weld in T-joint

For class A, B and C For manholes, nozzles and stiffening rings

a = 0,7 smin smin= thickness of the thinner plate

17

EN 12285-1:2003 (E)

Table 6 — Types of welded joints (concluded)

No.

Types of welded joints

Class of tanks an liquid (liquid-touched wall)

7a

Fillet weld in overlap joint

For class A, B and C For compartment dished ends with knuckle radius

7b

Fillet weld in overlap joint

For class A, B and C For compartment dished ends with knuckle radius Not permissible with inner coating

8

Butt joint

For class A and B For compartment dished ends with knuckle radius Not permissible with inner coating

9

Double fillet weld in T-joint

For class A and B For compartment dished ends without knuckle radius

a = 0,7 s5

18

EN 12285-1:2003 (E)

8.5 External coating 8.5.1

General

General Each tank shall be provided with an external protective coating. All coatings, when applied by the tank manufacturer, shall be in accordance with the coating manufacturer's instructions. Where the temperature of carbon steel can fall below normal operating temperatures and the tanks are used for products without corrosion inhibitor, the tanks shall be provided with internal coating. In addition to any national requirements the external coating shall meet at least the requirements given in 7.5.2 and 7.5.3. 8.5.2

Surface preparation

The surface shall be prepared in accordance with the coating manufacturer's specifications for application to ensure permanent adhesion of the external coating. Where impressed current cathodic protection is required by the purchaser all surfaces shall be prepared by grit blasting to at least SA 2.5 as defined in EN ISO 8501-1. 8.5.3

Surface coating

Table 7 shows the external coatings permitted, the minimum thickness, and minimum test voltage. External coatings shall not contain chlorofluorocarbons (CFCs). Table 7 — External coating - minimum thickness and minimum test voltage

Coating material

Min. thickness mm

External surface coating tested to the following minimum test voltage V

Bitumen

with fabric reinforcement

3

14 000

without ment

5

20 000

0,7

6 000

2

15 000

Polyurethane

0,8

6 000

PVC

1,25

10 000

Epoxy Glassfibre (GRP)

reinforce-

NOTE The minimum test voltages indicated are related to the minimum thickness mentioned in this table. If the thickness is increased, the voltages should also be increased. Coatings can be tested at higher voltage than indicated.

9

Testing

9.1 General The following tests shall be carried out in the manufacturer's workshop.

19

EN 12285-1:2003 (E)

9.2 Pressure testing Single skin and inner tanks of double skin tanks and the interstitial space shall be tested in accordance with Table 8. No leakage may be observed during the pressure testing.

Table 8 — Test pressure Pt1 and Pt2 Test

Tank class

Prototype test Leak tightness interstitial space

test

of

Leak tightness test of tank

A

B

C

Test pressure

Test pressure

Test pressure

pt1 and pt2

pt1 and pt2

pt1 and pt2

in bar

in bar

in bar

0,75 air/liquid

2,0 air/liquid

10,0 or 11,0 liquid

0,4 air/liquid

0,6 air/iquid

0,6 air/liquid

0,75 liquid

2,0 liquid

2,0 liquid

or 0,3 air

or 0,3 air

9.3 Testing of the external coating Before leaving the workshop the external coating of each and every tank should be submitted to a high voltage test in order to prove its integrity. The minimum test voltage is given in Table 7. NOTE Owing to possible damage during transport, storage and handling, it is essential that this test is repeated on the site by the installer immediately before lowering the tank into the pit.

10 Handling and installation 10.1 Handling The tank shall only be lifted by the liftings lugs provided by the tank manufacturer. The lifting lugs have to be designed to lift the tank with the inner compartments empty.

10.2 Installation Tanks designed to this standard allow for an earth cover of up to 1,5 m and for the tank to withstand imposed traffic loads from a properly constructed roadway. This will provide a reasonable safety factor. A greater or lower earth cover may require calculation. The access chamber shall be designed in such a way to prevent loads from the traffic area above being transmitted to the tank. The methods used to secure the tank in the excavation shall not damage the coating of the tank. NOTE

20

For further information see annex A.

EN 12285-1:2003 (E)

11 Marking of the tank and manufacturer's statement


Marking of the tank Each tank shall be marked using a durable label which shall be corrosion resistant and resistant to the stored product. The label shall be fixed to the tank on or close to the manhole of the tank. The label shall contain the following information as a minimum: 

Name and address of manufacturer



Year of manufacture



Serial number of tank



Designation in accordance with 3



Type of coatings



Mass of empty tank



Type of leak detection liquid (when supplied)

In addition each compartment shall be provided with a label indicating the nominal volume in m³ of that compartment.

11.2 Manufacturer's statement The manufacturer shall provide a statement for each tank giving at least the information included in 10.1 and the material chosen.



 Drawings The manufacturer shall provide a drawing showing all important dimensions, compartments and connections.

21

EN 12285-1:2003 (E)

Annex A (informative) Transport, storage and installation procedure

A.1

Transport

The tank should be placed on the vehicle in such a way to ensure that the surface coating of the tank is not damaged. The tanks should be carefully fixed on the vehicle to prevent movement while being transported, using webbing or other fixing methods, which will not damage the tank coating. The tank should be controlled while suspended by the use of guide ropes when placing the tank in position. Where two lifting lugs are used the lifting angle between the guide ropes should not exceed 120°. A.2

Storage

When stored on site before installation the tanks should be placed on a level surface, free from protrusions, and on a suitable base to protect the coating (i. e. sand, foam etc.). The position should be chosen to avoid accidental damage from site traffic and the tanks should be restrained from rolling. A.3 A.3.1

Installation procedure Planning

Prior to commencement of the installation the site conditions should be determined and recorded, the type of ground will determine the need and type of ground support. Overhead cables and underground service should be plotted. The installation should be set out, taking care not to undermine any existing structures or damage underground services. A.3.2

Ground works

Proper care should be taken to ensure that the excavation does not collapse, the use of sheet piling or other proved methods should be adopted. De-watering facilities should be provided in cases of high water table. Owing to possible damage during transport, storage and handling, it is essential that the coating of each tank should be subject to a high voltage test in accordance with Table 7. Where coating is damaged it should be repaired and retested. The tank should be securely fixed in the installation using a suitable method to prevent any movement of the tank (e. g. anchored to a concrete base). The tank should be installed on a levelled base. A.3.3

Backfill materials

The backfill used should be non-cohesive granular material which will surround the tank to give adequate support and restrain. The choice of backfill used may well depend upon the native soils and their compatibility with the coating of the tank. For possible combinations see Table A.1. 22

EN 12285-1:2003 (E)

All backfill material should be washed, graded and free flowing, free from ice, clay, organic materials and free of 3 heavy objects. The minimum bulk density should be 1500kg/m . Table A.1 — Recommended backfill according to coating used BACKFILL

Sand

Gravel

Stone crushings

COATING Bitumen

__

X

X

Epoxy

__

_

X

Glassfibre

__

_

_

Polyurethane

__

_

_

PVC

__

_

_

_ _ Recommended _

Possible

X

Not recommended (but eventually according to coating producers instructions possible, see 7.5.1)

Sand Sand should be well graded and shall have less than 8 % passing a 75
m screen with the largest particle size less than 3 mm. Gravel The backfill material should not have more than 3 % passing a 2,4 mm screen. The material shall be well-rounded pea gravel with a mix of particle size not less than 3 mm and not more than 20 mm. Stone crushings Stone crushings with angular particle size of not less than 3 mm not more than 16 mm, not more than 3 % should pass a 2,4 mm screen. A.3.4

Installing backfill

Sufficient backfill should be placed on the excavation base before the tank is lowered in the excavation. Backfill should be carefully placed around the installation. The installer should compact the backfill and where necessary use mechanical methods to ensure the backfill reaches all parts of the excavation. Sufficient backfill should be placed above the top of the tank. A.3.5

Access chamber

An access chamber being liquid tight and capable of preventing any spilt liquid being stored from entering the environment should be fitted to the tank.

23

EN 12285-1:2003 (E)

Annex B (informative) Evaluation of liquid-material-combinations for storage tanks according to this standard

B.1

General

This Annex provides evaluations of chemical loads resulting from liquids stored in tanks as described in this standard, considering specific materials used and specific working conditions. Owing to the number of possible liquid-material-combinations, the list cannot be final and complete and should always be open for new liquids and new materials to be added. NOTE This Annex applies to above- and underground tanks. It should be considered, as far as this standard is concerned, that the groups C and F relate to underground tanks.

B.2

Criteria for evaluation

B.2.1

Conditions for resistance

B.2.1.1

Design for tanks

The tank should be manufactured in accordance with the standard. The materials defined by EN 10025 and EN 10088-1 may be used. In addition to that P235GH and P265GH of EN 10028-2 may also be used. The positive-liquid list provides information about the use of the relevant liquid when storing in tanks whose liquidtouched wall consists of the following materials: Table B.1 — Tank materials Steel specification

24

Material Code

Standard

S235JRG1

1.0036

EN 10025

S235JR

1.0037

EN 10025

S235JRG2

1.0038

EN 10025

S235J2G3

1.0116

EN 10025

S275J2G3

1.0144

EN 10025

P235GH

1.0345

EN 10028-2

P265GH

1.0425

EN 10028-2

X2CrNi 1911

1.4306

EN 10088-1

X6CrNiTi 1810

1.4541

EN 10088-1

X6CrNiMoTi 17 122

1.4571

EN 10088-1

X4CrNiMo 17 121

1.4401

EN 10088-1

X2CrNiMo 17 122

1.4404

EN 10088-1

X2CrNiMo 18 143

1.4435

EN 10088-1

EN 12285-1:2003 (E)

B.2.1.2

Purity of liquids

The evaluations of resistance of materials are valid for tradable and technically pure liquids only. The evaluations are not valid for waste or mixtures containing an undefined number and concentration of liquid-additions or impurities. B.2.1.3

Conditions

The safe working of a tank during its lifetime needs to consider the liquid-material combination. Therefore, conditions in B 2.2 to B 4.3.2 are defined. The conditions belonging to a material-liquid combination are identified in table B 2. The liquid-material combination is safe when the conditions are fulfilled. B.2.2

Condition for an evaluation Liquid-materials-combinations are considered valid when

B.2.2.1 

the decrease of the wall thickness caused by corrosion (area-corrosion) does not exceed 0,1 mm per year and



local corrosion is not expected.

B.2.2.2

Liquid-material-combinations are not considered valid when one of the listed points is given:



the decrease of the wall thickness by area-corrosion exceeds 0,1 mm per year,



liquids will cause stress corrosion at the working temperature,



other local corrosions, e. g. pitting corrosion, are to be expected under the given conditions,



the liquid can react with the tank wall in a dangerous way (e. g. catalytic decomposition of the liquid).

B.3

Evaluation of liquids not mentioned in the positive-liquid-list

The storage of liquids, which are not mentioned in the positive-liquid-list, may also be approved if the qualification of the liquid-material-combination according to B 2.2.1, B 2.2.2 and B 4.2 is demonstrated by using the form shown in appendix 1, laboratory tests or relevant literature. If required by national regulation, the references by laboratory tests or relevant literature should be confirmed according to the national rules. NOTE

B.4

Information usually is sent to the national competent authority.

Use of the positive-liquid-list

B.4.1 1)

1)

Classification1) of the flammable liquids into danger classes (Table B.2 column 5) Danger class A:

Liquids with a flamepoint not exceeding 100°C, which do not show any property of danger class B regarding water solubility, namely

Danger class A I:

Liquids with a flash point below 21°C,

Danger class A II:

Liquids with a flash point of 21°C up to 55°C,

Danger class A III:

Liquids with a flash point above 55°C up to 100°C

Danger classes of liquids of this Standard should not be interpreted as tank classes defined in 3.1.4

25

EN 12285-1:2003 (E)

2)

B.4.2

Danger class B:

Liquids with a flash point below 21°C, which are water soluble at 15°C or the flammable liquid elements of which are water soluble at 15°C.

Classification of the tanks according to their working conditions (Table B.2 columns 7, 9 and 11)

B.4.2.1

Pressureless tanks

Group A:

Pressureless tank without specific precautions against heating up.

Group B: Pressureless tank with a temperature under working conditions measured directly at the tank wall not exceeding 40°C (e. g. aboveground tank standing in a room or tank with specific precaution against heating up). Maintaining a light coloured coating is considered as suitable precaution against radiated heat. Group C: Pressureless tank with a temperature under working conditions measured directly at the tank wall not exceeding 30°C (e. g. underground tank, 0,8 m earth-covered, or tank with an equivalent isolation). B.4.2.2

Tanks with internal working pressure (less than 0,5 bar)

Group D:

Tank with internal working pressure without any precaution against radiated heat.

Group E: Tank with internal working pressure with a temperature under working conditions measured directly at the tank wall not exceeding 40°C (e. g. aboveground tank standing in a room or tank with specific precaution against heating up). Maintaining a light coloured coating is considered a suitable precaution against radiated heat. Group F: Tank with internal working pressure with a temperature under working conditions measured directly at the tank wall not exceeding 30°C (e. g. underground tank, 0,8 m earth-covered, or tank with an equivalent isolation). B.4.3

Conditions for the use of the liquids (Table B.2 columns 8, 10 and 12)

B.4.3.1

Conditions related to liquids

Code/purity A:

Free from water

A1: Mass of water ≤ 10 % A2: Mass of water < 0,05 % A3: Mass of water < 0,08 % and free from amines A4: Mass of water < 0,001 % A5: Mass of water < 0,3 % A6: Mass of water < 0,1 % A7: Mass of water < 0,2 % B:

Free from bromide and chloride

B1: Mass of hydrocarbon mixtures shall only consist of aliphatic and alicyclic settled hydrocarbonates, monoolefines and aromatic hydrocarbonates. B2: Only alcohols free from bromide and chloride and without further functional groups in the molecule (only OH groups in hydrocarbon groundstructure) 26

EN 12285-1:2003 (E)

C:

Free from acid (pH value 6,5 to 8,5)

C1: Free from sulphur acid C2: Alkaline (pH value > 8,5) C3: pH value ≤ 7 C4: pH value 3 to 6 C5: Mass of formic acid ≤ 2 % C6: Mass of sulphur trioxide > 25 % C7: pH value of the water 5 to 9 D:

Mass of chloride < 0,5 %; pH value 5 at minimum

E:

Free from mixtures; except necessary stabilizers

E1: Free from iron salts E2: Free from arsen-V-connections F:

Free from fluoride

F1: Mass of fluoride < 0,5 % and mass of chloride < 350 ppm G: Free from ammonium salts I:

Only with inhibitors against corrosion, e. g. amines or ammonia

L:

Not free from water

L1: Mass of water > 0,05 %; no copper, tin or lead as part of the metal alloy S:

Free from sulphur

B.4.3.2

Conditions related to working conditions

Code H, H1,

Temperature of the liquid under working conditions, in particular when heating, filling and evacuating

H2,H3: the tank, should not exceed 30°C. H4: Temperature of the liquid under working conditions, in particular when heating, filling and evacuating the tank, should not exceed 40°C. H5: Temperature of the liquid under working conditions, in particular when heating, filling and evacuating the tank, should not exceed 65°C. H6: Temperature of the liquid under working conditions, in particular when heating, filling and evacuating the tank, should not exceed 100°C. H7: Tanks should be installed in a manner to take into account heating, caused by climatic changes. The temperature at the tank wall should not exceed 25°C. 27

EN 12285-1:2003 (E)

H8: Temperature of the liquid under working conditions, in particular when heating, filling and evacuating the tank, should not exceed 200°C. K1: Inner tank wall completely free from rust K2: Material free from copper K3: When changing the liquid the tanks should be passivated by an oxal solution before filling. M: The tanks should be installed in such a manner that the temperature of the liquid does not exceed 30°C. N:

Nitrogen or another suitable inert gas should be introduced into the tanks in order to create a permanent overpressure.

T:

At the time of filling it is essential that the tank is technically free from water and should be tightly sealed to avoid moisture increase. Where moisture may gain entry condition N is applicable.

T1: It is essential that the tank under working condition is properly vented. The vent should have an air drying system to avoid moisture entering the tank. U:

Only solution liquids (alcalic solutions) and their defined mixtures of which (or of its components) the acceptance with the tank material is proved or certified according to 3.

U1: The solution is permitted for warm hydrous solutions of ammonium nitrate in concentration of more than 80 % and 93 % at maximum assuming that a)

the pH value of the liquid measured in a 10 % hydrous solution is between 5 and 7 and

b)

the solutions do not include more than 0,2 % flammable liquids and chloreous compounds of chlorine with a chloreous content of more than 0,2 %.

The tanks are provided with a shut-off-device, which is designed in such a way that no overpressure will exist in the tank and which protects the tank against leakage and the increase of foreign liquids. The shut-off-device of the tank should be designed in such a way that the storaged ammonium nitrate will not effect its operation. B.4.4 act. aq. b.p. conc. ctg. f.p. liq. n.i.l. p(50) soln. subst. u.o.n. °C + 0 UN-Nr.

28

Explanation of the abbreviations in the positive-liquid-list Active Aqueous Start of boiling (boiling point) Concentration Containing Flash point Liquid Only solvents mentioned in the positive-liquid-list Vapour pressure at 50°C Solution Substance Unless otherwise named in the positive-liquid-list Degrees centigrade Liquid is allowed Liquid is not allowed Liquid has not been evaluated Number for the marking of the medium according to a medium list prepared by the United Nations

EN 12285-1:2003 (E)

Table B.2 — Positive-liquid-list No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C °C

Material No. kg/l

mbar

1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying

Group of tank

Qualifying

Group of tank

Qualifying

A B C D E F

conditions

A B C D E F

conditions A B C D E F

conditions

2

3

4

5

6

7

8

9

10

11

12

1

Acetal, with a f.p. of -18 to below 21°C

1088

102

0,16

AI




++++++

AC

++++++

++++++

2

Acetal, with a f.p. below -18°C

1088

102

0,16

AI

0,83

++++++

AC

++++++

++++++

3

Acetaldehyde

1089

21

2,8

B

0,79

---+++

EN

---+++

4

Acetaldol

2839

182




1,11

++++++

AC

++++++

5

Acetic acid, aq. soln. ctg. 50 to 80% of pure acid

2790









------

++++++

BH4

++++++

B

6

Acetic acid, aq. soln. ctg. over 25% to below 50% of pure acid

2790









------

++++++

BH4

++++++

B

7

Acetic acid, aq. soln. ctg. more than 80% of pure acid

2789









------

++++++

BH4

++++++

B

8

Acetic acid, technical grade, purity 99,7% min.

2789

118

0,08

1,06

------

++++++

BH4

++++++

B

9

Acetic anhydride

1715

140

0,04

1,09

------

++++++

10

Acetoin, monomeric, 85% aq. soln.

2621

 


 

1,02

------

M1

------

11

Acetone

1090

56

0,84

B

0,8

++++++

C

++++++

12

Acetone cyanohydrin, stabilized

1541

115

0,02

A III

0,93

++++++

C3

++++++

13

Acetone oil, with a f.p. of -18 to below 0°C

1091

75




AI

0,89

0 0 0 0 0 0

++++++

++++++

14

Acetone oil, with a f.p. of 0 to below 21°C

1091

75




AI

0,89

0 0 0 0 0 0

++++++

++++++

A II

N

---+++

N

++++++

++++++ M1

0 0 0 0 0 0 ++++++

C3

++++++

C3

29

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling Vapour Danger Density point pressure class at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425 Group of tank

1

Group of tank

Qualifying

A B C D E F conditions A B C D E F conditions A B C D E F

conditions

2

3

4

5

6

7

1648

80

0,37

B

0,79

++++++

202




A III

1,03

++++++

15

Acetonitrile

16

Acetophenone

17

Acetylacetone

2310

140

0,07

A II

0,98

------

18

Acrolein, stabilized

1092

53

0,92

AI

0,87

-----+

19

Acrylamide, aq. soln.

2074









------

20

Acrylonitrile, stabilized

1093

77

0,4

AI

0,81

--+--+

21

Acrylic acid, stabilized

2218

141

0,03

A II

1,06

0 0 0 0 0 0

22

Adhesives, in flammable solvent, n.i.l., liq., with a

1133




 

AI


 

++++++

1133

 




AI


 

1133

 




A II


 

Qualifying

8

Group of tank

9

Qualifying

10

++++++ C

11

12

++++++

++++++

B

++++++

B

---+++

AN

---+++

AN

-----+

MN

-----+

M

0 0 +0 0 +

H3

0 0 +0 0 +

H3

--+--+

M

--+--+

M

--+--+

M

--+--+

M

U

++++++

U

++++++

U

++++++

U

++++++

U

++++++

U

++++++

U

++++++

U

++++++

U

MN

M

f.p. of-18 to below 0°C and a b.p. over 35°C 23

Adhesives, in flammable solvent, n.i.l., liq., with a f.p. of 0 to below 21°C and a b.p. over 50°C

24

Adhesives, in flammable solvents, n.i.l., liq., with a f.p. of 21 to 55°C and a b.p. over 50°C

30

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling Vapour Danger Density point pressure class at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1 25

Adhesives, in flammable solvents, n.i.l., liq., with a

Group of tank

Qualifying

Group of tank Qualifying

Group of tank

Qualifying

A B C D E F

conditions A B C D E F conditions A B C D E F

conditions

2

3

4

5

6

7

8

9

10

11

12

1133




 

A III


 

++++++

U

++++++

U

++++++

U




 

A III


 

++++++

U

++++++

U

++++++

U

1133




 

AI


 

++++++

U

++++++

U

++++++

U

1133




 

AI


 

++++++

U

++++++

U

++++++

U

1133

 




AI


 

++++++

U

++++++

U

++++++

U

f.p. of 55 up to 61°C and a b.p. over 100°C 26

Adhesives, in flammable solvents, n.i.l., liq., with a f.p. over 61 to 100°C and a b.p. over 100°C

27

Adhesives, in flammable solvents, n.i.l., liq., with a f.p. below -18°C and a b.p. over 35°C

28

Adhesives, in flammable solvents, n.i.l., viscous, with a f.p. of -18 to below 0°C and a b.p. over 35°C

29

Adhesives, in flammable solvents, n.i.l., viscous, with a f.p. of 0 to below 21°C and a b.p. over 50°C

30

Adhesives, in flammable solvents, n.i.l., viscous,

1133




 

3065

78

0,31

AI


 

++++++

U

++++++

U

++++++

U




++++++

BC

++++++

B

++++++

B

with a f.p. below -18°C and a b.p. over 35°C 31

Alcoholic beverages, with a f.p. of 21 to 55°C

31

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling Vapour Danger Density point pressure class at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

2

3

4

5

Group of tank

Qualifying

Group of tank Qualifying

Group of tank

Qualifying

A B C D E F

conditions A B C D E F conditions A B C D E F

conditions

6

7

8

9

10




++++++

BC

++++++

B

11

12

32

Alcoholic beverages, with a f.p. over 55°C up to 61°C

3065

78

0,31

33

Alcohols, injurious to health, u.o.n., liq. with a f.p.

2810




 

A III




0 0 0 0 0 0

++++++

B2

++++++

B2

2810

 




A III




0 0 0 0 0 0

++++++

B2

++++++

B2

2929

35

1,75

A II

1

0 0 0 0 0 0

++++++

B2

++++++

B2

2929

 




A II




0 0 0 0 0 0

++++++

B2

++++++

B2

2929




 

A III




0 0 0 0 0 0

++++++

B2

++++++

B2

2929

 




A III




0 0 0 0 0 0

++++++

B2

++++++

B2

over 61°C, and a b.p. over 35 to below 200°C 34

Alcohols, injurious to health, u.o.n., liq., with a f.p. over 61°C and a b.p. of 200°C min.

35

Alcohols, toxic, u.o.n., liq., with a f.p. of 21 to 55°C and a b.p. over 35 to below 200°C

36

Alcohols, toxic, u.o.n., liq., with a f.p. of 21 to 55°C and a b.p. of 200°C min.

37

Alcohols, toxic, u.o.n., liq., with a f.p. over 55°C up to 61°C and a b.p. over 35 to below 200°C or more

38

Alcohols, toxic, u.o.n., liq., with a f.p. over 55°C up to 61°C and a b.p. of 200°C min.

32

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling Vapour Danger Density point pressure class at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1 39

Alcohols, toxic, u.o.n., with a f.p.

Group of tank

Qualifying

Group of tank

Qualifying

A B C D E F

conditions A B C D E F conditions A B C D E F

conditions

2

3

4

5

6

7

1986

 




AI




1986




 

AI

1986

 




1986



2810

2810

8

Group of tank Qualifying

9

10

11

12

0 0 0 0 0 0

++++++

B2

++++++

B2




0 0 0 0 0 0

++++++

B2

++++++

B2

AI




0 0 0 0 0 0

++++++

B2

++++++

B2


 

AI




0 0 0 0 0 0

++++++

B2

++++++

B2




 

A III




0 0 0 0 0 0

++++++

B2

++++++

B2

 




A III




0 0 0 0 0 0

++++++

B2

++++++

B2

of -18 to below 21°C and a b.p. of 35°C max. 40

Alcohols, toxic, u.o.n., with a f.p. of -18°C to below 21°C and a b.p. over 35°C

41

Alcohols, toxic, u.o.n., with a f.p. below -18°C and a b.p. of 35°C max.

42

Alcohols, toxic, u.o.n., with a f.p. below -18°C and a b.p. over 35°C

43

Alcohols, toxic, u.o.n., liq., with a f.p. over 61°C and a b.p. over 35 to below 200°C

44

Alcohols, toxic, u.o.n., with a f.p. over 61°C and a b.p. of 200°C min.

33

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling Vapour Danger Density point pressure class at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425 Group of tank

1 45

Alcohols, injurious to health, u.o.n., with a f.p. of -18

Group of tank

Qualifying

Group of tank

A B C D E F conditions A B C D E F

conditions

A B C D E F conditions

2

3

4

5

6

7

1987

 




AI




1987

 




AI

1987




 

1987



1987

Qualifying

8

Qualifying

9

10

11

12

0 0 0 0 0 0

++++++

B2

++++++

B2




0 0 0 0 0 0

++++++

B2

++++++

B2

AI




0 0 0 0 0 0

++++++

B2

++++++

B2


 

AI




0 0 0 0 0 0

++++++

B2

++++++

B2

 




AI




0 0 0 0 0 0

++++++

B2

++++++

B2

1987

 




A II




0 0 0 0 0 0

++++++

B2

++++++

B2

1987




 

A III




0 0 0 0 0 0

++++++

B2

++++++

B2

to below 21°C and a b.p. of 35°C max. 46

Alcohols, not toxic or corrosive, u.o.n., with a f.p. of -18 to below 21°C and a b.p. of 35°C max.

47

Alcohols, injurious to health, u.o.n., with a f.p. of -18 to below 21°C and a b.p. over 35°C

48

Alcohols, not toxic or corrosive, u.o.n., with a f.p. of -18 to below 21°C and a b.p. over 35°C

49

Alcohols, not toxic or corrosive, u.o.n., with a f.p. of -18 to below 21°C and a b.p. over 50°C

50

Alcohols, not toxic or corrosive, u.o.n., with a f.p. of 21 to 55°C and a b.p. over 50°C

51

Alcohols, not toxic or corrosive, u.o.n., with a f.p. over 55°C up to 61°C and a b.p. over 100°C

34

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling Vapour Danger Density point pressure class at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425 Group of tank

1 52

2

Group of tank

Qualifying

Group of tank

A B C D E F conditions A B C D E F

conditions

A B C D E F conditions

3

4

5

6

7




 

A III




1987

 




AI

1987

 




1987



1987

1987

Alcohols, not toxic or corrosive, u.o.n., with a f.p.

Qualifying

8

Qualifying

9

10

11

12

0 0 0 0 0 0

++++++

B2

++++++

B2




0 0 0 0 0 0

++++++

B2

++++++

B2

AI




0 0 0 0 0 0

++++++

B2

++++++

B2


 

AI




0 0 0 0 0 0

++++++

B2

++++++

B2




 

AI




0 0 0 0 0 0

++++++

B2

++++++

B2

 




AI




0 0 0 0 0 0

++++++

B2

++++++

B2




 




0 0 0 0 0 0

++++++

B2

++++++

B2

over 61°C up to 100°C and a b.p. over 100°C 53

Alcohols, injurious to health, u.o.n., with a f.p. below -18°C and a b.p. of 35°C max.

54

Alcohols, not toxic or corrosive, u.o.n., with a f.p. below -18°C and a b.p. of 35°C max.

55

Alcohols, injurious to health, u.o.n., with a f.p. below -18°C and a b.p. over 35°C

56

Alcohols, not toxic or corrosive, u.o.n., with a f.p. below -18°C and a b.p. over 35°C

57

Alcohols, not toxic or corrosive, u.o.n., with a f.p. below -18°C and a b.p. over 50°C

58

Alcohols, not toxic or corrosive, u.o.n., with a f.p. over 100°C,

35

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling Vapour Danger Density point pressure class at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425 Group of tank

1 59

Alcohols, injurious to health, u.o.n., liq., with a f.p.

Group of tank

Qualifying

A B C D E F conditions A B C D E F conditions A B C D E F

conditions

2

3

4

5

6

7

1987

 




A II




1987

 




A II

1987

 




1987

 

1986

1986

Qualifying

8

Group of tank

Qualifying

9

10

11

12

0 0 0 0 0 0

++++++

B2

++++++

B2




0 0 0 0 0 0

++++++

B2

++++++

B2

A III




0 0 0 0 0 0

++++++

B2

++++++

B2




A III




0 0 0 0 0 0

++++++

B2

++++++

B2




 

AI




0 0 0 0 0 0

++++++

B2

++++++

B2




 

AI




0 0 0 0 0 0

++++++

B2

++++++

B2

of 21 to 55°C and a b.p. of 50 to 200°C 60

Alcohols, injurious to health, u.o.n., liq., with a f.p. of 21 to 55°C and a b.p. of 200°C

61

Alcohols, injurious to health, u.o.n., liq., with a f.p. over 55 up to 61°C and a b.p. below 200°C

62

Alcohols, injurious to health, u.o.n., liq., with a f.p. over 55 up to 61°C and a b.p. of 200°C min.

63

Alcohols, highly toxic on swallowing or skin contact, u.o.n., with a f.p. of -18 to below 21°C and a b.p over 35°C

64

Alcohols, highly toxic on swallowing or skin contact, u.o.n., with a f.p. below -18°C and a b.p. over 35°C

36

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling Vapour Danger Density point pressure class at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425 Group of tank

1 65

Alcohols, highly toxic on swallowing or skin contact,

2 1986

3  

4


5

6


AI

Group of tank

Qualifying

A B C D E F conditions A B C D E F conditions A B C D E F

conditions

7 0 0 0 0 0 0

Qualifying

8

Group of tank

Qualifying

9 ++++++

10 B2

11 ++++++

12 B2

u.o.n., with a f.p. below -18°C and a b.p. of 35°C max. 66

Alcohols, highly toxic on swallowing or skin contact,

1986

 




AI




0 0 0 0 0 0

++++++

B2

++++++

B2

2929

 




AI




0 0 0 0 0 0

++++++

B2

++++++

B2

2929




 

AI




0 0 0 0 0 0

++++++

B2

++++++

B2

2929




 

A II




0 0 0 0 0 0

++++++

B2

++++++

B2

2929

 




A II




0 0 0 0 0 0

++++++

B2

++++++

B2

u.o.n., with a f.p. of -18 to below 21°C and a b.p. of 35°C max. 67

Alcohols, highly toxic on inhalation, u.o.n., with a f.p. below 21°C and a b.p. of 35°C max.

68

Alcohols, highly toxic on inhalation, u.o.n., with a f.p. below 21°C and a b.p. over 35°C

69

Alcohols, highly toxic, u.o.n., liq., with a f.p. of 21 to 55°C and a b.p. over 35°C to below 200°C

70

Alcohols, highly toxic, u.o.n., liq., with a f.p. of 21 to 55°C and a b.p. of 200°C min.

37

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling Vapour Danger Density point pressure class at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425 Group of tank

1 71

Alcohols, highly toxic, u.o.n., liq., with a f.p. over 55

Group of tank

Qualifying

A B C D E F conditions A B C D E F conditions A B C D E F

conditions

2

3

4

5

6

7

2929




 

A III




2929

 




A III

2810




 

2810

 

2762

Qualifying

8

Group of tank

Qualifying

9

10

11

12

0 0 0 0 0 0

++++++

B2

++++++

B2




0 0 0 0 0 0

++++++

B2

++++++

B2

A III




0 0 0 0 0 0

++++++

B2

++++++

B2




A III




0 0 0 0 0 0

++++++

B2

++++++

B2

 




AI


 

------

0 0 0 0 0 0

++++++

ACU

2762




 

AI


 

------

0 0 0 0 0 0

++++++

ACU

2995




 

A II


 

------

------

++++++

ACU

up to 61°C and a b.p. over 35°C to below 200°C 72

Alcohols, highly toxic, u.o.n., liq., with a f.p. over 55°C up to 61°C and a b.p. of 200°C min.

73

Alcohols, highly toxic, u.o.n., liq., with a f.p. over 61°C and a b.p. over 35°C to below 200°C

74

Alcohols, highly toxic, u.o.n., liq., with a f.p. over 61°C and a b.p. of 200°C min.

75

Aldrin preparation, liq., ctg. 7 to 75% act. subst., with a f.p. of -18 to below 21°C and a b.p. of 35°C max.

76

Aldrin preparation, liq., ctg. 7 to 75% act. subst., with a f.p. of -18 to below 21°C and a b.p. over 35°C

77

Aldrin preparation, liq., ctg. 7 to 75% act. subst., with a f.p. of 21 to 55°C and a b.p. over 35°C

38

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling Vapour Danger Density point pressure class at 50°C

°C

mbar

Material No.

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425 Group of tank

1 78

Aldrin preparation, liq., ctg. 7 to 75% act. subst.,

Group of tank

Qualifying

A B C D E F conditions A B C D E F conditions A B C D E F

conditions

2

3

4

5

6

7

2996




 

A III


 

------

2762

 




AI


 

2762




 

AI

2995




 

2996



Qualifying

8

Group of tank

9

Qualifying

10

11

12

------

++++++

ACU

------

0 0 0 0 0 0

++++++

ACU


 

------

0 0 0 0 0 0

++++++

ACU

A II


 

------

------

++++++

ACU


 

A III


 

------

------

++++++

ACU

with a f.p. over 61°C and a b.p. over 35°C 79

Aldrin preparation, liq., ctg. over 75 up to 100% act. subst., with a f.p. over -18 to below 21°C and a b.p. of 35°C max.

80

Aldrin preparation, liq., ctg. over 75 up to 100% act. subst., with a f.p. of -18 to 21°C and a b.p. over 35°C max.

81

Aldrin preparation, liq., ctg. over 75 up to 100% act. subst., with a f.p. of 21 to 61°C and a b.p. over 35°C

82

Aldrin preparation, liq., ctg. over 75 up to 100% act. subst., with a f.p. over 61°C and a b.p. over 35°C

83

Allyl acetate

2333

103

0,18

AI

0,93

0 0 +0 0 +

ECH3

0 0 -0 0 +

H3N

0 0 -0 0 +

H3N

84

Allyl isothiocyanate, stabilized

1545

151

0,03

A II

1,02

++++++

A

++++++

BC

++++++

BC

39

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling Vapour Danger Density point pressure class at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425 Group of tank

1

Qualifying

Group of tank

Qualifying

Group of tank

Qualifying

A B C D E F conditions A B C D E F conditions A B C D E F

conditions

2

3

4

5

6

7

8

9

10

11

12

A

++++++

BC

++++++

BC

85

Allyl mustard oil, stabilized

1545

151

0,03

A II

1,02

++++++

86

Amino-p-xylene, liq.

1711

 




A III




++++++

++++++

++++++

87

2-amino-m-xylene, liq.

1711

 




A III




++++++

++++++

++++++

88

4-amino-m-xylene, liq.

1711

 




A III




++++++

++++++

++++++

89

5-amino-m-xylene, liq.

1711

 




A III




++++++

++++++

++++++

90

3-amino-o-xylene, liq.

1711

 




A III




++++++

++++++

++++++

91

Aminonitrobenzenes, isomer mixture, liq.

1661

 







++++++

92

2-(2-aminoethoxy)ethanol

3055

232




1,06

93

3-(2-aminoethylamino)propylamine

2735

200




94

N-(2-aminoethyl)ethanolamine

1760

244

95

N,N'-bis(2-aminoethyl)ethylenediamine

2259

96

N-aminoethylpiperazine

97 98

40

++++++

BH6

++++++

BH6

++++++

++++++

B

++++++

D

0,94

++++++

++++++

B

++++++

D




1,04

++++++

+++++

260

0,02

0,98

++++++

++++++

B

++++++

D

2815

220




0,99

0 0 0 0 0 0

++++++

B

++++++

D

1-aminonaphthalene, liq.

2077

299




1,13

++++++

++++++

++++++

2-aminonaphthalene, liq.

1650

306




1,06

++++++

++++++

++++++

A III

AH6

++++++

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling Vapour Danger Density point pressure class at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425 Group of tank

1

Qualifying

Group of tank

Qualifying

A B C D E F conditions A B C D E F conditions A B C D E F

conditions

8

Group of tank

9

Qualifying

2

3

4

5

6

7

10

11

A III

1,05

0 0 0 0 0 0

++++++

++++++

12

99

2'-aminophenetole

2311

233




100

3'-aminophenetole

2311

 







0 0 0 0 0 0

++++++

++++++

101

4'-aminophenetole

2311

250




1,07

0 0 0 0 0 0

++++++

++++++

102

2-aminopropane

1221

32

2,1

0,69

++++++

++++++

++++++

103

N,N'-bis(3-aminopropyl)ethylenediamine

2735

200




0,96

++++++

++++++

104

Ammonia solutions, 10 to 35%, density: 0,88 to

2672









++++++

++++++

++++++

2426

 





 

------

0 0 0 0 0 0

++++++

U1

++++++

C2

B

BG

B

++++++

D

0,957 at 15°C, in water 105

Ammonium nitrate, aq. soln., hot, conc. over 80% up to 93%

106

Ammonium polysulfide solns.

2818










++++++

C2

++++++

C2

107

Ammonium sulfide soln. with a f.p. of 21 to 61°C

2683

 


 

1,03

++++++

C2

++++++

C2

108

Ammonium sulfide, solns. with a f.p. over 61°C

2683

 


 

1,03

++++++

C2

++++++

C2

++++++

C2

109

Amyl alcohol, with a f.p. of -18 to below 21°C

1201

100

0,11

A II

0,82

++++++

ABC

++++++

B

++++++

B

110

Amyl alcohol, with a f.p. of 21 to below 55°C

1201

100

0,11

A II

0,82

++++++

ABC

++++++

B

++++++

B

41

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling Vapour Danger Density point pressure class at 50°C

°C

mbar

Material No.

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425 Group of tank

1

2

3

4

5

Qualifying

Group of tank

Qualifying

Group of tank

Qualifying

A B C D E F conditions A B C D E F conditions A B C D E F

conditions

6

7

8

9

10

11

K3

++++++

++++++

111

Aniline

1547

184




1,02

++++++

112

m-anisidine

2810

251




1,1

------

++++++

++++++

113

o-anisidine

2431

225




A III

1,09

------

++++++

++++++

114

Anisole

2222

155

0,03

A II

1

++++++

++++++

++++++

115

Aviation turbine fuel ASTM D 1695 Jet A

1223

 




A II




++++++

I

++++++

++++++

116

Aviation turbine fuel ASTM D 1695 Jet A1

1223

 




A II




++++++

I

++++++

++++++

117

Aviation turbine fuel ASTM D 1695 Jet B, with a f.p.

1863




 

AI




++++++

I

++++++

++++++

1863




 

AI




++++++

I

++++++

++++++

of -18 to below 0°C 118

Aviation turbine fuel ASTM D 1695 Jet B, with a f.p. of 0 to below 21°C

119

Aviation turbine fuel JP-1

1223

 




A II




++++++

I

++++++

++++++

120

Aviation turbine fuel JP-4, with a f.p. of

1863 


 

AI




++++++

I

++++++

++++++

1863 


 

AI




++++++

I

++++++

++++++

-18 to below 0°C 121

42

Aviation turbine fuel JP-4, with a f.p. of 0 to below 21°C

12

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling Vapour Danger Density point pressure class at 50°C

°C

mbar

Material No.

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425 Group of tank

1 122

Aviation turbine fuel JP-5, with a f.p. over 55 up to

Qualifying

Group of tank

Qualifying

Group of tank

Qualifying

A B C D E F conditions A B C D E F conditions A B C D E F

conditions

2

3

4

5

6

7

8

9

10

11

1223

 




A III




++++++

I

++++++

++++++

 




A III




++++++

I

++++++

++++++

1863




 

AI




++++++

I

++++++

++++++

1863




 

AI




++++++

I

++++++

++++++

1223

 




A III




++++++

I

++++++

++++++

= 150




A III




++++++

I

++++++

++++++

139

0,05

B

0,88

0 0 0 0 0 0

178




A III

1,05

++++++

80

0,37

AI

0,88

++++++

12

61°C 123

Aviation turbine fuel JP-5, with a f.p. over 61 up to 100°C

124

Aviation turbine fuel JP-6, with a f.p. of -18 to below 0°C

125

Aviation turbine fuel JP-6, with a f.p. of 0 to below 21°C

126

Aviation turbine fuel JP-7, with a f.p. over 55 up to 61°C

127

Aviation turbine fuel JP-7, with a f.p. over 61°C up to 100°C

128

Azacycloheptane

129

Benzaldehyde

130

Benzene

2493

1114

++++++

B

++++++

D

AC

++++++

AB

++++++

AB

ACS

++++++

++++++

43

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling Vapour Danger Density point pressure class at 50°C

°C

mbar

Material No.

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425 Group of tank

1

Qualifying

Group of tank

Qualifying

Group of tank

Qualifying

A B C D E F conditions A B C D E F conditions A B C D E F

conditions

2

3

4

5

6

7

8

9

10

11

A

++++++

++++++ ++++++

131

Benzonitrile

2224

191




A III

1,01

++++++

132

Benzothiol

2337

169




A II

1,08

------

++++++

133

Benzylamine, with a f.p. over 61°C

1719

185




A III

0,99

++++++

++++++

134

Benzyl chloride, stabilized

1738

179




A III

1,1

0 0 0 0 0 0

0 0 0 0 0 0

135

Benzyldimethylamine

2619

185




A II

0,9

++++++

BG

++++++

136

Benzylidene chloride

1886

205




A III

1,26

---+++

CET

0 0 0 0 0 0

0 0 0 0 0 0

137

Bicyclo[2.2.1]hepta-2,5-diene, stabilized,

2251

89

0,29

AI

0,91

0 0 0 0 0 0

++++++

++++++

2251

89

0,29

AI

0,91

0 0 0 0 0 0

++++++

++++++

B

B

12

++++++

D

--+--+

M

++++++

D

with a f.p. of -18 to below 21°C 138

Bicyclo[2.2.1]hepta-2,5-diene, stabilized, with a f.p. below -18°C

139

Bis(trimethylsilyl)amine

1993

126

0,08

AI

0,78

0 0 0 0 0 0

---+++

140

Bitumen, in petroleum distillates, liq., with

1999

 




AI


 

++++++

++++++

a f.p. of -18 to below 21°C and a b.p. over 50°C

44

T

---+++ ++++++

T

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling Vapour Danger Density point pressure class at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425 Group of tank

1 141

Bitumen, in petroleum distillates, liq., with

Qualifying

Group of tank

Qualifying

A B C D E F conditions A B C D E F conditions A B C D E F

conditions

8

Group of tank

9

Qualifying

2

3

4

5

6

7

10

11

1999




 

A II


 

++++++

++++++

++++++

1999

 




A III


 

++++++

++++++

++++++

 




A III


 

++++++

++++++

++++++

 




AI


 

++++++

++++++

++++++

 





 

++++++

++++++

++++++

12

a f.p. of 21 to 55°C and a b.p. over 100°C 142

Bitumen, in petroleum distillates, liq., with a f.p. over 55 up to 61°C and a b.p. over 150°C

143

Bitumen, in petroleum distillates, liq., with a f.p. over 61°C up to 100°C and a b.p. over 150°C

144

Bitumen, in petroleum distillates, viscous,

1999

with a f.p. of -18 up to 21°C and a b.p. over 50°C 145

Bitumen, in petroleum distillates, liq., with a f.p. over 100°C

45

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling Vapour Danger Density point pressure class at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425 Group of tank

1 146

2

Brake fluid, hydraulic, with a f.p. of 0 to

Qualifying

Group of tank

Qualifying

A B C D E F conditions A B C D E F conditions A B C D E F

conditions

8

Group of tank

9

Qualifying

3

4

5

6

7

10

11

100




AI




++++++

++++++

++++++

12

below 21°C 147

Brake fluid, hydraulic, with a f.p. of 21 to 55°C

100




A II




++++++

++++++

++++++

148

Brake fluid, hydraulic, with a f.p. over 55

100




A III




++++++

++++++

++++++

100




A III




++++++

++++++

++++++

100




AI




++++++

++++++

++++++

up to 61°C 149

Brake fluid, hydraulic, with a f.p. over 61 up to 100°C

150

Brake fluid, hydraulic, with a f.p. below 0°C

151

1-bromo-2-methylpropane

2342

92

0,28

AI

1,27

++++++

AC

------

++++++

AC

152

2-bromo-2-methylpropane

2342

74

0,47

AI

1,22

++++++

AC

------

++++++

AC

153

1-bromo-3-chloropropane

2688

142

0,05

A III

1,6

++++++

AC

------

++++++

AC

154

1-bromo-3-methylbutane

2341

121

0,09

A II

1,26

++++++

AC

------

++++++

A

155

Bromobenzene

2514

156

0,03

A II

1,5

++++++

46

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling Vapour Danger Density point pressure class at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425 Group of tank

1

Qualifying

Group of tank

Group of tank

Qualifying

A B C D E F conditions A B C D E F conditions A B C D E F

conditions

2

3

4

5

6

7

8

9

Qualifying

10

11

12

156

1-bromobutane, with a f.p. below 21°

1126

101

0,18

AI

1,28

++++++

AC

------

++++++

A

157

1-bromobutane, with a f.p. of 21°C min.

1126

101

0,18

A II

1,28

++++++

AC

------

++++++

A

158

2-bromobutane

2339

91

0,23

AI

1,26

++++++

AC

------

++++++

AC

159

Bromoethane

1891

38

1,48

AI

1,46

++++++

AC

------

0 0 0 0 0 0

160

2-bromopentane

2343

116

0,11

AI

1,22

++++++

AC

------

++++++

AC

161

1-bromopropane, with a f.p. of -18 to

1993

71

0,51

AI

1,35

++++++

AC

------

++++++

AC

1993

71

0,51

A II

1,35

++++++

AC

------

++++++

AC

AC

------

++++++

AC EHN

below 21°C 162

1-bromopropane, with a f.p. of 21 to 55°C

163

2-bromopropane

2344

60

0,74

AI

1,32

+ + + + +.+

164

3-bromopropene

1099

70

0,51

AI

1,43

------

------

-----+

165

Butanedione

2346

88

0,35

AI

0,99

------

++++++

++++++

166

Butanethiol, isomer mixture, with a f.p. of

2347




 

AI




------

++++++

++++++

-18 to below 21°C

47

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling Vapour Danger Density point pressure class at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425 Group of tank

1 167

Butanethiol, isomer mixture, with a f.p.

Qualifying

Group of tank

Qualifying

A B C D E F conditions A B C D E F conditions A B C D E F

conditions

8

Group of tank

9

Qualifying

2

3

4

5

6

7

10

11

2347




 

AI




------

+++++

++++++

12

below -18°C 168

1-butanethiol

2347

98

0,2

AI

0,85

------

++++++

++++++

169

2-butanethiol

2347

85

0,31

AI

0,83

------

++++++

++++++

170

1-butanol

1120

118

0,06

A II

0,81

++++++

BC

++++++

B

++++++

B

171

2-butanol, with a f.p. below 21°C

1120

100

0,12

A II

0,81

++++++

BC

++++++

B

++++++

B

172

2-butanol, with a f.p. of 21°C min.

1120

100

0,12

A II

0,81

++++++

BC

++++++

B

++++++

B

173

tert-butanol

1120

83

0,25

AI

0,79

++++++

BC

++++++

B

++++++

B

174

2-butanone

1193

80

0,38

AI

0,81

---+++

N

++++++

++++++

175

2-buten-1-ol

2614

115

0,11

A II

0,86

++++++

EC

++++++

++++++

176

2-butenal, stabilized

1143

102

0,17

AI

0,85

---+++

AN

---+++

177

2-butoxyethanol, with a f.p. of 61°C

2369

171




0,9

++++++

++++++

++++++

2369

171




0,9

++++++

++++++

++++++

N

---+++

max. 178

48

2-butoxyethanol, with a f.p. over 61°C

N

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling Vapour Danger Density point pressure class at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425 Group of tank

1

Qualifying

Group of tank

Qualifying

Group of tank

Qualifying

A B C D E F conditions A B C D E F conditions A B C D E F

conditions

2

3

4

5

6

7

8

9

10

11

12

179

Butoxyl

2708

166

0,03

A III

0,96

++++++

AC

++++++

C1

++++++

180

n-butyl acetate

1123

127

0,07

A II

0,88

++++++

AC

++++++

C1

++++++

181

sec-butyl acetate

1123

112

0,11

AI

0,87

++++++

AC

++++++

C1

++++++

182

tert-butyl acetate

1123

98

0,18

AI

0,87

++++++

AC

++++++

C1

++++++

183

n-butyl acrylate, stabilized

2348

148

0,04

A II

0,9

--+--+

CM

--+--+

C1M

--+--+

M

184

sec-butyl alcohol

1120

100

0,12

A II

0,81

++++++

BC

++++++

B

++++++

B

185

Di-n-butylamine

2248

159

0,03

A II

0,77

++++++

G

++++++

B

++++++

D

186

Di-sec-butylamine

2734

134

0,06

A II

0,75

++++++

G

++++++

B

++++++

D

187

n-butylamine

1125

78

0,32

B

0.74

++++++

BG

++++++

B

++++++

188

N,N-Di-n-butylaminoethanol

2873

222




0,86

0 0 0 0 0 0

---+++

A5BN

---+++

189

N-n-butylaniline

2738

241




0,93

++++++

++++++

++++++

190

n-butylbenzene

183




A III

0,86

++++++

EC

++++++

++++++

191

sec-butylbenzene

2709

173

0,02

A II

0,86

++++++

EC

++++++

++++++

192

tert-butylbenzene

2709

169

0,02

A II

0,87

++++++

EC

++++++

++++++

A5DN

49

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling Vapour Danger Density point pressure class at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425 Group of tank

1

Qualifying

Group of tank

Group of tank

Qualifying

A B C D E F conditions A B C D E F conditions A B C D E F

conditions

2

3

4

5

6

7

8

9

Qualifying

10

11

12 AC

193

tert-butyl bromide

2342

74

0,47

AI

1,22

++++++

AC

------

++++++

194

n-butyl butyrate

1993

166

0,02

A II

0,87

++++++

AC

++++++

++++++

195

Butyl chloride, isomer mixture, with a f.p.

1127

 




AI




++++++

AC

0 0 0 0 0 0

0 0 0 0 0 0

1127

 




AI




++++++

AC

0 0 0 0 0 0

0 0 0 0 0 0

of -18 to below 21°C 196

Butyl chloride, isomer mixture, with a f.p. below -18°C

197

sec-butyl chloride

1127

68

0,57

AI

0,88

++++++

AC

0 0 0 0 0 0

0 0 0 0 0 0

198

tert-butyl chloride

1127

51

0,99

AI

0,85

++++++

AC

0 0 0 0 0 0

0 0 0 0 0 0

199

Di-n-butyl ether

1149

140

0,04

A II

0,77

++++++

A

++++++

++++++

200

n-butyl formate

1128

107

0,14

AI

0,9

++++++

AC

++++++

201

n-butylglycol acetate

184




A III

0,94

++++++

AC

++++++

202

n-butyl isocyanate

2485

115

0,1

AI

0,89

0 0 0 0 0 0

---+++

BCT

---+++

BCT

203

tert-butyl isocyanate

2484

84

0,3

AI

0,85

0 0 0 0 0 0

---+++

BCT

---+++

BCT

204

n-butyl methacrylate, stabilized

2227

163

0,02

A II

0,9

0 0 0 0 0 0

--+--+

M

--+--+

M

50

AC1

++++++ ++++++

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

°C

Vapour Danger Density pressure class at 50°C mbar

Material No.

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425 Group of tank

Qualifying

A B C D E F

conditions

Group of tank

Qualifying

Group of tank

Qualifying

conditions

A B C D E F

conditions

10

11

12

A B C D E F 1

2

3

4

5

6

7

8

9

A

++++++

++++++ ++++++

205

n-butyl methyl ether

2350

70

0,55

AI

0,74

++++++

206

tert-butyl methyl ketone

1224

106

0,11

AI

0,81

------

++++++

207

Butylphenol, liq.

2228

200




1,03

------

++++++

E

++++++

208

Butylphenol, melted

2228

200




0,92

------

++++++

EH6

++++++

209

2-sec-butylphenol

2228

226




0,98

------

++++++

E

++++++

210

2-tert-butylphenol

2228

222




0,98

------

++++++

E

++++++

211

n-butyl propionate

1914

146

0,03

A II

0,88

++++++

AC

++++++

AC1

++++++

212

Butyltoluenes, with a f.p. of 61°C max.

2667

190




A III

0,85

++++++

AC

++++++

++++++

213

Butyltoluenes, with a f.p. over 61°C

2667

190




A III

0,85

++++++

AC

++++++

++++++

214

4-tert-butyltoluene

2667

193




A III

0,85

++++++

AC

++++++

++++++

215

n-butyl vinyl ether, stabilized

2352

94

0,22

AI

0,78

-----+

ACMN

-----+

ACMN

-----+

ACMN

216

Butyraldehyde

1129

76

0,44

AI

0,82

------

---+++

CN

---+++

N

217

n-butyric acid

2820

164

0,08

0,96

------

------

++++++

218

Butyric anhydride

2739

198




0,98

0 0 0 0 0 0

0 0 0 0 0 0

++++++

A III

BH8

51

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

°C

Vapour Danger Density pressure class at 50°C mbar

Material No.

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425 Group of tank

Qualifying

A B C D E F

conditions

Group of tank

Qualifying

Group of tank

Qualifying

conditions

A B C D E F

conditions

10

11

12

A B C D E F 1

2

3

4

5

6

7

8

9

AI

0,8

++++++

C

++++++


 

++++++

BC

++++++

219

Butyronitrile

2411

118

0,09

220

Calcium chlorate, aq. solns. with a conc.

2429






++++++ BC

++++++

BC

of 65% max. 221

Camphor oil

1130

100




A II

0,86

0 0 0 0 0 0

222

Carbon disulfide

1131

46

1,15

AI

1,27

-----+

EHN

-----+

223

Carbon tetrachloride

1846

77

0,42

1,6

--+--+

ACH

224

1-chloro-3-bromopropane

2688

142

0,05

A III

1,6

++++++

225

1-chloro-2,2-dimethylpropane

1107

84

0,4

AI

0,87

226

1-chloro-2,3-epoxypropane

2023

116

0,09

A II

227

2-chloro-4-methylaniline

2239

223




A III

228

3-chloro-2-methylaniline

2239

241




229

3-chloro-4-methylaniline, liq.

2239

241




230

4-chloro-2-methylaniline, liq.

2239

240

231

5-chloro-2-methylaniline, liq.

2239

237

52

++++++

++++++ -----+

HN

------

++++++

AC

AC

------

++++++

AC

--+--+

ACH2

------

------

1,18

++++++

AC

------

++++++

1,16

++++++

E

++++++

E

++++++

E

1,19

++++++

E

++++++

E

++++++

E

1,19

++++++

E

++++++

E

++++++

E




1,14

++++++

E

++++++

E

++++++

E




1,17

++++++

E

++++++

E

++++++

E

A III

HN

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

°C

Vapour Danger Density pressure class at 50°C mbar

Material No.

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425 Group of tank

Qualifying

A B C D E F

conditions

Group of tank

Qualifying

Group of tank

Qualifying

conditions

A B C D E F

conditions

A B C D E F 1

2

3

4

5

6

7

8

9

10

11

12

232

6-chloro-2-methylaniline

2239

220




1,19

++++++

E

++++++

E

++++++

E

233

6-chloro-3-methylaniline, liq.

2239

228




1,19

++++++

E

++++++

E

+++++

E

234

2-chloro-3-methylbutane

1107

93

0,36

AI

0,86

--+--+

ACH2

------

------

235

1-chloro-2-methylbutane

1107




 

AI




--+--+

ACH2

------

------

236

2-chloro-2-methylbutane

1107

86

0,4

AI

0,87

--+--+

ACH2

------

------

237

1-chloro-3-methylbutane

1107

99

0,22

AI

0,87

--+--+

ACH2

------

------

238

3-chloro-4-methylphenyl isocyanate, liq.

2206

226




1,21

---+++

CET

++-+++

239

1-chloro-2-methylpropane

1127

68

0,56

AI

0,88

++++++

AC

0 0 0 0 0 0

0 0 0 0 0 0

240

2-chloro-2-methylpropane

1127

51

1

AI

0,85

++++++

AC

0 0 0 0 0 0

0 0 0 0 0 0

241

1-chloro-2-nitrobenzene, liq.

1578

246




1,35

++++++

AC

0 0 0 0 0 0

0 0 0 0 0 0

242

1-chloro-3-nitrobenzene, liq.

1578

236




1,35

++++++

AC

0 0 0 0 0 0

0 0 0 0 0 0

243

2-chloro-6-nitrobenzene, liq.

2810

238




1,27

++++++

AC

0 0 0 0 0 0

0 0 0 0 0 0

244

4-chloro-2-nitrotoluene, liq.

2810

240




1,26

++++++

AC

0 0 0 0 0 0

0 0 0 0 0 0

245

4-chloro-3-nitrotoluene, liq.

2810

260




1,37

++++++

AC

0 0 0 0 0 0

0 0 0 0 0 0

CEH5T

++-+++

CEH5T

53

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

°C

Vapour Danger Density pressure class at 50°C

mbar

Material No.

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425 Group of tank

Qualifying

A B C D E F

conditions

Group of tank

Qualifying

Group of tank

Qualifying

conditions

A B C D E F

conditions

10

11

12

A B C D E F 1

2

3

4

5

6

7

8

9

246

5-chloro-2-nitrotoluene, liq.

2810

260




1,32

++++++

AC

0 0 0 0 0 0

247

1-chloro-4-nitrobenzene, liq.

1578

242




1,3

++++++

AC

0 0 0 0 0 0

0 0 0 0 0 0

248

2-chloro-4-nitrotoluene, liq.

2810

260




1,27

++++++

AC

0 0 0 0 0 0

0 0 0 0 0 0

249

3-chloro-4-nitrotoluene, liq.

2810

200




1,27

++++++

AC

0 0 0 0 0 0

0 0 0 0 0 0

250

3-chloro-1-propene

1100

44

1,21

0,95

------

------

-----+

EHN

251

2-chloroaniline, liq.

2019

209




1,21

------

++++++

E

++++++

E

252

3-chloroaniline, liq.

2019

231




1,22

------

++++++

E

++++++

E

253

Chloroanilines, isomer mixture, liq.

2019

 







------

++++++

E

++++++

E

254

Chlorobenzene

1134

132

0,07

A II

1,11

++++++

AC

------

------

255

Chlorobutane, isomer mixture, with a f.p.

1127

 




AI




++++++

AC

0 0 0 0 0 0

0 0 0 0 0 0

1127

 




AI




++++++

AC

0 0 0 0 0 0

0 0 0 0 0 0

1127

79

0,4

AI

0,89

++++++

AC

0 0 0 0 0 0

0 0 0 0 0 0

AI

of -18 to below 21°C 256

Chlorobutane, isomer mixture, with a f.p. below -18°C

257

54

1-chlorobutane

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

°C

Vapour Danger Density pressure class at 50°C

mbar

Material No.

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425 Group of tank

Qualifying

A B C D E F

conditions

Group of tank

Qualifying

Group of tank

Qualifying

conditions

A B C D E F conditions

A B C D E F 1

2

3

4

5

6

7

8

9

AI

0,88

++++++

AC

0 0 0 0 0 0

10

11

12

258

2-chlorobutane

1127

68

0,57

0 0 0 0 0 0

259

2-chloroethanol

1135

128

0,05

1,21

++++++

AC

++++++

AC

++++++

AC

260

alpha-chlorohydrin

2689

213




1,32

++++++

AC

++++++

AC

++++++

AC

261

Chloroform, stabilized with alcohols or

1888

62

0,71

1,5

--+--+

A2CM

------

--+--+

AEM

182

0,02

A III

0,87

++++++

AC

++++++

AC

++++++

AC

1993

175

0,02

A II

0,88

++++++

AC

++++++

AC

++++++

AC

1993

175

0,02

A III

0,88

++++++

AC

++++++

AC

++++++

AC

olefins 262

1-chlorooctane, pure

263

1-chlorooctane, technical grade, with a f.p. of 21 to 55°C

264

1-chlorooctane, technical grade, with a f.p. over 55°C up to 61°C

265

1-chloropentane

1107

108

0,15

AI

0,89

--+--+

ACH2

------

------

266

2-chloropentane

1107

97

0,23

AI

0,87

--+--+

ACH2

- - -- - -

------

267

3-chloropentane

1107

98

0,22

AI

0,87

--+--+

ACH2

------

------

268

3-chlorophenyl isocyanate

2810

204




1,27

---+++

CT

---+++

CT

---+++

CT

55

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour Danger Density pressure class at 50°C Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425 Group of tank

Qualifying

A B C D E F

conditions

Group of tank

Qualifying

Group of tank

Qualifying

conditions

A B C D E F conditions

A B C D E F 1

2

3

4

5

6

7

269 Chloroprene, stabilized

1991

59

0,75

AI

0,96

0 0 0 0 0 0

270 1-chloropropane

1278

47

1,16

AI

0,9

++++++

AC

------

------

271 2-chloropropane

2356

35

1,61

AI

0,87

++++++

AC

------

++++++

C

272 3-chloropropane-1,2-diol

2689

213




1,32

++++++

AC

++++++

++++++

AC

273 3-chloropropene

1100

44

1,21

AI

0,95

------

------

-----+

EHN

274 2-chlorotoluene

2238

158

0,03

A II

1,07

++++++

AC

------

------

275 3-chlorotoluene

2238

162

0,03

++++++

AC

------

------

276 4-chlorotoluene

2238

162

0,03

A II

1,06

++++++

AC

------

------

277 2-chlorotrifluoromethylbenzene

2234

137

0,05

A II

1,45

++++++

A

------

------

278 3-chlorotrifluoromethylbenzene

2234

153

0,04

A III

1,37

++++++

A

------

------

279 4-chlorotrifluoromethylbenzene

2234

139

0,05

A II

1,35

++++++

A

------

------

280 Coal tar distillate, with a f.p. of -18 to

1136




 

AI




++++++

AB

++++++

below 0°C and a b.p. over 35°C

56

8

9

10

11

12

-----+

ACMN

-----+

ACMN

AC

B

++++++

B

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C

°C

Material No.

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425 Group of tank

Qualifying

A B C D E F

conditions

Group of tank

Qualifying

Group of tank

Qualifying

conditions

A B C D E F conditions

A B C D E F 1 281 Coal tar distillate, with a f.p. of 0 to

2

3

4

5

6

7

8

9

10

11

12

1136

 




AI




++++++

AB

++++++

B

++++++

B

1136

 




A II




++++++

AB

++++++

B

++++++

B

1136




 

A III




++++++

AB

++++++

B

++++++

B




 

A III




++++++

AB

++++++

B

++++++

B

2553

 




AI




0 0 0 0 0 0

++++++

++++++

2553



0,41

A II

0,9

0 0 0 0 0 0

++++++

++++++

2553




 

A III




0 0 0 0 0 0

++++++

++++++

below 21°C and a b.p. over 50°C 282 Coal tar distillate, with a f.p. of 21 to 55°C and a b.p. over 50°C 283 Coal tar distillate, with a f.p. over 55 up to 61°C and a b.p. over 100°C 284 Coal tar distillate, with a f.p. over 61 up to 100°C and a b.p. over 100°C 285 Coal tar naphtha, with a f.p. of -18 to below 21°C and a b.p. over 50°C 286 Coal tar naphtha, with a f.p. of 21 to 55°C and a b.p. over 60°C 287 Coal tar naphtha, with a f.p. over 55 up to 61°C and a b.p. over 100°C

57

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425 Group of tank

Qualifying

A B C D E F

conditions

Group of tank

Qualifying

Group of tank

Qualifying

conditions

A B C D E F conditions

A B C D E F 1

2

288 Coal tar naphtha, with a f.p. over 61 up to 100°C and a b.p. over 100°C

3

4

5

6

7

8

9




 

A III




0 0 0 0 0 0

++++++

10

11

12

++++++

289 Cresol, isomer mixture, liq.

2076

 




A III




------

++++++

BH5

++++++

BH6

290 m-cresol, liq.

2076

202




A III

1,03

------

++++++

BH5

++++++

BH6

291 o-cresol, liq.

2076

191




A III

1,05

------

++++++

BH5

++++++

BH6

292 p-cresol, liq.

2076

202




A III

1,02

------

++++++

BH5

++++++

BH6

293 Cresols, aqueous alkaline soln.s with a

2922

= 100







------

++++++

B

++++++

B

2922







 

------

++++++

B

++++++

B

2022






A III




------

0 0 0 0 0 0

++++++

BH6

296 Cumene

1918

152

0,04

A II

0,86

++++++

A

++++++

++++++

297 Cyanamide, aq. soln. with a conc. of 50% max.

1760









--+--+

C4M

--+--+

density of not more than 1,3 kg/l 294 Cresols, aq. alkaline soln.s, with a density of not more than 1,5 kg/l 295 Cresylic acid, liq., mixture of cresols, xylenols etc.

58

C4M

--+--+

C4M

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Qualifying Group of tank Qualifying

Group of tank

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

6

7

8

9

10

11

12




------

--+--+

H1

--+--+

H1

0,79

0 0 0 0 0 0

++++++




------

--+--+

2

3

4

1935






299 Cyanoethane

2404

97

0,21

300 Inorganic cyanides, aq. solns., with a

1935






301 Cycloheptane

2241

119

0,11

AI

0,81

++++++

A

++++++

++++++

302 Cycloheptene

2242

112




AI

0,83

++++++

A

++++++

++++++

303 Cyclohexane

1145

81

0,39

AI

0,78

++++++

++++++

++++++

304 Cyclohexanethiol

3054

158

0,03

A II

0,98

------

++++++

++++++

305 Cyclohexanone

1915

156

0,03

A II

0,95

++++++

AC

++++++

++++++

306 Cyclohexene, with a f.p. of -18 to below

2256

83

0,34

AI

0,82

---+++

N

---+++

N

2256

83

0,34

AI

0,82

---+++

N

---+++

N

298 Cyanide, aq. solns., with a conc. of 30%

5

Group of tank

Qualifying

max. B

++++++ H1

--+--+

H1

conc. of 30% max.

---+++

N

21°C, stabilized 307 Cyclohexene, with a f.p. below -18°C, stabilized

59

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank Qualifying

Group of tank

Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F

conditions

12

2

3

4

5

6

7

8

9

10

11

308 Cyclohexyl acetate

2243

176

0,04

A III

0,97

++++++

AC

++++++

C1

++++++

309 Cyclohexylamine, with a f.p. of from -18

2357

135

0,07

B

0,87

++++++

++++++

++++++

310 Cyclohexylamine, with a f.p. of 21°C min.

2357

135

0,07

0,87

++++++

++++++

++++++

311 N-cyclohexylethylamine

2734

165

0,02

A II

0,88

++++++

++++++

++++++

312 Cyclohexyl isocyanate

2488

171

0,02

A II

0,99

---+++

CT

---+++

BCT

---+++

BCT

313 1,3-cyclooctadiene, stabilized

2520

143

0,04

A II

0,87

---+++

N

---+++

N

---+++

N

314 cis,cis-1,5-cyclooctadiene, stabilized

2520

151

0,04

A II

0,88

---+++

N

---+++

N

---+++

N

315 Cyclooctatetraene, stabilized

2358

142

0,04

A II

0,92

------

M1N

------

M1N

------

M1N

316 Cyclopentane

1146

49

1,05

AI

0,75

++++++

317 Cyclopentanol

2244

141

0,02

A II

0,95

++++++

BC

++++++

318 Cyclopentanone

2245

131

0,05

A II

0,95

++++++

AC

++++++

++++++

319 Cyclopentene

2246

44

1,23

AI

0,78

---+++

N

++++++

++++++

to below 21°C

60

++++++

++++++ B

++++++

B

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

5

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

6

7

8

9

10

11

12

0,89

---+++

A5N

---+++

A5BN

---+++

A5DN

2

3

4

320 Deanol

2051

134

0,04

321 Decahydronaphthalene, isomer mixture,

1147






A II




++++++

A

++++++

++++++

1147

189

0,03

A III

0,89

++++++

A

++++++

++++++

323 cis-decahydronaphthalene

1147

195

0,02

A III

0,9

++++++

A

++++++

++++++

324 trans-decahydronaphthalene

1147

187

0,03

A II

0,87

++++++

A

++++++

++++++

325 n-decane

2247

174




A II

0,73

++++++

A

++++++

++++++

197




A III

0,87

0 0 0 0 0 0

++++++

++++++

Qualifying

with a f.p. of 55°C max. 322 Decahydronaphthalene, isomer mixture, with a f.p. over 55°C

326 Dehydrolinalool 327 1,2-bis(dimethylamino)ethane

2372

120

1

B

0,77

++++++

BG

++++++

B

++++++

D

328 Di-n-propylamine

2383

105

0,17

AI

0,74

++++++

BG

++++++

B

++++++

D

329 Diacetone alcohol, pure

1148

168


 

0,94

++++++

++++++

++++++

330 Diacetone alcohol, technical grade, ctg.

1148

167

0,05

0,94

++++++

++++++

++++++

acetone, with a f.p. of 21 to 55°C

61

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F

conditions

8

9

10

11

12

2

3

4

5

6

7

1148

166

0,05

B

0,94

++++++

332 2,2'-diaminodiethylamine

2079

207




0,96

++++++

333 1,6-diaminohexane, aq. soln.

1783









------

++++++

334 1,2-diaminopropane, with a f.p. over -18

2258

119




AI

0,87

0 0 0 0 0 0

++++++

B

++++++

D

2258

119




A II

0,87

0 0 0 0 0 0

++++++

B

++++++

D

2373

88

0,29

AI

0,84

++++++

AC

++++++

++++++

2373

88

0,29

AI

0,84

++++++

AC

++++++

++++++

338 N,N-diethyl-1,3-propanediamine

2684

159

0,02

0,83

++++++

339 N,N-diethylethanolamine

2686

162

0,02

0,89

---+++

331 Diacetone alcohol, technical grade, ctg.

++++++

++++++

acetone, with a f.p. below 21°C AG

++++++

B

++++++

D

++++++

to below 21°C 335 1,2-diaminopropane, with a f.p. of 21 to 55°C 336 Diethoxymethane, with a f.p. of -18 to below 21°C 337 Diethoxymethane, with a f.p. below -18°C

62

A5N

++++++

B

++++++

D

---+++

A5BN

---+++

A5DN

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

10

11

Qualifying

2

3

4

5

6

7

8

9

12

340 Diethyl ether

1155

35

1,76

AI

0,72

++++++

A

++++++

341 Diethylamine

1154

56

0,87

B

0,71

++++++

BG

++++++

B

++++++

D

342 N,N-diethylaniline

2432

217




0,94

++++++

A

++++++

B

++++++

D

343 Diethylbenzene, isomer mixture, with a

2049






A II




++++++

AC

++++++

++++++

2049






A III




++++++

AC

++++++

++++++

345 1,2-diethylbenzene

2049

184




A II

0,87

++++++

AC

++++++

++++++

346 1,3-diethylbenzene

2049

181




A II

0,86

++++++

AC

++++++

++++++

347 1,4-diethylbenzene

2049

184




A III

0,86

++++++

AC

++++++

++++++

348 Diethyl carbonate

2366

126

0,07

A II

0,98

++++++

AC

++++++

AB

++++++

B

349 1,4-diethylenediamine, 65% aq. soln.,

2579

 







++++++

GH5K4

++++++

BH5K4

++++++

DH5K4

2685

144

0,04

0,83

------

++++++

B

++++++

D

++++++

f.p. of 21 to 55°C 344 Diethylbenzene, isomer mixture, with a f.p. over 55°C

melted 350 N,N-diethylethylenediamine

63

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C

°C

Material No.

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

2

3

4

5

6

7

8

9

10

11

12

351 1,4-diethylene dioxide

1165

101

0,17

B

1,03

---+++

EN

---+++

N

---+++

N

352 Diethylenetriamine

2079

207




0,96

++++++

AG

++++++

B

++++++

D

353 Diethyl ketone

1156

102

0,11

AI

0,81

++++++

AC

++++++

++++++

354 3,3-diethylpentane

1993

146

0,05

AI

0,75

++++++

A

++++++

++++++

355 Diethyl sulfate

1594

208




1,18

---+++

ACT

---+++

356 Diethyl sulfide

2375

92

0,25

AI

0,84

0 0 0 0 0 0

357 Diallylamine

2359

112

0,15

AI

0,79

--+--+

GH

--+--+

BH

++++++

B

358 1,2-bis(dimethylamino)ethane

2372

120

1

B

0,77

++++++

BG

++++++

B

++++++

D

359 Dibutylethanolamine

2873

222




0,86

0 0 0 0 0 0

---+++

A5BN

---+++

A5DN

360 Dibutyl ether, isomer mixture, with a f.p.

1149

 







++++++

361 Dichloroaniline, isomer mixture, liq.

1590

 





 

------

++++++

E

++++++

E

362 2,3-dichloroaniline, liq.

1590

252




1,37

------

++++++

E

++++++

E

363 2,4-dichloroaniline, liq.

1590

242




1,37

------

++++++

EH5

++++++

EH5

A II

AT

++++++

A

++++++

++++++

++++++

21°C min.

64

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

5

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

6

7

8

9

10

11

12

2

3

4

364 2,5-dichloroaniline, liq.

1590

251




1,37

------

++++++

EH5

++++++

EH5

365 2,6-dichloroaniline, liq.

1590

200




1,37

------

++++++

EH5

++++++

EH5

366 3,5-dichloroaniline, liq.

1590

266




1,37

------

++++++

EH5

++++++

EH5

367 1,2-dichlorobenzene

1591

179




A III

1,31

++++++

368 1,1-dichloroethane

2362

58

0,8

AI

1,18

------

369 1,2-dichloroethane

1184

83

0,33

AI

1,26

++++++

370 2,2'-dichloroethyl ether

1916

178




A II

1,22

------

371 cis-1,2-dichloroethylene

1150

60

0,72

AI

1,28

++++++

372 trans-1,2-dichloroethylene

1150

49

1,1

AI

1,26

373 1,2-dichloroethylene, isomer mixture

1150






AI

374 Dichloropentane, isomer mixture

1152






375 1,5-dichloropentane

1152

180




376 3,4-dichlorophenyl isocyanate, liq.

2206

238




377 1,2-dichloropropane, technical grade

1279

97

0,21

------

------

------

--+--+

EH2

0 0 0 0 0 0

---+++

ET

------

---+++

ET

AI

0 0 0 0 0 0

++++++

AI

++++++

AI

0 0 0 0 0 0

++++++

AI




++++++

AI

0 0 0 0 0 0

++++++

AI

A II




++++++

AC

------

------

A II

1,11

++++++

AC

------

------

1,39

---+++

CET

++-+++

1,16

++++++

AC

------

AI

AC

E

CEH5T

++-+++

CEH5T

++++++

AC

65

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

10

2

3

4

5

6

7

8

9

2047




 

A II




++++++

AC

------

------

379 1,2-dichloropropene, trans isomer

1993

77

0,43

AI

1,18

++++++

AC

------

------

380 1,3-dichloropropene, isomer mixture of

2047




 

A II




++++++

AC

------

------

381 3,3-dichloropropene

1993

84

0,33

AI

1,18

++++++

AC

------

------

382 1,1-dichloro-1-propene

1993

76

0,43

AI

1,17

++++++

AC

------

------

383 2,3-dichloro-1-propene

1993

94

0,28

AI

1,21

++++++

AC

------

------

384 Dicyclohexylamine

2565

256




A III

0,91

++++++

++++++

++++++

385 N,N-dicyclohexylamine

2264

159

0,03

A II

0,85

++++++

386 Dicyclopentadiene

2048

167

0,03

A II

0,98

++++++

++++++

++++++

387 Diesel fuel, DK type

1202




 

A III




++++++

++++++

++++++

388 Diisobutyl ether

1993

121

0,09

AI

0,76

++++++

A

++++++

++++++

389 Diisobutylamine

2361

139

0,05

A II

0,75

++++++

G

++++++

378 Dichloropropene, isomer mixture, with a

11

Qualifying

12

f.p. of 21°C min.

the cis and trans forms

66

BG

++++++

B

B

++++++

++++++

D

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

A B C D E F

conditions A B C D E F

conditions

A B C D E F conditions

10

11

Qualifying

2

3

4

5

6

7

8

9

12

390 Diisobutyl ketone

1157

168

0,02

A II

0,81

++++++

AC

++++++

++++++

391 Diisopentyl ether, mixture of 2- and 3-

1993

 




A II


 

0 0 0 0 0 0

++++++

++++++

1158

84

0,34

B

0,72

++++++

++++++

B

++++++

D

191




0,87

0 0 0 0 0 0

---+++

A5BN

---+++

A5DN

methyl butyl ether 392 Diisopropylamine 393 N,N-diisopropylethanolamine 394 Diisopropyl ether

1159

69

0,55

AI

0,73

++++++

A

++++++

++++++

395 1,2-dimethoxyethane

2252

85

0,28

B

0,87

---+++

CN

---+++

396 1,1-dimethoxyethane, with a f.p. of -18

2377

65

0,64

B

0,85

---+++

CN

++++++

++++++

2377

65

0,64

B

0,85

---+++

CN

++++++

++++++

398 Dimethoxymethane

1234

42

1,35

B

0,86

++++++

AC

++++++

++++++

399 Dimethyl sulfate

1595

188




A III

1,34

---+++

CT

---+++

400 Dimethyl sulfide

1164

37

1,63

AI

0,85

++++++

C

++++++

N

++++++

N

to below 21°C 397 1,1-dimethoxyethane, with a f.p. below -18°C

CT

---+++

CT

++++++

67

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

10

2

3

4

5

6

7

8

9

401 2,3-dimethyl-1-butene

2288

56

0,9

AI

0,69

---+++

N

++++++

++++++

402 2,3-dimethyl-2-butene

2288

73

0,47

AI

0,71

---+++

N

++++++

++++++

403 3,3-dimethyl-1-butene

2288

41

1,48

AI

0,66

---+++

N

++++++

++++++

404 2,5-dimethyl-1,4-dioxane

2707

118

0,1

AI

0,93

0 0 0 0 0 0

---+++

N

---+++

N

405 4,4-dimethyl-1,3-dioxane

2707

117

0,1

A II

0,95

0 0 0 0 0 0

---+++

N

---+++

N

406 2,3-dimethyl-3-ethylpentane

1993

142

0,04

AI

0,75

++++++

A

++++++

++++++

407 2,4-dimethyl-3-ethylpentane

1993

137

0,05

AI

0,74

++++++

A

++++++

++++++

408 2,2-dimethyl-1-propylamine

1106

81

0,41

B

0,75

++++++

G

++++++

B

++++++

D

409 Dimethyl-N-propylamine

2266

77

0,48

B

0,75

++++++

G

++++++

B

++++++

D

410 Dimethylamine, 25% soln. in water

1160




 

B

0,95

++++++

G

++++++

B

++++++

D

411 Dimethylamine, 40% soln. in water

1160






B

0,9

++++++

G

++++++

B

++++++

D

412 Dimethylamine, 60% soln. in water

1160




 

B

0,83

++++++

G

++++++

B

++++++

D

413 Dimethylamine, aq. soln., with a f.p. of

1160




 

B




++++++

G

++++++

B

++++++

D

-18 to below 21°C and a b.p. over 35°C.

68

11

Qualifying

12

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

2

3

4

5

6

7

8

9

10

11

12

2924

 




B




++++++

G

++++++

B

++++++

D

1160




 

B




++++++

G

++++++

B

++++++

D

416 N,N-dimethylaniline

2253

193




A III

0,96

++++++

A

++++++

B

++++++

D

417 Dimethylaniline, isomer mixture, liq.

1711

 




A III




++++++

++++++

++++++

418 2,3-dimethylaniline, liq.

1711

 




A III




++++++

++++++

++++++

419 2,4-dimethylaniline, liq.

1711

 




A III




++++++

++++++

++++++

420 2,5-dimethylaniline, liq.

1711

 




A III




++++++

++++++

++++++

421 2,6-dimethylaniline, liq.

1711

 




A III




++++++

++++++

++++++

422 3,5-dimethylaniline, liq.

1711

 




A III




++++++

++++++

++++++

423 N,N-dimethylbenzylamine

2619

185




A II

0,9

++++++

BG

++++++

B

++++++

D

424 2-methylbutan-2-ol

1105

102

0,11

B

0,81

++++++

ABC

++++++

B

++++++

B

414 Dimethylamine, aq. soln., with a f.p. below -18°C and a b.p. of 35°C max. and a p(50) of 3 bar max. 415 Dimethylamine, aq. soln., with a f.p. below -18°C and a b.p. over 35°C

69

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

10

2

3

4

5

6

7

8

9

425 2,2-dimethylbutane

1208

50

1,03

AI

0,65

++++++

A

++++++

++++++

426 2,3-dimethylbutane

2457

58

0,79

AI

0,67

++++++

A

++++++

++++++

427 1,3-dimethylbutylamine

2379

106

0,15

B

0,75

++++++

G

++++++

B

++++++

428 Dimethyl carbonate

1161

90

0,23

AI

1,07

++++++

AC

++++++

A

++++++

429 1,1-dimethylcyclohexane

2263

120

0,11

AI

0,78

++++++

A

++++++

++++++

430 cis-1,2-dimethylcyclohexane

2263

129

0,11

AI

0,8

++++++

A

++++++

++++++

431 cis-1,3-dimethylcyclohexane

2263

120

0,11

AI

0,78

++++++

A

++++++

++++++

432 cis-1,4-dimethylcyclohexane

2263

124

0,11

AI

0,78

++++++

A

++++++

++++++

433 trans-1,2-dimethylcyclohexane

2263

123

0,11

AI

0,77

++++++

A

++++++

++++++

434 trans-1,4-dimethylcyclohexane

2263

120

0,11

AI

0,76

++++++

A

++++++

++++++

435 1,2-dimethylcyclohexane, isomer mixture

2263






AI


 

++++++

A

++++++

++++++

436 1,3-dimethylcyclohexane, isomer mixture

2263

 




AI


 

++++++

A

++++++

++++++

437 Dimethyldioxanes with a f.p. of -18 to

2707

120

0,11

A II

0,95

0 0 0 0 0 0

below 21°C

70

---+++

N

11

---+++

Qualifying

12

D

N

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1 438 Dimethyldioxanes with a f.p. of 21 to

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

8

9

10

11

12

2

3

4

5

6

7

2707

120

0,11

A II

0,95

0 0 0 0 0 0

---+++

N

---+++

N

2707

120

0,11

A III

0,95

0 0 0 0 0 0

---+++

N

---+++

N

120

0,11

A III

0,95

0 0 0 0 0 0

---+++

N

---+++

N

A5BN

---+++

A5DN

55°C 439 Dimethyldioxanes with a f.p. over 55°C up to 61°C 440 Dimethyldioxanes with a f.p. over 61°C 441 N,N-dimethylethanolamine

2051

134

0,04

0,89

---+++

A5N

---+++

442 N,N-dimethylformamide

2265

153

0,03

0,95

++++++

A1G

++++++

++++++

443 2,3-dimethylheptane

1920

141

0,05

A II

0,73

++++++

A

++++++

++++++

444 2,4-dimethylheptane

1993

134

0,06

A II

0,71

++++++

A

++++++

++++++

445 2,5-dimethylheptane

1920

136

0,06

A II

0,72

++++++

A

++++++

++++++

446 2,6-dimethylheptane

1920

135

0,06

A II

0,71

++++++

A

++++++

++++++

447 3,3-dimethylheptane

1920

137

0,05

A II

0,73

++++++

A

++++++

++++++

448 3,5-dimethylheptane

1920

136

0,06

A II

0,72

++++++

A

++++++

++++++

449 4,4-dimethylheptane

1920

135

0,06

A II

0,72

++++++

A

++++++

++++++

71

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

10

2

3

4

5

6

7

8

9

450 2,2-dimethylhexane

1262

107

0,15

AI

0,7

++++++

A

++++++

++++++

451 2,3-dimethylhexane

1262

116

0,11

AI

0,71

++++++

A

++++++

++++++

452 2,4-dimethylhexane

1262

109

0,14

AI

0,7

++++++

A

++++++

++++++

453 2,5-dimethylhexane

1262

109

0,14

AI

0,69

++++++

A

++++++

++++++

454 3,3-dimethylhexane

1262

112

0,13

AI

0,71

++++++

A

++++++

++++++

455 3,4-dimethylhexane

1262

118

0,11

AI

0,72

++++++

A

++++++

++++++

456 N,N'-dimethylhydrazine

2382

80

0,32

AI

0,83

0 0 0 0 0 0

++++++

0 0 0 0 0 0

457 N-N-dimethylhydrazine

1163

63

0,63

B

0,79

---+++

++++++

0 0 0 0 0 0

458 2,6-cis-dimethylmorpholine

1993

142




A II

0,94

++++++

++++++

++++++

459 Dimethylnitrobenzene, isomer mixture, liq.

1665

 




A III




++++++

C

++++++

++++++

460 2,3-dimethylnitrobenzene, liq.

1665

245




1,14

++++++

C

++++++

++++++

461 2,4-dimethylnitrobenzene, liq.

1665

244




1,13

++++++

C

++++++

++++++

462 2,5-dimethylnitrobenzene, liq.

1665

241




1,13

++++++

C

++++++

++++++

463 2,6-dimethylnitrobenzene, liq.

1665

225




1,11

++++++

C

++++++

++++++

72

A III

T

11

12

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

5

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

6

7

8

9

10

1,14

++++++

C

++++++

++++++

11

Qualifying

2

3

4

12

464 3,4-dimethylnitrobenzene, liq.

1665

244




465 2,3-dimethyloctane

1993

164

0,03

AI

0,75

++++++

A

++++++

++++++

466 2,5-dimethyloctane

1993




 

A II


 

++++++

A

++++++

++++++

467 2,7-dimethyloctane

1993

160

0,03

AI

0,73

++++++

A

++++++

++++++

468 4,5-dimethyloctane

1993

162

0,03

A II

0,76

++++++

A

++++++

++++++

469 2,2-dimethylpentane

1206

79

0,42

AI

0,67

++++++

A

++++++

++++++

470 2,3-dimethylpentane

1206

90

0,29

AI

0,7

++++++

A

++++++

++++++

471 2,4-dimethylpentane

1206

81

0,37

AI

0,68

++++++

A

++++++

++++++

472 3,3-dimethylpentane

1206

86

0,32

AI

0,69

++++++

A

++++++

++++++

473 Dimethylphenol, isomer mixture, liq.

2261

 




A III




------

++++++

++++++

474 2,4-dimethylphenol, liq.

2261

 







------

++++++

++++++

475 2,6-dimethylphenol, liq.

2261

 




A III




------

++++++

++++++

476 1,1-dimethylpropylamine

1106

77

0,48

B

0,75

++++++

G

++++++

B

++++++

D

477 1,2-dimethylpropylamine

2924

82

0,41

B

0,76

++++++

G

++++++

B

++++++

D

73

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying

Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F

conditions

2

3

4

5

6

7

8

9

10

11

12

478 N,N-dimethylpropylamine

2266

77

0,48

B

0,75

++++++

G

++++++

B

++++++

D

479 1,1-dimethylpropyl methyl ether

1993

85

0,36

AI

0,77

0 0 0 0 0 0

++++++

++++++

480 Dimethylthiophosphoryl chloride

2267

170




A III

1,31

------

0 0 0 0 0 0

-----+

EH1T

481 N,N-dimethyltrimethylenediamine, with a

2733

134

0,04

AI

0,81

++++++

++++++

B

++++++

D

2733

134

0,04

0,82

++++++

++++++

B

++++++

D

483 4,6-dinitro-o-cresol, liq., pure

1598

312




1,4

0 0 0 0 0 0

++++++

BH8

++++++

BH8

484 Dinitroanilines, liq.

1596

300




1,62

++++++

AH6

++++++

BH6

++++++

BH6

485 1,2-dinitrobenzene, liq.

1597

318




1,31

++++++

ACH8

++++++

H8

++++++

H8

486 1,3-dinitrobenzene, liq.

1597

302




1,36

++++++

ACH8

++++++

H8

++++++

H8

487 1,4-dinitrobenzene, liq.

1597

298




1,4

++++++

ACH8

++++++

H8

++++++

H8

488 Dinitrobenzenes, isomer mixture, liq.

1597

 







++++++

ACH8

++++++

H8

++++++

H8

489 2,4-dinitrophenol, aq. soln.

1599









------

f.p. of 0 to below 21°C 482 N,N-dimethyltrimethylenediamine, with a f.p. of 21 to 55°C

74

++++++

++++++

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

5

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

6

7

8

9

10

2

3

4

11

12

490 Dinitrotoluene, isomer mixture, liq.

2038









++++++

C

++++++

491 Dinitrotoluene, isomer mixture, melted

1600







 

++++++

CH8K4

++++++

H8KA

++++++

H8KA

492 Dioxane

1165

101

0,17

B

1,03

---+++

EN

---+++

N

---+++

N

493 Dioxolane

1166

74

0,46

B

1,07

0 0 0 0 0 0

---+++

N

---+++

N

494 Dipentene, isomer mixture

2052




 

A II




------

++++++

++++++

495 Dipentyl ether, technical grade, mixture of

1993

 




A II


 

0 0 0 0 0 0

++++++

++++++

2489









0 0 0 0 0 0

---+++

BCT

---+++

BCT

2489

300




1,24

0 0 0 0 0 0

---+++

BCT

---+++

BCT

498 Dodecaethyl pentasilicate

1993

160




A II

1,06

++++++

++++++

++++++

499 Dodecadiphenylamine

2565

256




A III

0,91

++++++

++++++

++++++

500 Dodecylbenzenesulfonic acid, pure

2586

230




1,06

------

0 0 0 0 0 0

++++++

++++++

di-n-amyl ether and diisoamyl ether 496 Diphenylmethane 4,4'-diisocyanate, isomer mixture, liq. 497 Diphenylmethane 4,4'-diisocyanate, technical grade, liq.

B

75

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

10

2

3

4

5

6

7

8

9

11

12

501 Epichlorohydrin

2023

116

0,09

A II

1,18

++++++

AC

------

++++++

E

502 1,2-epoxybutane, stabilized

3022

63

0,56

AI

0,84

-----+

EK1MN

-----+

EMN

-----+

EMN

503 1,2-epoxypropane, stabilized

1280

34

1,71

AI

0,84

-----+

EK1MN

-----+

EMN

-----+

EMN

504 Ethanol

1170

78

0,31

B

0,79

++++++

BC

++++++

B

++++++

B

505 Ethanol, aq. soln. ctg. over 24% up to

1170

 







++++++

BC

++++++

B

++++++

B

1170

 







++++++

BC

++++++

B

++++++

B

 







++++++

BC

++++++

B

++++++

B

70% of ethanol 506 Ethanol, aq. soln. ctg. more than 70% of

B

ethanol 507 Ethanol, aq. soln. ctg. not more than 24% of ethanol 508 Ethanolamine

2491

169




1,02

++++++

++++++

++++++

509 Ethanolamine soln.

2491









++++++

++++++

++++++

510 Ethanethiol

2363

35

1,72

AI

0,85

--+--+

++++++

++++++

511 3-ethoxy-1-propene

2335

65

0,66

AI

0,77

0 0 0 0 0 0

76

AH

0 0 -0 0 +

H3N

0 0 -0 0 +

H3N

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Qualifying Group of tank

Qualifying

Group of tank

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

6

7

8

9

10

0,93

++++++

2

3

4

512 2-ethoxyethanol

1171

135

0,35

513 2-ethoxyethyl acetate

1172

156

0,03

A II

0,98

++++++

514 2-ethoxyaniline

2311

233




A III

1,05

515 3-ethoxyaniline

2311

 




516 4-ethoxyaniline

2311

250




517 Ethyl acetate

1173

77

0,3

181

518 Ethyl acetoacetate

5

Group of tank

11

Qualifying

12

++++++

++++++

++++++

++++++

0 0 0 0 0 0

++++++

++++++




0 0 0 0 0 0

++++++

++++++

1,07

0 0 0 0 0 0

++++++

++++++

AI

0,9

++++++

AC

++++++

C1

++++++




A III

1,03

--+--+

CH

++++++

C

++++++

C

CM

--+--+

M

--+--+

M

0 0 -0 0 +

H3N

0 0 -0 0 +

H3N

++++++

B

++++++

B

519 Ethyl acrylate, stabilized

1917

98

0,18

AI

0,92

--+--+

520 Ethyl allyl ether

2335

65

0,66

AI

0,77

0 0 0 0 0 0

521 Ethylamine, aq. soln. with a conc. Below

2924




 

B




++++++

A

BG

50%, a f.p. of -18 to below 0°C and a b.p. over 35°C

77

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1 522 Ethylamine, aq. soln., with a conc. Below

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

2

3

4

5

6

7

8

9

10

11

12

2924




 

B




++++++

BG

++++++

B

++++++

B

2920




 




++++++

BG

++++++

B

++++++

B

2270




 

B




++++++

BG

++++++

B

++++++

B

1036

 




B




++++++

BG

++++++

B

++++++

B

2270




 

B




------

++++++

B

++++++

B

50%, a f.p. of 0 to below 21°C and a b.p. over 35°C 523 Ethylamine, aq. soln., with a conc. Below 50%, a f.p. of 21 to 55°C and a b.p. over 35°C 524 Ethylamine, aq. soln., with a conc. up to 70%, a f.p. below -18°C and a b.p. over 35°C 525 Ethylamine, aq. soln., with a conc. Over 70% and a p(50) of 3 bar max. 526 Ethylamine, aq. soln., with a conc. of 50 to 70%, a f.p. of -18 to below 21°C and a b.p. over 35°C

78

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

8

9

10

2

3

4

5

6

7

527 3-(ethylamino)toluene

2754

221




A III

0,95

++++++

++++++

++++++

528 4-(ethylamino)toluene

2754

217




A III

0,94

++++++

++++++

++++++

529 2-ethylaniline

2273

210




A III

0,98

++++++

++++++

++++++

530 N-ethylaniline

2272

205




A III

0,96

++++++

++++++

++++++

531 Ethylbenzene, chemically pure

1175






A II




++++++

AF

++++++

++++++

532 Ethylbenzene, technical

1175

136

0,06

AI

0,87

++++++

AF

++++++

++++++

213




A III

1,05

++++++

E

++++++

1,03

++++++

533 Ethyl benzoate

E

11

++++++

534 N-ethyl-N-benzylaniline

2274

314




535 2-ethylbutanol

2275

149




A II

0,83

++++++

BC

++++++

536 2-ethyl-1-butene

2288

65

0,7

AI

0,7

---+++

N

++++++

537 2-ethyl-n-butyl acetate

1177

162




A II

0,88

++++++

AC

++++++

C1

++++++

538 2-ethylbutyl alcohol

2275

149




A II

0,83

++++++

BC

++++++

B

++++++

539 N-ethylbutylamine

2733

109

0,11

AI

0,74

++++++

BG

++++++

B

++++++

++++++

12

E

++++++ B

++++++

B

++++++

B

79

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

10

2

3

4

5

6

7

8

9

540 Ethyl n-butyl ether

1179

91

0,27

AI

0,76

++++++

A

++++++

++++++

541 2-ethylbutyraldehyde

1178

117




AI

0,82

++++++

AC

++++++

++++++

542 Ethyl butyrate

1180

122

0,07

A II

0,88

++++++

C

++++++

193




A III

0,92

------

++++++

++++++

0,93

++++++

++++++

++++++

543 2-ethylbutyric acid

C1

11

++++++

544 Ethyl cellosolve

1171

135

0,35

545 3-ethyl-2,3-dimethylpentane

1993

142

0,04

AI

0,75

++++++

A

++++++

++++++

546 3-ethyl-2,4-dimethylpentane

1993

137

0,05

AI

0,74

++++++

A

++++++

++++++

547 4-ethyl-2-methylhexane

1993

134

0,06

AI

0,72

++++++

A

++++++

++++++

548 4-ethyl-3-methylhexane

1920

140

0,05

A II

0,74

++++++

A

++++++

++++++

549 3-ethyl-2-methylpentane

1262

116

0,12

AI

0,72

++++++

A

++++++

++++++

550 3-ethyl-3-methylpentane

1262

118

0,11

AI

0,73

++++++

A

++++++

++++++

551 Ethyl-2-methylpropanoate

2385

110

0,12

AI

0,87

++++++

C

++++++

552 5-ethyl-2-methylpyridine

2300

178




A III

0,92

0 0 0 0 0 0

++++++

++++++

553 Ethyl pentanoate

1993






A II




++++++

++++++

++++++

80

C1

++++++

12

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

10

2

3

4

5

6

7

8

9

554 3-ethyl-2-pentene

2287

95

0,21

AI

0,72

---+++

N

++++++

++++++

555 5-ethyl-2-picoline

2300

178




A III

0,92

0 0 0 0 0 0

++++++

++++++

556 Ethyl-n-propyl ether

2615

64

0,64

AI

0,74

++++++

++++++

++++++

557 N-ethyl-m-toluidine

2754

221




A III

0,95

++++++

++++++

++++++

558 N-ethyl-p-toluidine

2754

217




A III

0,94

++++++

++++++

++++++

559 Ethyl carbonate

2366

126

0,07

A II

0,98

++++++

AC

++++++

AB

++++++

560 Ethyl crotonate

1862

137

0,07

AI

0,92

--+--+

CH

++++++

C1

++++++

561 Ethyl cyanoacetate

2666

206




1,06

++++++

C

++++++

C

++++++

562 N-ethylcyclohexylamine

2734

165

0,02

0,88

++++++

563 Ethylenecyanohydrin

2810

228




1,04

++++++

564 Ethylenediamine

1604

116

0,08

0,9

------

++++++

204




0,84

++++++

++++++

565 Ethylene glycol di-n-butyl ether

A II

A

A

11

++++++

++++++

++++++

++++++ B

++++++

12

B

C

D

++++++

566 Ethylene glycol diethyl ether

1153

121

0,14

A II

0,84

---+++

CN

---+++

N

---+++

N

567 Ethylene glycol dimethyl ether

2252

85

0,28

B

0,87

---+++

CN

---+++

N

---+++

N

81

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

5

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

6

7

8

9

10

0,93

++++++

0,98

++++++

2

3

4

568 Ethylene glycol monoethyl ether

1171

135

0,35

569 Ethylene glycol monoethyl ether acetate

1172

156

0,03

570 Ethylene glycol monobutyl ether with a

2369

171




0,9

2369

171




572 Ethylene glycol monomethyl ether

1188

125

573 Ethylene glycol monomethyl ether acetate

1189

574 Ethyleneimine, stabilized, pure 575 Ethylene oxide and propylene oxide,

11

12

++++++

++++++

++++++

++++++

++++++

++++++

++++++

0,9

++++++

++++++

++++++

0,07

0,97

++++++

++++++

++++++

145

0,05

1,01

++++++

A

++++++

++++++

1185

57

0,79

AI

0,83

------

C2H7N

------

C2H7N

------

C2H7N

2983

 




AI




0 0 0 0 0 0

-----+

HK1N

-----+

HK1N

576 Ethyl formate

1190

54

0,93

AI

0,93

++++++

AC

++++++

++++++

577 4-ethylheptane

1920

141

0,05

A II

0,73

++++++

A

++++++

++++++

A II

A

f.p.of 61°C max. 571 Ethylene glycol monobutyl ether with a f.p. over 61°C

mixture ctg. not more than 30% of ethylene oxide

82

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

10

11

Qualifying

2

3

4

5

6

7

8

9

578 Ethylhexaldehyde

1191

176




A II

0,85

++++++

C

++++++

++++++

579 3-ethylhexane

1262

119

0,1

AI

0,71

++++++

A

++++++

++++++

580 2-ethylhexanol

183




A III

0,83

++++++

BC

++++++

B

++++++

B

581 2-ethylhexyl acrylate, stabilized

229




A III

0,89

0 0 0 0 0 0

--+--+

M

--+--+

M

++++++

B

++++++

D

C1

++++++

582 2-ethylhexylamine

2276

169

0,02

A II

0,79

++++++

583 Ethyl isobutyrate

2385

110

0,12

AI

0,87

++++++

C

++++++

584 Ethyl isopropyl ether

2615

63

0,65

AI

0,72

++++++

A

++++++

585 Ethyl lactate

1192

154

0,02

1,03

++++++

C

++++++

C1

++++++

586 Ethyl methacrylate, stabilized

2277

117

0,1

AI

0,91

0 0 0 0 0 0

--+--+

M

--+--+

587 Ethyl nonanoate

220




A III

0,87

++++++

++++++

++++++

588 Ethyl octadecanoate

201




1,06

++++++

++++++

++++++

12

++++++

589 3-ethyloctane

1993

167

0,03

A II

0,75

++++++

A

++++++

++++++

590 4-ethyloctane

1993

164

0,03

A II

0,75

++++++

A

++++++

++++++

591 3-ethylpentane

1206

94

0,24

AI

0,7

++++++

A

++++++

++++++

M

83

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UN-No.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

2

3

4

5

6

7

8

9

10

11

12

592 N-ethylpiperidine

2386

131

0,05

AI

0,83

++++++

G

++++++

B

++++++

D

593 Ethyl polysilicate

1993

160




A II

1,06

++++++

594 Ethyl propionate

1195

99

0,17

AI

0,89

++++++

595 1-ethylpropylamine

1106

91

0,28

B

0,75

++++++

201




1,06

++++++

++++++

++++++

2754

 




A II




++++++

++++++

++++++

2754

 




A III




++++++

++++++

++++++

1197

 




B


 

0 0 0 0 0 0

++++++

596 Ethyl stearate 597 N-ethyltoluidine, isomer mixture with a

++++++

++++++

C

++++++

++++++

G

++++++

B

++++++

f.p. of 21 to 61°C 598 N-ethyltoluidine, isomer mixture with a f.p. over 61°C 599 Extracts, flavourings in alcoholic solution, n.i.l., with a f.p. over -18 up to 0°C and a b.p. over 50°C

84

U

++++++

U

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1 600 Extracts, flavourings in alcoholic soln.,

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

8

9

10

11

12

2

3

4

5

6

7

1197

 




B


 

0 0 0 0 0 0

++++++

U

++++++

U

1197

 





 

0 0 0 0 0 0

++++++

U

++++++

U

1197




 


 

0 0 0 0 0 0

++++++

U

++++++

U




 


 

0 0 0 0 0 0

++++++

U

++++++

U

n.i.l., with a f.p. of 0 to below 21°C and a b.p. over 50°C 601 Extracts, flavourings in alcoholic soln., n.i.l., with a f.p. of 21 to 55°C and a b.p. over 50°C 602 Extracts, flavourings in alcoholic soln., n.i.l., with a f.p. over 55 up to 61°C and a b.p. over 100°C 603 Extracts, flavourings in alcoholic soln., n.i.l., with a f.p. over 61°C up to 100°C and a b.p. over 100°C

85

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1 604 Extracts, perfumes in alcoholic soln.,

Group of tank

Qualifying Group of tank

Qualifying

A B C D E F

conditions

A B C D E F

conditions

9

10

11

12

8

Group of tank

Qualifying conditions

A B C D E F

2

3

4

5

6

7

1169

 




B


 

0 0 0 0 0 0

++++++

U

++++++

U

1169






B


 

0 0 0 0 0 0

++++++

U

++++++

U

1169







 

0 0 0 0 0 0

++++++

U

++++++

U

1169




 


 

0 0 0 0 0 0

++++++

U

++++++

U

n.i.l., with a f.p. of -18 to below 0°C and a boiling point over 50°C 605 Extracts, perfumes in alcoholic soln., n.i.l., with a f.p. of 0 to below 21°C and a boiling point over 50°C 606 Extracts, perfumes in alcoholic soln., n.i.l., with a f.p. of 21 to 55°C and a boiling point over 100°C 607 Extracts, perfumes in alcoholic soln., n.i.l., with a f.p. of 55 to 61°C and a boiling point over 50°C

86

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

2

608 Extracts, perfumes in alcoholic soln.,

3

4




 

5

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

6

7

8

9

10

11

12


 

0 0 0 0 0 0

++++++

U

++++++

U

+ + + + ++

n.i.l., with a f.p. over 21 up to 55°C and a boiling point over 50°C 609 FAM standard mineral spirit, A type

1271

65

0,71

AI

0,71

++++++

610 Fluorobenzene

2387

85

0,31

AI

1,03

++++++

611 Fluorosulfonic acid

1777

163

0,02

1,74

0 0 0 0 0 0

612 2-fluorotoluene

2388

114

0,12

AI

1,01

++++++

AC

++++++

613 3-fluorotoluene

2388

116

0,11

AI

1

++++++

AC

614 4-fluorotoluene

2388

117

0,11

AI

1

++++++

AC

615 Formaldehyde, aq. soln., with a

1198




 




------

AC

++++++

++++++ AC

++++++

AC

0 0 -0 0 +

H3T

AC

++++++

AC

++++++

AC

++++++

AC

++++++

AC

++++++

AC

++++++

C3C5

++++++

C3

0 0 0 0 0 0

formaldehyde content of 37% and a methanol content of 10 to 15%

87

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Qualifying Group of tank

Qualifying

Group of tank

Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

6

7

8

9

10

11

12

2

3

4

2209









------

++++++

C3C5

++++++

C3

1198




 




------

++++++

C3C5

++++++

C3

2209




 




------

++++++

C3C5

++++++

C3

619 Formic acid, ctg. 50 to 70% of pure acid

1779

101

0,18

= 1,17

------

------

--+--+

H2

620 Formic acid, ctg. 70 to 85% of pure acid

1779

106

0,18




------

------

--+--+

H2

621 Formic acid, ctg. 85 to 97% of pure acid

1779

101

0,18




------

------

++++++

616 Formaldehyde, aq. soln., with a

5

Group of tank

formaldehyde content below 5% and a f.p. over 100°C 617 Formaldehyde, aq. soln., with a formaldehyde content of 5 % min. a methanol content of 15% max. and a b.p. of 21 to 61°C 618 Formaldehyde, aq. soln., with a formaldehyde content of 5 % min. a methanol content of 15% max. and a b.p over 61°C

88

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1 622 Formic acid ctg. more than 97% of pure

5

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

6

7

8

9

10

2

3

4

11

1779

101

0,18




------

++++++

++++++

1779









------

------

--+--+

1202




 

A III




++++++

++++++

++++++

 




A III




++++++

A

------

++++++




 

A III




++++++

A

++++++

++++++




 

A III


 

++++++

A

++++++

++++++

12

acid 623 Formic acid ctg. less than 50% of pure

H2

acid 624 Fuel oil, EL-01 type 625 Fuel oil, S-03 type 626 Fuel oil, light

1202

627 Fuel oil, medium 628 Furan

2389

31

1,96

AI

0,94

0 0 0 0 0 0

---+++

N

---+++

N

629 Furfuraldehyde, with a f.p. over 55°C

1199

162

0,02

A III

1,16

------

---+++

N

---+++

N

630 Furfuryl alcohol

2874

171




A III

1,13

------

---+++

CN

---+++

CN

631 Furfurylamine

2526

146

0,03

A II

1,05

---+++

---+++

BN

---+++

DN

632 Gas oil, with a f.p. of 21 to 55°C and a

1202




 

A II




0 0 0 0 0 0

GN

0 0 0 0 0 0

++++++

b.p. over 100°C

89

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1 633 Gas oil, with a f.p. over 55 up to 61°C,

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

8

9

10

2

3

4

5

6

7

11

1202




 

A III




0 0 0 0 0 0

0 0 0 0 0 0

++++++




 

A III




0 0 0 0 0 0

0 0 0 0 0 0

++++++

12

and a b.p. over 100°C 634 Gas oil, with a f.p. of 61°C to 100°C and a b.p over 100°C 635 Glacial acetic acid, purity 99,7% min.

2789

118

0,08

1,06

------

--+--+

BH1

++++++

B

636 Glutaraldehyde, aq. soln., with a f.p. over

2810









------

++++++

C

++++++

C




 


 

0 0 0 0 0 0

++++++

U

++++++

U

61°C 637 Gutta-percha, in flammable liq., n.i.l., with a f.p. of -18 to below 0°C and a b.p. over 35°C

90

AI

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

2

638 Gutta-percha, in flammable liq., n.i.l., with

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

8

9

10

11

12

3

4

5

6

7

 




AI


 

0 0 0 0 0 0

++++++

U

++++++

U

 




A II


 

0 0 0 0 0 0

++++++

U

++++++

U




 

A III


 

0 0 0 0 0 0

++++++

U

++++++

U




 

A III


 

0 0 0 0 0 0

++++++

U

++++++

U

a f.p. of 0°C to below 21°C and a b. p over 50°C. 639 Gutta-percha, in flammable liq., n.i.l., with a f.p. of 21 to 55°C, and a b.p. over 50°C 640 Gutta-percha, in flammable liq., n.i.l., with a f.p. over 55 up to 61°C, and a b.p. over 100°C 641 Gutta-percha, in flammable liq., n.i.l., with a f.p. over 61 up to 100°C, and a b.p. over 100°C 642 n-heptaldehyde

3056

153




A II

0,82

++++++

AC

++++++

++++++

643 Heptane, isomer mixture

1206

 


 

AI


 

++++++

A

++++++

++++++

644 n-heptane

1206

98

0,2

AI

0,68

++++++

A

++++++

++++++

645 2-heptanone

1110

150




A II

0,82

++++++

AC

++++++

++++++

646 4-heptanone

2710

144

0,04

A II

0,82

++++++

AC

++++++

++++++

91

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

10

2

3

4

5

6

7

8

9

11

647 1-heptene

2278

94

0,23

AI

0,7

---+++

N

++++++

++++++

648 3-heptene, mixture of cis and trans forms

1993




 

AI


 

---+++

N

++++++

++++++

649 cis-2-heptene

1993

98

0,2

AI

0,71

---+++

N

++++++

++++++

650 cis-3-heptene

1993

96

0,21

AI

0,7

---+++

N

++++++

++++++

651 trans-2-heptene

1993

98

0,2

AI

0,7

---+++

N

++++++

++++++

652 trans-3-heptene

1993

96

0,21

AI

0,7

---+++

N

++++++

++++++

653 Hexachlorobutadiene

2279

215




1,68

++++++

AC

------

++++++

E

654 Hexachlorocyclopentadiene

2646

239




1,72

++++++

AC

------

++++++

E

655 Hexadiene, isomer mixture, with a f.p. of

2458

 




AI




---+++

N

++++++

++++++

2458

 




AI




---+++

N

++++++

++++++

2458

76

0,51

AI

0,72

---+++

N

++++++

++++++

-18 to 21°C 656 Hexadiene, isomer mixture, with a f.p. below -18°C 657 1,2-hexadiene

92

12

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

10

2

3

4

5

6

7

8

9

2458






AI


 

---+++

N

++++++

++++++

659 1,5-hexadiene

2458

60

0,81

AI

0,69

---+++

N

++++++

++++++

660 2,4-hexadiene, mixture of cis and trans

2458




 

AI




---+++

N

++++++

++++++

661 trans-1,3-hexadiene

2458

73

0,51

AI

0,71

---+++

N

++++++

++++++

662 Hexahydropyridine

2401

106

0,14

B

0,86

++++++

BG

++++++

663 Hexaldehyde

1207

129

0,07

A II

0,82

++++++

AC

++++++

664 1,1,1,3,3,3-hexamethyldisilazane

1993

126

0,08

AI

0,78

0 0 0 0 0 0

---+++

T

---+++

T

665 Hexamethylene diisocyanate

2281

250




1,05

0 0 0 0 0 0

---+++

BCT

---+++

BCT

666 Hexamethyleneimine

2493

139

0,05

B

0,88

0 0 0 0 0 0

++++++

B

++++++

D

667 Hexane, isomer mixture

1208

 




AI

0,67

++++++

A

++++++

++++++

668 n-hexane

1208

69

0,56

AI

0,66

++++++

A

++++++

++++++

669 Hexanol

2282

149




A III

0,83

++++++

BC

++++++

658 1,4-hexadiene, mixture of cis and trans

11

12

isomers

isomers

B

++++++

D

++++++

B

++++++

B

93

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

10

2

3

4

5

6

7

8

9

11

670 1-hexene

2370

64

0,65

AI

0,68

---+++

N

++++++

671 Hydrazine, anhydrous

2029

114

0,09

AI

1,01

------

---+++

K1N

------

672 Hydrazine, aq. soln., ctg. 15% of

2030







A III




------

---+++

K1N

0 0 0 0 0 0

2030






A II




------

---+++

K1N

0 0 0 0 0 0

2030






A II




------

---+++

K1N

0 0 0 0 0 0

2030






A II




------

---+++

K1N

0 0 0 0 0 0

2030






A II




------

---+++

K1N

------

2029






AI




------

---+++

K1N

0 0 0 0 0 0

++++++

hydrazine 673 Hydrazine, aq. soln., ctg. 36% max. of hydrazine 674 Hydrazine, aq. soln., ctg. over 36% up to 64% of hydrazine 675 Hydrazine, aq. soln., ctg. 51% of hydrazine 676 Hydrazine, aq. soln., ctg. 64% of hydrazine 677 Hydrazine, aq. soln., ctg. over 64% of hydrazine

94

12

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1 678 Hydrocarbons, u.o.n., with a f.p. of -18

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

8

9

10

11

12

2

3

4

5

6

7

1993

 




AI




0 0 0 0 0 0

++++++

B1

++++++

B1

1993




 

A II




0 0 0 0 0 0

++++++

B1

++++++

B1

1993




 

A III




0 0 0 0 0 0

++++++

B1

++++++

B1




 

A III


 

0 0 0 0 0 0

++++++

B1

++++++

B1

1993

 




AI




0 0 0 0 0 0

++++++

B1

++++++

B1

1993




 

AI




0 0 0 0 0 0

++++++

B1

++++++

B1

1993

 




AI




0 0 0 0 0 0

++++++

B1

++++++

B1

to below 21°C and a b.p. over 50°C 679 Hydrocarbons, u.o.n., with a f.p. of 21 to 55°C and a b.p. over 100°C 680 Hydrocarbons, u.o.n., with a f.p. over 55 up to 61°C and a b.p. over 100°C 681 Hydrocarbons, u.o.n., with a f.p. over 61 up to 100°C and a b.p. over 100°C 682 Hydrocarbons, u.o.n., with a f.p. below -18°C and a b.p. of 35°C max. 683 Hydrocarbons, u.o.n., with a f.p. below -18°C and a b.p. over 35°C 684 Hydrocarbons, u.o.n., with a f.p. below -18°C and a b.p. over 50°C

95

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

2

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

6

7

8

9

10

11

12


 

0 0 0 0 0 0

++++++

B1

++++++

B1

3

4




 

1993

 




AI




0 0 0 0 0 0

++++++

B1

++++++

B1

1993




 

A II




0 0 0 0 0 0

++++++

B1

++++++

B1

1993




 

A III




0 0 0 0 0 0

++++++

B1

++++++

B1




 

A III


 

0 0 0 0 0 0

++++++

B1

++++++

B1

 




AI




0 0 0 0 0 0

++++++

B1

++++++

B1

685 Hydrocarbons, not toxic and corrosive,

5

Group of tank

u.o.n., with a f.p over 100°C 686 Hydrocarbon mixture, u.o.n., with a f.p. of -18 to below 21°C and a b.p. over 50°C 687 Hydrocarbon mixture, u.o.n., with a f.p. of 21 to 55°C and a b.p. over 100°C 688 Hydrocarbon mixture, u.o.n., with a f.p. over 55 up to 61°C and a b.p. over 100°C 689 Hydrocarbon mixture, u.o.n., with a f.p. over 61 up to 100°C and a b.p. over 100°C 690 Hydrocarbon mixture, u.o.n., with a f.p. below -18°C and a b.p. of 35°C max.

96

1993

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1 691 Hydrocarbon mixture, u.o.n., with a f.p.

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

8

9

10

11

12

2

3

4

5

6

7

1993




 

AI




0 0 0 0 0 0

++++++

B1

++++++

B1

1993

 




AI




0 0 0 0 0 0

++++++

B1

++++++

B1




 


 

0 0 0 0 0 0

++++++

B1

++++++

BH6

below -18°C and a b.p. over 35°C 692 Hydrocarbon mixture, u.o.n., with a f.p. below -18°C and a b.p. over 50°C 693 Hydrocarbon mixture, not toxic and corrosive, u.o.n., with a f.p. over 100°C 694 Hydroquinone, aq. soln.

2662









------

++++++

++++++

695 N-(2-hydroxethyl)ethylenediamine

1760

244




1,04

++++++

++++++

++++++

696 4-hydroxy-4-methyl-2-pentanone

1148

168




0,94

++++++

++++++

++++++

697 Hydroxybenzene, aq. soln., not alkaline

2821









------

------

++++++

698 3-hydroxybutanal

2839

182




1,11

++++++

AC

++++++

++++++

699 3-hydroxypropionitrile

2810

228




1,04

++++++

A

++++++

++++++

A III

97

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

10

2

3

4

5

6

7

8

9

1993




 

A II


 

++++++

A

++++++

++++++

701 Isohexane

1208

60

0,73

AI

0,66

++++++

A

++++++

++++++

702 Isobutyl acetate

1213

117

0,09

AI

0,87

++++++

AC

++++++

C1

++++++

703 Isobutyl acrylate, stabilized

2527

133

0,14

A II

0,9

--+--+

CM

--+--+

C1M

--+--+

M

704 Isobutyl alcohol

1212

108

0,08

A II

0,81

++++++

BC

++++++

B

++++++

B

705 Isobutylamine

1214

66

0,55

B

0,74

++++++

BG

++++++

B

++++++

706 Isobutylbenzene

2709

173

0,02

A II

0,87

++++++

EC

++++++

707 Isobutyl formate

2393

98

0,19

AI

0,89

++++++

AC

++++++

708 Isobutylisoamyl

1920

135

0,06

A II

0,71

++++++

A

++++++

709 Isobutyl isobutyrate

2528

142

0,03

A II

0,88

++++++

AC

++++++

C1

++++++

710 Isobutyl isocyanate

2486

102

0,15

AI

0,89

0 0 0 0 0 0

---+++

BCT

---+++

711 Isobutyl isovalerate

1993

171




A II

0,87

++++++

AC

++++++

712 Isobutyl methacrylate, stabilized

2283

155

0,03

A II

0,89

--+--+

CM

--+--+

700 Isodecane, isomer mixture, with a f.p.

11

12

from 21 to 55°C

98

++++++ AC1

++++++ ++++++

BCT

++++++ M

--+--+

M

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

2

3

4

5

6

7

8

9

10

11

713 Isobutyl propionate

2394

137

0,07

A II

0,87

++++++

AC

++++++

A

++++++

714 Isobutyraldehyde

2045

65

0,63

AI

0,79

------

---+++

CN

---+++

715 Isobutyric acid

2529

155

0,02

A II

0,96

------

--+--+

H

++++++

716 Isobutyric anhydride

2530

183

0,08

A III

0,96

0 0 0 0 0 0

0 0 0 0 0 0

++++++

717 Isobutyronitrile

2284




 

AI




0 0 0 0 0 0

++++++

++++++

718 3-isocyanatotoluene

2810

189




A III

1,06

0 0 0 0 0 0

---+++

719 Isododecane

2286

150

0,04

A II

0,75

++++++

A

++++++

++++++

720 Isoheptene, isomer mixture, with a f.p. of

2287

 


 

AI




---+++

N

++++++

++++++

2287

 


 

AI


 

---+++

N

++++++

++++++

2288

 


 

AI




---+++

N

++++++

BCT

---+++

Qualifying

12

N

BCT

-18 to below 21°C 721 Isoheptene, isomer mixture, with a f.p. below -18°C 722 Isohexene, isomer mixture, with a b.p. of 50°C max.

99

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

10

2

3

4

5

6

7

8

9

2288

 




AI




---+++

N

++++++

724 Isohexyl acetate

1177

162




A II

0,88

++++++

AC

++++++

725 Isooctene

1216

102




AI

0,72

---+++

N

++++++

726 Isopentane

1265

28

2,06

AI

0,62

++++++

A

++++++

727 Isopentene, isomer mixture

2371

 


  

AI




---+++

AN

++++++

728 Isopentyl acetate, mixture of 2- and 3-

1104






A II




++++++

AC

++++++

C1

++++++

729 Isopentyl alcohol

1105

131

0,04

A II

0,81

++++++

ABC

++++++

B

++++++

B

730 Isopentyl bromide

2341

121

0,09

A II

1,26

++++++

AC

------

++++++

A

731 Isopentyl butyrate

2620

179




A III

0,87

++++++

AC

++++++

++++++

732 Isopentyl chloride

1107

99

0,22

AI

0,87

--+--+

ACH2

------

------

733 Isopentyl formate

1109

124

0,08

A II

0,88

++++++

AC

++++++

++++++

734 Isopentyl nitrite, pure

1113






AI




0 0 0 0 0 0

723 Isohexene, isomer mixture, with a b.p.

11

12

++++++

over 50°C C1

++++++ ++++++

A

++++++

A

++++++

methylbutyl acetate

100

++++++

A

++++++

A

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

5

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

6

7

8

9

10

11

12

2

3

4

735 Isophoronediamine

2289

247




0,92

0 0 0 0 0 0

++++++

B

++++++

D

736 Isophorone diisocyanate

2290

280




1,06

0 0 0 0 0 0

---+++

BCT

---+++

BCT

737 Isoprene, stabilized

1218

34

1,72

AI

0,69

---+++

AN

---+++

N

---+++

N

738 Isopropanol

1219

82

0,24

B

0,79

++++++

C

++++++

++++++

739 Isopropenyl acetate

2403

97

0,22

AI

0,92

++++++

AC

++++++

++++++

740 Isopropyl acetate

1220

88

0,26

AI

0,87

++++++

AC

++++++

741 Isopropyl alcohol

1219

82

0,24

B

0,79

++++++

C

++++++

++++++

742 Isopropylamine

1221

32

2,1

B

0,69

++++++

BG

++++++

++++++

743 Isopropyl butyrate

2405

130

0,07

AI

0,86

++++++

AC

++++++

744 Isopropyl chloride

2356

35

1,61

AI

0,87

++++++

AC

------

++++++

745 Isopropyl cyanide

2284




 

AI




0 0 0 0 0 0

++++++

++++++

746 Isopropylethylene

2561

20

2,71

AI

0,64

---+++

AN

++++++

++++++

747 Isopropyl formate

1281

68

0,53

AI

0,87

++++++

AC

++++++

++++++

748 4-isopropylheptane

1993

159

0,03

A II

0,75

++++++

A

++++++

++++++

C1

C1

++++++

++++++ C

101

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

2

3

4

5

6

7

8

9

10

11

749 Isopropyl isobutyrate

2406

119

0,13

AI

0,84

++++++

AC

++++++

C1

++++++

750 Isopropyl isocyanate

2483

75

0,39

AI

0,88

0 0 0 0 0 0

751 4-isopropylmethylbenzene

2046

176




A II

0,86

++++++

752 Isopropyl nitrate

1222

101

0,16

AI

1,04

753 Isopropyl propionate

2409

109

0,14

a ii

754 Kerosine

1223





 

755 Kerosine, with a f.p. of 21 to 55°C

1223

 

756 Kerosine, with a f.p. over 55 up to 61°C

1223

757 Ligroin, with a f.p. of -18 to below 21°C

0 0 0 0 0 0

---+++

A

++++++

++++++

++++++

AC

++++++

++++++

0,87

++++++

AC

++++++

A II




++++++


 

A II




++++++

 


 

A III







 

AI

 




 




C1

++++++

++++++

++++++

A

++++++

++++++

++++++

A

++++++

++++++


 

++++++

A

++++++

++++++

AI


 

++++++

A

++++++

++++++

AI




++++++

A

++++++

++++++

and a b.p. over 35°C 758 Ligroin, with a f.p. of -18 to below 21°C and a b.p. over 50°C 759 Ligroin, with a f.p. below -18°C, a b.p. of 35°C max. and a p(50) of 3 bar max.

102

Qualifying

12

BCT

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

2

760 Ligroin, with a f.p. below -18°C and a

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

10

3

4

5

6

7

8

9

11




 

AI




++++++

A

++++++

++++++

 




AI




++++++

A

++++++

++++++

A II




------

++++++

++++++




------

++++++

12

b.p. over 35°C 761 Ligroin, with a f.p. below -18°C and a b.p. over 50°C 762 dl-limonene, isomer mixture

2052




 

763 Lithium hydroxide, aq. soln., ctg. not

2679






764 dl-p-mentha-1,8-diene, isomer mixture

2052




 

A II




------

++++++

++++++

765 Mesityl oxide

1229

130

0,07

A II

0,86

++++++

++++++

++++++

766 Methacrylaldehyde, stabilized

2396

69

0,54

B

0,85

0 0 0 0 0 0

-----+

MN

-----+

MN

767 Methacrylic acid, stabilized

2531

161




1,02

--+--+

AM

--+--+

M

--+--+

M

768 Methallyl alcohol

2614

115

0,11

A II

0,86

++++++

EC

++++++

++++++

769 Methanol

1230

65

0,56

B

0,8

++++++

++++++

++++++

H5

++++++

H5

more than 11% of LiOH

103

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Qualifying Group of tank

Qualifying

Group of tank

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

6

7

8

9

10

11

Qualifying

2

3

4

1993




 




++++++

++++++

++++++

1993




 




++++++

++++++

++++++

772 4-methoxy-4-methylpentan-2-one

2293

147




1

++++++

++++++

++++++

773 2-methoxyethanol

1188

125

0,07

0,97

++++++

++++++

++++++

774 2-methoxyethyl acetate

1189

145

0,05

1,01

++++++

++++++

++++++

775 m-methoxyaniline

2810

251




1,1

------

++++++

++++++

776 o-methoxyaniline

2431

225




A III

1,09

------

++++++

++++++

777 Methoxybutyl acetate

2708

166

0,03

A III

0,96

++++++

AC

++++++

778 Methyl acetate

1231

57

0,77

B

0,93

++++++

C

++++++

++++++

779 Methylacetic acid, pure, 99,8% min.

1848

141

0,03

1

------

------

0 0 +0 0 +

H3









------

------

--+--+

H

770 Methanol, aq. soln., with a f.p. of 21 to

5

Group of tank

12

55°C 771 Methanol, aq. soln., with a f.p. over 55 up to 61°C

780 Methylacetic acid, aq. soln., ctg. 50 to below 80% of pure acid

104

A II

AC

A

C1

++++++

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Densit y class

at 50°C Material No. °C

mbar kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425 Group of tank

Qualifying

A B C D E F

conditions

Group of tank

Qualifying

Group of tank

Qualifying

conditions

A B C D E F conditions

A B C D E F 1

2

3

4

6

7









1848






1848






784 Methyl acetoacetate

170




785 Methylacetone, anhydrous mixture of



781 Methylacetic acid, aq. soln., ctg. less than

5

8

9

10

11

12

------

--+--+

H2

++++++




------

------

0 0 +0 0 +

H3




------

------

0 0 +0 0 +

H3

A III

1,08

--+--+

CH

++++++

C

++++++

C




AI




++++++

C

++++++

C1

++++++

50% of pure acid 782 Methylacetic acid, aq. soln., ctg. 80% min. of pure acid, with a f.p. of 61°C max. 783 Methylacetic acid, aq. soln., ctg. 80% min. of pure acid, with a f.p. over 61°C

methanol, methyl acetate and acetone 786 Methyl acrylate, stabilized

1919

80

0,35

AI

0,96

--+--+

M

--+--+

M

--+--+

M

787 Methylamine, 40% aq. soln.

1235

 


 

B




++++++

BG

++++++

B

++++++

D

105

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

2

3

4

5

6

7

8

9

10

11

12

2924

 




B




++++++

BG

++++++

B

++++++

D

2924




 

B




++++++

BG

++++++

B

++++++

D

1235

 


 

B




++++++

BG

++++++

B

++++++

D

1235




 

B




++++++

BG

++++++

B

++++++

D

792 N-methylaniline

2294

195




A III

0,99

++++++

G

++++++

B

++++++

D

793 Methylaniline, isomer mixture, liq.

1708

 




A III




++++++

++++++

++++++

794 2-methylaniline, liq.

1708

200




A III

1

++++++

++++++

++++++

795 3-methylaniline, liq.

1708

203




A III

1

++++++

++++++

++++++

796 Methyl benzoate

2938

199




A III

1,09

++++++

++++++

++++++

788 Methylamine, aq. soln., with a f.p. below -18°C, a b.p. of 35°C max. and a p(50) of 3 bar max. 789 Methylamine, aq. soln., with a f.p. below -18°C and a b.p. over 35°C 790 Methylamine, aq. soln., with a conc. of 40% max. 791 Methylamine, aq. soln., with a conc. of 40% min. and a f.p. of -18°C min.

106

E

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

10

2

3

4

5

6

7

8

9

11

12

797 2-methyl-1-butanethiol

1111

118

0,13

AI

0,85

0 0 +0 0 +

AH3

++++++

++++++

798 2-methyl-2-butanethiol

1111




 

AI




0 0 +0 0 +

AH3

++++++

++++++

799 3-methyl-1-butanethiol

1111

118

0,13

AI

0,84

0 0 +0 0 +

AH3

++++++

++++++

800 1-methyl-1-butanol

1105

119

0,05

A II

0,81

++++++

ABC

++++++

B

++++++

B

801 2-methyl-1-butanol

1105

128

0,05

A II

0,82

++++++

ABC

++++++

B

++++++

B

802 2-methyl-2-butanol

1105

102

0,11

B

0,81

++++++

ABC

++++++

B

++++++

B

803 3-methyl-1-butanol

1105

131

0,04

A II

0,81

++++++

ABC

++++++

B

++++++

B

804 3-methyl-1-butanol, ctg. fractions of 2,2-

1105

129

0,05

A II

0,81

++++++

ABC

++++++

B

++++++

B

805 3-methyl-2-butanol

1105

113

0,04

A II

0,82

++++++

ABC

++++++

B

++++++

B

806 3-methyl-2-butanone

2397

94

0,23

AI

0,81

0 0 0 0 0 0

807 2-methyl-1-butene

2459

31

1,85

AI

0,66

---+++

808 2-methyl-2-butene

2460

39

1,51

AI

0,67

809 3-methyl-1-butene

2561

20

2,71

AI

0,64

dimethyl-1-propanol

++++++

++++++

AN

++++++

++++++

---+++

AN

++++++

++++++

---+++

AN

++++++

++++++

107

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

2

3

4

5

6

7

8

9

10

11

12

810 2-methylbutan-2-ol

1105

102

0,11

B

0,81

++++++

ABC

++++++

B

++++++

B

811 1-methylbutylamine

1106

92

0,28

B

0,74

++++++

G

++++++

B

++++++

D

812 2-methylbutylamine

1106

95

0,28

B

0,74

++++++

G

++++++

B

++++++

D

813 3-methylbutylamine

1106

95

0,28

B

0,75

++++++

G

++++++

B

++++++

D

814 2-methyl-2-butylamine

1106

77

0,48

B

0,75

++++++

G

++++++

B

++++++

D

815 3-methylbutyl butyrate

2620

179




A III

0,87

++++++

AC

++++++

816 3-methylbutyl nitrite, pure

1113






AI

= 0,89

0 0 0 0 0 0

817 3-methyl-2-butylamine

2924

82

0,41

B

0,76

++++++

818 Methyl butyrate

1237

102

0,15

AI

0,9

++++++

819 Methyl-tert-butyl ether

2398

55

0,92

AI

0,76

820 Methyl chloroacetate

2295

130

0,06

A II

821 Methylcyclohexane

2296

101

0,21

822 2-methylcyclohexanone

2297

162

823 3-methylcyclohexanone

2297

169

108

++++++

++++++

A

++++++

A

G

++++++

B

++++++

D

C

++++++

++++++

0 0 0 0 0 0

++++++

++++++

1,24

0 0 0 0 0 0

0 0 0 0 0 0

++++++

AI

0,77

++++++

++++++

++++++




A II

0,93

++++++

++++++

++++++




A II

0,92

++++++

++++++

++++++

A

AC

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

8

9

10

2

3

4

5

6

7

11

824 4-methylcyclohexanone

2297

169




A II

0,92

++++++

++++++

++++++

825 Methylcyclohexanone, mixture of 3- and

2297






A II




++++++

++++++

++++++

826 Methylcyclopentane

2298

72

0,5

AI

0,75

++++++

++++++

++++++

827 Methyldithiomethane

2381

110

0,13

AI

1,06

0 0 0 0 0 0

828 Methylene chloride

1593

40

1,45

1,34

++++++

AC

829 3-methylenepentane

2288

65

0,7

AI

0,7

---+++

830 2-methyl-4-ethylhexane

1993

134

0,06

AI

0,72

831 3-methyl-4-ethylhexane

1920

140

0,05

A II

832 Methyl ethyl ketone

1193

80

0,38

833 2-methyl-3-ethylpentane

1262

116

834 3-methyl-2-ethylpentane

1262

835 2-methyl-5-ethylpyridine 836 Methyl formate

Qualifying

12

4-methylcyclohexanone A

++++++

++++++

B

------

--+--+

ACH1

N

++++++

++++++

++++++

A

++++++

++++++

0,74

++++++

A

++++++

++++++

AI

0,81

---+++

N

++++++

++++++

0,12

AI

0.72

++++++

A

++++++

++++++

118

0,11

AI

0,73

++++++

A

++++++

++++++

2300

178




A III

0,92

0 0 0 0 0 0

++++++

++++++

1243

32

1,95

B

0,98

++++++

++++++

++++++

C

B

109

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

10

2

3

4

5

6

7

8

9

837 2-methylheptane

1262

118

0,1

AI

0,7

++++++

R

++++++

++++++

838 3-methylheptane

1262

119

0,1

AI

0,71

++++++

A

++++++

++++++

839 4-methylheptane

1262

118

0,1

AI

0,72

++++++

A

++++++

++++++

840 2-methylhexane

1206

90

0,28

AI

0,68

++++++

A

++++++

++++++

841 3-methylhexane

1206

91

0,26

AI

0,69

++++++

A

++++++

++++++

842 5-methyl-2-hexanone

2302

144

0,05

A II

0,81

++++++

AC

++++++

++++++

843 2-methyl-1-hexene

2287

91

0,23

AI

0,7

---+++

N

++++++

++++++

844 3-methyl-1-hexene

2287

84

0,33

AI

0,69

---+++

N

++++++

++++++

845 Methyl-2-hydroxypropionate

1993

144

0,03

A II

1,09

++++++

AC

++++++

846 Methyl isobutyl ketone

1245

116

0,1

AI

0,8

------

847 Methyl isopropyl ether

1993

32

2,11

AI

0,74

++++++

848 Methyl isothiocyanate, liq.

2477

118

0,1

A II

1,07

0 0 0 0 0 0

849 Methyl isovalerate

2400

116

0,1

AI

0,88

++++++

AC

++++++

C1

++++++

850 Methyl lactate

1993

144

0,03

A II

1,09

++++++

AC

++++++

AC1

++++++

110

A

AC1

11

++++++

++++++

++++++

++++++

++++++

0 0 0 0 0 0

---+++

Qualifying

12

C1

ET

C1

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

2

3

4

5

6

7

8

9

10

11

12

1247

101

0,18

AI

0,95

--+--+

AM

--+--+

M

--+--+

M

2535

113

0,1

AI

0,92

++++++

BG

++++++

B

++++++

D

2535

113

0,1

AI

0,92

++++++

BG

++++++

B

++++++

D

2535

114

0,1

A II

0,92

++++++

BG

++++++

B

++++++

D

2535

114

0,1

A II

0,92

++++++

BG

++++++

B

++++++

D

856 2-methylnonane

1993

167

0,03

A II

0,74

++++++

A

++++++

++++++

857 2-methyloctane

1920

143

0,08

A II

0,71

++++++

A

++++++

++++++

858 3-methyloctane

1920

144

0,08

A II

0,72

++++++

A

++++++

++++++

859 4-methyloctane

1920

142

0,05

A II

0,72

++++++

A

++++++

++++++

851 Methyl methacrylate, monomeric, stabilized 852 4-methylmorpholine, with a f.p. below 21°C 853 N-methylmorpholine, with a f.p. below 21°C 854 4-methylmorpholine, with a f.p. of 21°C min. 855 N-methylmorpholine, with a f.p. of 21°C min.

111

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

2

3

4

5

6

7

8

9

10

11

12

860 Methyloxirane, stabilized

1280

34

1,71

AI

0,84

-----+

EK1MN

-----+

EMN

-----+

EMN

861 2-methylpentane

1208

60

0,73

AI

0,66

++++++

A

++++++

++++++

862 3-methylpentane

1208

63

0,66

AI

0,67

++++++

A

++++++

++++++

863 2-methylpentanal

2367

118

0,1

AI

0,81

++++++

AC

++++++

++++++

864 Methyl pentanoate

1993

 




A II




++++++

AC

++++++

++++++

865 2-methyl-1-pentene

2288

62

0,7

AI

0,69

---+++

N

++++++

++++++

866 2-methyl-2-pentene

2288

67

0,64

AI

0,69

---+++

N

++++++

++++++

867 3-methyl-1-pentene

2288

54

0,9

AI

0,67

---+++

N

++++++

++++++

868 3-methyl-2-pentene, cis/trans mixture

2288




 

AI


 

---+++

N

++++++

++++++

869 4-methyl-1-pentene

2288

54

0,9

AI

0,67

---+++

N

++++++

++++++

870 4-methyl-2-pentene, cis/trans mixture

2288

 




AI




---+++

N

++++++

++++++

871 4-methyl-3-pentene-2-one

1229

130

0,07

A II

0,86

++++++

++++++

++++++

872 4-methylpentyl-2-acetate

1233

146

0,04

A II

0,86

++++++

AC

++++++

++++++

873 4-methyl-1,3-phenylenediamine, liq.

1709

 







++++++

AE

++++++

++++++

112

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

2

3

4

5

6

7

8

9

10

11

12

874 1-methylpiperidine

2399

106

0,15

B

0,82

++++++

G

++++++

B

++++++

D

875 2-methylpiperidine

1993

118

0,11

B

0,84

++++++

G

++++++

B

++++++

D

876 3-methylpiperidine

1993

126

0,08

B

0,85

++++++

G

++++++

B

++++++

D

877 4-methylpiperidine

1993

125

0,07

B

0,84

++++++

G

++++++

B

++++++

D

878 2-methyl-1-propanethiol

2347

88

0,28

AI

0,84

------

++++++

++++++

879 2-methyl-2-propanethiol

2347

64

0,65

AI

0,82

------

++++++

++++++

880 2-methyl-2-propanol

1120

83

0,25

AI

0,79

++++++

BC

++++++

881 Methyl propionate

1248

80

0,35

AI

0,92

++++++

C

++++++

++++++

882 Methyl propyl ether

2612

39

1,49

AI

0,74

++++++

A

++++++

++++++

883 Methyl propyl ketone, pure

1249

102

0,1

AI

0,82

++++++

++++++

++++++

884 Methyl propyl ketone, technical

1249






AI




++++++

++++++

++++++

885 2-methylpyridine

2313

128

0,06

0,95

++++++

++++++

++++++

886 3-methylpyridine

2313

144

0,06

A II

0.96

++++++

++++++

++++++

887 4-methylpyridine

2313

145

0,06

A II

0,96

++++++

++++++

++++++

B

++++++

B

113

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

2

3

4

5

6

7

8

9

10

11

12

888 alpha-methylstyrene, stabilized

2303

165

0,03

A II

0,91

--+--+

CM

--+--+

M

--+--+

M

889 2-methylvaleraldehyde

2367

118

0,1

AI

0,81

++++++

AC

++++++

++++++

890 1-methylvinyl acetate

2403

97

0,22

AI

0,92

++++++

AC

++++++

++++++

891 Mineral spirit, A type

1271

60

0,76

AI

0,7

++++++

++++++

++++++

892 C9-monoolefin mixture, with a f.p. of -18

2057




 

AI




0 0 0 0 0 0

++++++

++++++

2057




 

A II




0 0 0 0 0 0

++++++

++++++

894 Morpholine

2054

128

0,06

1,01

++++++

++++++

++++++

895 1-naphthylamine, liq.

2077

299




1,13

++++++

++++++

++++++

896 2-naphthylamine, liq.

1650

306




1,06

++++++

++++++

++++++

897 alpha-naphthyl isocyanate

2810

269




A II

1,18

------

---+++

BCT

---+++

BCT




 

AI




++++++

++++++

BC

++++++

BC

to below 21°C 893 C9-monoolefin mixture, with a f.p. of 21 to 55°C

898 Natural gas condensate, with a f.p. below -18°Cand a b.p. over 35°C

114

ACS

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

2

899 Natural gas condensate, with a f.p. below

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

3

4

5

6

7

8

9

10

11

12

 




AI




++++++

ACS

++++++

BC

++++++

BC

 




AI




++++++

ACS

++++++

BC

++++++

BC




 

AI




++++++

ACS

++++++

BC

++++++

BC

 




AI




++++++

ACS

++++++

BC

++++++

BC

-18°C and a b.p. over 50°C 900 Natural gasolene, with a f.p. below -18°C and a b.p.of 35°C max. and a p(50) of 3 bar max. 901 Natural gasolene, with a f.p. below -18°C and a b.p. over 35°C 902 Natural gasolene, with a f.p. below -18°C and a b.p. over 50°C 903 Nicotine sulfate, aq. soln., 40% max.

1658









0 0 0 0 0 0

++++++

++++++

904 Nitrating acid, mixtures, ctg. over 30% up

1796




 




0 0 0 0 0 0

++++++

++++++

to 40% of nitric acid and up to 70% of sulfuric acid

115

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1 905 Nitrating acid, mixtures, ctg. over 30 up

5

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

6

7

8

9

10

11

2

3

4

1796




 




------

--+--+

H2

++++++

1796




 


 

------

--+--+

H2

++++++

1796




 




0 0 0 0 0 0

++++++

++++++

1796




 




------

------

--+--+

1796




 


 

------

--+--+

12

to 50% of nitric acid and sulfuric acid 906 Nitrating acid, mixtures, ctg. over 30 up to 50% of nitric acid, over 15% of sulfuric acid and 5% max. of water 907 Nitrating acid, mixtures, ctg. over 40% up to 50% of nitric acid and 30% max. of sulfuric acid 908 Nitrating acid, mixtures, ctg. over 5 up to 8% of nitric acid and sulfuric acid 909 Nitrating acid, mixtures, ctg. over 50 up to 60% of nitric acid, 25% min. of sulfuric acid, and 15% max. of water

116

H2

++++++

H2

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1 910 Nitrating acid, mixtures, ctg. over 50 up

5

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

6

7

8

9

10

11

H2

++++++

2

3

4

1796




 


 

------

--+--+

1796




 


 

0 0 0 0 0 0

++++++

1796




 


 

------

--+--+

H2

++++++

1796




 




------

--+--+

H2

++++++

1796




 




0 0 0 0 0 0

++++++

Qualifying

12

to 80% nitric acid, 15% max. of sulfuric acid, and 5% max. of water 911 Nitrating acid, mixtures, ctg. over 50 up

++++++

to 80% of nitric acid and 30% max. of sulfuric acid 912 Nitrating acid, mixtures, ctg. over 50 up to 90% nitric acid and sulfuric acid 913 Nitrating acid, mixtures, ctg. over 8 up to 30% of nitric acid and sulfuric acid 914 Nitrating acid, mixtures, ctg. over 8 up to

++++++

30% of nitric acid and 80% max. of sulfuric acid

117

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1 915 Nitrating acid, mixtures, ctg. over 90 up

5

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

6

7

8

9

10

11

H2

++++++

2

3

4

1796




 




------

--+--+

1796




 




------

------

--+--+

1796




 




------

0 0 0 0 0 0

0 0 0 0 0 0

1796




 

1,76

------

0 0 0 0 0 0

0 0 0 0 0 0

12

to 95% nitric acid and 5% min of sulfuric acid 916 Nitrating acid, mixtures, ctg. over 95 up to 97% of nitric acid and 3% min. of sulfuric acid 917 Nitrating acid, mixtures, ctg. 10% max. of nitric acid, 65% min. of sulfuric acid and 25% max. of water 918 Nitrating acid, mixtures, ctg. 30% max. of nitric acid, 50% min. of sulfuric acid and 20% max. of water

118

H2

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

6

7

8

9

10

2

3

4

1796




 


 

------

0 0 0 0 0 0

920 Nitric acid with 65% max. of pure acid

2031







 

------

++++++

E

0 0 0 0 0 0

921 Nitroanilines, isomer mixture, liq.

1661

 







++++++

AH6

++++++

BH6

++++++

922 Nitrobenzene

1662

211




1,2

++++++

A

++++++

923 Nitrophenol, isomer mixture, melted

1663

 







++++++

AH6K4

++++++

924 Nitropropane, isomer mixture

2608

 




A II




++++++

A

++++++

++++++

925 1-nitropropane

2608

131

0,06

A II

1

++++++

A

++++++

++++++

926 2-nitropropane

2608

120

0,16

A II

0,99

++++++

A

++++++

++++++

927 Nitrotoluene, isomer mixture, liq.

1664






A III




++++++

C

++++++

++++++

928 2-nitrotoluene, liq.

1664

222




A III

1,16

++++++

C

++++++

++++++

929 3-nitrotoluene, liq.

1664

232




1,16

++++++

C

++++++

++++++

930 Nitroxylene, isomer mixture, liq.

1665

 







++++++

C

++++++

++++++

919 Nitrating acid, mixtures, ctg. over 30% up

5

Group of tank

11

12

0 0 0 0 0 0

to 50% of nitric acid, 25% min. of sulfuric acid and 15% max. of water

A III

A III

BH6

++++++ BH8K4

++++++

BH8K4

119

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

5

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

6

7

8

9

10

1,13

++++++

C

++++++

++++++

1,11

++++++

C

++++++

++++++

2

3

4

931 Nitro-4-xylene, liq.

1665

241




932 2-nitro-3-xylene, liq.

1665

225




933 3-nitro-2-xylene, liq.

1665

245




1,14

++++++

C

++++++

++++++

934 4-nitro-2-xylene, liq.

1665

244




1,14

++++++

C

++++++

++++++

935 4-nitro-3-xylene, liq.

1665

244




1,13

++++++

C

++++++

++++++

936 n-Nonane

1920

151

0,03

A II

0,72

++++++

A

++++++

++++++

937 Nonane, isomer mixture, with a f.p. of 21

1920






A II




++++++

A

++++++

++++++

1993

 




AI


 

++++++

A

++++++

++++++

939 1,7-octadiene

2309

= 116




AI


 

++++++

A

++++++

++++++

940 Octane, isomer mixture, with a f.p. of -12

1262

= 99


 

AI




++++++

A

++++++

++++++

1262

126

0,08

A

0,7

++++++

A

++++++

++++++

A III

11

to 31°C 938 Nonane, isomer mixture, with a f.p. below 21°C

to 12°C 941 n-octane

120

Qualifying

12

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

2

942 1-octanol

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

3

4

5

6

7

8

9

10

11

12

195




A III

0,83

++++++

BC

++++++

B

++++++

B

943 3-octanone

2271

162

0,06

A II

0,82

++++++

AC

++++++

++++++

944 iso-octene

1216

102




AI

0,72

---+++

N

++++++

++++++

945 C12-olefin mixture , with a f.p. of 21 to

2850

= 100


 

A II




0 0 0 0 0 0

++++++

++++++

2850

= 100


 

A III




0 0 0 0 0 0

++++++

++++++

3017

 




A II


 

------

--+--+

HU

--+--+

HU

3018




 

A III


 

------

--+--+

HU

--+--+

HU

55°C 946 C12-olefin mixture , with a f.p. over 55 to 61°C 947 Parathion-methyl, ctg. more than 12% of active substance, in solvents, n.i.l., with a f.p. of 21 to 61°C and a b.p. over 50°C 948 Parathion-methyl with more than 12% of active substance, in solvents, n.i.l., with a f.p. over 61°C and a b.p. over 100°C

121

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

8

9

10

11

12

2

3

4

5

6

7

3017

 




A II


 

------

--+--+

HU

--+--+

HU

3018




 

A III


 

------

--+--+

HU

--+--+

HU

951 Parathion-methyl, pure, liq.

3017

200




A II

1,23

------

--+--+

H

--+--+

H

952 Pentachloroethane

1669

161

0,03

1,68

---+++

ACN

------

953 Pentamethyleneimine

2401

106

0,14

B

0,86

++++++

BG

++++++

954 Pentanal

2058




 

AI




++++++

C

++++++

955 n-pentane

1265

36

1,6

AI

0,63

++++++

A

++++++

A

++++++

A

956 Pentanedial, aq. soln., with a f.p. over 61°C

2810









------

++++++

C

++++++

C

957 2,4-pentanedione

2310

140

0,07

0,98

------

---+++

AN

---+++

AN

949 Parathion-methyl, with 1,2% to 12% of active substance, in solvents, n.i.l., with a f.p. up to 61°C and a b.p. over 50°C 950 Parathion-methyl, with 1,2% to 12% of active substance, in solvents, n.i.l., with a f.p. over 61°C and a b.p. over 100°C

122

A II

-----B

++++++

D

++++++

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

10

2

3

4

5

6

7

8

9

11

12

958 Pentanethiol, active form

1111

118

0,13

AI

0,85

0 0 +0 0 +

AH3

++++++

++++++

959 Pentanethiol, isomer mixture

1111






AI




0 0 +0 0 +

AH3

++++++

++++++

960 sec-pentanethiol

1111

113

0,13

AI

0,83

0 0 +0 0 +

AH3

++++++

++++++

961 1-pentanethiol

1111

127

0,08

AI

0,86

0 0 +0 0 +

AH3

++++++

++++++

962 2-pentanethiol

1111

113

0,13

AI

0,83

0 0 +0 0 +

AH3

++++++

++++++

963 3-pentanethiol

1111

105

0,21

AI

0,84

0 0 +0 0 +

AH3

++++++

++++++

964 1-pentanol

1105

138

0,03

A II

0,82

++++++

ABC

++++++

B

++++++

B

965 2-pentanol

1105

119

0,05

A II

0,81

++++++

ABC

++++++

B

++++++

B

966 3-pentanol

1105

116

0,07

A II

0,82

++++++

ABC

++++++

B

++++++

B

967 2-pentanone, pure

1249

102

0,1

AI

0,82

++++++

++++++

++++++

968 2-pentanone/3-pentanone mix (3:1)

1249






AI




++++++

++++++

++++++

969 1-pentene

1108

30

ß950

AI

0,65

---+++

N

++++++

++++++

970 Pentyl acetate, technical grade, with a

1104

105

0,16

AI

0,88

++++++

AC

++++++

C1

f.p. of -18 to below 21°C

123

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

2

3

4

5

6

7

8

9

10

11

1104

121

0,04

A II

0,88

++++++

AC

++++++

C1

++++++

972 Pentyl alcohol, optically act.

1105

128

0,05

A II

0,82

++++++

ABC

++++++

B

++++++

B

973 Pentyl alcohol, primary, mixture of

1105




 

A II




++++++

ABC

++++++

B

++++++

B

1105




 

AI




------

++++++

B

++++++

B

1105




 

A II




------

++++++

B

++++++

B

1106




 

B




++++++

G

++++++

B

++++++

D

1106




 

B




++++++

G

++++++

B

++++++

D

1106

104

0,15

B

0,76

++++++

G

++++++

B

++++++

971 Pentyl acetate, technical grade, with a

12

f.p. of 21 to 55°C

pentan-1-ol and 2-methyl-butan-1-ol 974 Pentyl alcohol, synthetic isomer mixture, with a f.p. of 0 to below 21°C 975 Pentyl alcohol, synthetic isomer mixture, with a f.p. of 21 to 55°C 976 Pentylamine, isomer mixture, with a f.p. of -18 to below 21°C 977 Pentylamine, isomer mixture, with a f.p. of 21 to 55°C 978 1-pentylamine

124

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

2

3

4

5

6

7

8

9

10

11

12

979 2-pentylamine

1106

92

0,28

B

0,74

++++++

G

++++++

B

++++++

D

980 3-pentylamine

1106

91

0,28

B

0,75

++++++

G

++++++

B

++++++

D

981 Di-n-pentylamine

2841

202




A II

0,78

++++++

G

++++++

B

++++++

D

982 n-pentyl butyrate

2620

165




A II

0,88

++++++

AC

++++++

++++++

983 Pentyl chloride, active form

1107




 

AI




--+--+

ACH2

------

------

984 Pentyl chloride, isomer mixture

1107




 

AI




--+--+

ACH2

------

------

985 Di-n-pentyl ether

1993

188




A II

0,79

0 0 0 0 0 0

++++++

++++++

986 Pentyl formate

1109

130

0,08

A II

0,89

++++++

AC

++++++

++++++

987 Pentyl nitrate, isomer mixture

1112









++++++

C

++++++

++++++

988 n-pentyl nitrite, pure

1113




 

AI




0 0 0 0 0 0

989 n-pentyl propionate

1993

169

0,03

A II

0,88

++++++

990 Perfume products, with flammable

1266




 

AI


 

0 0 0 0 0 0

++++++ AC

A

++++++ ++++++

++++++

A

++++++ U

++++++

U

solvents, n.i.l., with a f.p. of -18 to below 0°C and a b.p. over 35°C

125

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1 991 Perfume products, with flammable

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

8

9

10

11

12

2

3

4

5

6

7

1266

 




AI


 

0 0 0 0 0 0

++++++

U

++++++

U

solvents, n.i.l., with a f.p. of -18°C to

1,100

below 0°C and a b.p. over 50°C 992 Perfume products, with flammable

1266

 




AI


 

0 0 0 0 0 0

++++++

U

++++++

U

1266

 




A II


 

0 0 0 0 0 0

++++++

U

++++++

U

1266





 

A III


 

0 0 0 0 0 0

++++++

U

++++++

U

solvents, n.i.l., with a f.p. of 0 to below 21°C and a b.p. over 50°C 993 Perfume products, with flammable solvents, n.i.l., with a f.p. of 21 to 55°C and a b.p. over 50°C 994 Perfume products, with flammable solvents, n.i.l., with a f.p. over 55°C up to 61°C and a b.p. over 100°C

126

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

2

995 Perfume products, with flammable

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

8

9

10

11

12

U

++++++

U

3

4

5

6

7




 

A III


 

0 0 0 0 0 0

++++++

solvents, n.i.l., with a f.p. over 61°C up to 100°C and a b.p. over 100°C 996 Petrol, premium, S type, leaded

1203

40




AI

0,78

++++++

++++++

++++++

997 Petrol, premium, S type, unleaded

1203

40




AI

0,79

++++++

++++++

++++++

998 Petrol, premium plus, SP type, unleaded

1203

40




AI

0,79

++++++

++++++

++++++

999 Petrol, regular, N type, unleaded

1203

40




AI

0,77

++++++

++++++

++++++

1000 Petroleum distillate, u.o.n., with a f.p. of

1268

 




AI




++++++

CS

++++++

++++++

1268



0,2

A II




++++++

CS

++++++

++++++

1268




 

A III




++++++

CS

++++++

++++++

-18 to below 21°C and a b.p. over 50°C 1001 Petroleum distillate, u.o.n., with a f.p. of 21 to 55°C and a b.p. over 100°C 1002 Petroleum distillate, u.o.n., with a f.p. over 55°C up to 61°C and a b.p. over 100°C

127

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

2

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

10

3

4

5

6

7

8

9




 

A III




++++++

CS

++++++

++++++

1268

 




AI




++++++

CS

++++++

++++++

1268




 

AI




++++++

CS

++++++

++++++

1268

 




AI




++++++

CS

++++++

++++++




 




++++++

CS

++++++

++++++




 

AI


 

++++++

A

++++++

++++++

 




AI


 

++++++

A

++++++

++++++

1003 Petroleum distillate, u.o.n., with a f.p.

11

over 61°C up to 100°C and a b.p. over 100°C 1004 Petroleum distillate, u.o.n., with a f.p. below -18°C and a b.p. of 20 to 35°C 1005 Petroleum distillate, u.o.n., with a f.p. below -18°C and a b.p. over 35°C 1006 Petroleum distillate, u.o.n., with a f.p. below -18°C and a b.p. over 50°C 1007 Petroleum distillate, u.o.n., with a f.p. over 100°C, not toxic and not corrosive 1008 Petroleum ether, with a f.p. of -18 to below 21°C and a b.p. over 35°C 1009 Petroleum ether, with a f.p. of -18 to below 21°C and a b.p. over 50°C

128

12

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

2

1010 Petroleum ether, with a f.p. below -18°C,

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F

conditions

10

11

12

3

4

5

6

7

8

9

 




AI




++++++

A

++++++

++++++




 

AI




++++++

A

++++++

++++++

 




AI




++++++

A

++++++

++++++






AI




++++++

++++++

++++++




0 0 0 0 0 0

++++++

++++++

1,05

0 0 0 0 0 0

++++++

++++++

++++++

++++++

a b.p. of 35°C max. and a p(50) of 3 bar max. 1011 Petroleum ether, with a f.p. below -18°C and a b.p. over 35°C 1012 Petroleum ether, with a f.p. below -18°C and a b.p. over 50°C 1013 Petroleum ether, A type 1014 m-phenetidine

2311

 




1015 o-phenetidine

2311

233




1016 p-phenetidine

2311

250




1,07

0 0 0 0 0 0

1017 Phenol, aq. soln., not alkaline

2821









++++++

H5

++++++

H5

++++++

H5

1018 Phenol, aq. alkaline soln. with a density of

2922









++++++

H5

++++++

H5

++++++

H5

A III

1,3 kg/l max.

129

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Qualifying Group of tank

Qualifying

Group of tank

Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

6

7

8

9

10

11

12


 

++++++

H5

++++++

H5

++++++

H5

---+++

BCT

---+++

BCT

--+--+

M

--+--+

M

2

3

4

2922






1020 Phenyl isocyanate

2487

165

0,02

A II

1,1

0 0 0 0 0 0

1021 2-phenylpropene, stabilized

2303

165

0,03

A II

0,91

--+--+

1022 Phosphoric acid, aq. soln., ctg. less than

1805









------

------

++++++

BF

1805







 

------

------

++++++

BF

1805




 


 

------

------

++++++

BF

1805

 







------

------

++++++

BF

1805









------

------

++++++

BF

1019 Phenol, aq. alkaline soln. with a density of

5

Group of tank

1,5 kg/l max.

CM

25% of pure acid 1023 Phosphoric acid, aq. soln., ctg. 25% to 75% of pure acid 1024 Phosphoric acid, aq. soln., ctg. 75% of pure acid 1025 Phosphoric acid, aq. soln., ctg. 80% of pure acid 1026 Phosphoric acid, aq. soln., ctg. 85% of pure acid

130

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Qualifying Group of tank

Qualifying

Group of tank

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

6

7

8

9

10

1,88

------

2

3

4

1805

213

0,03

1028 Pinacolone

1224

106

0,11

AI

0,81

1029 2-pinene

2368

155

0,03

A II

1030 Piperazine, 65% aq. soln., melted

2579

 




1031 Piperidine

2401

106

0,14

1032 Potassium chlorate, aq. soln., with a

2427



1033 Potassium cyanide, aq. soln.

1680

1034 Potassium fluoride, aq. soln. 1035 Potassium hydroxide, aq. soln., with a

1027 Phosphoric acid, aq. soln., ctg. more than

5

Group of tank

Qualifying

11

12

------

++++++

BF

------

++++++

++++++

0,86

0 0 0 0 0 0

++++++

++++++




++++++

GH5K4

++++++

BH5K4

++++++

DH5K4

0,86

++++++

BG

++++++

B

++++++

D





 

------

--+--+

BCH

++++++

BC









------

++++++

++++++

1812







 

0 0 0 0 0 0

++++++

++++++

1814







 

++++++

++++++

++++++

1814






1,5

0 0 0 0 0 0

++++++

++++++

85% of pure acid

B

conc. of 30% max. of potassium chlorate

conc. of 20% max. 1036 Potassium hydroxide, aq. soln., with a

H5

conc. of 50% max.

131

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

8

9

10

2

3

4

5

6

7

1037 1-propanethiol

2402

68

0,56

AI

0,85

------

++++++

++++++

1038 2-propanethiol

2402

53

0,94

AI

0,83

------

++++++

++++++

1039 1-propanol

1274

97

0,13

B

0,8

++++++

C

++++++

++++++

1040 2-propanol

1219

82

0,24

B

0,79

++++++

C

++++++

++++++

1041 2-propen-1-ol, with a f.p. of 21 to below 23°C

1098

97

0,15

A II

0,85

++++++

EC

++++++

++++++

1042 2-propen-1-ol, with a f.p. of 23°C min.

1098

97

0,15

A II

0,85

++++++

EC

++++++

++++++

1043 2-propenylamine

2334

53

0,93

B

0,76

--+--+

GH

--+--+

1044 Propenylidene dichloride

1993

76

0,43

AI

1,17

++++++

AC

------

1045 Propionaldehyde

1275

49

1,11

AI

0,81

------

---+++

1046 Propionic acid, pure, 

1848

141

0,03

A II

1

------

------









------

--+--+

1047 Propionic acid, aq. soln., ctg. less than 50% of pure acid

132

BH

11

--+--+

Qualifying

12

BH

-----CN

H2

---+++

CN

0 0 +0 0 +

H3

++++++

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

2

Qualifying Group of tank

Qualifying

Group of tank

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

6

7

8

9

10

3

4









------

1848









1848






1051 Propionic anhydride

2496

167




1052 Propionitrile

2404

97

1053 n-propyl acetate

1276

1054 n-propylamine

Qualifying

11

12

------

--+--+

H

------

------

0 0 +0 0 +

H3




------

------

0 0 +0 0 +

H3

A III

1,02

0 0 0 0 0 0

0 0 0 0 0 0

++++++

B

0,21

B

0,79

0 0 0 0 0 0

++++++

++++++

102

0,16

AI

0,89

++++++

AC

++++++

++++++

1277

48

1,11

B

0,72

++++++

BG

++++++

++++++

1055 n-propylbenzene

2364

159

0,03

A II

0,86

++++++

A

++++++

++++++

1056 Propylene tetramer, with a f.p. of min. 21

2850




 

A II




0 0 0 0 0 0

++++++

++++++

1048 Propionic acid, aq. soln., ctg. 50% to

5

Group of tank

below 80% of pure acid 1049 Propionic acid, aq. soln., ctg. 80% min. of pure acid, with a f.p. of 61°C max. 1050 Propionic acid, aq. soln., ctg. 80% min. of pure acid, with a f.p. over 61°C

up to 55°C

133

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

8

9

10

2

3

4

5

6

7

2850




 

A III

= 1,00

0 0 0 0 0 0

++++++

++++++

2057




 

AI




0 0 0 0 0 0

++++++

++++++

1059 Propylene trimer, with a f.p. of 21 to 55°C

2057




 

A II




0 0 0 0 0 0

++++++

++++++

1060 n-propylethanolamine

1760

180

0,04

0,9

++++++

++++++

++++++

1061 Di-n-propyl ether, with a f.p. of -18 to

2384

90

0,27

AI

0,75

++++++

A

++++++

++++++

2384

90

0,27

AI

0,75

++++++

A

++++++

++++++

1063 n-propyl formate

1281

81

0,35

AI

0,91

++++++

AC

++++++

++++++

1064 Pyridine, pure

1282

114

0,11

B

0,99

++++++

A7

++++++

++++++

1057 Propylene tetramer, with a f.p. of min. 55

11

up to 61°C 1058 Propylene trimer, with a f.p. of -18 to below 21°C

below 21°C 1062 Di-n-propyl ether, with a f.p. below -18°C

134

12

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

8

9

10

2

3

4

5

6

7

1282

115

0,11

B

0,99

0 0 0 0 0 0

++++++

1066 Pyrrolidine

1922

87

0,37

B

0,86

0 0 0 0 0 0

++++++

1067 Quinoline, with a f.p. of 61°C max.

2656

237




A III

1,1

------

++++++

++++++

1068 Quinoline, with a f.p. over 61°C

2656

237




A III

1,1

------

++++++

++++++

1069 Resins, in hydrocarbons or alcohols, n.i.l.,

1866




 

AI


 

0 0 0 0 0 0

++++++

U

++++++

U

1866

 




AI


 

0 0 0 0 0 0

++++++

U

++++++

U

1866

 




A II


 

0 0 0 0 0 0

++++++

U

++++++

U

1065 Pyridine, technical grade, with admixture

11

Qualifying

12

++++++

of methylpyridines E

0 0 0 0 0 0

with a f.p. of -18 to below 0°C and a b.p. over 35°C 1070 Resins, in hydrocarbons or alcohols, n.i.l., with a f.p. of 0 to below 21°C and a b.p. over 50°C 1071 Resins, in hydrocarbons or alcohols, n.i.l,. with a f.p. of 21 to 55°C and a b.p. over 50°C

135

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1 1072 Resins, in hydrocarbons or alcohols, n.i.l.,

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

8

9

10

11

12

2

3

4

5

6

7

1866




 

A III


 

0 0 0 0 0 0

++++++

U

++++++

U




 

A III


 

0 0 0 0 0 0

++++++

U

++++++

U

1999

 




AI


 

++++++

++++++

++++++

1999




 

A II


 

++++++

++++++

++++++

1999

 




A III


 

++++++

++++++

++++++

 




A III


 

++++++

++++++

++++++

with a f.p. over 55 up to 61°C and a b.p. over 100°C 1073 Resins, in hydrocarbons or alcohols, n.i.l., with a f.p. over 61 up to 100°C and a b.p. over 100°C 1074 Road asphalt, liq., with a f.p. of -18 to below 21°C and a b.p. over 50°C 1075 Road asphalt, liq., with a f.p. of 21 to 55°C and a b.p. over 100°C 1076 Road asphalt, liq., with a f.p. over 55 up to 61°C and a b.p. over 150°C 1077 Road asphalt, liq., with a f.p. over 61 up to 100°C and a b.p. over 150°C

136

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

2

1079 Road asphalt, viscous, with a f.p. of

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

6

7

8

9

10


 

++++++

++++++

++++++

++++++

++++++

3

4

 




1999

 




AI


 

++++++

1999

 




AI




++++++

ABC

++++++

B

++++++

B

1999




 

A II




++++++

ABC

++++++

B

++++++

B

1999

 




A III




++++++

ABC

++++++

B

++++++

B

 




A III




++++++

ABC

++++++

B

++++++

B

 







++++++

ABC

++++++

B

++++++

B

 







++++++

ABC

++++++

B

++++++

B

1078 Road asphalt, liq., with a f.p. over 100°C

5

Group of tank

11

12

-18°C to below 21°C and a b.p over 50°C 1080 Road tar, liq., with a f.p. of -18 to below 21°C and a b.p. over 50°C 1081 Road tar, liq., with a f.p. of 21 to 55°C and a b.p. over 100°C 1082 Road tar, liq., with a f.p. over 55 up to 61°C and ab.p. over 150°C 1083 Road tar, liq., with a f.p over 61 up to 100°C and a b.p. over 150°C 1084 Road tar, liq., with a f.p. over 100°C 1085 Road tar, viscous, with a f.p. of -18 to

1999

AI

below 21°Cand a b.p. over 50°C

137

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1 1086 Shale oil, with a f.p. of -18 to below 0°C

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

8

9

10

2

3

4

5

6

7

11

1288




 

AI




0 0 0 0 0 0

++++++

++++++

1288

 




AI




0 0 0 0 0 0

++++++

++++++

1288

 




AI




0 0 0 0 0 0

++++++

++++++

1288




 

A II




0 0 0 0 0 0

++++++

++++++

1288




 

A III




0 0 0 0 0 0

++++++

++++++




 

A III




0 0 0 0 0 0

++++++

++++++

AI

0,65

++++++

++++++

++++++




++++++

++++++

++++++

and a b.p. over 35°C 1087 Shale oil, with a f.p. of -18 to below 0°C and a b.p. over 50°C 1088 Shale oil, with a f.p. 0 to below 21°C and a b.p. over 50°C 1089 Shale oil, with a f.p. of 21 to 55°C and a b.p. over 100°C 1090 Shale oil, with a f.p. over 55 up to 61°C and a b.p. over 100°C 1091 Shale oil, with a f.p. over 61 to 100°C and a b.p. over 100°C 1092 Silicon tetramethyl

2749

26

2,21

1093 Sodium-meta-aluminate, aq. soln.

1819






138

A

12

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

6

7

8

9

10

2

3

4

1686









++++++

++++++

++++++

1686









++++++

++++++

++++++









------

------

++++++

C2

1908









------

------

++++++

C2

1689







 

------

0 0 +0 0 +

0 0 +0 0 +

H3

1099 Sodium fluoride, aq. soln.

1690









0 0 0 0 0 0

------

--+--+

CH1

1100 Sodium hydrogen sulfide, aq. soln., ctg.

1719







 

++++++

++++++

++++++

1824









++++++

++++++

++++++

1094 Sodium arsenite, aq. soln., injurious to

5

Group of tank

11

12

health 1095 Sodium arsenite, aq. soln., toxic 1096 Sodium chlorite, aq. soln., ctg. not more than 5% of active chlorine 1097 Sodium chlorite, aq. soln., ctg. more than 5% of active chlorine 1098 Sodium cyanide, aq. soln. with a density

H3

of 1,2 kg/l max.

30% of NaHS 1101 Sodium hydroxide, aq. soln., ctg. 5% max. of NaOH

139

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

5

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

6

7

8

9

10

2

3

4

11

12

1102 Sodium hydroxide, aq. soln., ctg. 10% max. of NaOH

1824









++++++

++++++

++++++

1103 Sodium hydroxide, aq. soln., ctg. 20%

1824









++++++

++++++

++++++

1824

 







++++++

++++++

++++++

1824

 





 

++++++

++++++

++++++

1289




 

B

0,97

---+++

++++++

++++++

1289




 

B




0 0 0 0 0 0

++++++

U

++++++

U

1289




 




0 0 0 0 0 0

++++++

U

++++++

U

max. of NaOH 1104 Sodium hydroxide, aq. soln., ctg. 33% max. of NaOH 1105 Sodium hydroxide, aq. soln., ctg. 50% max. of NaOH 1106 Sodium methoxide, soln., 30%, in

N

methanol 1107 Sodium methoxide, alcoholic soln., n.i.l., with a f.p. of -18 to below 21°C 1108 Sodium methoxide, alcoholic soln., n.i.l., with a f.p. of 21 to 61°C

140

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

10

2

3

4

5

6

7

8

9

1289




 

B

0,97

---+++

N

++++++

1289




 

B




0 0 0 0 0 0

++++++

U

++++++

U

1289




 




0 0 0 0 0 0

++++++

U

++++++

U

1112 Sodium sulfide, aq. soln.

1849







 

------

------

++++++

1113 Solvent naphtha, light, C9-Ar type

1136

 




A II




++++++

AC

++++++

++++++

1114 Solvent naphtha, heavy, C10-Ar type,

1136

 




A III




++++++

AC

++++++

++++++

 




A III




++++++

AC

++++++

++++++

80

0,37

AI

0,88

++++++

ACS

++++++

++++++

1109 Sodium methylate, soln., 30%, in

11

Qualifying

12

++++++

methanol 1110 Sodium methylate, alcoholic soln., n.i.l., with a f.p. of -18 to below 21°C 1111 Sodium methylate, alcoholic soln., n.i.l., with a f.p. of 21 to 61°C

with a f.p. over 55 up to 61°C 1115 Solvent naphtha, heavy, C10-Ar type,with a f.p. over 61 up to 100°C 1116 Solvent naphtha, with a f.p. of -18 to

1256

below 0°C

141

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

10

2

3

4

5

6

7

8

9

1256

80

0,37

AI

0,88

++++++

ACS

++++++

++++++

1256

80

0,37

A II

0,88

++++++

ACS

++++++

++++++

1119 Special boiling point spirit, 1-A type

1271

60

0,76

AI

0,68

++++++

++++++

++++++

1120 Special boiling point spirit, 1-B type

1271

60

0,76

AI

0,68

++++++

++++++

++++++

1121 Special boiling point spirit, 2-A type

1271

80

0,51

AI

0,7

++++++

++++++

++++++

1122 Special boiling point spirit, 2-B type

1271

80

0,51

AI

0,7

++++++

++++++

++++++

1123 Special boiling point spirit, 3 type

1271




 

AI




++++++

++++++

++++++

1124 Styrene, monomeric, stabilized

2055

145

0,04

A II

0,91

--+--+

1125 Sulfuric acid, ctg. over 90% up to 92%

1830

300




1,83

-++-++

1830

280




1,85

-++-++

1117 Solvent naphtha, with a f.p. of 0 to below

11

12

21°C 1118 Solvent naphtha, with a f.p. of 21 to 55°C

BCM

--+--+

M

--+--+

M

------

0 ++0 ++

BT1

------

0 ++0 ++

BT1

of pure acid 1126 Sulfuric acid, ctg. over 98% of pure acid

142

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

6

7

8

9

10

1,84

-++-++

2

3

4

1830

300




1128 Tall oil

1272




 

A III




0 0 0 0 0 0

1129 Tar, in petroleum distillate, liq., with a f.p.

1999

 




AI




++++++

ABC

++++++

B

++++++

B

1999




 

A II




++++++

ABC

++++++

B

++++++

B

1999

 




A III




++++++

ABC

++++++

B

++++++

B

 




A III




++++++

ABC

++++++

B

++++++

B

1127 Sulfuric acid, ctg. 92% to 98% of pure

5

Group of tank

11

12

------

0 ++0 ++

BT1

++++++

++++++

acid

of -18 to below 21°C and a b.p. over 50°C 1130 Tar, in petroleum distillate, liq., with a f.p. of 21 to 55°C and a b.p. over 100°C 1131 Tar, in petroleum distillate, liq., with a f.p. over 55 up to 61°C and a b.p. over 150°C 1132 Tar, in petroleum distillate, liq., with a f.p. over 61 up to 100°C and a b.p. over 150°C

143

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1 1133 Tar, in petroleum distillate, viscous, with

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

2

3

4

5

6

7

8

9

10

11

12

1999

 




AI




++++++

ABC

++++++

B

++++++

B

 







++++++

ABC

++++++

B

++++++

B

2319

 




A II


 

0 0 0 0 0 0

++++++

B

++++++

B

2319






A III




0 0 0 0 0 0

++++++

B

++++++

B

0 0 0 0 0 0

++++++

B

++++++

B

AC

a f.p. of -18 to below 21°C, and a b.p. over 50°C 1134 Tar, in petroleum distillate, liq., with a f.p. over 100°C 1135 Terpenes, u.o.n., with a f.p. of 21 to 55°C and a b.p. over 50°C 1136 Terpenes, u.o.n.,with a f.p. over 55 up to 61°C and a b.p. over 100°C

1,200 

1137 Terpenes, u.o.n., with a f.p. over 61 up




A III

to 100°C and a b.p. over 100°C 1138 Tetrachloroethylene

0,120 1897

1139 n-tetradecane 1140 Tetraethyl orthosilicate

144




1292

120

0,1

254




166

0,02

1,63

--+--+

ACH

------

++++++

A III

0,76

++++++

A

++++++

++++++

A II

0,93

++++++

++++++

++++++

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425 Group of tank

Qualifying

A B C D E F

conditions

Group of tank

Qualifying conditions

A B C D E F

conditions

A B C D E F 1

2

3

4

1141 1,2,3,6-tetrahydrobenzaldehyde

2498






1142 Tetrahydrofuran, with a f.p. of -18 to

2056

64

2056

5

6

Group of tank Qualifying

7

8

9

10

11

12

B

++++++

B

A II




++++++

AC

++++++

0,63

AI

0,89

++++++

A

++++++

++++++

64

0,63

B

0,89

++++++

A

++++++

++++++

206




A III

0,97

++++++

A

++++++

++++++

++++++

++++++

below 21°C 1143 Tetrahydrofuran, with a f.p. below -18°C 1144 Tetrahydronaphthalene 1145 Tetrahydrothiophene

2412

121

0,09

AI

1

0 0 0 0 0 0

1146 2,2,3,3-tetramethylbutane

1262

107

0,12

AI

0,82

++++++

A

++++++

++++++

1147 2,2,3,3-tetramethylpentane

1993

140

0,05

AI

0,76

++++++

A

++++++

++++++

1148 2,2,3,4-tetramethylpentane

1993

133

0,06

AI

0,74

++++++

A

++++++

++++++

1149 2,3,3,4-tetramethylpentane

1993

142

0,04

AI

0,75

++++++

A

++++++

++++++

1150 Tetramethylsilane

2749

26

2,21

AI

0,65

++++++

A

++++++

++++++

1151 Tetrapropyl orthotitanate

2413

 




A II




0 0 0 0 0 0

0 0 0 0 0 0

++++++

1152 4-thiapentanal, with a f.p. over 55 up to 61°C

2785




 

A III




------

++++++

++++++

145

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

8

9

10

2

3

4

5

6

7

1153 4-thiapentanal, with a f.p. over 61°C

2785




 

A III




------

1154 Thioglycolic acid

1940

200




1,33

0 0 +0 0 +

AH3

0 0 +0 0 +

1155 Thiophene

2414

84

0,32

AI

1,06

++++++

C

++++++

++++++

1156 Thiophenol

2337

169




A II

1,08

------

++++++

++++++

1157 Tinctures, pharmaceutical, in alcoholic

1293

 




B




0 0 0 0 0 0

++++++

U

++++++

U

1293

 




B




0 0 0 0 0 0

++++++

U

++++++

U

1293

 







0 0 0 0 0 0

++++++

U

++++++

U

++++++

11

12

++++++ H3

++++++

solvents, n.i.l., with a f.p. of -18 to below 0°C and a b.p. over 50°C 1158 Tinctures, pharmaceutical, in alcoholic solvents, n.i.l., with a f.p. of 0 to below 21°C and a b.p. over 50°C 1159 Tinctures, pharmaceutical, in alcoholic solvents, n.i.l., with a f.p. of 21 to 55°C and a b.p. over 50°C

146

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1 1160 Tinctures, pharmaceutical, in alcoholic

5

Group of tank

Qualifying Group of tank

Qualifying

Group of tank

Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

6

7

8

9

10

11

12

2

3

4

1293




 




0 0 0 0 0 0

++++++

U

++++++

U




 




0 0 0 0 0 0

++++++

U

++++++

U

0,87

++++++

AC

++++++

++++++

AE

++++++

++++++

solvents, n.i.l., with a f.p. over 55 up to 61°C and a b.p. over 100°C 1161 Tinctures, pharmaceutical, in alcoholic solvents, n.i.l., with a f.p. over 61 up to 100°C and a b.p. over 100°C 1162 Toluene

1294

111




1163 2,4-tolylenediamine, liq.

1709

 







++++++

1164 2,4-tolylene diisocyanate and isomer

2078









0 0 0 0 0 0

2075

98




1,51

---+++

ET

1166 Trichloroethylene

1710

85

0,29

1,47

--+--+

1167 Trichloromethylbenzene

2226

221




1,38

0 0 -0 0 +

AI

---+++

BCT

---+++

BCT

0 0 0 0 0 0

------

EH2

ACH

0 0 0 0 0 0

++++++

AC

CEH3T

------

0 0 -0 0 +

CEH3T

mixtures, liq. 1165 Trichloroacetaldehyde, anhydrous, stabilized

147

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

8

9

10

11

12

++++++

B

++++++

B

++++++

B

++++++

2

3

4

5

6

7

1168 Triethoxymethane

2524

146

0,03

A II

0,89

------

1169 Triethylamine

1296

89

0,32

B

0,73

++++++

1170 Triethylenetetraamine

2259

260

0,02

0,98

++++++

++++++

B

++++++

D

1171 Triethyl phosphate

2810

215




1,07

0 0 0 0 0 0

++++++

BC

++++++

BC

1172 Trifluoromethylbenzene

2338

102

0,17

AI

1,2

++++++

++++++

A

++++++

A

1173 Trimethoxymethane

1993




 

B




0 0 0 0 0 0

++++++

B

++++++

B

1174 Trimethoxyvinylsilane, stabilized

1993

123

0,09

A II

1,13

0 0 0 0 0 0

-----+

MT

-----+

MT

1175 Trimethylamine, 45% aq. soln.

1297




  

B




++++++

BG

++++++

B

++++++

1176 Trimethylamine, aq. soln., with a conc.

1297

 




B




++++++

BG

++++++

B

++++++

1297




 

B




++++++

BG

++++++

B

++++++

2924

 




B




++++++

BG

++++++

B

++++++

BG

AC

over 30% up to 50% and a b.p. of 35°C max. 1177 Trimethylamine, aq. soln., with a conc. of 30% max. and a b.p. over 35°C 1178 Trimethylamine, aq. soln., with a conc. over 50% and a p(50) of 3 bar max.

148

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

10

2

3

4

5

6

7

8

9

1179 1,2,3-trimethylbenzene

1993

176




A II

0,88

++++++

A

++++++

++++++

1180 1,2,4-trimethylbenzene

1993

169

0,02

A II

0,88

++++++

A

++++++

++++++

1181 1,3,5-trimethylbenzene

2325

165

0,02

A II

0,87

++++++

A

++++++

++++++

1182 2,2,3-trimethylbutane

1206

81

0,39

AI

0,7

++++++

A

++++++

++++++

1183 2,3,3-trimethyl-1-butene

2287

78

0,42

AI

0,71

---+++

N

++++++

++++++

1184 2,5,5-trimethylheptane

1993

151

0,04

A II

0,74

++++++

A

++++++

++++++

1185 Trimethylhexamethylene diisocyanate

2328

200




1,01

0 0 0 0 0 0

1186 2,2,5-trimethylhexane

1993

124

0,08

AI

0,71

++++++

A

++++++

++++++

1187 2,3,3-trimethylhexane

1920

138

0,06

A II

0,73

++++++

A

++++++

++++++

1188 2,3,4-trimethylhexane

1920

139

0,05

A II

0,74

++++++

A

++++++

++++++

1189 3,3,4-trimethylhexane

1920

141

0,05

A II

0,74

++++++

A

++++++

++++++

1190 Trimethyl orthoformate

1993




 

B




0 0 0 0 0 0

1191 2,2,3-trimethylpentane

1262

110

0,15

AI

0,72

++++++

A

++++++

++++++

1192 2,2,4-trimethylpentane

1262

99

0,21

AI

0,69

++++++

A

++++++

++++++

---+++

++++++

BCT

B

11

---+++

++++++

12

BCT

B

149

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

10

2

3

4

5

6

7

8

9

11

1193 2,3,3-trimethylpentane

1262

115

0,13

AI

0,73

++++++

A

++++++

++++++

1194 2,3,4-trimethylpentane

1262

114

0,13

AI

0,72

++++++

A

++++++

++++++

1195 2,2,4-trimethyl-1-pentene

2050

101

0,23

AI

0,72

---+++

N

++++++

++++++

1196 2,2,4-trimethyl-2-pentene

2050

105

0,18

AI

0,72

---+++

N

++++++

++++++

1197 Trimethyl phosphite

2329

112




A II

1,05

++++++

A

++++++

++++++

1198 2,4,6-trimethyl-1,3,5-trioxane

1264

124

0,07

A II

1

++++++

C

++++++

++++++

1199 Turpentine

1299

 


 

A II




++++++

A

++++++

++++++

1200 Turpentine spirit, with a f.p. of -18 to

1300

 




AI




0 0 0 0 0 0

++++++

++++++

1300




 

A II




0 0 0 0 0 0

++++++

++++++

1300




 

A III




0 0 0 0 0 0

++++++

++++++

below 21°C and a b.p. over 50°C 1201 Turpentine spirit, with a f.p. of 21 to 55°C and a b.p. over 100°C 1202 Turpentine spirit, with a f.p. over 55 up to 61°C and a b.p. over 100°C

150

12

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

2

1203 Turpentine spirit, with a f.p. over 61 up

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

8

9

10

3

4

5

6

7




 

A III




0 0 0 0 0 0

11

++++++

++++++

12

to 100°C and a b.p. over 100°C 1204 Undecane

2330

196




A III

0,74

++++++

A

++++++

++++++

1205 Vinyl acetate, stabilized

1301

72

0,45

AI

0,93

++++++

C

++++++

++++++

1206 Vinyltrimethoxysilane, stabilized

1993

123

0,09

A II

1,13

0 0 0 0 0 0

-----+

1207 White spirit, 1 type

1300

130

0,11

A II

0,75

++++++

++++++

++++++

1208 White spirit, 2 type

1300

140

0,07

A II

0,75

++++++

++++++

++++++

1209 White spirit, 3 type

1300

150

0,07

A II

0,75

++++++

++++++

++++++

1210 White spirit, 4 type, with a f.p. over 55

1300

180

0,07

A III

0,8

++++++

++++++

++++++

180

0,07

A III

0,8

++++++

++++++

++++++

++++++

++++++

++++++

++++++

MT

-----+

MT

up to 61°C 1211 White spirit, 4 type, with a f.p. over 61 up to 100°C 1212 White spirit, 5 type

1300

130

0,11

A II

0,75

++++++

1213 Wood alcohol

1230

65

0,56

B

0,8

---+++

N

151

EN 12285-1:2003 (E)

Table B.2 (continued) No.

Liquid

UNNo.

Boiling point

Vapour pressure at 50°C

Danger Density class Material No.

°C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

10

2

3

4

5

6

7

8

9

1993




 

A II




---+++

N

++++++

++++++

1993




 

A III




---+++

N

++++++

++++++

1216 m-xylene

1307

139

0,05

A II

0,86

++++++

AC

++++++

++++++

1217 p-xylene

1307

138

0,05

A II

0,86

++++++

AC

++++++

++++++

80

0,37

AI

0,88

++++++

ACS

++++++

++++++

80

0,37

AI

0,88

++++++

ACS

++++++

++++++

80

0,37

A II

0,88

++++++

ACS

++++++

++++++




 

AI




++++++

AC

++++++

++++++

1214 Wood alcohol, aq. soln., with a b.p. of 21

11

to 55°C 1215 Wood alcohol, aq. soln., with a b.p. over 55 up to 61°C

1218 Xylene, ctg. small fractions of benzene and toluene, with a f.p. of -18 to below 0°C 1219 Xylene, ctg. small fractions of benzene and toluene, with a f.p. of 0 to below 21°C 1220 Xylene, ctg. small fractions of benzene and toluene, with a f.p. of 21 to 55°C 1221 Xylene, isomer mixture, with a f.p. of 1 to below 21°C

152

1307

12

EN 12285-1:2003 (E)

Table B.2 (concluded) No.

Liquid

UNNo.

Boiling point

Vapour pressure

Danger Density class

at 50°C Material No. °C

mbar

kg/l 1.0036, 1.0037, 1.0038,

1.4306, 1.4541

1.4571, 1.4401, 1.4404,

1.0116, 1.0144, 1.0345,

1.4435

1.0425

1

Group of tank

Qualifying Group of tank

Qualifying

Group of tank Qualifying

A B C D E F

conditions

A B C D E F

conditions

A B C D E F conditions

10

2

3

4

5

6

7

8

9

1307




 

A II




++++++

AC

++++++

++++++

1223 o-xylene, with a f.p. of 17 to below 21°C

1307

144

0,07

AI

0,88

++++++

AC

++++++

++++++

1224 o-xylene, with a f.p. of 21 to 55°C

1307

144

0,07

A II

0,88

++++++

AC

++++++

++++++

1225 Solvent xylene (C8H10 type), with a f.p.

1136




 

A II




++++++

AC

++++++

++++++

1222 Xylene, isomer mixture, with a f.p. of 21

11

12

to 55°C

of 21 to 55°C

153

EN 12285-1:2003 (E)

Appendix 1 to annex B: Example of a Form for the approval of liquid-material combination Approval of the following liquid-material-combination under the following conditions It is approved that there have been positive experiences over a min. period of 5 years for the qualification of the following liquid-material-combination considering the following conditions: 

chemical name of the liquid or data for unambigouos identification



............................................................................................................................................................................



flash point



boiling point °C



density . . . . . . . . . . . . . . . . . . . . kg/m ; storage temperatures . . . . . . . . . . . . . . . . . . .°C



material of the shell in contact with the liquid (in case of double-skin tanks: material of the inner skin)



name according to material standard



wall thickness (in case of double-skin tanks from the inner skin) . . . . . . . . . . . . . mm



installation and operation-conditions of the tank

°C

3






underground

light coating of the outside shell





above ground

insulation thickness . . . . . . . mm





in building

heating temp. . . . . . . .°C

cooling temp. . . . . . . . . . .°C



period during which the liquid has been stored in the tank



from . . . . . . . .



number of internal coatings............



testing institution ...........................

to ...................

.....................................................

...................................................

Company, place, date

Place, date

Signed by the customer to guarantee the

Signed by an expert acredited to the

above data

relevant national authority for approval of suitability

154

EN 12285-1:2003 (E)

Annex C (informative) A-devitations

A-deviation: National deviation due to regulations, the alteration of which is for the time being outside the competence of the CEN/CENELEC member. This European Standard does not fall under any Directive of the EC. In the relevant CEN/CENELEC countries these A-deviations are valid instead of the provisions of the European Standard until they have been removed. C.1

Finland

Clause

Deviation

National legislative/

Requirements for storage of flammable liquids are given in the Finishlaw 313/85 with amendments (Kauppa- ja teollisuusministeriön päätös palavista nesteistä) where the provisions of the national standard SFS 2736 (Palavien nesteiden varastointi ja käsittely. Teräksinen maanalainen lieriömäinen makaava säiliö.) are given an obligatory status.

administrative deviations

6.12 Stiffening rings

In accordance with the regulations 39 – 45 § of the Finnish law 313/85 and the standard SFS 2736 the following additional requirements are obligatory concerning stiffening rings in tanks for flammable liquids: In the event that the tank is provided with stiffenings rings, these rings shall be continuously welded. Stiffening rings shall not be located on a plate joint. The lowest point of the stiffening ring shall be provided with a flow opening.

7 Additional

In accordance with the regulations 39 – 45 § of the Finnish law 313/85 and

requirements for internal

the standard SFS 2736 the following additional requirements are

coating

obligatory concerning internal coating in tanks for flammable liquids:

A tank for storage of flammable liquids shall be provided with internal coating in accordance with the requirements of SFS 2736 clause 6.2. 7.3 Types of joints

In accordance with regulations 39 - 45 § of the Finnish law 313/85 and the standard SFS 2736 the following additional requirements are obligatory concerning types of joints in tanks for flammable liquids: Tank plates (shell and dished ends) shall be welded on both sides with square butt joints. Plate misalignment shall not exceed 0,25 s. The weld joint types 2 a, 2 b, 3a, 3b, 7b and 8 are not allowed.

C.2

Netherlands

Reference to legal requirements



Belsuit van 15 januari 1993, houdende regels met betrekking tot het opslaan van vloeistoffen in ondergrondse tanks (Besluit opslaan in ondergrondse tanks);



Belsuit van 12 maart 1996, houdende regels voor tuinbouwbedrijven met bedekte teelt (Besluit tuinbouwbedrijven met bedekte teelt milieubeheer);



Commissie Preventie van Rampen door Gevaarlijke Stoffen CPR 9-1;



Commissie Preventie van Rampen door Gevaarlijke Stoffen CPR 9-6;



Beoordelingsrichtlijn BRL-K747/01 d.d. 1996-11-01 "Horizontale cilindrische stalen tanks voor de drukloze opslag van vloeistoffen van ten hoogste 150 155

in the Netherlands

EN 12285-1:2003 (E)

m³".In addition to the requirements in clause 7.3 "Joggle joint weld construction" of this European Standard, the following will be applicable in the Netherlands:

Weld inspection



The circumferential and longitudinal welds of the tank shell and the shell to the dished ends shall be welded on both sides. The weld joint type 2a as detailed in Table 6 of EN 12285 is not acceptable for the inner skin of a double skin tank or for single skin tanks.



A new paragraph 7.4a "Additional requirements for the performance of welds" shall be added to this European Standard, as follows for the Netherlands:

Visual inspection The weld shall be inspected visually. Porosity and intermittent welds are not allowed. Undercutting is only allowed to a limited extent as indicated in Table 1. Radiographic inspection The longitudinal and circumferential welds shall be randomly inspected by means of radiographic inspection. The acceptance criteria for evaluation of the weld quality shall be as detailed in Table 1 and the number and method of sampling used shall be as detailed in Table II. The personnel responsible for the radiographic inspection shall be qualified to at least level 1 for making the photographs and to level 2 for the interpretation of the photographs.

156

EN 12285-1:2003 (E)

Table C.1 — Acceptation levels for welded butt joints Description

Sketch

Acceptance level

Cracks

---

not permitted

Crater cracks

permitted provided l ≤ 2 mm

Lack of fusion not breaking the surface (see note 1)

permitted provided l ≤ 10 mm

Lack of root penetration (see note 1)

permitted provided l ≤ 10 mm

Gas and Slag inclusions (see note 1)

permitted provided l ≤ 10 mm and w < 1,5 mm

Through thickness (e. g. wormhole, etc.)

permitted provided: Individual pores: ≤ 5 mm0/

porosity

Localized ≤ 4 % by area (see note 2)

Undercut

permitted provided:

h < 0,5 mm is always acceptable; 0,5 ≤ h ≤ 1,0 mm maximum if l ≤ 10 % of length of weld Symobls:

h = height of imperfection

l = length of imperfection

w = width of imperfection

NOTE 1 Short imperfections are one or more imperfections of total length not greater than 25 mm in any 100 mm length of weld or a maximum of 25 % of the weld length for a weld shorter than 100 mm. Long imperfections are one or more imperfections of total length greater than 25 mm in any 100 mm length of the weld or a minimum of 25 % of the weld length for a weld shorter than 100 mm. Long imperfections constituting lack of fusion, lack of root penetration and/or slag inclusions are not acceptable. NOTE 2

The area to be considered should be the length of weld affected by porosity times the maximum width of the weld.

157

EN 12285-1:2003 (E)

Table C.2 — Sampling ispection of welds for Steel storage tanks Start at level 10 Level

Minimum photo frequency

1

2 photos per 27 tanks

2

2 photos per 24 tanks

3

2 photos per 21 tanks

4

2 photos per 18 tanks

5

2 photos per 15 tanks

6

2 photos per 13 tanks

7

2 photos per 11 tanks

8

2 photos per 10 tanks

9

2 photos per 9 tanks

10

2 photos per 8 tanks

The two photos are to be made of the weld T-crossings from a randomly selected tank. One photo whereby the longitudinal weld at the T-crossing has been photographed and one photo whereby the circumferential weld as the T-crossing has been photographed. Manufacturers producing less than 2 tanks per week should radiograph all tanks. Due to the low production rate the use of sampling inspection is not allowed. For determining the production rate, the number of tanks produced during the last two months will be used. New certificate holders must photograph every tank during the starting up phase. The photo frequency level may be changed depending on the number of rejected photographs as follows: 0 rejected photos

1 level lower

1 or 2 rejected photos

same level

3 or 4 rejected photos

1 level higher

5 rejected photos or more

100 % inspection (see note)

The change in frequency may only be affected after 8 tanks have been photographed. NOTE When the number of defects is high, all the tanks should be photographed. In this case, in addition to the two photos of the T-crossings, two extra photographs need to be taken - one of the longitudinal weld and one of the circumferential weld. When the cause of the poor weld quality has been ascertained - determined by 0 rejected photos after 8 tanks have been photographed - the frequency can be set at level 10.

Rejected photos: All defects found are to be repaired. When carrying out repairs, the adjoining area also has to be photographed. In the event that in these areas faults are found, the 100 % of that particular weld needs to be photographed. Photographs of repairs are not to be counted in determining the weld frequency level.

158

EN 12285-1:2003 (E)

Bibliography

EN 10028–2, Flat products made of steels for pressure purposes — Part 2: Non-alloy and alloy steels with specified elevated temperature properties. EN 10055, Hot rolled steel equal flange tees with radiused root and toes — Dimensions and tolerances on shape and dimensions. EN 10088–1, Stainless steels — Part 1: List of stainless steels.

159